超滤法在含乳化油废水处理中的应用研究
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摘要
随着含油废水量的增加,油类物质的去除成为了水处理领域的热点课题。与传统生物处理法相比,超滤法以其高效率、低污染、操作简单等优点,被人们广泛用于废水的处理中。近些年,其应用范围也逐渐扩大,不仅用于处理生活污水,更帮助人们解决了油类物质难去除的问题。本文通过对含油废水中油类成分的分析,相关去除机理的研究,对比了不同类型膜材料对油类物质的去除效率,总结了超滤法在处理含乳化油废水中的优点及不足,并对目前超滤法在含油废水中的应用进展分析,提出了展望和建议。
With the increase of oily waste water,the removal of oil has become a hot topic in the field of water treatment.Compared with traditional biological treatment,ultrafiltration is widely used in waste water treatment because of its advantages of high efficiency,low pollution and simple operation.In recent years,its application scope has gradually expanded,not only for the treatment of domestic sewage,but also to help people solve the problem of difficult removal of oil substances.In this paper,through the analysis of oil components in the oily wastewater and the related removal mechanism,the removal efficiency of different types of membrane materials to oil materials was compared.The advantages and disadvantages of ultrafiltration in treating emulsified oil wastewater were summarized.The application of ultrafiltration in oily wastewater is analyzed,and prospects and suggestions are put forward.
With the increase of oily waste water,the removal of oil has become a hot topic in the field of water treatment.Compared with traditional biological treatment,ultrafiltration is widely used in waste water treatment because of its advantages of high efficiency,low pollution and simple operation.In recent years,its application scope has gradually expanded,not only for the treatment of domestic sewage,but also to help people solve the problem of difficult removal of oil substances.In this paper,through the analysis of oil components in the oily wastewater and the related removal mechanism,the removal efficiency of different types of membrane materials to oil materials was compared.The advantages and disadvantages of ultrafiltration in treating emulsified oil wastewater were summarized.The application of ultrafiltration in oily wastewater is analyzed,and prospects and suggestions are put forward.
引文
[1]吴爱兵,孔繁钰,胡海修,等.膜技术在含油废水处理中的应用及研究现状[J].重庆石油高等专科学校学报,2003(04):35-37.
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[15]王明花,王利,方少明,等.两亲聚合物改性PVDF膜处理含油废水的研究[J].膜科学与技术,2015,35(03):76-80+125.
[16]孙鸿,宋华,芦艳.Al2O3/TiO2/PVDF杂化超滤膜的制备及其性能研究[J].功能材料,2012,43(18):2558-2563.
[17]Yuliwati E,Ismail A F,MatsuuraT,et al.Effect of modified PVDF hollow fiber submerged ultrafiltration membrane for refinery waste-water treatment[J].Desalination,2011,283:214-220.
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[19]Harjot Kaur,Vijaya Kumar Bulasara,Raj Kumar Gupta,et al.Influence of pH and temperature of dip-coating solution on the properties of cellulose acetate-ceramic composite membrane for ultrafiltration[J].Carbohydrate Polymers,2018,195.
[20]Zhang,Xiaojing,Zhao,Yuxin,Mu,Shanjun,et al.UiO-66-Coated Mesh Membrane with Underwater Superoleophobicity for High-Efficiency Oil-Water Separation[J].ACS Applied Materials&Interfaces,2018,(10):17301-17308.
[2]宋万召,杨云军.含油废水的膜分离技术研究[J].北方环境,2011(10):45-47.
[3]周洵平,周兴海,张晓美.陶瓷膜处理含油乳化废水的技术研究[J].环境与发展,2014(03):46-48.
[4]康丽曼,张申,殷现国.膜技术在含油污水处理中的应用[J].中国城市经济,2010(11):137-138.
[5]马立艳.超滤法处理含油废水技术研究[D].西安:长安大学,2004.
[6]韩月梅.含油废水的膜精细微滤技术研究[D].青岛:中国石油大学,2010.
[7]杨轶珣,蒋翼,王媛媛,等.含油废水处理技术的研究进展[J].化学工业与工程技术,2007(05):29-32.
[8]蔺爱国,刘培勇,刘刚,等.膜分离技术在油田含油污水处理中的应用研究进展[J].工业水处理,2006(01):5-8.
[9]董晶颢.破乳-分置式MBR工艺处理特低渗透油田采出水的效能研究[D].哈尔滨:哈尔滨工业大学,2013.
[10]刘锋平.水解酸化-膜生物反应器工艺处理含油废水的可行性研究[D].北京:华北电力大学,2012.
[11]方志斌.无机膜技术在含油乳化液处理中的应用[A].中国膜工业协会、中国金属学会、中国有色金属学会、中国有色金属工业协会、中国环保产业协会.第三届膜分离技术在冶金工业中应用研讨会论文集[C].中国膜工业协会、中国金属学会、中国有色金属学会、中国有色金属工业协会、中国环保产业协会:中国有色金属学会,2009:3.
[12]Ebrahimi M,AshaghiK.Shams,EngelL.etal.Characterization and application of different ceramic membranes for the oil-field produced water treatment[J].Desalination,2009,245(1-3):533540.
[13]Ebrahimi M,WillrshausenD,Ashaghi K Shams,et al.Investigations on the use of dfferent ceramic membranes for efficient oilfield produced water treatment[J].Desalination,2010,250(3):991-996.
[14]谷玉洪,薛家慧,刘凯文,等.陶瓷微滤膜处理油田采出水试验[J].油气田地面工程,2001(01):18-19.
[15]王明花,王利,方少明,等.两亲聚合物改性PVDF膜处理含油废水的研究[J].膜科学与技术,2015,35(03):76-80+125.
[16]孙鸿,宋华,芦艳.Al2O3/TiO2/PVDF杂化超滤膜的制备及其性能研究[J].功能材料,2012,43(18):2558-2563.
[17]Yuliwati E,Ismail A F,MatsuuraT,et al.Effect of modified PVDF hollow fiber submerged ultrafiltration membrane for refinery waste-water treatment[J].Desalination,2011,283:214-220.
[18]You Yong Sung,Kang Seongchan,MauchaufféRodolphe,et al.Rapid and selective surface functionalization of the membrane for high efficiency oil-water separation via an atmospheric pressure plasma process.[J].Scientific reports,2017,7(1).
[19]Harjot Kaur,Vijaya Kumar Bulasara,Raj Kumar Gupta,et al.Influence of pH and temperature of dip-coating solution on the properties of cellulose acetate-ceramic composite membrane for ultrafiltration[J].Carbohydrate Polymers,2018,195.
[20]Zhang,Xiaojing,Zhao,Yuxin,Mu,Shanjun,et al.UiO-66-Coated Mesh Membrane with Underwater Superoleophobicity for High-Efficiency Oil-Water Separation[J].ACS Applied Materials&Interfaces,2018,(10):17301-17308.