二氟草酸硼酸锂的电化学性能、制备和表征
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摘要
二氟草酸硼酸锂是具有很好市场前景的二次锂离子电池电解质锂盐及添加剂。主要介绍了二氟草酸硼酸锂的电化学性能及制备和表征方法。
Lithium difluoro(oxalate) borate can be used for the second lithium-ion battery electrolyte lithium salts and additive with a good market prospect.This paper mainly introduces the electrochemical performance,preparation and characterization of lithium difluoro(oxalate) borate.
Lithium difluoro(oxalate) borate can be used for the second lithium-ion battery electrolyte lithium salts and additive with a good market prospect.This paper mainly introduces the electrochemical performance,preparation and characterization of lithium difluoro(oxalate) borate.
引文
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[24]李荐,周宏明,刘芙蓉.一种高纯草酸二氟硼酸锂的制备方法:中国,102070661A[P].2011-01-25.
[25]王坤,刘红光,叶学海,等.一种二氟草酸硼酸锂的制备方法:中国,105399761A[P].2015-10-22.
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[28]韩鸿波,陈靖淞,覃旭松,等.一种二氟草酸硼酸锂的制备方法:中国,103483368A[P].2013-09-17.
[29]Sandra Z,Dominik M,Marius A.Electrochemical characterization of electrolytes for lithium-ion batteries based on lithium di?uoromono(oxalato)borate[J].J.Power Sources,2011,196:1417-1424.
[30]Zhou Y,Zhang X Y,Nian H E,et al.Preparation and characterization of Li BF4by gradient heating dehydration[J].Acta Chemica Sinica,2010,68(14):1399-1403.
[31]周宏明,刘芙蓉,李荐,等.锂电池电解质草酸二氟硼酸锂水解过程及其对理化性能的影响[J].中南大学学报:自然科学版,2012,43(11):4228-4233.
[32]崔孝玲,唐凤娟,张宇,等.草酸二氟硼酸锂和四氟硼酸锂的分离方法:中国,106632437A[P].2017-05-10.
[33]Tobias H,Christian S,Dirk G,et al.Characterisation and properties of new ionic liquids with the difluoro[1,2-oxalato(2-)-O,O’]borate anion[J].J.Fluorine Chem.,2007,128(21):612-618.
[34]Gao H Q,Zhang Z A,Lai Y Q,et al.Structure characterization and electrochemical properties of new lithium salt Li ODFB for electrolyte of lithium ion batteries[J].Journal of Central South University of Technology,2008,15(6):830-834.
[2]Aurbach D,Markovsky B,Salitra G,et al.Review on electrode-electrolyte solution interactions related to cathode materials for Li-ion batteries[J].J.Power Sources,2007,165(2):491-499.
[3]Zhang S,Xu K,Jow T R.Low-temperature performance of Li-ioncells with a Li BF4-based electrolyte[J].J.Solid State Electrochem,2003,7(3):147-151.
[4]Len J L,Han S D,Paul D,et al.Crystal structure and physical properties of lithium difluoro(oxalato)borate(Li DFOB or Li BF2Ox)[J].J.Power Sources,2011,196(22):9737-9742.
[5]秦利平,郭为民.新型锂盐二氟草酸硼酸锂的研究进展[J].电源技术,2014,38(6):1159-1165.
[6]邓凌峰,陈洪.锂离子电池电解质的合成与电化学性能[J].电源技术,2010,34(30):237-240.
[7]付茂华.磷酸铁锂电池用高低温电解液的研究[D].长沙:中南大学,2010.
[8]Abraham D P,Furczon M M,Kang S H,et al.Effect of electrolyte composition on initial cycling impedance characteristics of lithium-ion cells[J].J.Power Sources,2008,180(1):612-620.
[9]Zhang S S.Electochemical study of the formation of a solid electrolyte interface on graphite in a Li BC2O4F2-based electrolyte[J].J.Power Sources,2007,163(2):713-718.
[10]Li S Y,Xu X L,Shi X M,et al.Electrochemical performance of lithiumdifluoro(oxalate)borate synthesized by a novel method[J].Advanced Materials Research,2011(197/198):l121-l124.
[11]Tsujioka S,Takase H,Takahashi M,et al.Electrolyte for electrochemical device:US,6787267B2[P].2002-05-23.
[12]Tsujioka S,Takase H,Takahashi,M I.Preparation of lithium(alkanoato)borates and(alkanoato)phosphates:EP,1308449 A2[P].2003-05-07.
[13]秘军林,黄辉桃,孙新华.新型锂盐二氟草酸硼酸锂制备的实验性研究[J].无机盐工业,2016,48(10):32-35.
[14]李新海,吴贤文,王志兴,等.一种二氟草酸硼酸锂的制备及纯化方法:中国,102702243 A[P].2012-06-12.
[15]Morinaka T,Muramoto S,Tateishi Y,et al.Preparation and purification of calcium,lithium and sodium fluorooxalato-phosphate and fluoro-oxalatobroate:WO,2013180174 A1[P].2013-12-05.
[16]Tsujioka S,Takase H,Takahashi M,et al.Electrolyte containing ionic metal complex for electrochemical device:EP,1195834A2[P].2002-04-10.
[17]许国荣,刘冬,张正洪,等.二氟草酸硼酸锂的制备方法:中国,103113396A[P].2013-01-21.
[18]Li S Y,Zhao W,Cui X L,et al.An improved method for synthesis of lithium difluoro(oxalato)borate and effects of sulfolane on the electrochemical performances of lithiumion batteries[J].Electrochimica Acta,2013,91:282-292.
[19]崔孝玲,赵伟,徐晓莉,等.草酸二氟硼酸锂与四氟硼酸锂的联产方法:中国,103374023 A[P].2013-10-30.
[20]王广强,沈枫锋.乙二酸氟硼酯制备二氟草酸硼酸锂与双草酸硼酸锂的方法:中国,106946921A[P].2017-04-07.
[21]周阳.一种草酸二氟硼酸锂盐的串联一锅法合成方法:中国,104387411A[P].2014-11-07.
[22]Zhou H M,Xiao K W,Li J,et al.Synthesis of lithium difluoro(oxalate)borate(Li ODFB),phase diagram and ions coordination of Li ODFB in dimethyl carbonate[J].J.Cent.South Univ.,2018(25):550-560.
[23]周宏明,耿文俊,李荐,等.一种草酸二氟硼酸锂电解质盐的制备方法:中国,104230970A[P].2013-06-21.
[24]李荐,周宏明,刘芙蓉.一种高纯草酸二氟硼酸锂的制备方法:中国,102070661A[P].2011-01-25.
[25]王坤,刘红光,叶学海,等.一种二氟草酸硼酸锂的制备方法:中国,105399761A[P].2015-10-22.
[26]陈琛.一种二氟草酸硼酸锂的制备方法:中国,104557995A[P].2013-10-12.
[27]周小进.一种草酸二氟硼酸锂的制备方法:中国,105481887A[P].2016-04-13.
[28]韩鸿波,陈靖淞,覃旭松,等.一种二氟草酸硼酸锂的制备方法:中国,103483368A[P].2013-09-17.
[29]Sandra Z,Dominik M,Marius A.Electrochemical characterization of electrolytes for lithium-ion batteries based on lithium di?uoromono(oxalato)borate[J].J.Power Sources,2011,196:1417-1424.
[30]Zhou Y,Zhang X Y,Nian H E,et al.Preparation and characterization of Li BF4by gradient heating dehydration[J].Acta Chemica Sinica,2010,68(14):1399-1403.
[31]周宏明,刘芙蓉,李荐,等.锂电池电解质草酸二氟硼酸锂水解过程及其对理化性能的影响[J].中南大学学报:自然科学版,2012,43(11):4228-4233.
[32]崔孝玲,唐凤娟,张宇,等.草酸二氟硼酸锂和四氟硼酸锂的分离方法:中国,106632437A[P].2017-05-10.
[33]Tobias H,Christian S,Dirk G,et al.Characterisation and properties of new ionic liquids with the difluoro[1,2-oxalato(2-)-O,O’]borate anion[J].J.Fluorine Chem.,2007,128(21):612-618.
[34]Gao H Q,Zhang Z A,Lai Y Q,et al.Structure characterization and electrochemical properties of new lithium salt Li ODFB for electrolyte of lithium ion batteries[J].Journal of Central South University of Technology,2008,15(6):830-834.
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