稀土系储氢合金和镍氢电池产业现状及标准化体系建设研究
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摘要
为了使稀土资源得到合理而充分地利用,对中国国内部分储氢合金和镍氢电池的生产企业进行了调研,了解了稀土系储氢合金和镍氢电池的产业化情况、产能情况以及市场现状和发展趋势等,并对稀土系储氢合金和镍氢电池行业存在的问题进行了分析,针对性地提出了解决思路。同时,从标准化的角度明确了制约储氢合金和镍氢电池产业发展的障碍,提出了规范行业发展所需的标准体系框架,对整个储氢合金和镍氢电池产业链的健康、可持续发展具有重要意义。
In order to make more reasonable and fully use of rare earth resources,a research was carried out on part of the domestic hydrogen storage alloy and nickel metal hydride battery enterprises. The industrialization status,capacity and market situation of the rare earth hydrogen storage alloys and nickel metal hydride batteries were studied in this paper,and also the existing problems were analyzed. In the end,a solution was given out to the existing problems. At the same time,this paper put forward the framework of standardization system construction of the RE-based hydrogen storage alloy and nickel metal hydride batteries. It is important to make the RE-based hydrogen storage alloys and nickel metal hydride batteries develop healthily and sustainably.
In order to make more reasonable and fully use of rare earth resources,a research was carried out on part of the domestic hydrogen storage alloy and nickel metal hydride battery enterprises. The industrialization status,capacity and market situation of the rare earth hydrogen storage alloys and nickel metal hydride batteries were studied in this paper,and also the existing problems were analyzed. In the end,a solution was given out to the existing problems. At the same time,this paper put forward the framework of standardization system construction of the RE-based hydrogen storage alloy and nickel metal hydride batteries. It is important to make the RE-based hydrogen storage alloys and nickel metal hydride batteries develop healthily and sustainably.
引文
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[17]周增林,宋月清,崔舜,等.Nd替代La对La-Mg-Ni系A2B7型储氢电极合金性能的影响[J].中国有色金属学报,2007,17(1):45-52.Zhou Z L,Song Y Q,Cui S,et al.The effect of Nd instead of La on the properties of the A2B7hydrogen storage electrode in La-Mg-Ni system[J].The Chinese Journal of Nonferrous Metals,2007,17(1):45-52.
[18]Akiba E,Hayakawa H,Kahno T.Crystal structures of novel La-Mg-Ni hydrogen absorbing alloys[J].J Alloys Comp,2006,280:408-412.
[19]张鲁山,王智敏,郭永权.La-Mg-Ni/Co储氢合金中的相结构[J].中国科学:物理学力学天文学,2012,42:46-53.Zhang L S,Wang Z M,Guo Y Q.The phase structure of La-Mg-Ni/Co hydrogen storage alloy[J].Chinese Science:the Mechanical Astronomy of Physics,2012,42:46-53.
[20]郑贞贞,王智敏,郭永权.贮氢合金中的相结构[R].上海:第十届全国x射线衍射学术大会暨国际衍射数据中心(ICDD)研讨会,2009.Zheng Z Z,Wang Z M,Guo Y Q.The phase structure of hydrogen storage alloy[R].Shanghai:The tenth national x ray diffraction academic conference and international diffraction data center(ICDD)seminar,2009.
[21]周秋红,谢建伟.推进稀土标准化的实践与展望[A].第十一届中国标准化论坛论文集[C].成都:中国标准化协会,2014.1000-1003.Zhou Q H,Xie J W.The practice and prospect of promoting the standardization of rare earth[A].The Eleventh Chinese Standardization Forum[C].Chengdu:China Association for Standardization,2014.1000-1003.
[2]Solomon B D,Banerjee A.A global survey of hydrogen energy research,development and policy[J].Energy Policy,2006,34(11):781-792.
[3]Urretavizcaya G,Chávez A C S,Castro F J.Hydrogen absorption and desorption in the Mg-Ag system[J].Alloys Compd,2014 Hydrogen-storage Materials for Mobile Applications,611(12):202-209.
[4]Schlapbach L,Zuttel A.Hydrogen-storage materials for mobile applications[J].Nature,2001,414(6861):353-353.
[5]闫慧忠.储氢材料产业现状及发展[J].高科技与产业化,2012,195(8):68-71.Yan H Z.Present situation and development of hydrogen storage material industry[J].High Technology and Industrialization,2012,195(8):68-71.
[6]Fetcenko M A.Recent advances in Ni MH battery technology[J].J Power Source,2007,165(2):544-551.
[7]牛丽贤.我国镍氢电池产业现状与发展对策研究[A].第三届中国包头稀土产业论坛专家报告集[C].包头:中国稀土学会,2011.160-167.Niu L X.Research on the current situation and development of Ni-MH battery industry in China[A].The Third Rare Earth Industry BBS Expert Report Baotou China[C].Baotou:Chinese Society of Rare Earths,2011.160-167.
[8]周增林,林晨光,惠志林.高容量A2B7型超晶格贮氢合金的发展历程及问题[J].稀有金属材料与工程,2012,41(8):1500-1504.Zhou Z L,Lin C H,Hui Z L.Development process and problems of high capacity A2B7superlattice hydrogen storage alloy[J].Rare Metal Materials and Engineering,2012,41(8):1500-1504.
[9]陈子亮,李永涛,张庆安.超点阵Re-Mg-Ni基合金结构和储氢特性研究现状[J].金属功能材料,2015,46(10):10007-10012.Chen Z L,Li Y T,Zhang Q A.Research status of superlattice Re-Mg-Ni based alloy structure and hydrogen storage characteristics[J].Metallic Functional Materials,2015,46(10):10007-10012.
[10]王大辉,钟燕萍,闫汝煦,等.La2Mg0.9Al0.1Ni7.5-xCo1.5Mnx贮氢合金的相结构和电化学性能[J].稀有金属材料与工程,2010,39(1):30-34.Wang D H,Zhong Y P,Yan R X,et al.Phase structure and electrochemical properties of La2Mg0.9Al0.1Ni7.5-xCo1.5Mnxhydrogen storage alloys[J].Rare Metal Materials and Engineering,2010,39(1):30-34.
[11]刘丽琴,唐睿,柳永宁.稀土元素对La0.8Mg0.2Ni2.8Co0.6储氢合金性能的影响[J].中国有色金属学报,2003,13(4):81-85.Liu L Q,Tang R,Liu Y N.Effects of rare earth elements on the properties of La0.8Mg0.2Ni2.8Co0.6of hydrogen storage[J].Journal of the Chinese Society of Rare Earths,2003,13(4):81-85.
[12]邓安强,罗永春.La-Mg-Ni系A2B7与A5B19型储氢合金电极合金的相结构与电化学性能研究.[D].兰州:兰州理工大学,2007.Deng A Q,Luo Y C.Study on phase structure and electrochemical properties of La-Mg-Ni based A2B7and A5B19type hydrogen storage alloy electrode alloys[D].Lanzhou:Lanzhou University of Technology,2007.
[13]Kohno T,Yoshida H,Kawashima F,et al.Hydrogen storage properties of new ternary system alloys:La Mg2Ni9,La5Mg2Ni23,La3Mg Ni14[J].Alloys Comp,2000,311(2):L5-L7.
[14]许剑轶,阎汝煦,罗永春,等.A2B7型La0.75Mg0.25Ni3.5-xFex(x=0~0.3)贮氢合金相结构及电化学性能研究[J].稀有金属,2009,33(3):323-327.Xu J T,Yan R X,Luo Y C.Study on the structure and electrochemical properties of A2B7type La0.75Mg0.25Ni3.5-xFex(x=0~0.3)hydrogen storage alloy[J].Chinese Journal of Rare Metal,2009,33(3):323-327.
[15]春林,盛丹,熊玮,等.贮氢合金La0.65Mg0.35Nix(x=3.0~3.5)的高温电化学性能的研究[J].金属功能材料,16(5):8-11.Chun L,Sheng D,Xiong W,et al.Study on high temperature electrochemical properties of La0.65Mg0.35Nix(x=3.0~3.5)hydrogen storage alloy[J].Metallic Functional Materials,16(5):8-11.
[16]王敬,江冰杰,穆道斌,等.La0.7-xNdxMg0.3Ni3.4Al0.1(x=0~0.4)储氢合金的相结构及电化学性能[J].中国稀土学报,2009,2(3):420-422.Wang J,Jiang B J,Mu D B,et al.The phase structure and electrochemical properties of La0.7-xNdxMg0.3Ni3.4Al0.1(x=0~0.4)hydrogen storage alloys[J].Journal of the Chinese Society of Rare Earths,2000,2(3):420-422.
[17]周增林,宋月清,崔舜,等.Nd替代La对La-Mg-Ni系A2B7型储氢电极合金性能的影响[J].中国有色金属学报,2007,17(1):45-52.Zhou Z L,Song Y Q,Cui S,et al.The effect of Nd instead of La on the properties of the A2B7hydrogen storage electrode in La-Mg-Ni system[J].The Chinese Journal of Nonferrous Metals,2007,17(1):45-52.
[18]Akiba E,Hayakawa H,Kahno T.Crystal structures of novel La-Mg-Ni hydrogen absorbing alloys[J].J Alloys Comp,2006,280:408-412.
[19]张鲁山,王智敏,郭永权.La-Mg-Ni/Co储氢合金中的相结构[J].中国科学:物理学力学天文学,2012,42:46-53.Zhang L S,Wang Z M,Guo Y Q.The phase structure of La-Mg-Ni/Co hydrogen storage alloy[J].Chinese Science:the Mechanical Astronomy of Physics,2012,42:46-53.
[20]郑贞贞,王智敏,郭永权.贮氢合金中的相结构[R].上海:第十届全国x射线衍射学术大会暨国际衍射数据中心(ICDD)研讨会,2009.Zheng Z Z,Wang Z M,Guo Y Q.The phase structure of hydrogen storage alloy[R].Shanghai:The tenth national x ray diffraction academic conference and international diffraction data center(ICDD)seminar,2009.
[21]周秋红,谢建伟.推进稀土标准化的实践与展望[A].第十一届中国标准化论坛论文集[C].成都:中国标准化协会,2014.1000-1003.Zhou Q H,Xie J W.The practice and prospect of promoting the standardization of rare earth[A].The Eleventh Chinese Standardization Forum[C].Chengdu:China Association for Standardization,2014.1000-1003.