用户名: 密码: 验证码:
圆柱形锂/氟化碳电池的安全性能
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Safety performance of cylindrical lithium/fluorinated carbon battery
  • 作者:曾子元 ; 张红梅 ; 王庆杰 ; 石斌
  • 英文作者:ZENG Zi-yuan;ZHANG Hong-mei;WANG Qing-jie;SHI Bin;Military Representative Office of the Navy in Guiyang;Guizhou Meiling Battery Co.,Ltd.;
  • 关键词:锂氟化碳(Li/CF_x)电池 ; 安全性能 ; 安全实验
  • 英文关键词:lithium/fluorinated carbon(Li/CF_x) battery;;safety performance;;safety test
  • 中文刊名:DACI
  • 英文刊名:Battery Bimonthly
  • 机构:海军驻贵阳地区军事代表室;贵州梅岭电源有限公司;
  • 出版日期:2019-04-25
  • 出版单位:电池
  • 年:2019
  • 期:v.49;No.256
  • 语种:中文;
  • 页:DACI201902016
  • 页数:4
  • CN:02
  • ISSN:43-1129/TM
  • 分类号:44-47
摘要
研制以改进的氟化石墨为正极、锂为负极的6. 0 Ah圆柱形锂/氟化碳(Li/CF_x)电池。通过过放、短路、针刺和挤压等安全实验,对Li/CF_x电池进行安全性能测试。电池以0. 20 C倍率过放至-2. 00 V,没有鼓胀、漏液、爆炸和起火,表面的最大温升不超过78℃;电池经短路实验,没有出现鼓胀、漏液、爆炸和起火,表面的最大温升不超过95℃;电池经过针刺和挤压后,没有爆炸、起火,表面的最大温升不超过92℃。
        Lithium/fluorinated carbon( Li/CF_x) battery which was cylindrical with 6. 0 Ah was prepared with improved fluorinated graphite as cathode,lithium flake as anode. The safe performance of Li/CF_xbattery was characterized by over-discharging test,shortcircuit test,puncturing test and compressing test. When overcharged to-2. 00 V at 0. 20 C,battery had no bulge,leakage,explosion and fire phenomenon,the maximum temperature rise of the surface didn't exceed 78 ℃. After short-circuit experiment,there was no bulge,leakage,explosion and fire phenomenon,the maximum temperature rise of the surface did not exceed 95 ℃. When compressed and punctured,battery had no explosion and fire phenomenon,the maximum temperature rise of the surface did not exceed 92 ℃.
引文
[1]KAZUHIKO M,LI J L,YOSHIMI O,et al. Surface structure and electrochemical characteristics of natural graphite fluorinated by ClF3[J]. J Fluorine Chemistry,2006,127(9):1 383-1 389.
    [2]毛敏,张红梅,姚华杰,等. Li/CFx电池的制备及性能研究[J].电池,2016,46(3):148-151.
    [3]LI Y,CHEN Y F,FENG W,et al. The improved discharge performance of Li/CFxbatteries by using multi-walled carbon nanotubes as conductive additive[J]. J Power Sources,2011,196(5):2 246-2 250.
    [4]SIDERIS P J,YEW R,NIEVES I,et al. Charge transfer in Li/CFxsilver vanadium oxide hybrid cathode batteries revealed by solid state7Li and19F nuclear magnetic resonance spectroscopy[J].J Power Sources,2014,254(2):293-297
    [5]ZHU L,PAN Y,LI L,et al. Preparation CFx@C microcapsules as a high-rate capability cathode of lithium primary battery[J]. J Electrochem Soc,2016,11(6):14-22.
    [6]张懋慧,杨炜婧,解晶莹,等.氟化磷酸酯对锂/氟化碳电池放电性能的影响[J].电池,2015,45(2):65-67.
    [7]张红梅,李国平,王庆杰,等. Mn O2掺杂对锂/氟化碳电池性能的影响[J].电池,2017,47(3):156-157.
    [8]YIN X D,LI Y,FENG Y Y,et al. Polythiophene/graphite fluoride composites cathode for high power,and energy densities lithium primary batteries[J]. Synthetic Metals,2016,220(15):560-566.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700