锂硫电池正极材料的研究进展
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摘要
从材料角度概述锂硫电池正极材料的研究进展,包括碳/硫复合材料、金属化合物/硫复合材料和混合型/硫复合材料等,并对硫正极的发展进行展望。
The research progress solutions for lithium( Li)-sulfur( S) battery cathode based on materials was reviewed,including carbon/sulfur composites,metal compounds/sulfur composites and hybrid/sulfur composites. The developments of sulfur cathode were discussed.
The research progress solutions for lithium( Li)-sulfur( S) battery cathode based on materials was reviewed,including carbon/sulfur composites,metal compounds/sulfur composites and hybrid/sulfur composites. The developments of sulfur cathode were discussed.
引文
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[25] LU Y,LI X N,LIANG J W,et al. A simple melting-diffusing-reacting strategy to fabricate S/Ni S2-C for lithium-sulfur batteries[J].Nanoscale,2016,8(40):17 616-17 622.
[26] CUI Z M,ZU C X,ZHOU W D,et al. Mesoporous titanium nitrideenabled highly stable lithium-sulfur batteries[J]. Adv Mater,2016,28(32):6 926-6 931.
[27] LIU X,HUANG J Q,ZHANG Q,et al. Nanostructured metal oxides and sulfides for lithium-sulfur batteries[J]. Adv Mater,2017,29(20):1 601 759.
[28] SEH Z W,ZHANG Q F,LI W Y,et al. Stably cycling of lithium sulfide cathodes through strong affinity with multifunctional binders[J]. Chem Sci,2015,62(79):3 673-3 677.
[29] LIANG K,MARCUS K,ZHANG S F,et al. Lithium batteries:Ni S2/Fe S holey film as freestanding electrode for high performance lithium battery[J]. Adv Energy Mater,2017,7(22):1 701 309.
[30] PANG Q,LIANG X,KWOK C Y,et al. Advances in lithium-sulfur batteries based on multifunctional cathodes and electrolytes[J].Nat Energy,2016,1(9):16 132.
[31] CHANG Z,DOU H,DING B,et al. Co3O4nanoneedle arrays as a multifunctional“super-reservoir”electrode for long cycle life Li-S batteries[J]. J Mater Chem A,2016,5(1):250-257.
[32] ZHOU T H,LV W,LI J,et al. Twinborn Ti O2-Ti N heterostructures enabling smooth trapping-diffusion-conversion of polysulfides towards ultralong life lithium-sulfur batteries[J]. Energy Environ Sci,2017,10(7):1 694-1 703.
[33] HU G G,SUN Z H,SHI C,et al. A sulfur-rich copolymer@CNT hybrid cathode with dual-confinement of polysulfides for high-performance lithium-sulfur batteries[J]. Adv Mater,2016,29(11):1 603 835.
[2] FANG R P,ZHAO S Y,SUN Z H,et al. More reliable lithium-sulfur batteries:status,solutions and prospects[J]. Adv Mater,2017,29(48):1 606 823.
[3] MANTHIRAM A,FU Y,CHUNG S H,et al. Rechargeable lithiumsulfur batteries[J]. Chem Rev,2014,114(23):11 751-11 787.
[4] JI X L,LEE K T,NAZAR L F. A highly ordered nanostructured carbon-sulphur,cathode for lithium-sulphur batteries[J]. Nat Mater,2009,8(6):5 00-506.
[5] SEH Z W,SUN Y,ZHANG Q,et al. Designing high-energy lithiumsulfur batteries[J]. Chem Soc Rev,2016,45(20):5 605-5 634.
[6] MANTHIRAM A,FU Y,SU Y S. Challenges and prospects of lithium-sulfur batteries[J]. Acc Chem Res,2013,46(5):1 125-1 134.
[7] ZHOU W D,GUO B K,GAO H C,et al. Low-cost higher loading of a sulfur cathode[J]. Adv Energy Mater,2016,6(5):1 502 059.
[8] CAO R G,CHEN J Z,HAN K S,et al. Effect of the anion activity on the stability of Li metal anodes in lithium-sulfur batteries[J].Adv Funct Mater,2016,26(18):3 059-3 066.
[9] XU H H,QIE L,MANTHIRAM A. An integrally-designed,flexible polysulfide host for high-performance lithium-sulfur batteries with stabilized lithium-metal anode[J]. Nano Energy,2016,26:224-232.
[10] ZHENG Z N,GUO H C,PEI F,et al. High sulfur loading in hierarchical porous carbon rods constructed by vertically oriented porous graphene-like nanosheets for Li-S batteries[J]. Adv Funct Mater,2016,26(48):8 952-8 959.
[11] KIM J H,KIM T,JEONG Y C,et al. Stabilization of insoluble discharge products by facile aniline modification for high performance Li-S batteries[J]. Adv Energy Mater,2015,5(14):1 500 268.
[12] SUN Q,HE B,ZHANG X Q,et al. Engineering of hollow core-shell interlinked carbon spheres for highly stable lithium-sulfur batteries[J]. ACS Nano,2015,9(8):8 504-8 513.
[13] ZANG J,AN T H,DONG Y J,et al. Hollow-in-hollow carbon spheres with hollow foam-like cores for lithium-sulfur batteries[J]. Nano Research,2015,8(8):2 663-2 675.
[14] PENG H J,XU W T,ZHU L,et al. Lithium-sulfur batteries:3D carbonaceous current collectors:the origin of enhanced cycling stability for high-sulfur-loading lithium-sulfur batteries[J]. Adv Funct Mater,2016,26(35):6 351-6 358.
[15]唐航,黎天保,姚山山,等.商品石墨烯用于高比能量锂硫电池[J].电池,2018,48(3):171-174.
[16] ZHANG C F,WU H B,YUAN C Z,et al. Chemlnform abstract:Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries[J]. Angew Chem Int Edit,2012,51(38):9 592-9 595.
[17] SUN L,WANG D T,LUO Y F,et al. Sulfur embedded in mesoporous carbon nanotube network as a binder-free electrode for high performance lithium sulfur batteries[J]. ACS Nano,2015,10(1):1 300-1 308.
[18] LIU Y Z,LI G R,FU J,et al. Strings of porous carbon polyhedrons as self-standing cathode host for high-energy-density lithium-sulfur batteries[J]. Angew Chem Int Edit,2017,56(22):6 176-6 180.
[19] SONG J X,GORDIN M L,XU T,et al. Strong lithium polysulfide chemisorption on electroactive sites of nitrogen-doped carbon composites for high-performance lithium-sulfur battery cathodes[J].Angew Chem Int Edit,2015,54(14):4 325-4 329.
[20] PANG Q,TANG J T,HUANG H,et al. A nitrogen and sulfur dualdoped carbon derived from polyrhodanine@cellulose for advanced lithium-sulfur batteries[J]. Adv Mater,2015,27(39):6 021-6 028.
[21] YUAN S Y,BAO J W,WANG L N,et al. Graphene-supported nitrogen and boron rich carbon layer for improved performance of lithium-sulfur batteries due to enhanced chemisorption of lithium polysulfides[J]. Adv Energy Mater,2015,6(5):1 501 733.
[22] HOU T Z,CHEN X,PENG H J,et al. Design principles for heteroatom-doped nanocarbon to achieve strong anchoring of polysulfides for lithium-sulfur batteries[J]. Small,2016,12(24):3 283-3 291.
[23] PANAKNOWITSH J P,THOMAS A. Doping carbons beyond nitrogen:an overview of advanced heteroatom doped carbons with boron,sulfur and phosphorus for energy applications[J]. Energy Environ Sci,2013,6(10):2 839-2 855.
[24] CHANG Z,DOU H,DING B,et al. Interconnected core-shell pyrolyzed polyacrylonitrile@sulfur/carbon nanocomposites for rechargeable lithium-sulfur batteries[J]. New J Chem,2016,40(9):7 680-7 686.
[25] LU Y,LI X N,LIANG J W,et al. A simple melting-diffusing-reacting strategy to fabricate S/Ni S2-C for lithium-sulfur batteries[J].Nanoscale,2016,8(40):17 616-17 622.
[26] CUI Z M,ZU C X,ZHOU W D,et al. Mesoporous titanium nitrideenabled highly stable lithium-sulfur batteries[J]. Adv Mater,2016,28(32):6 926-6 931.
[27] LIU X,HUANG J Q,ZHANG Q,et al. Nanostructured metal oxides and sulfides for lithium-sulfur batteries[J]. Adv Mater,2017,29(20):1 601 759.
[28] SEH Z W,ZHANG Q F,LI W Y,et al. Stably cycling of lithium sulfide cathodes through strong affinity with multifunctional binders[J]. Chem Sci,2015,62(79):3 673-3 677.
[29] LIANG K,MARCUS K,ZHANG S F,et al. Lithium batteries:Ni S2/Fe S holey film as freestanding electrode for high performance lithium battery[J]. Adv Energy Mater,2017,7(22):1 701 309.
[30] PANG Q,LIANG X,KWOK C Y,et al. Advances in lithium-sulfur batteries based on multifunctional cathodes and electrolytes[J].Nat Energy,2016,1(9):16 132.
[31] CHANG Z,DOU H,DING B,et al. Co3O4nanoneedle arrays as a multifunctional“super-reservoir”electrode for long cycle life Li-S batteries[J]. J Mater Chem A,2016,5(1):250-257.
[32] ZHOU T H,LV W,LI J,et al. Twinborn Ti O2-Ti N heterostructures enabling smooth trapping-diffusion-conversion of polysulfides towards ultralong life lithium-sulfur batteries[J]. Energy Environ Sci,2017,10(7):1 694-1 703.
[33] HU G G,SUN Z H,SHI C,et al. A sulfur-rich copolymer@CNT hybrid cathode with dual-confinement of polysulfides for high-performance lithium-sulfur batteries[J]. Adv Mater,2016,29(11):1 603 835.