锂辉石浮选机理研究现状
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摘要
论文从锂辉石的晶体结构、浮选溶液中Fe3+离子和其它金属阳离子、阴离子等三个方面,系统评述了锂辉石浮选机理的研究进展。认为矿石浮选机理的研究有助于选矿药剂的开发,根据锂辉石的特点开发适宜的浮选药剂,对我国锂资源的综合高效利用具有理论和实际意义。
Research progress about spodumene flotation mechanism were systematically reviewed,mainly from the three aspects,that is crystal structure of spodumene,Fe3 +ions in flotation solution,and other metal cations and anions. It pointed out that the research of spodumene mechanism would be good for the development of the mineral processing reagents,develop suitable flotation reagent according to the characteristics of spodumene have theoretical and practical significance on lithium resources comprehensive utilization.
Research progress about spodumene flotation mechanism were systematically reviewed,mainly from the three aspects,that is crystal structure of spodumene,Fe3 +ions in flotation solution,and other metal cations and anions. It pointed out that the research of spodumene mechanism would be good for the development of the mineral processing reagents,develop suitable flotation reagent according to the characteristics of spodumene have theoretical and practical significance on lithium resources comprehensive utilization.
引文
[1]Ji Z Y,Jiao P P,Yuan J S,et al.The exploitation and utilization of lithium resources and its development[J].Light metals,2013,(5):1-5.
[2]Lee J H.Novel state-of-charge estimation method for lithium polymer batteries using electrochemical impedance spectroscopy[J].Journal of Power Electronics,2011,11(2):237-243.
[3]伊新辉.锂辉石低温浮选试验研究[J].中国矿山工程,2011,40(6):20-22.
[4]宋雪娟.手选作业在某锂辉石矿选别中的应用[J].新疆有色金属,2012,(5):50-51.
[5]廖石林,刘端春.锂辉石热裂法选矿试验[J].四川有色金属,1991,(1):33-37.
[6]陶家荣.锂辉石矿重介质选矿工业试验与研究[J].有色金属(选矿部分),2002,(2):13-16.
[7]Tippin R B,Browning J S,Llewellyn T O.Continuous heavy liquid concentration of spodumene[J].US Bur Mines,1970,(7379):1-6.
[8]Rosales,Gustavo D,Del C R,et al.Alkaline metal fluoride synthesis as a subproduct ofβ-spodumene leaching[J].Hydrometallurgy,2013,(139):73-78.
[9]李新冬,黄万抚,文金磊,等.锂辉石矿的工艺矿物学与选矿工艺研究[J].硅酸盐通报,2014,33(5):1207-1213.
[10]张杰,王维清,董发勤,等.锂辉石矿浮选试验研究[J].矿物学报,2013,33(3):423-425.
[11]Xian Y J,Nie Q,Wen S M,et al.Contribution of components from volume defect in natural pyrite and quartz to solution chemistry of flotation pulp[J].Transactions of Nonferrous Metals Society of China,2015,25(9):3119-3125.
[12]凌竞宏.三种不同类型矿体黄铁矿的晶体特性与可浮性的关系[D].长沙:中南大学硕士学位论文,1981.
[13]李天伶.β-锂辉石的晶体化学性质及其低热膨胀性的结构解释[J].硅酸盐通报,1995,(2):27-32,44.
[14]孙传尧,印万忠.关于硅酸盐矿物的可浮性与其晶体结构及表面特性关系的研究[J].矿冶,1998,7(3):22-28.
[15]肖祎.碱基不同配对构型氢键作用机理及电子特性理论研究[D].重庆:西南大学硕士学位论文,2014.
[16]项华妹.锂辉石电子结构及其可浮性的量子化学研究[D].赣州:江西理工大学硕士学位论文,2014.
[17]项华妹,何芮,张海天.基于锂辉石纯矿物的浮选研究[J].中国科技信息,2015,(5):64-66.
[18]曾小钦.晶格缺陷对闪锌矿电子结构影响的第一性原理研究[D].南宁:广西大学硕士学位论文,2009.
[19]陈建华,王进明,龙贤灏,等.硫化铜矿物电子结构的第一性原理研究[J].中南大学学报(自然科学版),2011,42(12):3612-3617.
[20]He G C,Xiang H M,Jiang W,et al.First-principles theory on electronic structure and floatability of spodumene[J].Rare Metals,2014,33(6):742-748.
[21]贾木欣,孙传尧.几种硅酸盐矿物晶体化学与浮选表面特性研究[J].矿产保护与利用,2001,(5):25-29.
[22]Beena R,Sathish P,Jyotsna T,et al.A molecular dynamics study of the interaction of oleate and dodecylammonium chloride surfactants with complex aluminosilicate minerals[J].Journal of Colloid and Interface Science,2011,(362):510-516.
[23]Kwang S M,Douglas W.Fuerstenau.Surface crystal chemistry in selective flotation of spodumene(Li Al[Si O3]2)from other aluminosilicates[J].Mineral Processing,2003,(72):11-24.
[24]任文斌.联合捕收剂浮选锂辉石生产实践[J].新疆有色金属,2012,(3):84-85.
[25]罗仙平,吕玲芝,陈晓明,等.江西某低品位难选锂辉石矿直接浮选工艺[J].有色金属工程,2012,(5):36-39.
[26]赵开乐,王昌良,邓伟,等.某锂辉石矿石工艺矿物学特征及选矿试验[J].矿物学报,2014,34(4):553-558.
[27]刘宁江.可可托海稀有矿V26、V38矿体锂辉石浮选试验研究[J].新疆有色金属,2008,31(5):48-49.
[28]孙传尧,印万忠.不同颜色锂辉石浮游性的差异及晶体化学分析[J].有色金属,2000,52(4):107-110.
[29]孙传尧,印万忠.同一矿体中锂辉石、霓石的浮游性差异分析[J].中国矿业大学学报,2001,30(6):531-536.
[30]朱建光,余明灯.磨矿铁介质对绿柱石、锂辉石的活化和浮选分离的作用机理[J].湖南有色金属,1993,9(6):332-336.
[31]徐龙华,董发勤,巫侯琴,等.油酸钠浮选锂辉石的作用机理研究[J].矿物学报,2013,33(2):181-184.
[32]Yu F S,Wang Y H,Zhang L,et al.Role of oleic acid ionic_molecular complexes in the flotation of spodumene[J].Minerals Engineering,2015,71:7-12.
[33]石海兰,朱文龙.Fe3+对锂辉石浮选的影响及机理研究[J].稀有金属与硬质合金,2015,43(4):5-9.
[34]Zhang J,Wang W Q,Liu J,et al.Fe(Ⅲ)as an activator for the flotation of spodumene,albite,and quartz minerals[J].Mineral Engineering,2014,61:16-22.
[35]王祥坤.组合捕收剂在锂辉石浮选中的试验研究及机理讨论[D].昆明:昆明理工大学硕士学位论文,2014.
[36]赵云.对高品位锂辉石浮选回收率的探索[J].新疆有色金属,2005,增刊:37-41.
[37]冯木.新型捕收剂在锂辉石浮选中的作用机理及表面化学分析[D].长沙:中南大学硕士学位论文,2014.
[38]Yu F S,Wang Y H,Wang J M,et al.First-principle investigation on mechanism of Ca ion activating flotation of spodumene[J].Rare Metals,2014,33(3):358-362.
[39]Wang Y H,Yu F S.Effects of Metallic ions on the flotation of spodumene and Beryl[J].Journal of China University of Mining&Technology,2007,17(1):35-39.
[40]Liu W J,Zhang S Q,Wang W Q,et al.The effects of Ca(Ⅱ)and Mg(Ⅱ)ions on the flotation of spodumene using Na Ol[J].Minerals Engineering,2015,(79):40-46.
[41]刘方,孙传尧.金属阳离子与十二胺添加顺序对硅酸盐矿物浮选的影响[J].有色金属(选矿部分),2011,(4):58-63.
[42]刘方,孙传尧.调整剂和油酸钠添加顺序对硅酸盐矿物浮选的影响[J].金属矿山,2011,(417):90-94.
[43]刘方.硅酸盐矿物浮选过程中调整剂对捕收剂作用方式的研究[D].沈阳:东北大学博士学位论文,2011.
[44]贾木欣,孙传尧.几种硅酸盐矿物对金属离子吸附特性的研究[J].矿冶,2001,10(3):25-30.
[45]张忠汉,李毓康,孙籍.关于碳酸钠、氟化钠、硫化钠对Ca2+、Fe3+活化的绿柱石、锂辉石作用规律及作用机理的研究[J].稀有金属,1983,(4):1-8.
[46]王毓华,于福顺,陈兴华,等.锂辉石与绿柱石浮选分离的试验研究[J].稀有金属,2005,29(3):320-323.
[47]于福顺.锂辉石与绿柱石浮选分离工艺及机理的研究[D].长沙:中南大学硕士学位论文,2005.
[48]Li M Y,Wei D Z,Shen Y B,et al.Selective depression effect in flotation separation of copper molybdenum sulfides using 2,3-disulfanylbutanedioic acid[J].Trans Nonferrous met.Soc.China,2015,(25):3126-3132.
[49]Watts H D,Tribe L,Kubicki J D.Arsenic adsorption onto minerals:connecting experimental observations with density functional theory calculations[J].Minerals,2014,4(2):208-240.
[50]秦伟,徐盛明,解强.巯基苯并咪唑类捕收剂的设计合成与性能[J].中国矿业大学学报,2014,43(2):309-324.
[2]Lee J H.Novel state-of-charge estimation method for lithium polymer batteries using electrochemical impedance spectroscopy[J].Journal of Power Electronics,2011,11(2):237-243.
[3]伊新辉.锂辉石低温浮选试验研究[J].中国矿山工程,2011,40(6):20-22.
[4]宋雪娟.手选作业在某锂辉石矿选别中的应用[J].新疆有色金属,2012,(5):50-51.
[5]廖石林,刘端春.锂辉石热裂法选矿试验[J].四川有色金属,1991,(1):33-37.
[6]陶家荣.锂辉石矿重介质选矿工业试验与研究[J].有色金属(选矿部分),2002,(2):13-16.
[7]Tippin R B,Browning J S,Llewellyn T O.Continuous heavy liquid concentration of spodumene[J].US Bur Mines,1970,(7379):1-6.
[8]Rosales,Gustavo D,Del C R,et al.Alkaline metal fluoride synthesis as a subproduct ofβ-spodumene leaching[J].Hydrometallurgy,2013,(139):73-78.
[9]李新冬,黄万抚,文金磊,等.锂辉石矿的工艺矿物学与选矿工艺研究[J].硅酸盐通报,2014,33(5):1207-1213.
[10]张杰,王维清,董发勤,等.锂辉石矿浮选试验研究[J].矿物学报,2013,33(3):423-425.
[11]Xian Y J,Nie Q,Wen S M,et al.Contribution of components from volume defect in natural pyrite and quartz to solution chemistry of flotation pulp[J].Transactions of Nonferrous Metals Society of China,2015,25(9):3119-3125.
[12]凌竞宏.三种不同类型矿体黄铁矿的晶体特性与可浮性的关系[D].长沙:中南大学硕士学位论文,1981.
[13]李天伶.β-锂辉石的晶体化学性质及其低热膨胀性的结构解释[J].硅酸盐通报,1995,(2):27-32,44.
[14]孙传尧,印万忠.关于硅酸盐矿物的可浮性与其晶体结构及表面特性关系的研究[J].矿冶,1998,7(3):22-28.
[15]肖祎.碱基不同配对构型氢键作用机理及电子特性理论研究[D].重庆:西南大学硕士学位论文,2014.
[16]项华妹.锂辉石电子结构及其可浮性的量子化学研究[D].赣州:江西理工大学硕士学位论文,2014.
[17]项华妹,何芮,张海天.基于锂辉石纯矿物的浮选研究[J].中国科技信息,2015,(5):64-66.
[18]曾小钦.晶格缺陷对闪锌矿电子结构影响的第一性原理研究[D].南宁:广西大学硕士学位论文,2009.
[19]陈建华,王进明,龙贤灏,等.硫化铜矿物电子结构的第一性原理研究[J].中南大学学报(自然科学版),2011,42(12):3612-3617.
[20]He G C,Xiang H M,Jiang W,et al.First-principles theory on electronic structure and floatability of spodumene[J].Rare Metals,2014,33(6):742-748.
[21]贾木欣,孙传尧.几种硅酸盐矿物晶体化学与浮选表面特性研究[J].矿产保护与利用,2001,(5):25-29.
[22]Beena R,Sathish P,Jyotsna T,et al.A molecular dynamics study of the interaction of oleate and dodecylammonium chloride surfactants with complex aluminosilicate minerals[J].Journal of Colloid and Interface Science,2011,(362):510-516.
[23]Kwang S M,Douglas W.Fuerstenau.Surface crystal chemistry in selective flotation of spodumene(Li Al[Si O3]2)from other aluminosilicates[J].Mineral Processing,2003,(72):11-24.
[24]任文斌.联合捕收剂浮选锂辉石生产实践[J].新疆有色金属,2012,(3):84-85.
[25]罗仙平,吕玲芝,陈晓明,等.江西某低品位难选锂辉石矿直接浮选工艺[J].有色金属工程,2012,(5):36-39.
[26]赵开乐,王昌良,邓伟,等.某锂辉石矿石工艺矿物学特征及选矿试验[J].矿物学报,2014,34(4):553-558.
[27]刘宁江.可可托海稀有矿V26、V38矿体锂辉石浮选试验研究[J].新疆有色金属,2008,31(5):48-49.
[28]孙传尧,印万忠.不同颜色锂辉石浮游性的差异及晶体化学分析[J].有色金属,2000,52(4):107-110.
[29]孙传尧,印万忠.同一矿体中锂辉石、霓石的浮游性差异分析[J].中国矿业大学学报,2001,30(6):531-536.
[30]朱建光,余明灯.磨矿铁介质对绿柱石、锂辉石的活化和浮选分离的作用机理[J].湖南有色金属,1993,9(6):332-336.
[31]徐龙华,董发勤,巫侯琴,等.油酸钠浮选锂辉石的作用机理研究[J].矿物学报,2013,33(2):181-184.
[32]Yu F S,Wang Y H,Zhang L,et al.Role of oleic acid ionic_molecular complexes in the flotation of spodumene[J].Minerals Engineering,2015,71:7-12.
[33]石海兰,朱文龙.Fe3+对锂辉石浮选的影响及机理研究[J].稀有金属与硬质合金,2015,43(4):5-9.
[34]Zhang J,Wang W Q,Liu J,et al.Fe(Ⅲ)as an activator for the flotation of spodumene,albite,and quartz minerals[J].Mineral Engineering,2014,61:16-22.
[35]王祥坤.组合捕收剂在锂辉石浮选中的试验研究及机理讨论[D].昆明:昆明理工大学硕士学位论文,2014.
[36]赵云.对高品位锂辉石浮选回收率的探索[J].新疆有色金属,2005,增刊:37-41.
[37]冯木.新型捕收剂在锂辉石浮选中的作用机理及表面化学分析[D].长沙:中南大学硕士学位论文,2014.
[38]Yu F S,Wang Y H,Wang J M,et al.First-principle investigation on mechanism of Ca ion activating flotation of spodumene[J].Rare Metals,2014,33(3):358-362.
[39]Wang Y H,Yu F S.Effects of Metallic ions on the flotation of spodumene and Beryl[J].Journal of China University of Mining&Technology,2007,17(1):35-39.
[40]Liu W J,Zhang S Q,Wang W Q,et al.The effects of Ca(Ⅱ)and Mg(Ⅱ)ions on the flotation of spodumene using Na Ol[J].Minerals Engineering,2015,(79):40-46.
[41]刘方,孙传尧.金属阳离子与十二胺添加顺序对硅酸盐矿物浮选的影响[J].有色金属(选矿部分),2011,(4):58-63.
[42]刘方,孙传尧.调整剂和油酸钠添加顺序对硅酸盐矿物浮选的影响[J].金属矿山,2011,(417):90-94.
[43]刘方.硅酸盐矿物浮选过程中调整剂对捕收剂作用方式的研究[D].沈阳:东北大学博士学位论文,2011.
[44]贾木欣,孙传尧.几种硅酸盐矿物对金属离子吸附特性的研究[J].矿冶,2001,10(3):25-30.
[45]张忠汉,李毓康,孙籍.关于碳酸钠、氟化钠、硫化钠对Ca2+、Fe3+活化的绿柱石、锂辉石作用规律及作用机理的研究[J].稀有金属,1983,(4):1-8.
[46]王毓华,于福顺,陈兴华,等.锂辉石与绿柱石浮选分离的试验研究[J].稀有金属,2005,29(3):320-323.
[47]于福顺.锂辉石与绿柱石浮选分离工艺及机理的研究[D].长沙:中南大学硕士学位论文,2005.
[48]Li M Y,Wei D Z,Shen Y B,et al.Selective depression effect in flotation separation of copper molybdenum sulfides using 2,3-disulfanylbutanedioic acid[J].Trans Nonferrous met.Soc.China,2015,(25):3126-3132.
[49]Watts H D,Tribe L,Kubicki J D.Arsenic adsorption onto minerals:connecting experimental observations with density functional theory calculations[J].Minerals,2014,4(2):208-240.
[50]秦伟,徐盛明,解强.巯基苯并咪唑类捕收剂的设计合成与性能[J].中国矿业大学学报,2014,43(2):309-324.