甲基汞化学传感器研究进展
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摘要
综述目前对食品、环境以及生物体中甲基汞含量进行快速检测的化学传感器的研究进展。介绍目前用于甲基汞快速检测的光化学传感器、电化学传感器,以及微悬臂梁等其他类型的化学传感器,通过分析上述传感器各自的工作原理,总结目前甲基汞化学传感器在选择性、适用性、灵敏度等方面存在的主要问题,并指出甲基汞传感器的研究发展方向。
The current research progress on the rapid detection of methylmercury in food,environment and organism was reviewed. The photochemical sensors,electrochemical sensors and other types of chemical sensors such as microcantilever currently used for the rapid detection of methylmercury were introduced. By analyzing the working principle of the above sensors,the main problems of methylmercury chemical sensors in selectivity,applicability and sensitivity were summarized,and the development direction of methylmercury sensor was pointed out.
The current research progress on the rapid detection of methylmercury in food,environment and organism was reviewed. The photochemical sensors,electrochemical sensors and other types of chemical sensors such as microcantilever currently used for the rapid detection of methylmercury were introduced. By analyzing the working principle of the above sensors,the main problems of methylmercury chemical sensors in selectivity,applicability and sensitivity were summarized,and the development direction of methylmercury sensor was pointed out.
引文
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[6]CLARKSON T W,MAGOS L.The toxicology of mercury and its chemical compounds[J].Critical reviews in toxicology,2006,36(8):609-662
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[8]CHUNG S W-C,CHAN B T-P.A reliable method to determine methylmercury and ethylmercury simultaneously in foods by gas chromatography with inductively coupled plasma mass spectrometry after enzymatic and acid digestion[J].Journal of Chromatography A,2011,1218(9):1260-1265
[9]HARRINGTON C F.The speciation of mercury and organomercury compounds by using high-performance liquid chromatography[J].TrAC Trends in Analytical Chemistry,2000,19(2):167-179
[10]FAN Z,LIU X.Determination of methylmercury and phenylmercury in water samples by liquid-liquid-liquid microextraction coupled with capillary electrophoresis[J].Journal of Chromatography A,2008,1180(1):187-192
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[16]ZOU Q,TIAN H.Chemodosimeters for mercury(II)and methylmercury(I)based on 2,1,3-benzothiadiazole[J].Sensors and Actuators B:Chemical,2010,149(1):20-27
[17]LIU Y,CHEN M,CAO T,et al.A cyanine-modified nanosystem for in vivo upconversion luminescence bioimaging of methylmercury[J].Journal of the American Chemical Society,2013,135(26):9869-9876
[18]DING L,ZOU Q,SU J.Novel fluorene-based chemodosimeters for mercury and methylmercury species in aqueous media[J].Se nsors and Actuators B:Chemical,2012,168:185-192
[19]GUO Z,ZHU W,ZHU M,et al.Near-Infrared Cell-Permeable Hg2+-Selective Ratiometric Fluorescent Chemodosimeters and Fast Indicator Paper for MeHg+Based on Tricarbocyanines[J].Chemistry-A European Journal,2010,16(48):14424-14432
[20]SANTRA M,ROY B,AHN K H.A“reactive”ratiometric fluorescent probe for mercury species[J].Organic letters,2011,13(13):3422-3425
[21]KO S-K,SHIN I,TAE J,et al.Fluorescent detection of methylmercury by desulfurization reaction of rhodamine hydrazide derivatives[J].Organic&Biomolecular Chemistry,2009,7:4590-4593
[22]YANG H,HAN C,ZHU X,et al.Upconversion luminescent chemodosimeter based on NIR organic dye for monitoring methylmercury in vivo[J].Advanced Functional Materials,2016,26(12):1945-1953
[23]SANTRA M,RYU D,CHATTERJEE A,et al.A chemodosimeter approach to fluorescent sensing and imaging of inorganic and methylmercury species[J].Chemical Communications,2009(16):2115-2117
[24]JIANG J,LIU W,CHENG J,et al.A sensitive colorimetric and ratiometric fluorescent probe for mercury species in aqueous solution and living cells[J].Chemical Communications,2012,48(67):8371-8373
[25]WANG H,CHAN W-H.Cholic acid-based fluorescent sensor for mercuric and methyl mercuric ion in aqueous solutions[J].Tetrahedron,2007,63(36):8825-8830
[26]YANG Y,YAO Z,LI W,et al.Selective detection of mercury(II)and methylmercury(II)via coordination-induced emission of a small-molecule probe[J].Science China Chemistry,2016,59(12):1651-1657
[27]LIN Y-H,TSENG W-L.Ultrasensitive sensing of Hg2+and CH3Hg+based on the fluorescence quenching of lysozyme type VI-stabilized gold nanoclusters[J].Analytical chemistry,2010,82(22):9194-9200
[28]CHEN L,LI J,CHEN L.Colorimetric detection of mercury species based on functionalized gold nanoparticles[J].ACS Appl.Mater.Interfaces,2014,6(18):15897-15904
[29]SUN Y,FENG W,YANG P,et al.The biosafety of lanthanide upconversion nanomaterials[J].Chemical Society Reviews,2015,44(6):1509-1525
[30]KRENO L E,LEONG K,FARHA O K,et al.Metal-organic framework materials as chemical sensors[J].Chem.Rev,2012,112(2):1105-1125
[31]XU F,KOU L,JIA J,et al.Metal-organic frameworks of zeolitic imidazolate framework-7 and zeolitic imidazolate framework-60 for fast mercury and methylmercury speciation analysis[J].Analytica chimica acta,2013,804:240-245
[32]JIA J,XU F,LONG Z,et al.Metal-organic framework MIL-53(Fe)for highly selective and ultrasensitive direct sensing of MeHg+[J].Chemical Communications,2013,49(41):4670-4672
[33]CHANG H-Y,HSIUNG T-M,HUANG Y-F,et al.Using rhodamine6G-modified gold nanoparticles to detect organic mercury species in highly saline solutions[J].Environmental science&technology,2011,45(4):1534-1539
[34]CLIMENT E,MARCOS M D,MART NEZ-M EZ R,et al.The determination of methylmercury in real samples using organically capped mesoporous inorganic materials capable of signal amplification[J].Angewandte Chemie,2009,121(45):8671-8674
[35]HEATON R,LAITINEN H.Electroanalytical studies of methylmercury in aqueous solution[J].Analytical chemistry,1974,46(4):547-553
[36]LAI R,HUANG E,ZHOU F,et al.Selective determination of methylmercury by flow-injection fast-scan voltammetry[J].Electroanalysis,1998,10(13):926-930
[37]MORETTO L,UGO P,LACASSE R,et al.Determination of methylmercury at NafionRcoated electrodes by single and multiple pulse voltammetric techniques[J].Journal of Electroanalytical Chemistry,1999,467(1):193-202
[38]IRELAND-RIPERT J,BERMOND A,DUCAUZE C.Determination of methylmercury in the presence of inorganic mercury by anodic stripping voltammetry[J].Analytica Chimica Acta,1982,143:249-254
[39]RIBEIRO F,NETO M,ROCHA M,et al.Voltammetric studies on the electrochemical determination of methylmercury in chloride medium at carbon microelectrodes[J].Analytica chimica acta,2006,579(2):227-234
[40]AGRAZ R,SEVILLA M T,HERNANDEZ L.Voltammetric quantification and speciation of mercury compounds[J].Journal of Electroanalytical Chemistry,1995,390(1/2):47-57
[41]KOROLCZUK M,RUTYNA I.New methodology for anodic stripping voltammetric determination of methylmercury[J].Electrochemistry Communications,2008,10(7):1024-1026
[42]KOROLCZUK M,STEPNIOWSKA A.Stripping Voltammetric Determination of Methylmercury in the Presence of Inorganic Mercury[J].Electroanalysis,2010,22(17/18):2087-2091
[43]ABOLLINO O,GIACOMINO A,MALANDRINO M,et al.Voltammetric determination of methylmercury and inorganic mercury with an home made gold nanoparticle electrode[J].Journal of applied electrochemistry,2009,39(11):2209
[44]XU Y,ZHANG W,SHI J,et al.Electrodeposition of gold nanoparticles and reduced graphene oxide on an electrode for fast and sensitive determination of methylmercury in fish[J].Food Chemistry,2017,237:423-430
[45]CHO E S,KIM J,TEJERINA B,et al.Ultrasensitive detection of toxic cations through changes in the tunnelling current across films of striped nanoparticles[J].Nature Materials,2012,11(11):978
[46]ZHANG H-Y,HONG-QING P,ZHANG B-L,et al.Microcantilever Sensors for Chemical and Biological Applications in Liquid[J].Chinese Journal of Analytical Chemistry,2012,40(5):801-808
[47]JI H-F,ZHANG Y,PURUSHOTHAM V V,et al.1,6-Hexanedithiol monolayer as a receptor for specific recognition of alkylmercury[J].Analyst,2005,130(12):1577-1579
[48]ZHOU L,LIN Y,HUANG Z,et al.Carbon nanodots as fluorescence probes for rapid,sensitive,and label-free detection of Hg2+and biothiols in complex matrices[J].Chemical communications,2012,48(8):1147-1149
[2]MERGLER D,ANDERSON H A,CHAN L H M,et al.Methylmercury exposure and health effects in humans:a worldwide concern[J].AMBIO:A Journal of the Human Environment,2007,36(1):3-11
[3]CHEN X,BAEK K-H,KIM Y,et al.A selenolactone-based fluorescent chemodosimeter to monitor mecury/methylmercury species in vitro and in vivo[J].Tetrahedron,2010,66(23):4016-4021
[4]BAKIR F,DAMLUJI S,AMIN-ZAKI L,et al.Methylmercury poisoning in Iraq[J].Science,1973,181(4096):230-241
[5]CELO V,LEAN D R,SCOTT S L.Abiotic methylation of mercury in the aquatic environment[J].Science of the Total Environment,2006,368(1):126-137
[6]CLARKSON T W,MAGOS L.The toxicology of mercury and its chemical compounds[J].Critical reviews in toxicology,2006,36(8):609-662
[7]LEVENSON C W,AXELRAD D M.Too much of a good thing?Update on fish consumption and mercury exposure[J].Nutrition reviews,2006,64(3)139-145
[8]CHUNG S W-C,CHAN B T-P.A reliable method to determine methylmercury and ethylmercury simultaneously in foods by gas chromatography with inductively coupled plasma mass spectrometry after enzymatic and acid digestion[J].Journal of Chromatography A,2011,1218(9):1260-1265
[9]HARRINGTON C F.The speciation of mercury and organomercury compounds by using high-performance liquid chromatography[J].TrAC Trends in Analytical Chemistry,2000,19(2):167-179
[10]FAN Z,LIU X.Determination of methylmercury and phenylmercury in water samples by liquid-liquid-liquid microextraction coupled with capillary electrophoresis[J].Journal of Chromatography A,2008,1180(1):187-192
[11]RlO-SEGADE S,BENDICHO C.On-line high-performance liquidchromatographic separation and cold vapor atomic absorption spectrometric determination of methylmercury and inorganic mercury[J].Talanta,1999,48(2):477-484
[12]GOMEZ-ARIZA J,LORENZO F,GARC1A-BARRERA T,et al.Analytical approach for routine methylmercury determination in seafood using gas chromatography-atomic fluorescence spectrometry[J].Analytica chimica acta,2004,511(1):165-173
[13]KOPLIK R,KLIME譒OV魣I,MALI譒OV魣K,et al.Determination of Mercury Species in Foodstuffs using LC-ICP-MS:the Applicability and Limitations of the Method[J].Czech Journal of Food Science,2014,32(3)
[14]RODIL R,CARRO A,LORENZO R,et al.Methylmercury determination in biological samples by derivatization,solid-phase microextraction and gas chromatography with microwave-induced plasma atomic emission spectrometry[J].Journal of chromatography A,2002,963(1):313-323
[15]GRINBERG P,CAMPOS R C,MESTER Z,et al.A comparison of alkyl derivatization methods for speciation of mercury based on solid phase microextraction gas chromatography with furnace atomization plasma emission spectrometry detection[J].Journal of Analytical Atomic Spectrometry,2003,18(8):902-909
[16]ZOU Q,TIAN H.Chemodosimeters for mercury(II)and methylmercury(I)based on 2,1,3-benzothiadiazole[J].Sensors and Actuators B:Chemical,2010,149(1):20-27
[17]LIU Y,CHEN M,CAO T,et al.A cyanine-modified nanosystem for in vivo upconversion luminescence bioimaging of methylmercury[J].Journal of the American Chemical Society,2013,135(26):9869-9876
[18]DING L,ZOU Q,SU J.Novel fluorene-based chemodosimeters for mercury and methylmercury species in aqueous media[J].Se nsors and Actuators B:Chemical,2012,168:185-192
[19]GUO Z,ZHU W,ZHU M,et al.Near-Infrared Cell-Permeable Hg2+-Selective Ratiometric Fluorescent Chemodosimeters and Fast Indicator Paper for MeHg+Based on Tricarbocyanines[J].Chemistry-A European Journal,2010,16(48):14424-14432
[20]SANTRA M,ROY B,AHN K H.A“reactive”ratiometric fluorescent probe for mercury species[J].Organic letters,2011,13(13):3422-3425
[21]KO S-K,SHIN I,TAE J,et al.Fluorescent detection of methylmercury by desulfurization reaction of rhodamine hydrazide derivatives[J].Organic&Biomolecular Chemistry,2009,7:4590-4593
[22]YANG H,HAN C,ZHU X,et al.Upconversion luminescent chemodosimeter based on NIR organic dye for monitoring methylmercury in vivo[J].Advanced Functional Materials,2016,26(12):1945-1953
[23]SANTRA M,RYU D,CHATTERJEE A,et al.A chemodosimeter approach to fluorescent sensing and imaging of inorganic and methylmercury species[J].Chemical Communications,2009(16):2115-2117
[24]JIANG J,LIU W,CHENG J,et al.A sensitive colorimetric and ratiometric fluorescent probe for mercury species in aqueous solution and living cells[J].Chemical Communications,2012,48(67):8371-8373
[25]WANG H,CHAN W-H.Cholic acid-based fluorescent sensor for mercuric and methyl mercuric ion in aqueous solutions[J].Tetrahedron,2007,63(36):8825-8830
[26]YANG Y,YAO Z,LI W,et al.Selective detection of mercury(II)and methylmercury(II)via coordination-induced emission of a small-molecule probe[J].Science China Chemistry,2016,59(12):1651-1657
[27]LIN Y-H,TSENG W-L.Ultrasensitive sensing of Hg2+and CH3Hg+based on the fluorescence quenching of lysozyme type VI-stabilized gold nanoclusters[J].Analytical chemistry,2010,82(22):9194-9200
[28]CHEN L,LI J,CHEN L.Colorimetric detection of mercury species based on functionalized gold nanoparticles[J].ACS Appl.Mater.Interfaces,2014,6(18):15897-15904
[29]SUN Y,FENG W,YANG P,et al.The biosafety of lanthanide upconversion nanomaterials[J].Chemical Society Reviews,2015,44(6):1509-1525
[30]KRENO L E,LEONG K,FARHA O K,et al.Metal-organic framework materials as chemical sensors[J].Chem.Rev,2012,112(2):1105-1125
[31]XU F,KOU L,JIA J,et al.Metal-organic frameworks of zeolitic imidazolate framework-7 and zeolitic imidazolate framework-60 for fast mercury and methylmercury speciation analysis[J].Analytica chimica acta,2013,804:240-245
[32]JIA J,XU F,LONG Z,et al.Metal-organic framework MIL-53(Fe)for highly selective and ultrasensitive direct sensing of MeHg+[J].Chemical Communications,2013,49(41):4670-4672
[33]CHANG H-Y,HSIUNG T-M,HUANG Y-F,et al.Using rhodamine6G-modified gold nanoparticles to detect organic mercury species in highly saline solutions[J].Environmental science&technology,2011,45(4):1534-1539
[34]CLIMENT E,MARCOS M D,MART NEZ-M EZ R,et al.The determination of methylmercury in real samples using organically capped mesoporous inorganic materials capable of signal amplification[J].Angewandte Chemie,2009,121(45):8671-8674
[35]HEATON R,LAITINEN H.Electroanalytical studies of methylmercury in aqueous solution[J].Analytical chemistry,1974,46(4):547-553
[36]LAI R,HUANG E,ZHOU F,et al.Selective determination of methylmercury by flow-injection fast-scan voltammetry[J].Electroanalysis,1998,10(13):926-930
[37]MORETTO L,UGO P,LACASSE R,et al.Determination of methylmercury at NafionRcoated electrodes by single and multiple pulse voltammetric techniques[J].Journal of Electroanalytical Chemistry,1999,467(1):193-202
[38]IRELAND-RIPERT J,BERMOND A,DUCAUZE C.Determination of methylmercury in the presence of inorganic mercury by anodic stripping voltammetry[J].Analytica Chimica Acta,1982,143:249-254
[39]RIBEIRO F,NETO M,ROCHA M,et al.Voltammetric studies on the electrochemical determination of methylmercury in chloride medium at carbon microelectrodes[J].Analytica chimica acta,2006,579(2):227-234
[40]AGRAZ R,SEVILLA M T,HERNANDEZ L.Voltammetric quantification and speciation of mercury compounds[J].Journal of Electroanalytical Chemistry,1995,390(1/2):47-57
[41]KOROLCZUK M,RUTYNA I.New methodology for anodic stripping voltammetric determination of methylmercury[J].Electrochemistry Communications,2008,10(7):1024-1026
[42]KOROLCZUK M,STEPNIOWSKA A.Stripping Voltammetric Determination of Methylmercury in the Presence of Inorganic Mercury[J].Electroanalysis,2010,22(17/18):2087-2091
[43]ABOLLINO O,GIACOMINO A,MALANDRINO M,et al.Voltammetric determination of methylmercury and inorganic mercury with an home made gold nanoparticle electrode[J].Journal of applied electrochemistry,2009,39(11):2209
[44]XU Y,ZHANG W,SHI J,et al.Electrodeposition of gold nanoparticles and reduced graphene oxide on an electrode for fast and sensitive determination of methylmercury in fish[J].Food Chemistry,2017,237:423-430
[45]CHO E S,KIM J,TEJERINA B,et al.Ultrasensitive detection of toxic cations through changes in the tunnelling current across films of striped nanoparticles[J].Nature Materials,2012,11(11):978
[46]ZHANG H-Y,HONG-QING P,ZHANG B-L,et al.Microcantilever Sensors for Chemical and Biological Applications in Liquid[J].Chinese Journal of Analytical Chemistry,2012,40(5):801-808
[47]JI H-F,ZHANG Y,PURUSHOTHAM V V,et al.1,6-Hexanedithiol monolayer as a receptor for specific recognition of alkylmercury[J].Analyst,2005,130(12):1577-1579
[48]ZHOU L,LIN Y,HUANG Z,et al.Carbon nanodots as fluorescence probes for rapid,sensitive,and label-free detection of Hg2+and biothiols in complex matrices[J].Chemical communications,2012,48(8):1147-1149