45钢表面微纳米多尺度结构制备及其抗硫化性能
|
摘要
采用阳极氧化工艺在45钢表面生成微纳米多尺度结构,分析了温度和氧化剂对45钢表面形貌的影响,通过抗热震性试验、硫化试验研究其表面性能。结果表明:温度降低,微纳结构形成速度变缓,数量较少;加入氧化剂,反应速度加快,表面纳米结构杂乱无序,分布不均匀;硫化试验发现污染物少,腐蚀较轻。
Micro/nano multi-scale structure on the surface of 45 steel was prepared by using the anodic oxidation process and the effect of temperature and oxidant on 45 steel surface morphology was analyzed. Its surface properties were studied by the thermal shock resistance test and vulcanized test. The results show that when the temperature decreases,the formation of micro/nano structure gets slowly,multi-scale nanostructure is less. Adding oxidant,the reaction rate increases, surface nanostructure is being disorder and uneven distribution;vulcanization fouling gets less,surface corrosion is also lighter.
Micro/nano multi-scale structure on the surface of 45 steel was prepared by using the anodic oxidation process and the effect of temperature and oxidant on 45 steel surface morphology was analyzed. Its surface properties were studied by the thermal shock resistance test and vulcanized test. The results show that when the temperature decreases,the formation of micro/nano structure gets slowly,multi-scale nanostructure is less. Adding oxidant,the reaction rate increases, surface nanostructure is being disorder and uneven distribution;vulcanization fouling gets less,surface corrosion is also lighter.
引文
[1]曾旭钊.轮胎模具行业技术现状及发展趋势[J].中国橡胶,2013,29(13):10-14.Zeng Xuzhao.The development trend of tire mold industry technology[J].China Rubber,2013,29(13):10-14.
[2]姜馨.我国轮胎模具行业发展概况及趋势[J].橡胶科技市场,2010,8(7):1-4.
[3]冯民堂,白文波,李志刚.我国轮胎模具行业现状和发展趋势[J].模具工业,2010,36(6):1-5.Feng Mintang,Bai Wenbo,Li Zhigang.The status and trend of development of tire mould industry in China[J].Die&Mould Industry,2010,36(6):1-5.
[4]王斌.我国轮胎模具制造和清洗技术概况[J].轮胎工业,2007,27(12):727-730.
[5]张佳琪,董梁,鞠恒,等.高速钢表面激光熔覆高硬涂层的组织性能[J].材料热处理学报,2016,37(9):196-200.Zhang Jiaqi,Dong Liang,Ju Heng,et al,et al.Microstructure and properties of surface coating on a high speed steel by laser cladding[J].Transactions of Materials and Heat Treatment,2016,37(9):196-200.
[6]王锐坤,揭晓华,曾旭钊,等.35钢表面微纳米化蒸发镀铝复合处理后的抗粘附性能[J].金属热处理,2013,38(4):97-100.Wang Ruikun,Jie Xiaohua,Zeng Xuzhao,et al.Anti-adhesion performance of 35 steel surface after micro-nano structured composite treatment and evaporated aluminum plating[J].Heat Treatment of Metals,2013,38(4):97-100.
[7]Mai Y J,Jie X H,Liu L L,et al.The study on vulcanization fouling behavior of nanocrystalline layer[J].Surface and Interface Analysis,2012,44(3):282-287.
[8]李文刚,石宝文.阳极氧化法处理的铝合金与橡胶粘合性能研究[J].新技术新工艺,2008(11):22-24.
[9]Habazaki H,Konno Y,Aoki Y,et al.Galvanostatic growth of nanoporous anodic films on iron in ammonium fluoride-ethylene glycol electrolytes with different water contents[J].The Journal of Physical Chemistry C,2010,114(44):18853-18859.
[10]Hao L,Chen Z,Wang R,et al.A non-aqueous electrodeposition process for fabrication of superhydrophobic surface with hierarchical micro/nano structure[J].Applied Surface Science,2012,258(22):8970-8973.
[11]詹玮婷.不锈钢表面微、纳米薄膜的制备及光催化和抗菌性能研究[D].武汉:武汉科技大学,2012.Zhan Weiting.Preparation of micro-and nanocomposite films on stainless steel surface for photocatalytic and antibacterial applications[D].Wuhan:Wuhan University of Science and Technology,2012.
[12]朱绪飞,宋晔,肖迎红,等.纳米多孔铝阳极氧化膜的形成机理研究[J].真空科学与技术学报,2007,2:113-117.Zhu Xufei,Song Ye,Xiao Yinghong,et al.Formation mechanism of nano-porous anodic alumina membranes[J].Chinese Journal of Vacuum Science and Technology,2007,2:113-117.
[13]万莹,赵蓉,宋筱露,等.阳极氧化法原位合成氧化铁纳米表面及其润湿性能研究[J].石油与天然气化工,2011,40(2):137-140.Wan Ying,Zhao Rong,Song Xiaolu,et al.hematite nanowire arrays on pure iron sheet by in situ anodization process and its wettability[J].Chemical Engineering of Oil and Gas,2011,40(2):137-140.
[2]姜馨.我国轮胎模具行业发展概况及趋势[J].橡胶科技市场,2010,8(7):1-4.
[3]冯民堂,白文波,李志刚.我国轮胎模具行业现状和发展趋势[J].模具工业,2010,36(6):1-5.Feng Mintang,Bai Wenbo,Li Zhigang.The status and trend of development of tire mould industry in China[J].Die&Mould Industry,2010,36(6):1-5.
[4]王斌.我国轮胎模具制造和清洗技术概况[J].轮胎工业,2007,27(12):727-730.
[5]张佳琪,董梁,鞠恒,等.高速钢表面激光熔覆高硬涂层的组织性能[J].材料热处理学报,2016,37(9):196-200.Zhang Jiaqi,Dong Liang,Ju Heng,et al,et al.Microstructure and properties of surface coating on a high speed steel by laser cladding[J].Transactions of Materials and Heat Treatment,2016,37(9):196-200.
[6]王锐坤,揭晓华,曾旭钊,等.35钢表面微纳米化蒸发镀铝复合处理后的抗粘附性能[J].金属热处理,2013,38(4):97-100.Wang Ruikun,Jie Xiaohua,Zeng Xuzhao,et al.Anti-adhesion performance of 35 steel surface after micro-nano structured composite treatment and evaporated aluminum plating[J].Heat Treatment of Metals,2013,38(4):97-100.
[7]Mai Y J,Jie X H,Liu L L,et al.The study on vulcanization fouling behavior of nanocrystalline layer[J].Surface and Interface Analysis,2012,44(3):282-287.
[8]李文刚,石宝文.阳极氧化法处理的铝合金与橡胶粘合性能研究[J].新技术新工艺,2008(11):22-24.
[9]Habazaki H,Konno Y,Aoki Y,et al.Galvanostatic growth of nanoporous anodic films on iron in ammonium fluoride-ethylene glycol electrolytes with different water contents[J].The Journal of Physical Chemistry C,2010,114(44):18853-18859.
[10]Hao L,Chen Z,Wang R,et al.A non-aqueous electrodeposition process for fabrication of superhydrophobic surface with hierarchical micro/nano structure[J].Applied Surface Science,2012,258(22):8970-8973.
[11]詹玮婷.不锈钢表面微、纳米薄膜的制备及光催化和抗菌性能研究[D].武汉:武汉科技大学,2012.Zhan Weiting.Preparation of micro-and nanocomposite films on stainless steel surface for photocatalytic and antibacterial applications[D].Wuhan:Wuhan University of Science and Technology,2012.
[12]朱绪飞,宋晔,肖迎红,等.纳米多孔铝阳极氧化膜的形成机理研究[J].真空科学与技术学报,2007,2:113-117.Zhu Xufei,Song Ye,Xiao Yinghong,et al.Formation mechanism of nano-porous anodic alumina membranes[J].Chinese Journal of Vacuum Science and Technology,2007,2:113-117.
[13]万莹,赵蓉,宋筱露,等.阳极氧化法原位合成氧化铁纳米表面及其润湿性能研究[J].石油与天然气化工,2011,40(2):137-140.Wan Ying,Zhao Rong,Song Xiaolu,et al.hematite nanowire arrays on pure iron sheet by in situ anodization process and its wettability[J].Chemical Engineering of Oil and Gas,2011,40(2):137-140.