生物油的精制及其研究进展
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摘要
生物质是唯一可以转化为液体燃料的、对环境友好的、清洁的可再生资源。通过高压液化或热裂解方法可将生物质制备成类似石油的黏稠状物质-生物油。生物油的高含氧量、低热值和化学不稳定等特性在一定程度上影响了其广泛应用,因此必须对生物油进行精制,以改善生物油的品质。从催化加氢、催化裂解、催化酯化、烯烃改性等方面阐述了生物油的精制技术及其研究进展。
Biomass is the only environmentally friendly,clean and renewable resource that can be converted into a liquid fuel.The biomass can be prepared into a petroleum-like viscous material by high-pressure liquefaction or thermal cracking.The characteristics of oxygen content,low calorific value and chemical instability affect its wide application to some extent.Therefore,bio-oil must be refined to improve the quality of bio-oil.In this paper,the bio-oil refining technology and its research progress are expounded from the aspects of catalytic hydrogenation,catalytic crac king,catalytic esterification and olefin modification.
Biomass is the only environmentally friendly,clean and renewable resource that can be converted into a liquid fuel.The biomass can be prepared into a petroleum-like viscous material by high-pressure liquefaction or thermal cracking.The characteristics of oxygen content,low calorific value and chemical instability affect its wide application to some extent.Therefore,bio-oil must be refined to improve the quality of bio-oil.In this paper,the bio-oil refining technology and its research progress are expounded from the aspects of catalytic hydrogenation,catalytic crac king,catalytic esterification and olefin modification.
引文
[1]GUEDES R E,LUNA A S,TORRES A R.Operating parameters for bio-oil production in biomass pyrolysis:A review[J].Journal of Analytical and Applied Pyrolysis,2018,12:134~149.
[2]BALAT M.Mechanisms of thermo chemical biomass conversion processes.Part 3:Reactions of liquefy action[J].Energy Sources,2008,30(7):649~659.
[3]王勇,邹献武,秦特夫.生物质转化及生物质油精制的研究进展[J].化学与生物工程,2010,27(9):1~5.
[4]PISKORZ J,MAJERSKI P,RADILEIN D,et a1.Conversion of Liginins to Hydrocarbon Fuels[J].Energy&Fuels,1989,(3):723~726.
[5]SOLTES E J,LIN S C K,SHEU Y H E.Catalyst specificities in high pressure hydroprocessing of pyrolysis and gasification tars[J].Prepr Pap,Am Chem Soc,Div Fuel Chem,1987,32:229~239.
[6]ZHANG XINGHUA,CHEN LUNGANG,KONG WEI,etal.Upgrading of bio-oil to boiler fuel by catalytic hydrotreatment and esterification in an efficient process[J].Energy,2015,84:83~90.
[7]刘荣厚,黄彩霞,蔡均猛,等.生物质热裂解生物油精制的研究进展[J].农业工程学报,2008,24(3):308~312.
[8]马文超,陈娇娇,王铁军,等.生物油模型化合物催化裂解机理[J].农业工程学报,2013,(9):207~213.
[9]郭晓亚,颜涌捷,李庭琛,等.生物质裂解油催化裂解精制[J].过程工程学报,2003,3(1):91~95.
[10]张琦,常杰,王铁军,等.生物质裂解油的性质及精制研究进展[J].石油化工,2006,35(5):493~498.
[11]王琦,姚燕,王树荣,等.生物油离子交换树脂催化酯化试验研究[J].浙江大学学报:工学,2009,43(5):927~930.
[12]杨续来,CHARLES U.PITTMAN JR,朱锡锋.固体酸催化烯烃改性生物油酚类化合物研究[J].高等学校化学学报,2010,31(7):1398~1404.
[13]KARNJANAKOM S,GUAN G Q,ASEP B,et al.A greenmethod to increase yield and quality of bio-oil:Ultrasonic pretreatment of biomass and catalytic upgrading of bio-oil over meta(Cu,Fe and/or Zn)/γ-Al2O3[J].RSC Advances,2015,101(5):83494~83503.
[14]CHIARAMONTIA D,BONINIA M,FRATINIA E,et al.Development of Emulsions from Biomass Pyrolysis Liquid and Diesel and Their Use in Engines[J].Biomass and Bioenergy,2003(25):85~111.
[15]许细薇,李治宇,庄文俞,等.超声波与添加醇和乳化剂乳化提质热解生物油研究[J].农业机械学报,2017,48(5):320~326.
[16]牛淼淼,黄亚继,金保昇,等.生物油/柴油乳化油制备及其在柴油机上的燃烧试验研究[J].中国电机工程学报,2013,32(20).96-101.
[17]汪永威,汪泽,宋文立,等.生物油水蒸气气化实验研究[J].燃料化学学报,2012,40(2):170~176.
[18]TIANJU CHEN,CENG WU,RONGHOU LIU.Steam reforming of bio-oil from rice husks fast pyrolysis for hydrogen production[J].Bioresource Technology,2011,102:9236~9240.
[19]袁丽霞.电催化水蒸气重整生物油及乙醇制氢的基础应用研究[D].安徽:中国科技大学,2008.
[20]YANG X L,ZHANG J,ZHU X F,Decomposition and calcination characteristics of calcium-enriched bio-oil[J].Energy Fuels,2008,22:2598~2603.
[2]BALAT M.Mechanisms of thermo chemical biomass conversion processes.Part 3:Reactions of liquefy action[J].Energy Sources,2008,30(7):649~659.
[3]王勇,邹献武,秦特夫.生物质转化及生物质油精制的研究进展[J].化学与生物工程,2010,27(9):1~5.
[4]PISKORZ J,MAJERSKI P,RADILEIN D,et a1.Conversion of Liginins to Hydrocarbon Fuels[J].Energy&Fuels,1989,(3):723~726.
[5]SOLTES E J,LIN S C K,SHEU Y H E.Catalyst specificities in high pressure hydroprocessing of pyrolysis and gasification tars[J].Prepr Pap,Am Chem Soc,Div Fuel Chem,1987,32:229~239.
[6]ZHANG XINGHUA,CHEN LUNGANG,KONG WEI,etal.Upgrading of bio-oil to boiler fuel by catalytic hydrotreatment and esterification in an efficient process[J].Energy,2015,84:83~90.
[7]刘荣厚,黄彩霞,蔡均猛,等.生物质热裂解生物油精制的研究进展[J].农业工程学报,2008,24(3):308~312.
[8]马文超,陈娇娇,王铁军,等.生物油模型化合物催化裂解机理[J].农业工程学报,2013,(9):207~213.
[9]郭晓亚,颜涌捷,李庭琛,等.生物质裂解油催化裂解精制[J].过程工程学报,2003,3(1):91~95.
[10]张琦,常杰,王铁军,等.生物质裂解油的性质及精制研究进展[J].石油化工,2006,35(5):493~498.
[11]王琦,姚燕,王树荣,等.生物油离子交换树脂催化酯化试验研究[J].浙江大学学报:工学,2009,43(5):927~930.
[12]杨续来,CHARLES U.PITTMAN JR,朱锡锋.固体酸催化烯烃改性生物油酚类化合物研究[J].高等学校化学学报,2010,31(7):1398~1404.
[13]KARNJANAKOM S,GUAN G Q,ASEP B,et al.A greenmethod to increase yield and quality of bio-oil:Ultrasonic pretreatment of biomass and catalytic upgrading of bio-oil over meta(Cu,Fe and/or Zn)/γ-Al2O3[J].RSC Advances,2015,101(5):83494~83503.
[14]CHIARAMONTIA D,BONINIA M,FRATINIA E,et al.Development of Emulsions from Biomass Pyrolysis Liquid and Diesel and Their Use in Engines[J].Biomass and Bioenergy,2003(25):85~111.
[15]许细薇,李治宇,庄文俞,等.超声波与添加醇和乳化剂乳化提质热解生物油研究[J].农业机械学报,2017,48(5):320~326.
[16]牛淼淼,黄亚继,金保昇,等.生物油/柴油乳化油制备及其在柴油机上的燃烧试验研究[J].中国电机工程学报,2013,32(20).96-101.
[17]汪永威,汪泽,宋文立,等.生物油水蒸气气化实验研究[J].燃料化学学报,2012,40(2):170~176.
[18]TIANJU CHEN,CENG WU,RONGHOU LIU.Steam reforming of bio-oil from rice husks fast pyrolysis for hydrogen production[J].Bioresource Technology,2011,102:9236~9240.
[19]袁丽霞.电催化水蒸气重整生物油及乙醇制氢的基础应用研究[D].安徽:中国科技大学,2008.
[20]YANG X L,ZHANG J,ZHU X F,Decomposition and calcination characteristics of calcium-enriched bio-oil[J].Energy Fuels,2008,22:2598~2603.