化学氧化法去除微囊藻毒素的研究进展

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英文篇名：Progress in the Removal of Microcystins by Chemical Oxidation 作者：何君 ; 张欣然 ; 杨欣 英文作者：He Jun;Zhang Xinran;Yang Xin;School of Environmental Science and Engineering,Sun Yat-sen University; 关键词：微囊藻毒素 ; 化学氧化降解 ; 动力学 ; 降解机理 ; 降解产物 英文关键词：Microcystins;;Chemical oxidation removal;;Kinetics;;Degradation mechanism;;Products 中文刊名：HXTB 英文刊名：Chemistry 机构：中山大学环境科学与工程学院; 出版日期：2018-11-18 出版单位：化学通报 年：2018 期：v.81 基金：国家自然科学基金项目(51708562,21622706);; 中央高校基本科研业务费专项资金(171gpy93);; 广东省科技计划项目(2017B020216005);; 佛山市科技创新项目(2016AG100991)资助 语种：中文; 页：HXTB201811003 页数：6 CN：11 ISSN：11-1804/O6 分类号：24-28+34

摘要

有害藻类水华污染已经成为世界范围性的环境难题。微囊藻毒素是藻细胞释放的一种毒性物质,具有极强的肝毒性和致癌性。当水源水受到藻类污染时,高效的微囊藻毒素去除技术十分必要。氧化法包括氯化、臭氧、高锰酸盐等化学氧化以及芬顿和基于紫外线的高级氧化,已经成功应用于微囊藻毒素的降解去除。本文综述了各种化学氧化法去除藻毒素的动力学、影响因素、降解机制和产物毒性等方面的研究进展,比较分析了各种氧化法的优、劣以及适用范围,并对未来藻毒素去除技术研究进行了展望,为微囊藻毒素的有效去除提供参考。
        Microcystins(MCs) are water soluble toxic compounds released from cyanobacteria(blue-green algae). MCs may induce apoptosis and promote tumor formation,posing a significant threat to the ecosystem integrity and human health. Recently,an increasing occurrence of toxic cyanobacterial outbreak results in the need of efficient treatment methods for MCs removal. Chemical oxidation processes provide a promising alternative treatment option because they completely degrade MCs and form less toxic by-products. In this paper,the current research status of conventional and advanced oxidation processes(AOPs) for MCs removal,in terms of the degradation efficiency,reaction kinetics,possible degradation mechanism,identity and toxicity of oxidation by-products,are summarized in brief. The advantages and disadvantages of each method are also compared. In addition,further research challenges and needs are also proposed.

引文

[1] G S Bullerjahn,R M Mckay,T W Davis et al. Harmful Algae,2016,54:223~238.
    [2] E P Preece,F J Hardy,B C Moore et al. Harmful Algae,2017,61:31~45.
    [3] V K Sharma,T M Triantis,M G Antoniou et al. Sep. Purif.Technol.,2012,91:3~17.
    [4]万翔,邰义萍,王瑞等.环境科学学报,2017,37(6):2040~2047.
    [5]范亚民,姜伟立,刘宝贵等.湖泊科学,2018,30(1):25~33.
    [6] X He,Y L Liu,A Conklin et al. Harmful Algae,2016,54:174~193.
    [7] J A Westrick,D C Szlag,B J Southwell et al. Anal.Bioanal. Chem.,2010,397(5):1705~1714.
    [8] D Pantelic',Z Svircˇev,J Simeunovic'et al. Chemosphere,2013,91(4):421~441.
    [9] L Chen,J Chen,X Zhang et al. J. Hazard. Mater.,2016,301:381~399.
    [10] A Campos,V Vasconcelos. Int. J. Mol. Sci.,2010,11(1):268~287.
    [11] Z Lun,Y Hai,C Kun. Biomed. Environ. Sci.,2002,15(2):166~171.
    [12] Begura,B Sedmak,M Filipicˇ. Toxicon,2003,41(1):41~48.
    [13] J L Acero,E Rodriguez,J Meriluoto. Water Res.,2005,39(8):1628~1638.
    [14] S Merel,B Lebot,M Clément et al. Chemosphere,2009,74(6):832~839.
    [15] B C Nicholson,J Rositano,M D Burch. Water Res.,1994,28(6):1297~1303.
    [16] A Zamyadi,L Ho,G Newcombe et al. Water Res.,2012,46(5):1524~1535.
    [17] S Merel,M Clément,O Thomas. Toxicon,2010,55(4):677~691.
    [18] L Ho,G Onstad,U V Gunten et al. Water Res.,2006,40(6):1200~1209.
    [19] Y Zhang,Y Shao,N Gao et al. Chem. Eng. J.,2016,287:189~195.
    [20] S Zhou,Y Shao,N Gao et al. Sci. Total Environ.,2014,482-483:208~213.
    [21] Y Ji,J L Huang,J Fu et al. J. China Univ. Mining Technol.,2008,18(4):623~628.
    [22] U Von Gunten. Water Res.,2003,37(7):1443~1467.
    [23] H F Miao,F Qin,G J Tao et al. Chemosphere,2010,79(4):355~361.
    [24] E Rodríguez,G D Onstad,T P J Kull et al. Water Res.,2007,41(15):3381~3393.
    [25] G D Onstad,S Strauch,J Meriluoto et al. Environ. Sci.Technol.,2007,41(12):4397~4404.
    [26] E Rodríguez,M E Majado,J Meriluoto et al. Water Res.,2007,41(1):102~110.
    [27] E Rodríguez,J L Acero,L Spoof et al. Water Res.,2008,42(6):1744~1752.
    [28] B L Yuan,J H Qu,M L Fu. Toxicon,2002,40(8):1129~1134.
    [29]鲁金凤,郭文娟,郭晓燕等.水处理技术,2010,36(4):14~18.
    [30] P J Senogles,J A Scott,G Shaw et al. Water Res.,2001,35(5):1245~1255.
    [31] K Tsuji,T Watanuki,F Kondo et al. Toxicon,1995,33(12):1619~1631.
    [32]刘海勇,刘建广,宋武昌等.净水技术,2017,8:20~25.
    [33] R P Qiao,N Li,X H Qi et al. Toxicon,2005,45(6):745~752.
    [34] G S Shephard,M S Stockenstr,D D Villiers et al. Water Res.,2002,36(1):140~146.
    [35] M G Antoniou,J A Shoemaker,A Armah et al. Toxicon,2008,51(6):1103~1118.
    [36]乔瑞平,漆新华,孙承林等.环境化学,2007,26(5):614~617.
    [37] Y Zhong,X Jin,R Qiao et al. J. Hazard. Mater.,2009,167(1/3):1114~1118.
    [38] E R Bandala,D Martl'nez,E Martnez et al. Toxicon,2004,43(7):829~832.
    [39] T P J Kull,O T Sj9vall,M K Tammenkoski et al. Environ.Sci. Technol.,2006,40(5):1504~1510.
    [40] F Al Momani,D W Smith,M G El-Din. J. Hazard. Mater.,2008,150(2):238~249.
    [41] M G Antoniou,A A De La Cruz,D D Dionysiou. Environ.Sci. Technol.,2010,44(19):7238~7244.
    [42] X Zhang,J Li,J Y Yang et al. Environ. Sci. Technol.,2016,50(14):7671~7678.
    [43] S Cheng,X Zhang,X Yang et al. Environ. Sci. Technol.,2018,52(4):1806~1816.