随州市环境空气中VOCs的污染特征
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摘要
该文调查了随州市专用汽车涂装VOCs废气产生、治理及排放现状,分别监测典型工业区以及居住区VOCs的排放特征,分析二者排放特征的区别以及典型工业区VOCs季节变化情况。根据调查及分析结果,预测随州市专用汽车涂装VOCs废气减排量,并提出污染控制建议。结果表明,随州市专汽行业对涂装VOCs的治理水平较低,迫切需要对喷涂废气进行收集并进行有效治理。随州市典型工业区VOCs主要污染物有二甲苯、乙苯、甲苯和三甲苯等,而办公居住区VOCs的种类较少且信号强度总体较弱,主要污染物有甲苯、二甲苯、乙苯和环己烷等。从季节变化方面,冬季VOCs浓度比春季高。应从源头管理、淘汰落后工艺产能、末端治理、明确重点控制有机污染物等方面加强对随州市专用汽车涂装行业的污染控制管理。
The present situation of the production, treatment and emission of VOCs exhaust gas in Suizhou was investigated.The emission characteristics of the typical industrial area and the residential area VOCs were monitored respectively. And the difference between the two emission characteristics and the seasonal variation of the typical industrial zone VOCs were analyzed. According to the results of investigation and analysis, the emission reduction of VOCs for special purpose vehicle in Suizhou is predicted, and suggestions for pollution control are put forward. The results show that the level of VOCs treatment in Suizhou's special steam industry is low, so it is urgent to collect and manage the spraying waste gas effectively. The main pollutants in the typical industrial area of Suizhou are xylene, ethylbenzene, toluene and trimethylbenzene, while the types of VOCs in the office residential area are less and the intensity of the signal is weak, and the main pollutants are toluene, xylene,ethylbenzene and cyclohexane. In terms of seasonal variation, the VOCs concentration in winter is higher than that in spring.Therefore, the pollution control management should be strengthened from the source management, the elimination of the backward process capacity, the end treatment, and the clear key control of organic pollutants in Suizhou special automobile painting industry.
The present situation of the production, treatment and emission of VOCs exhaust gas in Suizhou was investigated.The emission characteristics of the typical industrial area and the residential area VOCs were monitored respectively. And the difference between the two emission characteristics and the seasonal variation of the typical industrial zone VOCs were analyzed. According to the results of investigation and analysis, the emission reduction of VOCs for special purpose vehicle in Suizhou is predicted, and suggestions for pollution control are put forward. The results show that the level of VOCs treatment in Suizhou's special steam industry is low, so it is urgent to collect and manage the spraying waste gas effectively. The main pollutants in the typical industrial area of Suizhou are xylene, ethylbenzene, toluene and trimethylbenzene, while the types of VOCs in the office residential area are less and the intensity of the signal is weak, and the main pollutants are toluene, xylene,ethylbenzene and cyclohexane. In terms of seasonal variation, the VOCs concentration in winter is higher than that in spring.Therefore, the pollution control management should be strengthened from the source management, the elimination of the backward process capacity, the end treatment, and the clear key control of organic pollutants in Suizhou special automobile painting industry.
引文
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[15]张远航,邵可声,唐孝炎,等.中国城市光化学烟雾污染研究[J].北京大学学报:自然科学版,1998,34(2/3):392-400.Zhang Yuanhang,Shao Kesheng,Tang Xiaoyan,et al.The study of urban photochemical smog pollution in China[J].Acta Scicentiarum Naturalum Universitis Pekinesis,1998,34(2/3):392-400.
[16]Hu Ruoyu,Liu Guijian,Zhang Hong,et al.Levels,characteristics and health risk assessment of VOCs in different functional zones of Hefei[J].Ecotoxicology and Environmental Safety,2018,160:301-307.
[17]Sema Yurdakul,Mihriban Civan 1,Oznur Kuntasal.Temporal variations of VOC concentrations in Bursa atmosphere[J].Atmospheric Pollution Research,2018,9:189-206.
[18]姚轶,王浙明,何志桥,等.浙江省木制品行业挥发性有机物排放特征及排放系数[J].环境科学,2016,37(11):4080-4085.Yao Yi,Wang Zheming,He Zhiqiao,et al.Pollution characteristics and emission coefficient of volatile organic compounds from woodwork-making industry in Zhejiang Province[J].Environmental Science,2016,37(11):4080-4085.
[19]Zhang Xueyang,Gao Bin,Creamer Anne Elise.Adsorption of VOCs onto engineered carbon materials:a review[J].Journal of Hazardous Materials,2017,338:102-123.
[20]Seo Hyun Pak,Mi Jin Jeon,Yong Woo Jeon.Study of sulfuric acid treatment of activated carbon used to enhance mixed VOC removal[J].International Biodeterioration&Biodegradation,2016,113:195-200.
[2]Shao M,Zhang Y H,Zeng L M,et al.Ground-level ozone in the Pearl Rivel Delta and the roles of VOC and Noxin its production[J].Jorunal of Environment Manage,2009,90(1):512-518.
[3]Boeglin M L,Wessels D,Henshel D.An investigation of the relationship between air emissions of volatile organic compounds and the incidence of cancer in Indiana counties[J].Environmental Research,2006,100(2):242-254.
[4]王倩,王红丽,周来东,等.成都市夏季大气挥发性有机物污染及其对二次有机气溶胶生成的贡献[J].环境污染与防治,2015,37(7):6-12.Wang Qian,Wang Hongli,Zhou Laidong,et al.Pollution of volatile organic compounds and their contribution to thesecondary organic aerosol formation in summer of Chengdu[J].Environmental Pollution&Control,2015,37(7):6-12.
[5]陆建海,董事壁,李文娟,等.浙江省工业涂装VOCs治理现状[J].环境保护科学,2018,44(1):113-117.Lu Jianhai,Dong Shibi,Li Wenjuan,et al.Present situation of VOCs control technologies for theindustrial coating process in Zhejiang Province[J].Environmental Protection Science,2018,44(1):113-117.
[6]杨忠平,王浙明,何志桥,等.浙江省汽摩配行业挥发性有机物排放特征及排放系数[J].环境科学,2018,39(2):551-556.Yang Zhongping,Wang Zheming,He Zhiqiao,et al.Pollution characteristics and emission coefficient of volatile organic compounds from auto/motorcycle parts&accessories manufacturing in Zhejiang Province[J].Environmental Science,2018,39(2):551-556.
[7]夏思佳,乔月珍,穆肃,等.江苏省典型汽车涂装企业VOCs排放特征与污染控制技术[J].环境监控与预警,2017,9(6):19-23.Xia Sijia,Qiao Yuezhen,Mu Su,et al.Emission characteristics and control of VOCs for typical automotive coating enterprise in Jiangsu[J].Environmental Monitoring and Forewarning,2017,9(6):19-23.
[8]张华钢,孔小莉,陈霞.十堰市汽车涂装VOCs污染状况及变化趋势分析[J].中国环境管理干部学院学报,2015,25(3):90-93.Zhang Huagang,Kong Xiaoli,Chen Xia.Pollution status and trend analysis of VOCs in car coatings of Shiyan City[J].Journal of Environmental Management College of China,2015,25(3):90-93.
[9]卢滨,黄成,卢清,等.杭州市工业源VOCs排放清单及排放特征[J].环境科学,2018,39(2):533-542.Lu Bin,Huang Cheng,Lu Qing,et al.Emission inventory and pollution characteristics of industrial VOCs in Hangzhou,China[J].Environmental Science,2018,39(2):533-542.
[10]高博,王淑娟,范莉茹,等.石家庄大气中优先控制挥发性有机物筛选[J].环境监测管理与技术,2017,29(2):68-71.Gao Bo,Wang Shujuan,Fan Liru,et al.Screening method for priority control volatile organic compounds in ambient air of Shijiazhuang[J].The Administration and Technique of Environmental Monitoring,2017,29(2):68-71.
[11]李友平,唐娅,范忠雨,等.成都市大气环境VOCs污染特征及其健康风险评价[J].环境科学,2018,39(2):576-584.Li Youping,Tang Ya,Fan Zhongyu,et al.Pollution characteristics and health risk assessment of atmospheric VOCs in Chengdu[J].Environmental Science,2018,39(2):576-584.
[12]朱丽波,徐能斌,应红梅,等.宁波市环境空气中VOCs污染状况及变化趋势分析[J].中国环境监测,2012,28(5):24-28.Zhu Libo,Xu Nengbin,Ying Hongmei,et al.Pollution status and trend analysis of volatile organic compounds in the ambient air of Ningbo City[J].Environmental Monitoring in China,2012,28(5):24-28.
[13]孙云杰,陆建刚,赵欣,等.南京市典型交通区与背景区春季大气中VOCs的污染水平与日变化趋势[J].生态与农村环境学报,2015,31(2):151-157.Sun Yunjie,Lu Jiangang,Zhao Xin,et al.Atmospheric VOCs pollution level and its diurnal variation in typical urban traffic area and background area of Nanjing of China in spring[J].Journal of Ecology and Rural Environment,2015,31(2):151-157.
[14]刘彬,李丹,刘振宇,等.天津市夏季挥发性有机物(VOCs)特征分析[J].环境与可持续发展,2018(2):137-139.Liu Bin,Li Dan,Liu Zhenyu,et al.Characteristics of volatile organic compounds(VOCs)in summer of Tianjin[J].Environment and Sustainable Development,2018(2):137-139.
[15]张远航,邵可声,唐孝炎,等.中国城市光化学烟雾污染研究[J].北京大学学报:自然科学版,1998,34(2/3):392-400.Zhang Yuanhang,Shao Kesheng,Tang Xiaoyan,et al.The study of urban photochemical smog pollution in China[J].Acta Scicentiarum Naturalum Universitis Pekinesis,1998,34(2/3):392-400.
[16]Hu Ruoyu,Liu Guijian,Zhang Hong,et al.Levels,characteristics and health risk assessment of VOCs in different functional zones of Hefei[J].Ecotoxicology and Environmental Safety,2018,160:301-307.
[17]Sema Yurdakul,Mihriban Civan 1,Oznur Kuntasal.Temporal variations of VOC concentrations in Bursa atmosphere[J].Atmospheric Pollution Research,2018,9:189-206.
[18]姚轶,王浙明,何志桥,等.浙江省木制品行业挥发性有机物排放特征及排放系数[J].环境科学,2016,37(11):4080-4085.Yao Yi,Wang Zheming,He Zhiqiao,et al.Pollution characteristics and emission coefficient of volatile organic compounds from woodwork-making industry in Zhejiang Province[J].Environmental Science,2016,37(11):4080-4085.
[19]Zhang Xueyang,Gao Bin,Creamer Anne Elise.Adsorption of VOCs onto engineered carbon materials:a review[J].Journal of Hazardous Materials,2017,338:102-123.
[20]Seo Hyun Pak,Mi Jin Jeon,Yong Woo Jeon.Study of sulfuric acid treatment of activated carbon used to enhance mixed VOC removal[J].International Biodeterioration&Biodegradation,2016,113:195-200.