超高浓度电解液的研究进展
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摘要
综述了超高浓度电解液基本的物理化学性质和独特功能,概述了超高浓度电解液对正负极材料的影响及其固体电解质界面膜(SEI)的形成机理,讨论了超高浓度电解液应用于锂离子电池所面临的挑战和亟待解决的问题,展望了超高浓度电解液未来发展的方向。
This paper reviews the basic physicochemical properties and unique functions of ultra-high concentration electrolytes,summarizes the effects of ultrahigh concentration electrolytes on positive and negative materials,and describes the formation mechanism of solid electrolyte interface membrane( SEI). It also discusses the challenges and problems in the application of ultrahigh concentration electrolytes for lithium-ion batteries and prospects the development of ultra-high concentration electrolytes.
This paper reviews the basic physicochemical properties and unique functions of ultra-high concentration electrolytes,summarizes the effects of ultrahigh concentration electrolytes on positive and negative materials,and describes the formation mechanism of solid electrolyte interface membrane( SEI). It also discusses the challenges and problems in the application of ultrahigh concentration electrolytes for lithium-ion batteries and prospects the development of ultra-high concentration electrolytes.
引文
[1]闫金定.锂离子电池发展现状及其前景分析[J].航空学报,2014,35(10):2767-2775.
[2]夏兰,余林颇,胡笛,等.锂离子电池高电压和耐燃电解液研究进展[J].化学学报,2017,75(12):1183-1195.
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[4]马国强,蒋志敏,陈慧闯,等.基于锂盐的新型锂电池电解质研究进展[J].无机材料学报,2018,33(7):699-710.
[5]Mckinnon W R,Dahn J R.How to reduce the cointercalation of propylene carbonate in LixZr S2and other layered compounds[J]. J Electrochem Soc Journal of the Electrochemical Society,1985,132,2(2):364-366.
[6]Pappenfus T M,Henderson W A,Owens B B,et al. Complexes of lithium imide salts with tetraglyme and their polyelectrolyte composite materials[J]. Journal of the Electrochemical Society,2004,151(2):A209-A215.
[7]Jeong S K,Inaba M,Iriyama Y,et al.AFM study of surface film formation on a composite graphite electrode in lithium-ion batteries[J].Journal of Power Sources,2003,119(6):555-560.
[8]Jeong S K,Inaba M,Iriyama Y,et al.Interfacial reactions between graphite electrodes and propylene carbonate-based solutions:Electrolyte-concentration dependence of electrochemical lithium intercalation reaction[J].Journal of Power Sources,2008,175(1):540-546.
[9]Suo L,Hu Y S,Li H,et al.A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries[J]. Nature Communications,2013,4(2):1481.
[10]Qian J,Henderson W A,Xu W,et al.High rate and stable cycling of lithium metal anode[J]. Nature Communications,2015,6:6362-6368.
[11]Matsumoto K,Inoue K,Nakahara K,et al.Suppression of aluminum corrosion by using high concentration Li TFSI electrolyte[J].Journal of Power Sources,2013,231(2):234-238.
[12]Yamada Y,Usui K,Chiang C H,et al. General observation of lithium intercalation into graphite in ethylene-carbonate-free superconcentrated electrolytes[J]. Acs Applied Materials&Interfaces,2014,6(14):10892-10899.
[13]Yamada Y,Yamada A. Review——Superconcentrated electrolytes for lithium batteries[J]. Journal of the Electrochemical Society,2015,162(14):A2406-A2423.
[14]Mcowen D W,Seo D M,Borodin O,et al.Electronic supplementary material-concentrated electrolytes:Decrypting electrolyte properties and reassessing Al corrosion mechanisms[J]. Energy Environ Sci,2014,1(1):416-426.
[15]Yoshida K,Nakamura M,Kazue Y,et al. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes[J]. Journal of the American Chemical Society,2011,133(33):13121-13129.
[16]Yamada Y. Developing new functionalities of superconcentrated electrolytes for lithium-ion batteries[J]. Electrochemistry,2017,85(9):559-565.
[17]Petibon R,Aiken C P,Ma L,et al.The use of ethyl acetate as a sole solvent in highly concentrated electrolyte for Li-ion batteries[J].Electrochimica Acta,2015,154(154):287-293.
[18]Mcowen D W,Seo D M,Borodin O,et al.Electronic supplementary material-concentrated electrolytes:Decrypting electrolyte properties and reassessing Al corrosion mechanisms[J]. Energy Environ Sci,2014,1(1):416-426.
[19]Lu D,Tao J,Yan P,et al.Formation of reversible solid electrolyte interface on graphite surface from concentrated electrolytes[J].Nano Lett,2017,17(3):1602-1609.
[20]Matsumoto K,Inoue K,Nakahara K,et al.Suppression of aluminum corrosion by using high concentration Li TFSI electrolyte[J].Journal of Power Sources,2013,231(2):234-238.
[21]Wang J,Yamada Y,Sodeyama K,et al. Superconcentrated electrolytes for a high-voltage lithium-ion battery[J]. Nature Communications,2016,7:12032-12039.
[22]Nie M,Abraham D P,Seo D M,et al.Role of solution structure in solid electrolyte interphase formation on graphite with Li PF6in propylene carbonate[J]. Journal of Physical Chemistry C,2013,117(48):25381-25389.
[23]Yamada Y,Chiang C H,Sodeyama K,et al. Corrosion prevention mechanism of aluminum metal in superconcentrated electrolytes[J].Chemelectrochem,2016,2(11):1687-1694.
[24]Kim J H,Jeong S K.Interfacial reactions between graphite and propylene carbonate-based solution after pre-generating a solid electrolyte interface[J]. Materials Research Innovations,2015,19(S1):207-209.
[25]Fang Z,Suo L,Ma J,et al.Optimized solvent-in-salt electrolytes for high-energy rechargeable metallic lithium batteries[C].International Meeting on Lithium Batteries,2014.
[26]BarréA,Deguilhem B,Grolleau S,et al. A review on lithium-ion battery ageing mechanisms and estimations for automotive applications[J].Power Sources,2013,241:680-689.
[27]Jow T R,Xu K,Borodin O,et al. Electrolytes for lithium and lithium-ion batteries[M].New York:Springer New York,2014.
[28]Wang M,Huai L,Hu G,et al.Effect of Li FSI concentrations to form thickness-and modulus-controlled sei layers on lithium metal anodes[J]. Journal of Physical Chemistry C,2018,122(18):9825-9834.
[29]Tsuzuki S,Shinoda W,Matsugami M,et al. Structures of[Li(glyme)](+)complexes and their interactions with anions in equimolar mixtures of glymes and Li[TFSA]:Analysis by molecular dynamics simulations[J]. Physical Chemistry Chemical Physics,2015,17(1):126-129.
[30]Yamada Y,Takazawa Y,Miyazaki K,et al.Electrochemical lithium intercalation into graphite in dimethyl sulfoxide-based electrolytes:Effect of solvation structure of lithium ion[J]. Journal of Physical Chemistry C,2010,114(26):11680-11685.
[2]夏兰,余林颇,胡笛,等.锂离子电池高电压和耐燃电解液研究进展[J].化学学报,2017,75(12):1183-1195.
[3]Yamada Y,Yaegashi M,Abe T,et al. A superconcentrated ether electrolyte for fast-charging Li-ion batteries[J]. Chemical Communications,2013,49(95):11194-11196.
[4]马国强,蒋志敏,陈慧闯,等.基于锂盐的新型锂电池电解质研究进展[J].无机材料学报,2018,33(7):699-710.
[5]Mckinnon W R,Dahn J R.How to reduce the cointercalation of propylene carbonate in LixZr S2and other layered compounds[J]. J Electrochem Soc Journal of the Electrochemical Society,1985,132,2(2):364-366.
[6]Pappenfus T M,Henderson W A,Owens B B,et al. Complexes of lithium imide salts with tetraglyme and their polyelectrolyte composite materials[J]. Journal of the Electrochemical Society,2004,151(2):A209-A215.
[7]Jeong S K,Inaba M,Iriyama Y,et al.AFM study of surface film formation on a composite graphite electrode in lithium-ion batteries[J].Journal of Power Sources,2003,119(6):555-560.
[8]Jeong S K,Inaba M,Iriyama Y,et al.Interfacial reactions between graphite electrodes and propylene carbonate-based solutions:Electrolyte-concentration dependence of electrochemical lithium intercalation reaction[J].Journal of Power Sources,2008,175(1):540-546.
[9]Suo L,Hu Y S,Li H,et al.A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries[J]. Nature Communications,2013,4(2):1481.
[10]Qian J,Henderson W A,Xu W,et al.High rate and stable cycling of lithium metal anode[J]. Nature Communications,2015,6:6362-6368.
[11]Matsumoto K,Inoue K,Nakahara K,et al.Suppression of aluminum corrosion by using high concentration Li TFSI electrolyte[J].Journal of Power Sources,2013,231(2):234-238.
[12]Yamada Y,Usui K,Chiang C H,et al. General observation of lithium intercalation into graphite in ethylene-carbonate-free superconcentrated electrolytes[J]. Acs Applied Materials&Interfaces,2014,6(14):10892-10899.
[13]Yamada Y,Yamada A. Review——Superconcentrated electrolytes for lithium batteries[J]. Journal of the Electrochemical Society,2015,162(14):A2406-A2423.
[14]Mcowen D W,Seo D M,Borodin O,et al.Electronic supplementary material-concentrated electrolytes:Decrypting electrolyte properties and reassessing Al corrosion mechanisms[J]. Energy Environ Sci,2014,1(1):416-426.
[15]Yoshida K,Nakamura M,Kazue Y,et al. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes[J]. Journal of the American Chemical Society,2011,133(33):13121-13129.
[16]Yamada Y. Developing new functionalities of superconcentrated electrolytes for lithium-ion batteries[J]. Electrochemistry,2017,85(9):559-565.
[17]Petibon R,Aiken C P,Ma L,et al.The use of ethyl acetate as a sole solvent in highly concentrated electrolyte for Li-ion batteries[J].Electrochimica Acta,2015,154(154):287-293.
[18]Mcowen D W,Seo D M,Borodin O,et al.Electronic supplementary material-concentrated electrolytes:Decrypting electrolyte properties and reassessing Al corrosion mechanisms[J]. Energy Environ Sci,2014,1(1):416-426.
[19]Lu D,Tao J,Yan P,et al.Formation of reversible solid electrolyte interface on graphite surface from concentrated electrolytes[J].Nano Lett,2017,17(3):1602-1609.
[20]Matsumoto K,Inoue K,Nakahara K,et al.Suppression of aluminum corrosion by using high concentration Li TFSI electrolyte[J].Journal of Power Sources,2013,231(2):234-238.
[21]Wang J,Yamada Y,Sodeyama K,et al. Superconcentrated electrolytes for a high-voltage lithium-ion battery[J]. Nature Communications,2016,7:12032-12039.
[22]Nie M,Abraham D P,Seo D M,et al.Role of solution structure in solid electrolyte interphase formation on graphite with Li PF6in propylene carbonate[J]. Journal of Physical Chemistry C,2013,117(48):25381-25389.
[23]Yamada Y,Chiang C H,Sodeyama K,et al. Corrosion prevention mechanism of aluminum metal in superconcentrated electrolytes[J].Chemelectrochem,2016,2(11):1687-1694.
[24]Kim J H,Jeong S K.Interfacial reactions between graphite and propylene carbonate-based solution after pre-generating a solid electrolyte interface[J]. Materials Research Innovations,2015,19(S1):207-209.
[25]Fang Z,Suo L,Ma J,et al.Optimized solvent-in-salt electrolytes for high-energy rechargeable metallic lithium batteries[C].International Meeting on Lithium Batteries,2014.
[26]BarréA,Deguilhem B,Grolleau S,et al. A review on lithium-ion battery ageing mechanisms and estimations for automotive applications[J].Power Sources,2013,241:680-689.
[27]Jow T R,Xu K,Borodin O,et al. Electrolytes for lithium and lithium-ion batteries[M].New York:Springer New York,2014.
[28]Wang M,Huai L,Hu G,et al.Effect of Li FSI concentrations to form thickness-and modulus-controlled sei layers on lithium metal anodes[J]. Journal of Physical Chemistry C,2018,122(18):9825-9834.
[29]Tsuzuki S,Shinoda W,Matsugami M,et al. Structures of[Li(glyme)](+)complexes and their interactions with anions in equimolar mixtures of glymes and Li[TFSA]:Analysis by molecular dynamics simulations[J]. Physical Chemistry Chemical Physics,2015,17(1):126-129.
[30]Yamada Y,Takazawa Y,Miyazaki K,et al.Electrochemical lithium intercalation into graphite in dimethyl sulfoxide-based electrolytes:Effect of solvation structure of lithium ion[J]. Journal of Physical Chemistry C,2010,114(26):11680-11685.