摘要
将微气泡臭氧化技术与UV照射相结合强化处理酸性大红3R废水,分析了UV强化微气泡臭氧化过程中的臭氧气液传质、酸性大红3R废水脱色和TOC去除效果。结果表明,UV强化微气泡的臭氧传质系数和分解系数分别为单独微气泡臭氧时的1.6、1.2倍。UV强化微气泡臭氧处理酸性大红3R废水的脱色速率常数为0.185 min~(-1),为单独微气泡臭氧处理的1.2倍。TOC去除反应速率常数为0.0255 min~(-1),为单独微气泡臭氧的1.6倍;TOC去除臭氧反应效率为0.1868 mg/mg,为单独微气泡臭氧的1.3倍。
Enhanced treatment of Acid Scarlet 3R wastewater has been implemented by the combination of microbubble ozonation technology with ultraviolet(UV) irradiation. The ozone gas-liquid mass transfer,decolorization of Acid Scarlet 3R wastewater and TOC removing effect in the UV enhanced micro-bubble ozonation process have been analyzed. The results show that the ozone mass transfer coefficient and decomposition coefficient of UV enhanced micro-bubbles are l.6 times and 1.2 times of those by single micro-bubble ozonation,respectively. The decolorization rate constant of Acid Scarlet 3R wastewater treated by UV enhanced micro-bubble ozonation is 0.185 min~(-1),which is 1.2 times of that by single micro-bubble ozonation treatment. The removing reaction rate constant of TOC is 0.0255 min~(-1),which is 1.6 times of that treated by single micro-bubble ozonation. The ozone removing reaction rate of TOC is 0.1868 mg/mg,which is 1.3 times of that treated by single micro-bubble ozonation.
引文
[1]蔡少卿,戴启洲,王佳裕,等.非均相催化臭氧处理高浓度制药废水的研究[J].环境科学学报,2011,3(7):1440-1449.
[2]Zhang Jing,Liu Jiansong,Liu Chun,et al.Characteristics of activated carbon modified with nitric acid and its performance in catalytic ozonation of acid red 3R[J].Advanced Material Research,2013,726-731:1687-1690.
[3]Liu Shu,Wang Qunhui,Ma Hongzhi,et al.Effect of microbubbles on coagulation flotation process of dyeing wastewater[J].Separation and Purification Technology,2010,71(3):337-346.
[4]Takahashi M,Chiba K,Li Pan.Free-radical generation from collapsing microbubbles in the absence of a dynamic stimulus[J].Physical Chemistry B,2007,111(6):1343-1347.
[5]张静,杜亚威,刘晓静,等.臭氧微气泡处理酸性大红3R废水特性研究[J].环境科学,2015,36(2):584-589.
[6]童少平,褚有群,马淳安,等.紫外光在臭氧降解不同有机物过程中的协同作用[J].环境科学学报,2005,25(8):1041-1045.
[7]Bader H,HoignéJ.Determination of ozone in water by the indigo method[J].Water Research,1981,15(4):449-456.
[8]宋仁元,张亚杰,王唯一,等.水和废水标准检验法[M].北京:中国建筑工业出版社,1985:368-370.
[9]李炳智,徐向阳,朱亮.氯代硝基苯类废水臭氧化动力学和机理[J].化工学报,2008,59(8):2111-2120.