核磁共振技术在食用油脂分析中的应用研究进展
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摘要
核磁共振技术作为一种结构鉴定的手段,近年来在食品、医学及化学等领域应用非常广泛。用于食用油脂分析是核磁共振技术在食品领域较早的应用之一。从核磁共振技术在煎炸油品质鉴定、食用油脂掺伪分析、食品或油料含油量分析和食用油脂其他方面的分析4个方面,总结了近年来核磁共振技术在食用油脂分析检测领域的应用研究进展,为进一步开发核磁共振技术在食用油脂分析检测中的新应用提供参考。
As a means of structural identification,nuclear magnetic resonance( NMR) technology has been extensively used in the fields of food,medicine and chemistry in recent years. The application of NMR technology in the analysis of edible oil is part of the earlier applications in the field of food. The application progress of NMR technology in analysis and detection of edible oil was summarized from four aspects,including quality identification of frying oil,adulteration analysis of edible oil,analysis of oil content in oilseeds or food and other aspects of edible oil. It provided some references for further developing the application of NMR technology in analysis and detection of edible oil.
As a means of structural identification,nuclear magnetic resonance( NMR) technology has been extensively used in the fields of food,medicine and chemistry in recent years. The application of NMR technology in the analysis of edible oil is part of the earlier applications in the field of food. The application progress of NMR technology in analysis and detection of edible oil was summarized from four aspects,including quality identification of frying oil,adulteration analysis of edible oil,analysis of oil content in oilseeds or food and other aspects of edible oil. It provided some references for further developing the application of NMR technology in analysis and detection of edible oil.
引文
[1]张瑜,刘睿杰,金青哲,等.低场核磁共振技术检测大豆煎炸油品质的研究[J].中国粮油学报,2014,29(9):115-119.
[2]樊之雄,范柳萍.基于介电常数和低场核磁共振技术的煎炸油品质分析[J].食品工业科技,2012,33(15):74-78.
[3] ZHANG Q,SALEH A S M,SHEN Q. Discrimination of edible vegetable oil adulteration with used frying oil by low field nuclear magnetic resonance[J]. Food Bioprocess Technol,2013,6(9):2562-2570.
[4]王永巍,王欣,刘宝林,等.煎炸油掺伪食用植物油的低场核磁共振检测[C]//科学仪器服务民生学术大会论文集.北京:中国仪器仪表学会,2011.
[5]王欣,夏义苗,史然,等.基于LF-NMR及主成分回归分析的油脂煎炸品质预测[J].中国食品学报,2015,15(4):155-163.
[6]赵婷婷,王欣,刘宝林,等.煎炸猪油掺杂比例对猪油低场核磁共振弛豫特性及脂肪酸组成的影响[J].食品科学,2015,36(1):6-12.
[7]申云刚,肖竹青,陈舜胜,等.低场核磁共振法快速检测煎炸油质量[J].食品科学技术学报,2013,31(5):37-42.
[8]杨雪萍,刘宝林,王欣,等.基于LF-NMR弛豫特性的煎炸油总极性化合物含量定量建模方法[J].食品科学,2014,35(24):110-114.
[9]HEIN M,HENNING H,ISENGARD H D. Determination of total polar parts with new methods for the quality survey of frying fats and oils[J]. Talanta,1998,47(2):447-454.
[10]王永巍,王欣,刘宝林,等.低场核磁共振技术检测煎炸油品质[J].食品科学,2012,33(6):171-175.
[11]史然,王欣,刘宝林,等.大豆油煎炸过程理化指标与LF-NMR弛豫特性的相关性研究[J].分析测试学报,2013,32(6):653-660.
[12] DAIS P. Handbook of olive oil:analysis and properties[M]. New York:Springer,2012.
[13]SACCHI R,ADDEO F,PAOLILLO L.1H and13C NMR of virgin olive oil. An overview[J]. Magn Res Chem,1998,35(13):S133-S145.
[14]VLAHOV G. Application of NMR to the study of olive oils[J]. Prog Nucl Mag Res Sp,1999,35(4):341-357.
[15]MAVROMOUSTAKOS T,ZERVOU M,BONAS G,et al.A novel analytical method to detect adulteration of virgin olive oil by other oils[J]. J Am Oil Chem Soc,2000,77(4):405-411.
[16]MEJKALOVD,PICCOLO A. High-power gradient diffusion NMR spectroscopy for the rapid assessment of extra-virgin olive oil adulteration[J]. Food Chem,2010,118(1):153-158.
[17]AGIOMYRGIANAKI A,PETRAKIS P V,DAIS P. Detection of refined olive oil adulteration with refined hazelnut oil by employing NMR spectroscopy and multivariate statistical analysis[J]. Talanta,2010,80(5):2165-2171.
[18]VIGLI G,PHILIPPIDIS A,SPYROS A,et al. Classification of edible oils by employing31P and1H NMR spectroscopy in combination with multivariate statistical analysis.A proposal for the detection of seed oil adulteration in virgin olive oils[J]. J Agric Food Chem,2003,51(19):5715-5722.
[19]王晓玲,吴晶,谭明乾.低场核磁共振结合化学计量学方法快速检测掺假核桃油[J].分析测试学报,2015,34(7):789-794.
[20]周凝,刘宝林,王欣,等.米糠毛油掺伪食用植物油的低场核磁共振检测[J].食品与发酵工业,2011,37(3):177-181.
[21]ZVEREV L V,PRUDNIKOV S M,VITYUK B Y,et al.Determination of the main fatty acids in sunflower-seed oil by a nuclear magnetic relaxation technique[J]. J Anal Chem,2001,56(11):1029-1031.
[22]LU R,ZHOU X,WU W,et al. Development of the miniature NMR apparatus for edible oil quality control[J].Appl Magn Res,2014,45(5):461-469.
[23]许秀丽,任荷玲,李娜,等.核磁共振技术在地沟油鉴别中的应用研究[J].检验检疫学刊,2012,22(4):25-31.
[24]毛锐,王欣,史然. LF-NMR结合化学模式识别鉴别油脂种类及餐饮废弃油脂[J].分析测试学报,2017,36(3):372-376.
[25]杨扬,殷乐,尹芳华,等.几种食用油的核磁共振光谱特征与地沟油的快速检测[J].中国油脂,2015,40(7):45-50.
[26] CHALAND B,MARIETTE F,MARCHAL P,et al.1H nuclear magnetic resonance relaxometric characterization of fat and water states in soft and hard cheese[J]. J Dairy Res,2000,67(4):609-618.
[27]TOUSSAINT C A,MDALE F,DAVENEL A,et al. Determination of the lipid content in fish muscle by a selfcalibrated NMR relaxometry method:comparison with classical chemical extraction methods[J]. J Sci Food Agric,2002,82(2):173-178.
[28]PEDERSEN H T,BERG H,LUNDBY F,et al. The multivariate advantage in fat determination in meat by bench-top NMR[J]. Innov Food Sci Emerg Technol,2001,2(2):87-94.
[29]CLAFLIN A E. Rapid determination of moisture and fat in meats by microwave and nuclear magnetic resonance analysis[D]. Texas:Texas A&M University,2013.
[30]NAGY E,LIS I,KRMENDY L,et al. Rapid method for determining fat content in meat by using continuous wave nuclear magnetic resonance(CW-NMR)technique[J]. Acta Aliment,2000,29(4):353-357.
[31]曹玉坡,刘义军,黄晖,等.应用低场核磁共振技术测定腰果仁中的含油量[J].食品与发酵科技,2016,52(5):71-74.
[32]蔡坚,刘喻娟,张应中,等.核磁共振法测定高州油茶种仁含油率试验[J].林业工程学报,2013,27(3):92-95.
[33]刘喻娟,蔡坚,张应中,等.核磁共振法测定广宁红花油茶含油率研究[J].广东农业科学,2012,39(20):91-93.
[34]肖志红,李昌珠,陈永忠,等.核磁共振法测油茶籽含油率的研究[J].粮油加工,2008(10):55-56.
[35]雷蕾,梁慧,彭彤,等.核磁共振法测麻疯树种子油含量的研究[J].种子,2009,28(5):78-80.
[36]王竹云,杨翠玲.核磁共振法在油菜种子含油量分析中的应用[J].分析仪器,2001(3):21-24.
[37]王小萍,张庶社.核磁共振法在油菜籽含油量测定技术中的应用[J].粮油仓储科技通讯,2006(5):43-44.
[38]罗援朝. MCY-4脉冲核磁共振含油含水分析仪[J].中国油脂,2008,33(4):78-79.
[39]马宏,马建雄.核磁共振含油量测试仪在粮油检验中的应用[J].中国油脂,1991,16(1):31-36.
[40]徐全生,张桂芳,向阳.核磁共振含油量测试仪在油菜籽含油量测定中的应用[J].粮油仓储科技通讯,1988(6):16-18.
[41]徐宁,董红健,万忠民,等.低场核磁技术测定菜籽含油率[J].粮油仓储科技通讯,2015(4):50-52.
[42]张钟华,贺青,李正坤.核磁共振法快速测量大豆含油量[C]//中国科协2005年学术年会分会场——农产品食品安全与品质检测技术学术研讨会.广州:中国科学技术协会,2005.
[43]徐玉书,许静.脉冲核磁共振油料种子含油量测定仪[J].电测与仪表,1989(1):40-42.
[44]徐玉书.利用核磁共振方法测定油料种子含油量[J].大豆科学,1990,9(2):177-182.
[45]宋同明.脉冲核磁共振仪(Pulsed NMR)对作物种子含油量的快速测定[J].作物学报,1989,15(2):160-166.
[46]陈利华,王欣,朱文冉,等. 3种油脂抗氧化剂的低场核磁共振弛豫特性变化规律的主成分分析[J].食品与发酵工业,2016,42(5):91-96.
[47]徐爱军,俞金波,张榴萍,等.油脂固体脂肪含量测定影响因素探讨[J].粮油加工,2010(9):26-29.
[48]陈琼,杨雪,赵金利,等.酶法制备甘油二酯与甘油三酯的结晶特性研究[J].中国油脂,2015,40(11):48-53.
[49]刘尊,仇超颖,宋佳,等.脂肪酶催化饱和单甘酯与棕榈油酯交换制备含甘油二酯油及其结晶特性研究[J].中国油脂,2017,42(6):44-49.
[50]刘纯友,马美湖,王庆玲,等.核磁共振技术在食品脂质研究中的应用新进展[J].食品工业科技,2017,38(12):342-346.
[51] BARISON A,DA S C,CAMPOS F R,et al. A simple methodology for the determination of fatty acid composition in edible oils through1H NMR spectroscopy[J]. Magn Res Chem,2011,48(8):642-650.
[52]BRATU A,MIHALACHE M,HANGANU A,et al. Quantitative determination of fatty acids from fish oils using GC-MS method and1H NMR spectroscopy[J]. UPB Sci Bull,2013,75(2):23-32.
[53]SICILIANO C,BELSITO E,DE M R,et al. Quantitative determination of fatty acid chain composition in pork meat products by high resolution1H NMR spectroscopy[J].Food Chem,2013,136(2):546-554.
[2]樊之雄,范柳萍.基于介电常数和低场核磁共振技术的煎炸油品质分析[J].食品工业科技,2012,33(15):74-78.
[3] ZHANG Q,SALEH A S M,SHEN Q. Discrimination of edible vegetable oil adulteration with used frying oil by low field nuclear magnetic resonance[J]. Food Bioprocess Technol,2013,6(9):2562-2570.
[4]王永巍,王欣,刘宝林,等.煎炸油掺伪食用植物油的低场核磁共振检测[C]//科学仪器服务民生学术大会论文集.北京:中国仪器仪表学会,2011.
[5]王欣,夏义苗,史然,等.基于LF-NMR及主成分回归分析的油脂煎炸品质预测[J].中国食品学报,2015,15(4):155-163.
[6]赵婷婷,王欣,刘宝林,等.煎炸猪油掺杂比例对猪油低场核磁共振弛豫特性及脂肪酸组成的影响[J].食品科学,2015,36(1):6-12.
[7]申云刚,肖竹青,陈舜胜,等.低场核磁共振法快速检测煎炸油质量[J].食品科学技术学报,2013,31(5):37-42.
[8]杨雪萍,刘宝林,王欣,等.基于LF-NMR弛豫特性的煎炸油总极性化合物含量定量建模方法[J].食品科学,2014,35(24):110-114.
[9]HEIN M,HENNING H,ISENGARD H D. Determination of total polar parts with new methods for the quality survey of frying fats and oils[J]. Talanta,1998,47(2):447-454.
[10]王永巍,王欣,刘宝林,等.低场核磁共振技术检测煎炸油品质[J].食品科学,2012,33(6):171-175.
[11]史然,王欣,刘宝林,等.大豆油煎炸过程理化指标与LF-NMR弛豫特性的相关性研究[J].分析测试学报,2013,32(6):653-660.
[12] DAIS P. Handbook of olive oil:analysis and properties[M]. New York:Springer,2012.
[13]SACCHI R,ADDEO F,PAOLILLO L.1H and13C NMR of virgin olive oil. An overview[J]. Magn Res Chem,1998,35(13):S133-S145.
[14]VLAHOV G. Application of NMR to the study of olive oils[J]. Prog Nucl Mag Res Sp,1999,35(4):341-357.
[15]MAVROMOUSTAKOS T,ZERVOU M,BONAS G,et al.A novel analytical method to detect adulteration of virgin olive oil by other oils[J]. J Am Oil Chem Soc,2000,77(4):405-411.
[16]MEJKALOVD,PICCOLO A. High-power gradient diffusion NMR spectroscopy for the rapid assessment of extra-virgin olive oil adulteration[J]. Food Chem,2010,118(1):153-158.
[17]AGIOMYRGIANAKI A,PETRAKIS P V,DAIS P. Detection of refined olive oil adulteration with refined hazelnut oil by employing NMR spectroscopy and multivariate statistical analysis[J]. Talanta,2010,80(5):2165-2171.
[18]VIGLI G,PHILIPPIDIS A,SPYROS A,et al. Classification of edible oils by employing31P and1H NMR spectroscopy in combination with multivariate statistical analysis.A proposal for the detection of seed oil adulteration in virgin olive oils[J]. J Agric Food Chem,2003,51(19):5715-5722.
[19]王晓玲,吴晶,谭明乾.低场核磁共振结合化学计量学方法快速检测掺假核桃油[J].分析测试学报,2015,34(7):789-794.
[20]周凝,刘宝林,王欣,等.米糠毛油掺伪食用植物油的低场核磁共振检测[J].食品与发酵工业,2011,37(3):177-181.
[21]ZVEREV L V,PRUDNIKOV S M,VITYUK B Y,et al.Determination of the main fatty acids in sunflower-seed oil by a nuclear magnetic relaxation technique[J]. J Anal Chem,2001,56(11):1029-1031.
[22]LU R,ZHOU X,WU W,et al. Development of the miniature NMR apparatus for edible oil quality control[J].Appl Magn Res,2014,45(5):461-469.
[23]许秀丽,任荷玲,李娜,等.核磁共振技术在地沟油鉴别中的应用研究[J].检验检疫学刊,2012,22(4):25-31.
[24]毛锐,王欣,史然. LF-NMR结合化学模式识别鉴别油脂种类及餐饮废弃油脂[J].分析测试学报,2017,36(3):372-376.
[25]杨扬,殷乐,尹芳华,等.几种食用油的核磁共振光谱特征与地沟油的快速检测[J].中国油脂,2015,40(7):45-50.
[26] CHALAND B,MARIETTE F,MARCHAL P,et al.1H nuclear magnetic resonance relaxometric characterization of fat and water states in soft and hard cheese[J]. J Dairy Res,2000,67(4):609-618.
[27]TOUSSAINT C A,MDALE F,DAVENEL A,et al. Determination of the lipid content in fish muscle by a selfcalibrated NMR relaxometry method:comparison with classical chemical extraction methods[J]. J Sci Food Agric,2002,82(2):173-178.
[28]PEDERSEN H T,BERG H,LUNDBY F,et al. The multivariate advantage in fat determination in meat by bench-top NMR[J]. Innov Food Sci Emerg Technol,2001,2(2):87-94.
[29]CLAFLIN A E. Rapid determination of moisture and fat in meats by microwave and nuclear magnetic resonance analysis[D]. Texas:Texas A&M University,2013.
[30]NAGY E,LIS I,KRMENDY L,et al. Rapid method for determining fat content in meat by using continuous wave nuclear magnetic resonance(CW-NMR)technique[J]. Acta Aliment,2000,29(4):353-357.
[31]曹玉坡,刘义军,黄晖,等.应用低场核磁共振技术测定腰果仁中的含油量[J].食品与发酵科技,2016,52(5):71-74.
[32]蔡坚,刘喻娟,张应中,等.核磁共振法测定高州油茶种仁含油率试验[J].林业工程学报,2013,27(3):92-95.
[33]刘喻娟,蔡坚,张应中,等.核磁共振法测定广宁红花油茶含油率研究[J].广东农业科学,2012,39(20):91-93.
[34]肖志红,李昌珠,陈永忠,等.核磁共振法测油茶籽含油率的研究[J].粮油加工,2008(10):55-56.
[35]雷蕾,梁慧,彭彤,等.核磁共振法测麻疯树种子油含量的研究[J].种子,2009,28(5):78-80.
[36]王竹云,杨翠玲.核磁共振法在油菜种子含油量分析中的应用[J].分析仪器,2001(3):21-24.
[37]王小萍,张庶社.核磁共振法在油菜籽含油量测定技术中的应用[J].粮油仓储科技通讯,2006(5):43-44.
[38]罗援朝. MCY-4脉冲核磁共振含油含水分析仪[J].中国油脂,2008,33(4):78-79.
[39]马宏,马建雄.核磁共振含油量测试仪在粮油检验中的应用[J].中国油脂,1991,16(1):31-36.
[40]徐全生,张桂芳,向阳.核磁共振含油量测试仪在油菜籽含油量测定中的应用[J].粮油仓储科技通讯,1988(6):16-18.
[41]徐宁,董红健,万忠民,等.低场核磁技术测定菜籽含油率[J].粮油仓储科技通讯,2015(4):50-52.
[42]张钟华,贺青,李正坤.核磁共振法快速测量大豆含油量[C]//中国科协2005年学术年会分会场——农产品食品安全与品质检测技术学术研讨会.广州:中国科学技术协会,2005.
[43]徐玉书,许静.脉冲核磁共振油料种子含油量测定仪[J].电测与仪表,1989(1):40-42.
[44]徐玉书.利用核磁共振方法测定油料种子含油量[J].大豆科学,1990,9(2):177-182.
[45]宋同明.脉冲核磁共振仪(Pulsed NMR)对作物种子含油量的快速测定[J].作物学报,1989,15(2):160-166.
[46]陈利华,王欣,朱文冉,等. 3种油脂抗氧化剂的低场核磁共振弛豫特性变化规律的主成分分析[J].食品与发酵工业,2016,42(5):91-96.
[47]徐爱军,俞金波,张榴萍,等.油脂固体脂肪含量测定影响因素探讨[J].粮油加工,2010(9):26-29.
[48]陈琼,杨雪,赵金利,等.酶法制备甘油二酯与甘油三酯的结晶特性研究[J].中国油脂,2015,40(11):48-53.
[49]刘尊,仇超颖,宋佳,等.脂肪酶催化饱和单甘酯与棕榈油酯交换制备含甘油二酯油及其结晶特性研究[J].中国油脂,2017,42(6):44-49.
[50]刘纯友,马美湖,王庆玲,等.核磁共振技术在食品脂质研究中的应用新进展[J].食品工业科技,2017,38(12):342-346.
[51] BARISON A,DA S C,CAMPOS F R,et al. A simple methodology for the determination of fatty acid composition in edible oils through1H NMR spectroscopy[J]. Magn Res Chem,2011,48(8):642-650.
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