环氧乙烷银催化剂技术进展
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摘要
环氧乙烷/乙二醇是第二大乙烯衍生物及重要的有机合成原料,银催化剂技术是工业生产环氧乙烷/乙二醇的核心。综述了银催化剂的制备与应用技术,系统总结并分析了中国石化YS系列银催化剂的研发、创新和应用情况,并对未来国产银催化剂的研究、开发和工业应用提出了发展建议。
Ethylene oxide/ethylene glycol is the second largest ethylene derivative and an important raw material for organic synthesis. Silver catalyst technology is the core of industrial production of ethylene oxide/ethylene glycol. The preparation and application technology of silver catalysts are reviewed. The research,innovation and application of YS silver catalysts in Sinopec are systematically summarized and analyzed. Some suggestions for future research,development and industrial application of domestic silver catalysts are put forward.
Ethylene oxide/ethylene glycol is the second largest ethylene derivative and an important raw material for organic synthesis. Silver catalyst technology is the core of industrial production of ethylene oxide/ethylene glycol. The preparation and application technology of silver catalysts are reviewed. The research,innovation and application of YS silver catalysts in Sinopec are systematically summarized and analyzed. Some suggestions for future research,development and industrial application of domestic silver catalysts are put forward.
引文
[1]Scientific Design Company,Inc.Method for producing porous bodies with enhanced properties:US10124318[P].2016-06-02.
[2]中国石油化工股份有限公司.催化剂载体及制备方法和由该载体制备的催化剂及其应用:103769233 B[P].2016-03-30.
[3]中国石油化工股份有限公司.制备用于银催化剂的氧化铝载体的方法及其银催化剂:103357437 B[P].2016-03-30.
[4]Norton Chemical Process Products Corporation.Catalyst carrier:WO9740932 A1[P].1997-11-06.
[5]Shell Int Research.A method of preparing a shaped catalyst,the catalyst,and use of the catalyst:EP1912738 A1[P].2008-04-23.
[6]国际壳牌研究有限公司.含银催化剂及其制备方法和用途:102000567 A[P].2011-04-06.
[7]Shell Oil Company.Catalyst composition:US7741499[P].2007-05-09.
[8]Saudi Basic Industries Corporation.Catalyst for epoxidation of an alkene to an alkene oxide,method of making and method of using thereof:US7655596[P].2010-02-02.
[9]Shell Oil Company.Carrier,a process for preparing the carrier,an olefin epoxidation catalyst,a process for preparing the catalyst,and a process for the production of an olefin oxide,a 1,2-diol,a 1,2-diol ether,or an alkanolamine:US7713903[P].2010-05-11.
[10]中国石油化工股份有限公司.用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用:1232349 C[P].2005-12-21.
[11]Scientific Design Co.,Inc.Ethylene oxide catalyst:US6858560[P].2003-04-23.
[12]Shell Int Research.A process for the production of an olefin oxide,a 1,2-diol,a 1,2-diol ether,or an alkanolamine:EP1765800 A2[P].2007-03-28.
[13]陶氏环球技术公司.α-氧化铝的成形多孔体及其制备方法:101534938[P].2009-09-16.
[14]Shell Oil Company.Manufacture of olefine oxides:US2040782[P].1936-05-12.
[15]林强,覃成鹏,沈洋,等.乙烯环氧化反应中银催化剂助剂的研究进展[J].工业催化,2013,21(2):1-7.
[16]Atkins M,Couves J,Hague M,et al.On the role of Cs,Cl and subsurface O in promoting selectivity in Ag/alpha-Al2O3catalysed oxidation of ethene to ethene epoxide[J].J Catal,2005,235(1):103-113.
[17]Minahan D M,Hoflund G B,Epling W S,et al.Study of Cs-promoted,α-alumina-supported silver,ethylene epoxidation catalystsⅢ.Characterization of Cs-promoted and nonpromoted catalysts[J].J Catal,1997,168(2):393-399.
[18]Deng Jingfa,Yang Jun,Zhang Shi,et al.Promoting effects of Re and Cs on silver catalyst in ethylene epoxidation[J].JCatal,1992,138(1):395-399.
[19]Dellamorte J C,Lauterbach J,Barteau M A.Rhenium promotion of Ag and Cu-Ag bimetallic catalysts for ethylene epoxidation[J].Catal Today,2007,120:182-185.
[20]Velocys Inc.Process for converting ethylene to ethylene oxide using microchannel process technology:EP1786797 A1[P].2007-05-23.
[21]Shell Oil Company and Shell Int Research.A process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide:WO2007076400 A3[P].2007-10-25.
[22]BASF SE.Method for production of ethylene oxide in a microchannel reactor:EP2013194 A2[P].2009-01-14.
[23]巴斯夫欧洲公司.在微通道反应器中制备环氧乙烷的方法:101448804[P].2009-06-03.
[24]万罗赛斯公司.使用微通道工艺技术制造环氧乙烷的方法:102099345 A[P].2011-06-15.
[25]国际壳牌研究有限公司.制备环氧乙烷的方法:100400524C[P].2008-07-09.
[26]国际壳牌研究有限公司.制备环氧乙烷的方法:100358881C[P].2008-01-02.
[27]Shell Int Research.A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin:EP1517751 A2[P].2005-03-30.
[28]国际壳牌研究有限公司.提高催化剂选择性的方法和烯烃环氧化方法:1665594[P].2005-09-07.
[29]Shell Oil Company and Shell Int Research.A process for treating a catalyst,the catalyst,and use of the catalyst:WO2007092738 A3[P].2008-04-10.
[30]SD Lizenzverwertungsgesellschaft mbH&Co.KG.Process for initiating a highly selective ethylene oxide catalyst:US7553980[P].2009-06-30.
[31]Shell Oil Company.Process for starting-up an ethylene oxide reactor:US4874879[P].1989-10-17.
[32]国际壳牌研究有限公司.环氧化方法的开车方法、烯烃环氧化的催化剂和方法:1665796[P].2005-09-07.
[33]Shell Oil Company.Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin:US7102022[P].2006-09-05.
[34]Dow Technology Investments LLC.Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages:WO2010123842[P].2010-10-28.
[35]Ren Dongmei,Xu Haoxiang,Li Jianwei,et al.Origin of enhanced ethylene oxide selectivity by Cs-promoted silver catalyst[J].Mol Catal,2017,441:92-99.
[36]李金兵,张志祥,林强,等.硫酸钡改性对Ag/α-Al2O3催化剂的乙烯环氧化催化性能的影响[J].工业催化,2011,19(12):55-58.
[37]China Petroleum&Chemical Corporation.Carrier for silver catalyst,its preparation,a silver catalyst made from the same and its use:US9144793 B2[P].2015-09-29.
[38]中国石油化工股份有限公司.通过选用不同粒度的水合氧化铝来调变氧化铝载体性能的方法、由此得到的载体及其应用:102145306 B[P].2013-05-01.
[39]中国石油化工股份有限公司.一种用于银催化剂的α-氧化铝载体的制备方法:104707664 B[P].2017-11-07.
[40]中国石油化工股份有限公司.一种α-氧化铝载体及其制备方法:103566981 B[P].2015-09-16.
[41]中国石油化工股份有限公司.用于环氧乙烷生产用银催化剂的载体其制备方法及其应用:1634652[P].2007-02-28.
[42]中国石油化工股份有限公司.由乙烯生产环氧乙烷的方法:102558099 B[P].2014-11-12.
[43]中国石油化工股份有限公司.一种高效银催化剂催化乙烯氧化制环氧乙烷的方法:103360345 B[P].2015-04-15.
[2]中国石油化工股份有限公司.催化剂载体及制备方法和由该载体制备的催化剂及其应用:103769233 B[P].2016-03-30.
[3]中国石油化工股份有限公司.制备用于银催化剂的氧化铝载体的方法及其银催化剂:103357437 B[P].2016-03-30.
[4]Norton Chemical Process Products Corporation.Catalyst carrier:WO9740932 A1[P].1997-11-06.
[5]Shell Int Research.A method of preparing a shaped catalyst,the catalyst,and use of the catalyst:EP1912738 A1[P].2008-04-23.
[6]国际壳牌研究有限公司.含银催化剂及其制备方法和用途:102000567 A[P].2011-04-06.
[7]Shell Oil Company.Catalyst composition:US7741499[P].2007-05-09.
[8]Saudi Basic Industries Corporation.Catalyst for epoxidation of an alkene to an alkene oxide,method of making and method of using thereof:US7655596[P].2010-02-02.
[9]Shell Oil Company.Carrier,a process for preparing the carrier,an olefin epoxidation catalyst,a process for preparing the catalyst,and a process for the production of an olefin oxide,a 1,2-diol,a 1,2-diol ether,or an alkanolamine:US7713903[P].2010-05-11.
[10]中国石油化工股份有限公司.用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用:1232349 C[P].2005-12-21.
[11]Scientific Design Co.,Inc.Ethylene oxide catalyst:US6858560[P].2003-04-23.
[12]Shell Int Research.A process for the production of an olefin oxide,a 1,2-diol,a 1,2-diol ether,or an alkanolamine:EP1765800 A2[P].2007-03-28.
[13]陶氏环球技术公司.α-氧化铝的成形多孔体及其制备方法:101534938[P].2009-09-16.
[14]Shell Oil Company.Manufacture of olefine oxides:US2040782[P].1936-05-12.
[15]林强,覃成鹏,沈洋,等.乙烯环氧化反应中银催化剂助剂的研究进展[J].工业催化,2013,21(2):1-7.
[16]Atkins M,Couves J,Hague M,et al.On the role of Cs,Cl and subsurface O in promoting selectivity in Ag/alpha-Al2O3catalysed oxidation of ethene to ethene epoxide[J].J Catal,2005,235(1):103-113.
[17]Minahan D M,Hoflund G B,Epling W S,et al.Study of Cs-promoted,α-alumina-supported silver,ethylene epoxidation catalystsⅢ.Characterization of Cs-promoted and nonpromoted catalysts[J].J Catal,1997,168(2):393-399.
[18]Deng Jingfa,Yang Jun,Zhang Shi,et al.Promoting effects of Re and Cs on silver catalyst in ethylene epoxidation[J].JCatal,1992,138(1):395-399.
[19]Dellamorte J C,Lauterbach J,Barteau M A.Rhenium promotion of Ag and Cu-Ag bimetallic catalysts for ethylene epoxidation[J].Catal Today,2007,120:182-185.
[20]Velocys Inc.Process for converting ethylene to ethylene oxide using microchannel process technology:EP1786797 A1[P].2007-05-23.
[21]Shell Oil Company and Shell Int Research.A process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide:WO2007076400 A3[P].2007-10-25.
[22]BASF SE.Method for production of ethylene oxide in a microchannel reactor:EP2013194 A2[P].2009-01-14.
[23]巴斯夫欧洲公司.在微通道反应器中制备环氧乙烷的方法:101448804[P].2009-06-03.
[24]万罗赛斯公司.使用微通道工艺技术制造环氧乙烷的方法:102099345 A[P].2011-06-15.
[25]国际壳牌研究有限公司.制备环氧乙烷的方法:100400524C[P].2008-07-09.
[26]国际壳牌研究有限公司.制备环氧乙烷的方法:100358881C[P].2008-01-02.
[27]Shell Int Research.A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin:EP1517751 A2[P].2005-03-30.
[28]国际壳牌研究有限公司.提高催化剂选择性的方法和烯烃环氧化方法:1665594[P].2005-09-07.
[29]Shell Oil Company and Shell Int Research.A process for treating a catalyst,the catalyst,and use of the catalyst:WO2007092738 A3[P].2008-04-10.
[30]SD Lizenzverwertungsgesellschaft mbH&Co.KG.Process for initiating a highly selective ethylene oxide catalyst:US7553980[P].2009-06-30.
[31]Shell Oil Company.Process for starting-up an ethylene oxide reactor:US4874879[P].1989-10-17.
[32]国际壳牌研究有限公司.环氧化方法的开车方法、烯烃环氧化的催化剂和方法:1665796[P].2005-09-07.
[33]Shell Oil Company.Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin:US7102022[P].2006-09-05.
[34]Dow Technology Investments LLC.Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages:WO2010123842[P].2010-10-28.
[35]Ren Dongmei,Xu Haoxiang,Li Jianwei,et al.Origin of enhanced ethylene oxide selectivity by Cs-promoted silver catalyst[J].Mol Catal,2017,441:92-99.
[36]李金兵,张志祥,林强,等.硫酸钡改性对Ag/α-Al2O3催化剂的乙烯环氧化催化性能的影响[J].工业催化,2011,19(12):55-58.
[37]China Petroleum&Chemical Corporation.Carrier for silver catalyst,its preparation,a silver catalyst made from the same and its use:US9144793 B2[P].2015-09-29.
[38]中国石油化工股份有限公司.通过选用不同粒度的水合氧化铝来调变氧化铝载体性能的方法、由此得到的载体及其应用:102145306 B[P].2013-05-01.
[39]中国石油化工股份有限公司.一种用于银催化剂的α-氧化铝载体的制备方法:104707664 B[P].2017-11-07.
[40]中国石油化工股份有限公司.一种α-氧化铝载体及其制备方法:103566981 B[P].2015-09-16.
[41]中国石油化工股份有限公司.用于环氧乙烷生产用银催化剂的载体其制备方法及其应用:1634652[P].2007-02-28.
[42]中国石油化工股份有限公司.由乙烯生产环氧乙烷的方法:102558099 B[P].2014-11-12.
[43]中国石油化工股份有限公司.一种高效银催化剂催化乙烯氧化制环氧乙烷的方法:103360345 B[P].2015-04-15.