石墨烯的制备及其在锂离子二次电池中的应用研究进展
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摘要
石墨烯是一种独特的二维纳米材料,具有许多特殊的物理化学性质,吸引了众多领域研究者的关注,已成为当今的研究热点之一。介绍了到目前为止石墨烯的主要制备方法及其优缺点,综述了石墨烯在磷酸亚铁锂电池、锂/硫电池、锂/硅电池中的应用,对石墨烯的未来发展前景做了展望。
Graphene,as a novel two-dimensional nanomaterial,was granted with a lot of excellent physical and chemical characteristics.This novel nanomaterial has attracted a lot of investigators and become a key-point for researchers in different fields.Here the popular synthesis methods with their advantages and defects of graphene were introduced,respectively.The application of graphene in lithium iron phosphate battery,lithium sulfur battery and lithium silicon battery is reviewed in details.Finally,the development of graphene in the future was prospected.
Graphene,as a novel two-dimensional nanomaterial,was granted with a lot of excellent physical and chemical characteristics.This novel nanomaterial has attracted a lot of investigators and become a key-point for researchers in different fields.Here the popular synthesis methods with their advantages and defects of graphene were introduced,respectively.The application of graphene in lithium iron phosphate battery,lithium sulfur battery and lithium silicon battery is reviewed in details.Finally,the development of graphene in the future was prospected.
引文
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[33]云强,周园,李翔,等.石墨烯改性LiFePO4正极材料的研究进展[J].电源技术,2015,139(7):1525-1529.
[34]孔令涌,尚伟丽,任诚,等.纳米磷酸铁锂/石墨烯复合正极材料的制备[J].电池,2016,46(1):38-41.
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[38]FANG R P,ZHAO S Y,SUN Z H,et al.More reliable lithium-sulfur batteries:status,solutions and prospects[J].Advanced Materials,2017,29:1606823-1606844.
[39]陈克,孙振华,方若翩,等.锂硫电池用石墨烯基材料的研究进展[J].物理化学学报,2018,34(4):377-390.
[40]朱孟康,王存国,潘璇,等.超大容量锂/硫电池硫基复合电极材料的研究进展[J].化工科技,2016,24(2):83-87.
[41]闫慧敏,李龙燕,陈彦逍,等.石墨烯在锂硫电池中的应用研究进展[J].化工新型材料,2016,44(8):32-37.
[42]徐朝,游慧慧,张磊,等.多硫化物阻隔层在锂硫电池中的应用研究进展[J].新型碳材料,2017,32(2):97-105.
[43]WANG J Z,LU L,CHOUCAIR M,et al.Sulfur-graphene composite for rechargeable lithium batteries[J].Journal of Power Sources,2011,196(16):7030-7034.
[44]PAPANDREAL B,XU X,XU Y X,et al.Three-dimensional graphene framework with ultra-high sulfur content for a robust lithium-sulfur battery[J].Nano Research 2016,9(1):240-248.
[45]MANTHIRAM A,CHUNG S H,ZU C,et al.Lithiumsulfur batteries:progress and prospects[J].Advanced Materials,2015,27(12):1980-2006.
[46]SONG R S,FANG R P,WEN L,et al.A trilayer separator with dual function for high performance lithium-sulfur batteries[J].Journal of Power Sources,2016,301:179-186.
[47]CHENG X B,PENG H J,HUANG J Q,et al.Dual-phase lithium metal anode containing apolysulfide-induced solid electrolyte interphase and nanostructured graphene framework for lithium sulfur batteries[J].ACS Nano,2015,9(6):6373-6382.
[48]梁初,周罗挺,夏阳,等.硅负极材料的储锂机理与电化学改性进展[J].功能材料,2016,47(8):8043-8049.
[49]LUO J Y,ZHAO X,WU J S,et al.Crumpled graphene-encapsulated si nanoparticles for lithium ion battery anodes[J].The Journal of Physical Chemistry Letters,2012,3:1824-1829.
[50]CHANG J B,HUANG X K,ZHOU G H,et al.Multilayered Si nanoparticle/reduced graphene oxide hybrid as a highperformance lithium-ion battery anode[J].Advanced Materials,2014,26:758-764.
[51]FENG K,AHN K,LUI G,et al.Implementing an in-situ carbon network in Si/reduced graphene oxide for high performance lithium-ion battery anodes[J].Nano Energy 2016,19:187-197.
[52]WANG C G,LI Q.Graphene and its applications in lithiumion battery[J].Current Physical Chemistry,2013,3(3):232-254.
[53]王存国,潘璇,张雷,等.高容量锂离子电池核壳型硅/碳复合电极材料的制备与性能[J].高等学校化学学报,2015,36(2):368-374.
[54]DAVID L,BHANDAVAT R,BARRERA U,et al.Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries[J].Nature,2016,7:10998.
[55]潘璇,王存国,朱孟康,等.锂离子电池大容量硅基负极材料的研究进展[J].化工科技,2017,25(1):67-72.
[56]ZHANG L,WANG Y H,KAN G W,et al.Scalable synthesis of porous silicon/carbon microspheres as improved anode materials for lithium ion batteries[J].RSC Advances,2014,4:43114-43120.
[2]IIJIMA S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56-58.
[3]GEIM A K,NOVOSELOV K S,MOROZOV S V,et al.Electricfield effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[4]傅强,包信和.石墨烯的化学研究进展[J].科学通报,2009,54(18):2657-2666.
[5]MEYER J C,GEIM A K,KATSNELSON M I,et al.The structure of suspended graphene sheets[J].Nature,2007,446(7131):60-63.
[6]胡耀娟,金娟,张卉,等.石墨烯的制备、功能化及在化学中的应用[J].物理化学学报,2010,26(8):2073-2086.
[7]LEE C,WEI X D,KYSAR J W,et al.Mearsurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[8]CHEN J H,JANG C,XIAO S D,et al.Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nat Nanotechnol,2008,3:206-209.
[9]BALANDIN A A,GHOSH S,BAO W Z,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letter,2008,8(3):902-907.
[10]孙建敏.Ca、B掺杂对石墨烯和碳纳米管储氢性能影响的第一原理研究[D].重庆:重庆师范大学,2015.
[11]姜小强,刘智波,田建国.石墨烯的光学性质及其应用研究进展[J].物理学进展,2017,37(1):22-36.
[12]赵娟平,李阳春,解念锁.掺杂石墨烯的研究进展[J].热加工工艺,2018,47(10):25-29.
[13]江莞,范宇驰,刘霞,等.机械剥离法制备石墨烯及其在石墨烯/陶瓷复合材料制备中的应用[J].中国材料进展,2011,30(1):12-26.
[14]申保收,冯旺军,郎俊伟,等.电弧放电法制备石墨烯的硝酸改性及其电化学性能増强[J].物理化学学报,2012,28(7):1726-1732.
[15]乔峰,朱海涛.石墨烯制备、表征及应用研究最新进展[J].化工新型材料,2010,38(10):15-17.
[16]吴洪鹏.石墨烯的制备及在超级电容器中的应用[D].北京:北京交通大学,2012.
[17]HUMMERS W S,OFFEMAN R E.Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(6):1339.
[18]STANKOVICH S,DIKIN D A,PINER R D,et al.Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon,2007,45:1558-1565.
[19]TIEN H W,HUANG Y L,YANG S Y,et al.The production of graphene nanosheets decorated with silver nanoparticles for use in transparent,conductive films[J].Carbon,2011,49(5):1550-1560.
[20]万武波,赵宗彬,胡涵,等.柠檬酸钠绿色还原制备石墨烯[J].新型碳材料,2011,26(1):16-20.
[21]ZHENG B,SHUAI X R,MAO S,et al.Green preparation of reduced graphene oxide for sensing and energy storage applications[J].Scientific,2014,4684(4):1-8.
[22]VOIRY D,YANG J,KUPFERBERG J,et al.High-quality graphene via microwave reduction of solution-exfoliated graphene oxide[J].Science,2016,353(6306):1413-1416.
[23]AKHAVAN O.Bacteriorhodopsin as a superior substitute for hydrazine in chemical reduction of single-layer graphene oxide sheets[J].Carbon,2015,81:158-166.
[24]任文才,高力波,马来鹏,等.石墨烯的化学气相沉积法制备[J].新型碳材料,2011,26(1):71-80.
[25]邹鹏,石文荣,杨书华,等.石墨烯的化学气相沉积法制备及其表征[J].材料科学与工程学报,2014,32(2):264-267.
[26]毕瑞可,张杰,吴玉玲,等.化学气相沉积法制备单层石墨烯的优化[J].微纳电子技术,2017,54(3):181-187.
[27]MCNERNY D Q,VISWANATH B,COPIC D,et al.Direct fabrication of graphene on SiO2enabled by thin film stress engineering[J].Scientific Reports,2014,5049(4):1-9.
[28]刘庆彬,蔚翠,何泽召,等.绝缘衬底上化学气相沉积法生长石墨烯材料[J].化工学报,2017,68:276-281.
[29]肖勇,马卫东,孙志勇,等.石墨烯制备与应用研究进展[J].功能材料与器件学报,2017,23(5):125-131.
[30]蔚翠,李佳,刘庆彬,等.Si面4H-SiC衬底上外延石墨烯近平衡态制备[J].物理学报,2014,63(3):038102-038107.
[31]郁万成,陈秀芳,孙丽,等.SiC衬底上外延石墨烯的氢插入及表征[J].人工晶体学报,2015,44(12):3384-3394.
[32]RIEDL C,COLETTI C,IWASAKI T,et al.Quasi-freestanding epitaxial graphene on sic obtained by hydrogen intercalation[J].Physical Review Letters,2009,103(24):246804-246807.
[33]云强,周园,李翔,等.石墨烯改性LiFePO4正极材料的研究进展[J].电源技术,2015,139(7):1525-1529.
[34]孔令涌,尚伟丽,任诚,等.纳米磷酸铁锂/石墨烯复合正极材料的制备[J].电池,2016,46(1):38-41.
[35]WANG Q,PENG D C,CHEN Y X,et al.A facile surfactant-assisted self-assembly of LiFePO4/graphene composites with improved rate performance for lithium ion batteries[J].Journal of Electroanalytical Chemistry,2018,818:68-75.
[36]李绮茹.石墨烯包覆磷酸铁锂正极材料的制备[D].苏州:苏州大学,2016.
[37]SU F Y,HE Y B,LI B,et al.Could graphene construct an effective conducting network in a high-power lithium ion battery[J].Nano Energy,2012,1:429-439.
[38]FANG R P,ZHAO S Y,SUN Z H,et al.More reliable lithium-sulfur batteries:status,solutions and prospects[J].Advanced Materials,2017,29:1606823-1606844.
[39]陈克,孙振华,方若翩,等.锂硫电池用石墨烯基材料的研究进展[J].物理化学学报,2018,34(4):377-390.
[40]朱孟康,王存国,潘璇,等.超大容量锂/硫电池硫基复合电极材料的研究进展[J].化工科技,2016,24(2):83-87.
[41]闫慧敏,李龙燕,陈彦逍,等.石墨烯在锂硫电池中的应用研究进展[J].化工新型材料,2016,44(8):32-37.
[42]徐朝,游慧慧,张磊,等.多硫化物阻隔层在锂硫电池中的应用研究进展[J].新型碳材料,2017,32(2):97-105.
[43]WANG J Z,LU L,CHOUCAIR M,et al.Sulfur-graphene composite for rechargeable lithium batteries[J].Journal of Power Sources,2011,196(16):7030-7034.
[44]PAPANDREAL B,XU X,XU Y X,et al.Three-dimensional graphene framework with ultra-high sulfur content for a robust lithium-sulfur battery[J].Nano Research 2016,9(1):240-248.
[45]MANTHIRAM A,CHUNG S H,ZU C,et al.Lithiumsulfur batteries:progress and prospects[J].Advanced Materials,2015,27(12):1980-2006.
[46]SONG R S,FANG R P,WEN L,et al.A trilayer separator with dual function for high performance lithium-sulfur batteries[J].Journal of Power Sources,2016,301:179-186.
[47]CHENG X B,PENG H J,HUANG J Q,et al.Dual-phase lithium metal anode containing apolysulfide-induced solid electrolyte interphase and nanostructured graphene framework for lithium sulfur batteries[J].ACS Nano,2015,9(6):6373-6382.
[48]梁初,周罗挺,夏阳,等.硅负极材料的储锂机理与电化学改性进展[J].功能材料,2016,47(8):8043-8049.
[49]LUO J Y,ZHAO X,WU J S,et al.Crumpled graphene-encapsulated si nanoparticles for lithium ion battery anodes[J].The Journal of Physical Chemistry Letters,2012,3:1824-1829.
[50]CHANG J B,HUANG X K,ZHOU G H,et al.Multilayered Si nanoparticle/reduced graphene oxide hybrid as a highperformance lithium-ion battery anode[J].Advanced Materials,2014,26:758-764.
[51]FENG K,AHN K,LUI G,et al.Implementing an in-situ carbon network in Si/reduced graphene oxide for high performance lithium-ion battery anodes[J].Nano Energy 2016,19:187-197.
[52]WANG C G,LI Q.Graphene and its applications in lithiumion battery[J].Current Physical Chemistry,2013,3(3):232-254.
[53]王存国,潘璇,张雷,等.高容量锂离子电池核壳型硅/碳复合电极材料的制备与性能[J].高等学校化学学报,2015,36(2):368-374.
[54]DAVID L,BHANDAVAT R,BARRERA U,et al.Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries[J].Nature,2016,7:10998.
[55]潘璇,王存国,朱孟康,等.锂离子电池大容量硅基负极材料的研究进展[J].化工科技,2017,25(1):67-72.
[56]ZHANG L,WANG Y H,KAN G W,et al.Scalable synthesis of porous silicon/carbon microspheres as improved anode materials for lithium ion batteries[J].RSC Advances,2014,4:43114-43120.