柔性聚苯胺与碳质材料协同改性锂硫电池正极研究进展
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摘要
锂硫电池具有高能量密度、低成本和环境友好等特点,被认为是最具潜力的下一代储能体系之一。介绍了柔性导电聚苯胺与碳质材料协同改性锂硫电池正极材料方面的研究进展,并与传统的聚苯胺或碳质材料单独改性硫基正极材料进行对比。围绕后者在单独改性中存在的电化学性能不佳的问题,对柔性导电聚苯胺与碳质材料二元复合改性硫基正极材料的结构设计和制备方法等进行综述,并对其未来发展方向和商业化应用进行展望。
Li-S battery(Li-S) is considered as one of the most promising battery candidate in the next-generation energy storage systems by virtue of its high theoretical energy density, low cost and environmental compatibility. This work systematically introduced the state-of-art cathode materials with co-modification of polyaniline and carbon materials for Li-S batteries, as compared with the those cathodes individually decorated with either polyaniline or carbon materials.Aimed at the intrinsic drawbacks, substantial research progresses were detailedly summarized. Furthermore, the structural design and preparing processes of the co-modified sulfur cathodes and their potential commercialization were illustrated.
Li-S battery(Li-S) is considered as one of the most promising battery candidate in the next-generation energy storage systems by virtue of its high theoretical energy density, low cost and environmental compatibility. This work systematically introduced the state-of-art cathode materials with co-modification of polyaniline and carbon materials for Li-S batteries, as compared with the those cathodes individually decorated with either polyaniline or carbon materials.Aimed at the intrinsic drawbacks, substantial research progresses were detailedly summarized. Furthermore, the structural design and preparing processes of the co-modified sulfur cathodes and their potential commercialization were illustrated.
引文
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[21]马萍,张宝宏,巩桂英,等.聚苯胺/硫复合材料作锂二次电池正极的研究[J].功能材料与器件学报,2007,13(5):437-442.Ma Ping,Zhang Baohong,Gong Guiying,et al.Polyaniline/sulfur composite as cathode for secondary lithium battery[J].Journal of Functional materials and Devices,2007,13(5):437-442(in Chinese).
[22]Zhou Weidong,Yu Yingchao,Chen Hao,et al.Yolk-shell structure of polyaniline-coated sulfur for lithium-sulfur batteries[J].Journal of the American Chemical Society,2017,135(44):16736-16743.
[23]Xu Fei,Tang Zhiwei,Huang Siqi,et al.Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres for enhanced adsorption and energy storage[J].Nature Communications,2015,6:1-10.
[24]Jung D S,Hwang T H,Ji H L,et al.Hierarchical porous carbon by ultrasonic spray pyrolysis yields stable cycling in lithium-sulfur battery[J].2014,14(8):4418-4425.
[25]Sun Xiaoming,Li Yadong.Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles[J].Angewandte Chemie,2004,43(5):597-601.
[26]Chang Binin,Guan Daxiang,Tian Yanlong,et al.Convenient synthesis of porous carbon nano-spheres with tunable pore structure and excellent adsorption capacity[J].Journal of Hazardous Materials,2013,262(8):256-264.
[27]Zheng Guangyuan,Yang Yang,Cha J J,et al.Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries[J].Nano Letters,2011,11(10):4462-4467.
[28]Rao Mumin,Geng Xiuyu,Li Xiaoping,et al.Lithium-sulfur cell with combining carbon nanofibers-sulfur cathode and gel polymer electrolyte[J].Journal of Power Sources,2012,212(9):179-185.
[29]Tang Cheng,Zhang Qiang,Zhao Mengqiang,et al.Nitrogen-doped aligned carbon nanotube/graphene sandwiches:facile catalytic growth on bifunctional natural catalysts and their applications as scaffolds for high-rate lithium-sulfur batteries[J].Advanced Materials,2014,26(35):6100-6105.
[30]Ji Liwei,Rao Mumin,Zheng Haimei,et al.Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells[J].Journal of the American Chemical Society,2011,133(46):18522-18525.
[31]Jia Junxiang,Wang Kai,Zhang Xiong,et al.Graphene based hierarchically micro/mesoporous nano-composites as sulfur immobilizers for high performance lithium-sulfur batteries[J].Chemistry of Materials,2016,28(21):7864-7871.
[32]Rehman S,Gu X,Khan K,et al.3D vertically aligned and interconnected porous carbon nanosheets as sulfur immobilizers for high performance lithium-sulfur batteries[J].Advanced Energy Materials,2016,6(12):1-8.
[33]Li Yunyong,Li Zesheng,Zhang Qinwei,et al.Sulfur-infiltrated three-dimensional graphene-like material with hierarchical pores for highly stable lithium-sulfur batteries[J].Journal of Materials Chemistry A,2014,2(13):4528-4533.
[34]Ji Xiulei,Lee K T,Nazar L F.A highly ordered nanostructured carbon-sulphur,cathode for lithium-sulphur batteries[J].Nature Materials,2009,8(6):500-506.
[35]Wang Dawei,Zeng Qingcong,Zhou Guangmin,et al.Carbon-sulfur composites for Li-S batteries:Status and prospects[J].Journal of Materials Chemistry A,2013,1(33):9382-9394.
[36]Lee J,Kim J,Hyeon T.Recent progress in the synthesis of porous carbon materials[J].Advanced Materials,2006,18(18):2073-2094.
[37]Zhou Lan,Mao Han,Yu Aishui.Polyaniline-coated partially unzipped vapor-grown carbon fibers/sulfur microsphere composites for Li-S cathodes[J].Journal of Electroanalytical Chemistry,2016,761:62-67.
[38]Li Xiaogang,Rao Mumin,Li Weishan.Sulfur encapsulated in porous carbon nanospheres and coated with conductive polyaniline as cathode of lithium-sulfur battery[J].Journal of Solid State Electrochemistry,2016,20(1):153-161.
[39]Li Xiaogang,Rao Mumin,Chen Dongrui,et al.Sulfur supported by carbon nanotubes and coated with polyaniline:Preparation and performance as cathode of lithium-sulfur cell[J].Electrochimica Acta,2015,166:93-99.
[40]Zhang Zhiliang,Li Qiang,Lai Yanqing,et al.Confine sulfur in polyaniline-decorated hollow carbon nano-fiber hybrid nanostructure for lithium-sulfur batteries[J].Journal of Physical Chemistry C,2014,118(25):13369-13376.
[41]Dirlam P T,Glass R S,Char K,et al.The use of polymers in Li-S batteries:A review[J].Journal of Polymer Science Part A Polymer Chemistry,2017,55:1635-1668.
[42]Qiu Yongcai,Li Wanfei,Li Guizhu,et al.Polyaniline-modified cetyltrimethylammonium bromide graphene oxidesulfur nanocomposites with enhanced performance for lithium-sulfur batteries[J].Nano Research,2014,7(9):1355-1363.
[43]Moon S,Jung Y H,Kim D K.Enhanced electrochemical performance of a crosslinked polyaniline-coated graphene oxide-sulfur composite for rechargeable lithium-sulfur batteries[J].Journal of Power Sources,2015,294:386-392.
[44]Li Guochun,Li Guoran,Ye Shihai,et al.A polyanilinecoated sulfur/carbon composite with an enhanced high-rate capability as a cathode material for lithium/sulfur batteries[J].Advanced Energy Materials,2012,2(10):1238-1245.
[45]Zhao Xiaohui,Kim J K,Ahn H J,et al.A ternary sulfur/polyaniline/carbon composite as cathode material for lithium sulfur batteries[J].Electrochimica Acta,2013,109(11):145-152.
[46]Zhao Xiaohui,Ahn H J,Kim K W,et al.Polyanilinecoated mesoporous carbon/sulfur composites for advanced lithium sulfur batteries[J].Journal of Physical Chemistry C,2015,119(15):7996-8003.
[47]Jin Jun,Wen Zhaoyin,Ma Guoqiang,et al.Mesoporous carbon/sulfur composite with polyaniline coating for lithium sulfur batteries[J].Solid State Ionics,2014,262(9):170-173.
[2]Wang Jiangang,Xie Keyu,Wei Bingqing.Advanced engineering of nanostructured carbons for lithium-sulfur batteries[J].Nano Energy,2015,15:413-444.
[3]Fang Xin,Peng Huisheng.A revolution in electrodes:recent progress in rechargeable lithium-sulfur batteries[J].Small,2015,11(13):1488-1511.
[4]Boyd D A.Sulfur and its role in modern materials science[J].Angewandte Chemie,2016,55(50):15486-15502.
[5]Li Zhen,Huang Yimeng,Yuan Lixia,et al.Status and prospects in sulfur-carbon composites as cathode materials for rechargeable lithium-sulfur batteries[J].Carbon,2015,92:41-63.
[6]Kang Weimin,Deng Nanping,Ju Jingge,et al.A review of recent developments in rechargeable lithium-sulfur batteries[J].Nanoscale,2016,8(37):16541-16588.
[7]黄勇,邓坤发,王黎晴,等.导电聚合物/硫复合材料用于锂硫电池正极研究进展[J].工程塑料应用,2015,43(8):119-123.Huang Yong,Deng Kunfa,Wang Liqing,et al.Research progress of conductive polymers/sulfur as cathode materials for lithium-sulfur batteries[J].Engineering Plastic Applicaton,2015,43(8):119-123(in Chinese).
[8]Snook G A,Kao P,Best A S.Conducting-polymer-based supercapacitor devices and electrodes[J].Journal of Power Sources,2011,196(1):1-12.
[9]Macdiarmid A G,Chiang J C,Richter A F,et al.Polyaniline:a new concept in conducting polymers[J].Synthetic Metals,1987,18(1):285-290.
[10]Wu Gang,More K L,Johnston C M,et al.High-performance electrocatalysts for oxygen reduction derived from polyaniline,iron,and cobalt[J].Science,2011,332(6028):443-447.
[11]Xin Sen,Guo Yuguo,Wan Lijun.Nanocarbon networks for advanced rechargeable lithium batteries[J].Accounts of Chemical Research,2012,45(10):1759-1769.
[12]He Guang,Mandlmeier B,Schuster J,et al.Bimodal mesoporous carbon nanofibers with high porosity:Freestanding and embedded in membranes for lithium-sulfur batteries[J].Chemistry of Materials,2014,26(13):3879-3886.
[13]Zheng W,Liu Y W,Hu Xiaogang,et al.Novel nanosized adsorbing sulfur composite cathode materials for the advanced secondary lithium batteries[J].Electrochimica Acta,2006,51(7):1330-1335.
[14]Wang Jiazhao,Chew S Y,Zhao Z W,et al.Sulfur-mesoporous carbon composites in conjunction with a novel ionic liquid electrolyte for lithium rechargeable batteries[J].Carbon,2008,46(2):229-235.
[15]Chen Jiajia,Jia Xin,She Qiujie,et al.The preparation of nano-sulfur/MWCNTs and its electrochemical performance[J].Electrochimica Acta,2010,55(27):8062-8066.
[16]He Xiangning,Ren Jianguo,Wang Li,et al.Expansion and shrinkage of the sulfur composite electrode in rechargeable lithium batteries[J].Journal of Power Sources,2009,190(1):154-156.
[17]Kang E T,Neoh K G,Tan K L.Polyaniline:A polymer with many interesting intrinsic redox states[J].Progress in Polymer Science,1998,23(2):277-324.
[18]俞栋,徐小虎,李宇洁,等.锂硫电池硫/导电聚合物正极材料的研究进展[J].材料导报,2014,28(23):141-146.Yu Dong,Xu Xiaohu,Li Yujie,et al.Research progress of sulfur/conductive polymers cathode materials for lithiumsulfur batteries[J].Material Review,2014,28(23):141-146(in Chinese).
[19]Cheng Fangyi,Tang Wei,Li Chunsheng,et al.Conducting poly(aniline)nanotubes and nanofibers:Controlled synthesis and application in lithium/poly(aniline)rechargeable batteries[J].Chemistry,2006,12(11):3082-3088.
[20]李高然,李洲鹏,林展.锂硫电池中碳质材料的研究进展[J].储能科学与技术,2016,5(2):135-148.Li Gaoran,Li Zhoupeng,Lin Zhan.Carbon-based materials for advanced lithium-sulfur batteries[J].Energy Storage Science and Technology,2016,5(2):135-148(in Chinese).
[21]马萍,张宝宏,巩桂英,等.聚苯胺/硫复合材料作锂二次电池正极的研究[J].功能材料与器件学报,2007,13(5):437-442.Ma Ping,Zhang Baohong,Gong Guiying,et al.Polyaniline/sulfur composite as cathode for secondary lithium battery[J].Journal of Functional materials and Devices,2007,13(5):437-442(in Chinese).
[22]Zhou Weidong,Yu Yingchao,Chen Hao,et al.Yolk-shell structure of polyaniline-coated sulfur for lithium-sulfur batteries[J].Journal of the American Chemical Society,2017,135(44):16736-16743.
[23]Xu Fei,Tang Zhiwei,Huang Siqi,et al.Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres for enhanced adsorption and energy storage[J].Nature Communications,2015,6:1-10.
[24]Jung D S,Hwang T H,Ji H L,et al.Hierarchical porous carbon by ultrasonic spray pyrolysis yields stable cycling in lithium-sulfur battery[J].2014,14(8):4418-4425.
[25]Sun Xiaoming,Li Yadong.Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles[J].Angewandte Chemie,2004,43(5):597-601.
[26]Chang Binin,Guan Daxiang,Tian Yanlong,et al.Convenient synthesis of porous carbon nano-spheres with tunable pore structure and excellent adsorption capacity[J].Journal of Hazardous Materials,2013,262(8):256-264.
[27]Zheng Guangyuan,Yang Yang,Cha J J,et al.Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries[J].Nano Letters,2011,11(10):4462-4467.
[28]Rao Mumin,Geng Xiuyu,Li Xiaoping,et al.Lithium-sulfur cell with combining carbon nanofibers-sulfur cathode and gel polymer electrolyte[J].Journal of Power Sources,2012,212(9):179-185.
[29]Tang Cheng,Zhang Qiang,Zhao Mengqiang,et al.Nitrogen-doped aligned carbon nanotube/graphene sandwiches:facile catalytic growth on bifunctional natural catalysts and their applications as scaffolds for high-rate lithium-sulfur batteries[J].Advanced Materials,2014,26(35):6100-6105.
[30]Ji Liwei,Rao Mumin,Zheng Haimei,et al.Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells[J].Journal of the American Chemical Society,2011,133(46):18522-18525.
[31]Jia Junxiang,Wang Kai,Zhang Xiong,et al.Graphene based hierarchically micro/mesoporous nano-composites as sulfur immobilizers for high performance lithium-sulfur batteries[J].Chemistry of Materials,2016,28(21):7864-7871.
[32]Rehman S,Gu X,Khan K,et al.3D vertically aligned and interconnected porous carbon nanosheets as sulfur immobilizers for high performance lithium-sulfur batteries[J].Advanced Energy Materials,2016,6(12):1-8.
[33]Li Yunyong,Li Zesheng,Zhang Qinwei,et al.Sulfur-infiltrated three-dimensional graphene-like material with hierarchical pores for highly stable lithium-sulfur batteries[J].Journal of Materials Chemistry A,2014,2(13):4528-4533.
[34]Ji Xiulei,Lee K T,Nazar L F.A highly ordered nanostructured carbon-sulphur,cathode for lithium-sulphur batteries[J].Nature Materials,2009,8(6):500-506.
[35]Wang Dawei,Zeng Qingcong,Zhou Guangmin,et al.Carbon-sulfur composites for Li-S batteries:Status and prospects[J].Journal of Materials Chemistry A,2013,1(33):9382-9394.
[36]Lee J,Kim J,Hyeon T.Recent progress in the synthesis of porous carbon materials[J].Advanced Materials,2006,18(18):2073-2094.
[37]Zhou Lan,Mao Han,Yu Aishui.Polyaniline-coated partially unzipped vapor-grown carbon fibers/sulfur microsphere composites for Li-S cathodes[J].Journal of Electroanalytical Chemistry,2016,761:62-67.
[38]Li Xiaogang,Rao Mumin,Li Weishan.Sulfur encapsulated in porous carbon nanospheres and coated with conductive polyaniline as cathode of lithium-sulfur battery[J].Journal of Solid State Electrochemistry,2016,20(1):153-161.
[39]Li Xiaogang,Rao Mumin,Chen Dongrui,et al.Sulfur supported by carbon nanotubes and coated with polyaniline:Preparation and performance as cathode of lithium-sulfur cell[J].Electrochimica Acta,2015,166:93-99.
[40]Zhang Zhiliang,Li Qiang,Lai Yanqing,et al.Confine sulfur in polyaniline-decorated hollow carbon nano-fiber hybrid nanostructure for lithium-sulfur batteries[J].Journal of Physical Chemistry C,2014,118(25):13369-13376.
[41]Dirlam P T,Glass R S,Char K,et al.The use of polymers in Li-S batteries:A review[J].Journal of Polymer Science Part A Polymer Chemistry,2017,55:1635-1668.
[42]Qiu Yongcai,Li Wanfei,Li Guizhu,et al.Polyaniline-modified cetyltrimethylammonium bromide graphene oxidesulfur nanocomposites with enhanced performance for lithium-sulfur batteries[J].Nano Research,2014,7(9):1355-1363.
[43]Moon S,Jung Y H,Kim D K.Enhanced electrochemical performance of a crosslinked polyaniline-coated graphene oxide-sulfur composite for rechargeable lithium-sulfur batteries[J].Journal of Power Sources,2015,294:386-392.
[44]Li Guochun,Li Guoran,Ye Shihai,et al.A polyanilinecoated sulfur/carbon composite with an enhanced high-rate capability as a cathode material for lithium/sulfur batteries[J].Advanced Energy Materials,2012,2(10):1238-1245.
[45]Zhao Xiaohui,Kim J K,Ahn H J,et al.A ternary sulfur/polyaniline/carbon composite as cathode material for lithium sulfur batteries[J].Electrochimica Acta,2013,109(11):145-152.
[46]Zhao Xiaohui,Ahn H J,Kim K W,et al.Polyanilinecoated mesoporous carbon/sulfur composites for advanced lithium sulfur batteries[J].Journal of Physical Chemistry C,2015,119(15):7996-8003.
[47]Jin Jun,Wen Zhaoyin,Ma Guoqiang,et al.Mesoporous carbon/sulfur composite with polyaniline coating for lithium sulfur batteries[J].Solid State Ionics,2014,262(9):170-173.
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