PPCPs在环境介质中的归趋及高级氧化降解研究进展
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摘要
药品和个人护理用品(PPCPs)是一类新兴污染物,其在环境介质中的迁移转化及去除受到环境科学研究者的广泛关注。综述了水环境中PPCPs的来源、迁移转化、生态毒性与潜在风险;总结了PPCPs高级氧化降解技术的研究进展,包括O_3氧化技术、光催化氧化技术、UV/H_2O_2技术、Fenton/联合Fenton技术及高铁酸盐(Fe(Ⅵ))氧化技术;最后对其未来研究方向进行了展望。
PPCPs are a kind of new emerging pollutants,and their migration,transformation and removal in environmental media have widely received attention from researchers of environmental science. The source,migration and transformation,eco-toxicity and potential risk of PPCPs in water environment are reviewed,and the research progress in the advanced oxidative degradation technology of PPCPs,including O_3 oxidation technology,photo-catalytic oxidation technology,UV/H_2O_2 technology,Fenton/combined Fenton technology,and ferrate(Fe(Ⅵ)) oxidation technology summarized. In addition,their future research directions are predicted.
PPCPs are a kind of new emerging pollutants,and their migration,transformation and removal in environmental media have widely received attention from researchers of environmental science. The source,migration and transformation,eco-toxicity and potential risk of PPCPs in water environment are reviewed,and the research progress in the advanced oxidative degradation technology of PPCPs,including O_3 oxidation technology,photo-catalytic oxidation technology,UV/H_2O_2 technology,Fenton/combined Fenton technology,and ferrate(Fe(Ⅵ)) oxidation technology summarized. In addition,their future research directions are predicted.
引文
[1] Daughton C G,Ternes T A. Pharmaceuticals and personal care products in the environment:Agents of subtle change[J]. Environmental Health Perspectives,1999,107(6):907-938.
[2]赵迎新,王亚舒,季民,等.吸附法去除水中药品及个人护理品(PPCPs)研究进展[J].工业水处理,2017,37(6):1-5.
[3] Evgenidou E N,Konstantinou I K,Lambropoulou D A. Occurrence and removal of transformation products of PPCPs and illicit drugs in wastewaters:A review[J]. Science of the Total Environment,2015,505:905-926.
[4] Sui Qian,Huang Jun,Deng Shubo,et al. Occurrence and removal of pharmaceuticals,caffeine and DEET in wastewater treatment plants of Beijing,China[J]. Water Research,2010,44(2):417-426.
[5] Wang Hexing,Wang Na,Wang Bin,et al. Antibiotics detected in urines and adipogenesis in school children[J]. Environment International,2016,89/90:204-211.
[6] Oliveira T S,Murphy M,Mendola N,et al. Characterization of pharmaceuticals and personal care products in hospital effluent and waste water influent/effluent by direct-injection LC-MS-MS[J]. Science of the Total Environment,2015,518/519:459-478.
[7] Mailler R,Gasperi J,Coquet Y,et al. Study of a large scale powdered activated carbon pilot:Removals of a wide range of emerging and priority micropollutants from wastewater treatment plant effluents[J].Water Research,2015,72:315-330.
[8] Sarrade S,Rios G M,Carlés M. Nanofiltration membrane behavior in a supercritical medium[J]. Journal of Membrane Science,2018,114(1):81-91.
[9] Oliveira G H D,Santos-Neto A J,Zaiat M. Evaluation of sulfamethazine sorption and biodegradation by anaerobic granular sludge using batch experiments[J]. Bioprocess&Biosystems Engineering,2016,39(1):115-124.
[10] Yi Xinzhu,Tran N H,Yin Tingru,et al. Removal of selected PPCPs,EDCs,and antibiotic resistance genes in landfill leachate by a fullscale constructed wetlands system[J]. Water Research,2017,121:46-60.
[11] Behin J,Farhadian N. Response surface methodology for ozonation of trifluralin using advanced oxidation processes in an airlift photoreactor[J]. Applied Water Science,2017,7(6):3103-3112.
[12]刘元坤,王建龙.水中磺胺二甲基嘧啶的辐照降解研究[J].中国环境科学,2017,37(1):123-130.
[13] Garcíagalán M J,Anfruns A,Gonzalezolmos R,et al. UV/H2O2degradation of the antidepressants venlafaxine and O-desmethylvenlafaxine:Elucidation of their transformation pathway and environmental fate[J]. Journal of Hazardous Materials,2016,311:70-80.
[14] Yang Xin,Sun Jianliang,Fu Wenjie,et al. PPCP degradation by UV/chlorine treatment and its impact on DBP formation potential in real waters[J]. Water Research,2016,98:309-318.
[15]魏红,李娟,李克斌,等.左氧氟沙星的超声/H2O2联合降解研究[J].中国环境科学,2013,33(2):257-262.
[16] Yi Y,Yong S O,Kim K H,et al. Occurrences and removal of pharmaceuticals and personal care products(PPCPs)in drinking water and water/sewage treatment plants:A review[J]. Science of the Total Environment,2017,596/597:303-320.
[17] Lei Meng,Zhang Lun,Lei Jianjun,et al. Overview of emerging contaminants and associated human health effects[J]. BioMed Research International,2015,2015(4):1-12.
[18]姜蕾,陈书怡,杨蓉,等.长江三角洲地区典型废水中抗生素的初步分析[J].环境化学,2008,27(3):371-374.
[19] Rodriguez-Mozaz S,Chamorro S,Marti E,et al. Occurrence of antibiotics and antibiotic resistance genes in hospital and urban wastewaters and their impact on the receiving river[J]. Water Research,2015,69:234-242.
[20]谭国赣,杜勇立,黄满红,等.污泥深度脱水对四环素耐药菌和耐药基因的去除特性[J].上海师范大学学报:自然科学版,2014,43(2):175-179.
[21] Cheng D L,Ngo H H,Guo W S,et al. Bioprocessing for elimination antibiotics and hormones from swine wastewater[J]. Science of the Total Environment,2018,621:1664-1682.
[22] Zhang Qianqian,Zhao Jianliang,Liu Yousheng,et al. Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin,South China and comparison with field data[J]. Environmental Science:Processes&Impacts,2013,15(11):2142-2152.
[23]刘晓晖,王炜亮,王玉番,等.水环境中药品和个人护理品的迁移转化、毒性效应及其风险评估[J].科技导报,2015,33(16):56-60.
[24] Wang Jianlong,Wang Shizong. Removal of pharmaceuticals and personal care products(PPCPs)from wastewater:A review[J]. Journal of Environmental Management,2016,182:620-640.
[25] Santos L V,Meireles A M,Lange L C. Degradation of antibiotics norfloxacin by Fenton,UV and UV/H2O2[J]. Journal of Environmental Management,2015,154:8-12.
[26] Keen O S,Linden K G. Degradation of antibiotic activity during UV/H2O2advanced oxidation and photolysis in wastewater effluent[J].Environmental Science&Technology,2013,47(22):13020-13030.
[27] Ma Jie,Sun Yiran,Fei Yu. Efficient removal of tetracycline with KOH-activated graphene from aqueous solution[J]. Royal Society Open Science,2017,4(11):170731.
[28] Zheng Senlin,Chen Bin,Qiu Xiaoyan,et al. Distribution and risk assessment of 82 pesticides in Jiulong River and estuary in South China[J]. Chemosphere,2016,144:1177-1192.
[29] Wilkinson J L,Hooda P S,Swinden J,et al. Spatial(bio)accumulation of pharmaceuticals,illicit drugs,plasticisers,perfluorinated compounds and metabolites in river sediment,aquatic plants and benthic organisms[J]. Environmental Pollution,2018,234:864-875.
[30] Sanderson H,Brain R A,Johnson D J,et al. Toxicity classification and evaluation of four pharmaceuticals classes:antibiotics,antineoplastic,cardiovascular,and sex hormones[J]. Toxicology,2004,203(1):27-40.
[31]刘晓玲,罗义,周启星.环境中两种沐浴露污染对大型蚤的生态毒性效应[J].环境科学学报,2008,28(6):1173-1177.
[32]金磊,姜蕾,韩琪,等.华东地区某水源水中13种磺胺类抗生素的分布特征及人体健康风险评价[J].环境科学,2016,37(7):2515-2521.
[33] Li Wenhui,Shi Yali,Gao Lihong,et al. Occurrence of antibiotics in water,sediments,aquatic plants,and animals from Baiyangdian Lake in North China[J]. Chemosphere,2012,89(11):1307-1315.
[34] Guo Wanqian,Yin Renli,Zhou Xianjiao,et al. Ultrasonic-assisted ozone oxidation process for sulfamethoxazole removal:Impact factors and degradation process[J]. Desalination&Water Treatment,2015,57(44):1-8.
[35]安盼盼,杨晓进,戚伟康,等.臭氧催化氧化处理制膜污水厂二级生化出水[J].工业水处理,2017,37(8):74-78.
[36]王涛,彭道平,李云祯,等.臭氧氧化去除二级出水中PPCPs的研究[J].安全与环境学报,2017,17(4):1454-1458.
[37]王涛,彭道平,李云祯,等. Hp-β-环糊精包络臭氧氧化去除水中PPCPs研究[J].环境工程,2016,34(7):25-28.
[38]孙秋月.饮用水臭氧催化氧化工艺去除典型抗生素的研究[D].济南:山东建筑大学,2014.
[39] Long M,Brame J,Qin F,et al. Phosphate changes effect of humic acids on TiO2photocatalysis:From inhibition to mitigation of electron-hole recombination[J]. Environmental Science&Technology,2017,51(1):514-521.
[40]高乃云,张晏晏,马艳. UV/TiO2去除水中磺胺甲唑的动力学及影响因素分析[J].中国环境科学,2013,33(11):1958-1964.
[41] Ofiarska A,Pieczynska A,Borzyszkowska A F,et al. Pt-TiO2-assisted photocatalytic degradation of the cytostatic drugs ifosfamide and cyclophosphamide under artificial sunlight[J]. Chemical Engineering Journal,2016,285:417-427.
[42]王炜亮,王玉番,卢少勇,等. US/UV-Fenton体系处理高浓度罗丹明B特性研究[J].中国环境科学,2016,36(8):2329-2336.
[43] Rivas J,Gimeno O,Borralho T,et al. UV-C photolysis of endocrine disruptors. The influence of inorganic peroxides[J]. Journal of Hazardous Materials,2010,174(1):393-397.
[44]苟玺莹,张盼月,钱锋,等. UV/H2O2降解水中磺胺嘧啶影响因素及机理[J].环境工程学报,2017,11(11):5810-5819.
[45]李文君,蓝梅,彭先佳. UV/H2O2联合氧化法去除畜禽养殖废水中抗生素[J].环境污染与防治,2011,33(4):25-28.
[46] Wang Nannan,Zheng Tong,Zhang Guangshan,et al. A review on Fenton-like processes for organic wastewater treatment[J]. Journal of Environmental Chemical Engineering,2016,4(1):762-787.
[47]冯精兰,师少辉,孙剑辉. Fenton法降解抗生素磺胺间甲氧嘧啶钠[J].环境工程学报,2012,6(9):3125-3131.
[48]唐玉芳.类Fenton法处理阿莫西林废水的研究[D].长沙:湖南大学,2010.
[49]王涛,彭道平,李云祯,等.高铁酸盐(Fe(Ⅵ))氧化去除水中PPCPs的研究进展[J].环境工程,2016,34(8):40-44.
[50]李通,刘国光,刘海津,等.高铁酸盐氧化降解环丙沙星的实验研究[J].环境科学与技术,2014(2):123-128.
[51] Zhou Jiaheng,Chen Kaibo,Hong Qiankun,et al. Degradation of chloramphenicol by potassium ferrate(Ⅵ)oxidation:Kinetics and products[J]. Environmental Science&Pollution Research,2017,24(11):10166-10171.
[52] Han Qi,Wang Hongjie,Dong Wenyi,et al. Degradation of bisphenol A by ferrate(Ⅵ)oxidation:Kinetics,products and toxicity assessment[J]. Chemical Engineering Journal,2015,262:34-40.
[2]赵迎新,王亚舒,季民,等.吸附法去除水中药品及个人护理品(PPCPs)研究进展[J].工业水处理,2017,37(6):1-5.
[3] Evgenidou E N,Konstantinou I K,Lambropoulou D A. Occurrence and removal of transformation products of PPCPs and illicit drugs in wastewaters:A review[J]. Science of the Total Environment,2015,505:905-926.
[4] Sui Qian,Huang Jun,Deng Shubo,et al. Occurrence and removal of pharmaceuticals,caffeine and DEET in wastewater treatment plants of Beijing,China[J]. Water Research,2010,44(2):417-426.
[5] Wang Hexing,Wang Na,Wang Bin,et al. Antibiotics detected in urines and adipogenesis in school children[J]. Environment International,2016,89/90:204-211.
[6] Oliveira T S,Murphy M,Mendola N,et al. Characterization of pharmaceuticals and personal care products in hospital effluent and waste water influent/effluent by direct-injection LC-MS-MS[J]. Science of the Total Environment,2015,518/519:459-478.
[7] Mailler R,Gasperi J,Coquet Y,et al. Study of a large scale powdered activated carbon pilot:Removals of a wide range of emerging and priority micropollutants from wastewater treatment plant effluents[J].Water Research,2015,72:315-330.
[8] Sarrade S,Rios G M,Carlés M. Nanofiltration membrane behavior in a supercritical medium[J]. Journal of Membrane Science,2018,114(1):81-91.
[9] Oliveira G H D,Santos-Neto A J,Zaiat M. Evaluation of sulfamethazine sorption and biodegradation by anaerobic granular sludge using batch experiments[J]. Bioprocess&Biosystems Engineering,2016,39(1):115-124.
[10] Yi Xinzhu,Tran N H,Yin Tingru,et al. Removal of selected PPCPs,EDCs,and antibiotic resistance genes in landfill leachate by a fullscale constructed wetlands system[J]. Water Research,2017,121:46-60.
[11] Behin J,Farhadian N. Response surface methodology for ozonation of trifluralin using advanced oxidation processes in an airlift photoreactor[J]. Applied Water Science,2017,7(6):3103-3112.
[12]刘元坤,王建龙.水中磺胺二甲基嘧啶的辐照降解研究[J].中国环境科学,2017,37(1):123-130.
[13] Garcíagalán M J,Anfruns A,Gonzalezolmos R,et al. UV/H2O2degradation of the antidepressants venlafaxine and O-desmethylvenlafaxine:Elucidation of their transformation pathway and environmental fate[J]. Journal of Hazardous Materials,2016,311:70-80.
[14] Yang Xin,Sun Jianliang,Fu Wenjie,et al. PPCP degradation by UV/chlorine treatment and its impact on DBP formation potential in real waters[J]. Water Research,2016,98:309-318.
[15]魏红,李娟,李克斌,等.左氧氟沙星的超声/H2O2联合降解研究[J].中国环境科学,2013,33(2):257-262.
[16] Yi Y,Yong S O,Kim K H,et al. Occurrences and removal of pharmaceuticals and personal care products(PPCPs)in drinking water and water/sewage treatment plants:A review[J]. Science of the Total Environment,2017,596/597:303-320.
[17] Lei Meng,Zhang Lun,Lei Jianjun,et al. Overview of emerging contaminants and associated human health effects[J]. BioMed Research International,2015,2015(4):1-12.
[18]姜蕾,陈书怡,杨蓉,等.长江三角洲地区典型废水中抗生素的初步分析[J].环境化学,2008,27(3):371-374.
[19] Rodriguez-Mozaz S,Chamorro S,Marti E,et al. Occurrence of antibiotics and antibiotic resistance genes in hospital and urban wastewaters and their impact on the receiving river[J]. Water Research,2015,69:234-242.
[20]谭国赣,杜勇立,黄满红,等.污泥深度脱水对四环素耐药菌和耐药基因的去除特性[J].上海师范大学学报:自然科学版,2014,43(2):175-179.
[21] Cheng D L,Ngo H H,Guo W S,et al. Bioprocessing for elimination antibiotics and hormones from swine wastewater[J]. Science of the Total Environment,2018,621:1664-1682.
[22] Zhang Qianqian,Zhao Jianliang,Liu Yousheng,et al. Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin,South China and comparison with field data[J]. Environmental Science:Processes&Impacts,2013,15(11):2142-2152.
[23]刘晓晖,王炜亮,王玉番,等.水环境中药品和个人护理品的迁移转化、毒性效应及其风险评估[J].科技导报,2015,33(16):56-60.
[24] Wang Jianlong,Wang Shizong. Removal of pharmaceuticals and personal care products(PPCPs)from wastewater:A review[J]. Journal of Environmental Management,2016,182:620-640.
[25] Santos L V,Meireles A M,Lange L C. Degradation of antibiotics norfloxacin by Fenton,UV and UV/H2O2[J]. Journal of Environmental Management,2015,154:8-12.
[26] Keen O S,Linden K G. Degradation of antibiotic activity during UV/H2O2advanced oxidation and photolysis in wastewater effluent[J].Environmental Science&Technology,2013,47(22):13020-13030.
[27] Ma Jie,Sun Yiran,Fei Yu. Efficient removal of tetracycline with KOH-activated graphene from aqueous solution[J]. Royal Society Open Science,2017,4(11):170731.
[28] Zheng Senlin,Chen Bin,Qiu Xiaoyan,et al. Distribution and risk assessment of 82 pesticides in Jiulong River and estuary in South China[J]. Chemosphere,2016,144:1177-1192.
[29] Wilkinson J L,Hooda P S,Swinden J,et al. Spatial(bio)accumulation of pharmaceuticals,illicit drugs,plasticisers,perfluorinated compounds and metabolites in river sediment,aquatic plants and benthic organisms[J]. Environmental Pollution,2018,234:864-875.
[30] Sanderson H,Brain R A,Johnson D J,et al. Toxicity classification and evaluation of four pharmaceuticals classes:antibiotics,antineoplastic,cardiovascular,and sex hormones[J]. Toxicology,2004,203(1):27-40.
[31]刘晓玲,罗义,周启星.环境中两种沐浴露污染对大型蚤的生态毒性效应[J].环境科学学报,2008,28(6):1173-1177.
[32]金磊,姜蕾,韩琪,等.华东地区某水源水中13种磺胺类抗生素的分布特征及人体健康风险评价[J].环境科学,2016,37(7):2515-2521.
[33] Li Wenhui,Shi Yali,Gao Lihong,et al. Occurrence of antibiotics in water,sediments,aquatic plants,and animals from Baiyangdian Lake in North China[J]. Chemosphere,2012,89(11):1307-1315.
[34] Guo Wanqian,Yin Renli,Zhou Xianjiao,et al. Ultrasonic-assisted ozone oxidation process for sulfamethoxazole removal:Impact factors and degradation process[J]. Desalination&Water Treatment,2015,57(44):1-8.
[35]安盼盼,杨晓进,戚伟康,等.臭氧催化氧化处理制膜污水厂二级生化出水[J].工业水处理,2017,37(8):74-78.
[36]王涛,彭道平,李云祯,等.臭氧氧化去除二级出水中PPCPs的研究[J].安全与环境学报,2017,17(4):1454-1458.
[37]王涛,彭道平,李云祯,等. Hp-β-环糊精包络臭氧氧化去除水中PPCPs研究[J].环境工程,2016,34(7):25-28.
[38]孙秋月.饮用水臭氧催化氧化工艺去除典型抗生素的研究[D].济南:山东建筑大学,2014.
[39] Long M,Brame J,Qin F,et al. Phosphate changes effect of humic acids on TiO2photocatalysis:From inhibition to mitigation of electron-hole recombination[J]. Environmental Science&Technology,2017,51(1):514-521.
[40]高乃云,张晏晏,马艳. UV/TiO2去除水中磺胺甲唑的动力学及影响因素分析[J].中国环境科学,2013,33(11):1958-1964.
[41] Ofiarska A,Pieczynska A,Borzyszkowska A F,et al. Pt-TiO2-assisted photocatalytic degradation of the cytostatic drugs ifosfamide and cyclophosphamide under artificial sunlight[J]. Chemical Engineering Journal,2016,285:417-427.
[42]王炜亮,王玉番,卢少勇,等. US/UV-Fenton体系处理高浓度罗丹明B特性研究[J].中国环境科学,2016,36(8):2329-2336.
[43] Rivas J,Gimeno O,Borralho T,et al. UV-C photolysis of endocrine disruptors. The influence of inorganic peroxides[J]. Journal of Hazardous Materials,2010,174(1):393-397.
[44]苟玺莹,张盼月,钱锋,等. UV/H2O2降解水中磺胺嘧啶影响因素及机理[J].环境工程学报,2017,11(11):5810-5819.
[45]李文君,蓝梅,彭先佳. UV/H2O2联合氧化法去除畜禽养殖废水中抗生素[J].环境污染与防治,2011,33(4):25-28.
[46] Wang Nannan,Zheng Tong,Zhang Guangshan,et al. A review on Fenton-like processes for organic wastewater treatment[J]. Journal of Environmental Chemical Engineering,2016,4(1):762-787.
[47]冯精兰,师少辉,孙剑辉. Fenton法降解抗生素磺胺间甲氧嘧啶钠[J].环境工程学报,2012,6(9):3125-3131.
[48]唐玉芳.类Fenton法处理阿莫西林废水的研究[D].长沙:湖南大学,2010.
[49]王涛,彭道平,李云祯,等.高铁酸盐(Fe(Ⅵ))氧化去除水中PPCPs的研究进展[J].环境工程,2016,34(8):40-44.
[50]李通,刘国光,刘海津,等.高铁酸盐氧化降解环丙沙星的实验研究[J].环境科学与技术,2014(2):123-128.
[51] Zhou Jiaheng,Chen Kaibo,Hong Qiankun,et al. Degradation of chloramphenicol by potassium ferrate(Ⅵ)oxidation:Kinetics and products[J]. Environmental Science&Pollution Research,2017,24(11):10166-10171.
[52] Han Qi,Wang Hongjie,Dong Wenyi,et al. Degradation of bisphenol A by ferrate(Ⅵ)oxidation:Kinetics,products and toxicity assessment[J]. Chemical Engineering Journal,2015,262:34-40.