两性淀粉制备与应用的机理及研究进展
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摘要
两性淀粉是指在原淀粉分子链上接上阳离子和阴离子基团的复合变性淀粉,兼具天然淀粉、阳离子与阴离子淀粉所特有的优良理化特性,应用前景广阔。本文从两性淀粉的制备工艺、应用领域所涉及的反应或作用机理出发,综述两性淀粉的研究进展,为进一步优化两性淀粉的制备工艺,拓展其应用领域提供理论参考与应用指导。
Amphoteric starch refered to a composite modi?ed starch with cationic and anionic groups attached to the molecular chains of raw starch.It had both excellent physical and chemical properties unique to natural starch,cationic and anionic starch,and had broad application prospects.Based on reaction or mechanism of action in the preparation process and application ?elds of amphoteric starch,the research progress of amphoteric starch was reviewed,which could provide theoretical reference and application guidance for further optimizing the preparation process of amphoteric starch and expanding its application ?elds.
Amphoteric starch refered to a composite modi?ed starch with cationic and anionic groups attached to the molecular chains of raw starch.It had both excellent physical and chemical properties unique to natural starch,cationic and anionic starch,and had broad application prospects.Based on reaction or mechanism of action in the preparation process and application ?elds of amphoteric starch,the research progress of amphoteric starch was reviewed,which could provide theoretical reference and application guidance for further optimizing the preparation process of amphoteric starch and expanding its application ?elds.
引文
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[24]Moser K B,Verbanac F.Process of making paper containing quaternary ammonium starch ethers containing anionic covalent phosphorus and paper made therefrom:US,3562103[P].1971-02-09.
[25]马希晨,秦鹏,聂新卫,等.淀粉基强阳离子两性絮凝剂的合成[J].应用化学,2004,21(12):1253-1256.
[26]Kumar K,Adhikary P,Karmakar N C,et al.Synthesis,characterization and application of novel cationic and amphoteric flocculants based on amylopectin[J].Carbohydrate Polymers,2015,127:275-281.
[27]唐宏科,周鹏刚.阳离子淀粉-丙烯酰胺接枝共聚物絮凝剂的制备及其絮凝性能[J].化工环保,2006,26(3):246-249.
[28]Fletcher N R,Kanda M,Ketelson H A,et al.Antiperspirant compositions:US,6261543[P].2001-07-17.
[29]曹丽琴,徐世美,封顺,等.两性淀粉的取代度与吸湿保湿性能关系的研究[J].日用化学工业,2004,34(2):97-99.
[30]张光华,陈蒙,任换换,等.两性淀粉接枝共聚物水煤浆分散剂的制备及性能[J].陕西科技大学学报,2015,33(2):83-87.
[2]Radosta S,Vorwerg W,Ebert A,et al.Properties of low-substituted cationic starch derivatives prepared by different derivatisation processed[J].Starch/St?rke,2004,56(7):277-287.
[3]Wang L F,Pan S Y,Hu H,et al.Synthesis and properties of carboxymethyl kudzu root starch[J].Carbohydrate Polymers,2010,80(1):174-179.
[4]Song H,Wu D,Zhang R Q,et al.Synthesis and application of amphoteric starch graft polymer[J].Carbohydrate Polymers,2009,78(2):253-257.
[5]Lin Q T,Qian S,Li C J,et al.Synthesis,flocculation and adsorption performance of amphoteric starch[J].Carbohydrate Polymers,2012,90(1):275-283.
[6]沈澄英,陈亚萍.黄原酸酯两性淀粉的合成及其应用[J].电镀与环保,2016,36(5):55-57.
[7]张翰君,曹晓辉,杨青松.造纸湿部施胶用两性淀粉LXB-3的制备及性能研究[J].化工技术与开发,2014,43(7):19-21.
[8]Tessler M M.Novel starch ether derivatives,a method for the preparation thereof and their use in paper:US,4243479A[P].1981-01-06.
[9]刘菲菲.新型水溶性叔胺淀粉醚的合成及其性能研究[D].大连:大连理工大学,2014.
[10]马希晨,于俊杰,宋辉,等.新型季铵烷基淀粉醚的研制[J].精细石油化工,2004(5):46-48.
[11]安鸿雁,佟毅,刘馨远,等.半干法磷酸酯淀粉的制备[J].食品工业科技,2018(5):226-229.
[12]唐晓珍,张慧,方松,等.微波干法羧甲基淀粉工艺优化及结构研究[J].粮食与油脂,2018,31(11):18-22.
[13]刘洁,玉琼广,陆娇笛.羧甲基两性淀粉的水相一步法制备及应用研究[J].造纸化学品,2012,24(6):19-23.
[14]Kweno M R,Sosulski F W,Bhirud P R.Preparation of amphoteric starches during aqueous alcoholic cationization[J].Starch/St?rke,1997,49(10):419-424.
[15]刘兆丽,曹亚峰,马希晨.淀粉接枝两性离子絮凝剂的制备[J].大连轻工业学院学报,2003,22(1):50-52.
[16]杨文秀,张占柱.新型两性变性淀粉浆料的制备及性能测试[J].染整技术,2013,35(11):22-24.
[17]张晓宇,刘新芳.磷酸型两性淀粉制备研究[J].粮食与饲料工业,2007(12):19-20.
[18]孙明东.阳离子化淀粉接枝聚丙烯酰胺及其包覆纳米Fe3O4的研究[D].武汉:武汉科技大学,2013.
[19]Solarek D B,Peek L R,Henley M J,et al.Method of papermaking using crosslinked cationic/amphoteric starches:US,5368690[P].1994-11-29.
[20]Hebeish A,Rahman A A,Hilw Z E,et al.Cationized starch derived from pre-oxidized starch for texile sizing and printing[J].Starch/St?rke,2005,57(12):616-623.
[21]陈家楠,刘淑芳,颜少琼,等.两性离子淀粉性质的研究[J].中国造纸,1992(1):51-54.
[22]文仁贵,罗明昌,王俊丽.磷酸醋型两性淀粉的制备、性能及其在造纸中的应用[J].造纸化学品,2010,22(4):34-38.
[23]张安平,任涛,刘书钗,等.阳离子淀粉-丙烯酰胺接枝共聚物的制备及应用[J].中华纸业,2003,24(3):27-29.
[24]Moser K B,Verbanac F.Process of making paper containing quaternary ammonium starch ethers containing anionic covalent phosphorus and paper made therefrom:US,3562103[P].1971-02-09.
[25]马希晨,秦鹏,聂新卫,等.淀粉基强阳离子两性絮凝剂的合成[J].应用化学,2004,21(12):1253-1256.
[26]Kumar K,Adhikary P,Karmakar N C,et al.Synthesis,characterization and application of novel cationic and amphoteric flocculants based on amylopectin[J].Carbohydrate Polymers,2015,127:275-281.
[27]唐宏科,周鹏刚.阳离子淀粉-丙烯酰胺接枝共聚物絮凝剂的制备及其絮凝性能[J].化工环保,2006,26(3):246-249.
[28]Fletcher N R,Kanda M,Ketelson H A,et al.Antiperspirant compositions:US,6261543[P].2001-07-17.
[29]曹丽琴,徐世美,封顺,等.两性淀粉的取代度与吸湿保湿性能关系的研究[J].日用化学工业,2004,34(2):97-99.
[30]张光华,陈蒙,任换换,等.两性淀粉接枝共聚物水煤浆分散剂的制备及性能[J].陕西科技大学学报,2015,33(2):83-87.