光固化环氧丙烯酸树脂水性化及其改性研究进展
|
摘要
近年来研究者越来越多地将水性光固化树脂应用于制备涂料,水性光固化树脂能用水作为溶剂,这样就减少了传统溶剂型树脂因为稀释剂而产生的气味,同时又利用紫外光进行树脂的快速固化,节能省时,已成为非常活跃的研发领域。水性光固化环氧丙烯酸酯树脂作为光固化树脂的一种,因其诸多优异的性能成为重要的研究方向。概述了光固化环氧丙烯酸树脂的组成以及对该树脂水性化的方法,重点介绍了对水性化后的环氧丙烯酸树脂的改性方法,最后对水性光固化体系的发展进行了展望。
In recent years,researchers applied widely waterborne UV-curable resin for the preparation of coatings. Waterborne UV-curable resin utilized water as solvent,thus reducing the smell of the diluents in traditional solvent resin. At the same time,this kind of resin system could be cured rapidly under UV-light to economize energy and time. Research on waterborne UV-curable resin became an active field. At present,waterborne UV-curable epoxy acrylate resin played an important role in research on UV-curable resin due to its various excellent properties. In this work,the composition of UV-curable epoxy acrylate resin and the waterbased process of the resin were summarized. Furthermore,it focused on the modification of waterborne epoxy acrylate resins. Finally,the development of waterborne UV-curable system was prospected.
In recent years,researchers applied widely waterborne UV-curable resin for the preparation of coatings. Waterborne UV-curable resin utilized water as solvent,thus reducing the smell of the diluents in traditional solvent resin. At the same time,this kind of resin system could be cured rapidly under UV-light to economize energy and time. Research on waterborne UV-curable resin became an active field. At present,waterborne UV-curable epoxy acrylate resin played an important role in research on UV-curable resin due to its various excellent properties. In this work,the composition of UV-curable epoxy acrylate resin and the waterbased process of the resin were summarized. Furthermore,it focused on the modification of waterborne epoxy acrylate resins. Finally,the development of waterborne UV-curable system was prospected.
引文
[1]CORCIONE C E,FRIGIONE M.Factors influencing photo curing kinetics of novel UV-cured siloxane-modified acrylic coatings:Oxygen inhibition and composition[J].Thermochim Acta,2012,534(8):21-27.
[2]HWANG H D,PARK C H,MOON J I,et al.UV-curing behavior and physical properties of waterborne UV-curable polycarbonate-based polyurethane dispersion[J].Prog Org Coat,2011,72(4):663-675.
[3]CONCEICAO A R D,PIMENTA E A R,FUJISAWA R S,et al.Comparative study of the quantity of volatile organic compounds in water-based paint and solvent-based applied polyurethane[J].Macromol Symposia,2012,316(1):108-111.
[4]CRIVELLO J V,REICHMANIS E.Photopolymer materials and processes for advanced technologies[J].Chem Mater,2014,26(1):533-548.
[5]DUAN Y,HUO Y,DUAN L.Preparation of acrylic resins modified with epoxy resins and their behaviors as binders of waterborne printing ink on plastic film[J].Colloids Surf A,2017,535(36):345-360.
[6]KARDAR P,EBRAHIMI M,BASTANI S,et al.Using mixture experimental design to study the effect of multifunctional acrylate monomers on UV cured epoxy acrylate resins[J].Prog Org Coat,2009,64(1):74-80.
[7]陈尊.紫外光固化水性环氧丙烯酸树脂的合成与表征[D].广州:华南理工大学,2010.
[8]SCHMITT M.Method to analyse energy and intensity dependent photo-curing of acrylic esters in bulk[J].Rsc Adv,2015,5(82):67284-67298.
[9]YAN R,YANG D,ZHANG N,et al.Performance of UVcurable lignin based epoxy acrylate coatings[J].Prog Org Coat,2018,116(45):83-89.
[10]LU Y,LAROCK R C.Synthesis and properties of grafted latices from a soybean oil-based waterborne polyurethane and acrylics[J].J Appl Polym Sci,2010,119(6):3305-3314.
[11]GOLAZ B,MICHAUD V,LETERRIER Y,et al.UV intensity,temperature and dark-curing effects in cationic photo-polymerization of a cycloaliphatic epoxy resin[J].Polymer,2012,53(10):2038-2048.
[12]HWANG H D,MOON J I,CHOI J H,et al.Effect of water drying conditions on the surface property and morphology of waterborne UV-curable coatings for engineered flooring[J].J Ind Eng Chem,2009,15(3):381-387.
[13]LIU F,MIAO L,WANG Y,et al.Green fabrication of ultraviolet curable epoxy acrylate-silica hybrid coatings[J].Prog Org Coat,2017,109(36):38-44.
[14]DASHTIZADEH A,ABDOUSS M,MAHDAVI H,et al.Acrylic coatings exhibiting improved hardness,solvent resistance and glossiness by using silica nano-composites[J].Appl Surf Sci,2011,257(6):2118-2125.
[15]PU Z B,CHEN Y,ZHANG L,et al.Preparation of water soluble acrylic resin adhesive for fluorescent lamps and its modification[J].Rare Metals,2011,30(1):657-660.
[16]XIAO X Y.Synthesis of waterborne epoxy acrylate[J].JSouth China University Technol,2009,37(6):47-52.
[17]焦泽鹏.水性紫外光固化树脂的合成以及结构与性能研究[D].广州:暨南大学,2010.
[18]张亚军.水溶性UV环氧丙烯酸酯预聚物的研究与制备[D].天津:河北工业大学,2013.
[19]JI L,WANG B,CHENG F,et al.The preparation and anticorrosive performance research of a novel UV-curable epoxy acrylate emulsion[J].Polym Bull,2017(60):234-260.
[20]胡杨明.水溶性UV环氧丙烯酸酯预聚物的合成与改性研究[D].广州:广州大学,2016.
[21]ZHANG Z,CHAO J,CHU F.Study on the synthesis and property of water-based UV-curable epoxy acrylate with low viscosity[J].Adv Graphic Commun,Packaging Technol Mater,2015,369(5):941-947.
[22]ZHANG Y,LI D,PI C,et al.Synthesis of new photosensitive and water-soluble copolymers and their photocrosslinking properties[J].China Sciencepaper,2012,300(2):367-378.
[23]XIAO X,HAO C.Preparation of waterborne epoxy acrylate/silica sol hybrid materials and study of their UV curing behavior[J].Colloids Surf A,2010,359(3):82-87.
[24]ROMO-URIBE A,SANTIAGO-SANTIAGO K,ZAVALA-PADILLA G,et al.Waterborne layered silicate/acrylate nano-composites by in-situ emulsion polymerization:Thermal and mechanical reinforcement[J].Prog Org Coat,2016,101(46):59-70.
[25]SONG X G,LOU H T,ZHAO L N.Study on organosilicone modified waterborne UV-cured epoxy resin[J].Guangzhou Chem,2013,89(45):268-270.
[26]LIU M,MAO X,ZHU H,et al.Water and corrosion resistance of epoxy-acrylic-amine waterborne coatings:Effects of resin molecular weight,polar group and hydrophobic segment[J].Corros Sci,2013,75(7):106-113.
[27]陈松.高性能水性光固化涂料的合成研究[D].北京:北京化工大学,2008.
[28]何游.水性UV固化含氟聚合物及涂料的制备及性能研究[D].广州:广东工业大学,2013.
[2]HWANG H D,PARK C H,MOON J I,et al.UV-curing behavior and physical properties of waterborne UV-curable polycarbonate-based polyurethane dispersion[J].Prog Org Coat,2011,72(4):663-675.
[3]CONCEICAO A R D,PIMENTA E A R,FUJISAWA R S,et al.Comparative study of the quantity of volatile organic compounds in water-based paint and solvent-based applied polyurethane[J].Macromol Symposia,2012,316(1):108-111.
[4]CRIVELLO J V,REICHMANIS E.Photopolymer materials and processes for advanced technologies[J].Chem Mater,2014,26(1):533-548.
[5]DUAN Y,HUO Y,DUAN L.Preparation of acrylic resins modified with epoxy resins and their behaviors as binders of waterborne printing ink on plastic film[J].Colloids Surf A,2017,535(36):345-360.
[6]KARDAR P,EBRAHIMI M,BASTANI S,et al.Using mixture experimental design to study the effect of multifunctional acrylate monomers on UV cured epoxy acrylate resins[J].Prog Org Coat,2009,64(1):74-80.
[7]陈尊.紫外光固化水性环氧丙烯酸树脂的合成与表征[D].广州:华南理工大学,2010.
[8]SCHMITT M.Method to analyse energy and intensity dependent photo-curing of acrylic esters in bulk[J].Rsc Adv,2015,5(82):67284-67298.
[9]YAN R,YANG D,ZHANG N,et al.Performance of UVcurable lignin based epoxy acrylate coatings[J].Prog Org Coat,2018,116(45):83-89.
[10]LU Y,LAROCK R C.Synthesis and properties of grafted latices from a soybean oil-based waterborne polyurethane and acrylics[J].J Appl Polym Sci,2010,119(6):3305-3314.
[11]GOLAZ B,MICHAUD V,LETERRIER Y,et al.UV intensity,temperature and dark-curing effects in cationic photo-polymerization of a cycloaliphatic epoxy resin[J].Polymer,2012,53(10):2038-2048.
[12]HWANG H D,MOON J I,CHOI J H,et al.Effect of water drying conditions on the surface property and morphology of waterborne UV-curable coatings for engineered flooring[J].J Ind Eng Chem,2009,15(3):381-387.
[13]LIU F,MIAO L,WANG Y,et al.Green fabrication of ultraviolet curable epoxy acrylate-silica hybrid coatings[J].Prog Org Coat,2017,109(36):38-44.
[14]DASHTIZADEH A,ABDOUSS M,MAHDAVI H,et al.Acrylic coatings exhibiting improved hardness,solvent resistance and glossiness by using silica nano-composites[J].Appl Surf Sci,2011,257(6):2118-2125.
[15]PU Z B,CHEN Y,ZHANG L,et al.Preparation of water soluble acrylic resin adhesive for fluorescent lamps and its modification[J].Rare Metals,2011,30(1):657-660.
[16]XIAO X Y.Synthesis of waterborne epoxy acrylate[J].JSouth China University Technol,2009,37(6):47-52.
[17]焦泽鹏.水性紫外光固化树脂的合成以及结构与性能研究[D].广州:暨南大学,2010.
[18]张亚军.水溶性UV环氧丙烯酸酯预聚物的研究与制备[D].天津:河北工业大学,2013.
[19]JI L,WANG B,CHENG F,et al.The preparation and anticorrosive performance research of a novel UV-curable epoxy acrylate emulsion[J].Polym Bull,2017(60):234-260.
[20]胡杨明.水溶性UV环氧丙烯酸酯预聚物的合成与改性研究[D].广州:广州大学,2016.
[21]ZHANG Z,CHAO J,CHU F.Study on the synthesis and property of water-based UV-curable epoxy acrylate with low viscosity[J].Adv Graphic Commun,Packaging Technol Mater,2015,369(5):941-947.
[22]ZHANG Y,LI D,PI C,et al.Synthesis of new photosensitive and water-soluble copolymers and their photocrosslinking properties[J].China Sciencepaper,2012,300(2):367-378.
[23]XIAO X,HAO C.Preparation of waterborne epoxy acrylate/silica sol hybrid materials and study of their UV curing behavior[J].Colloids Surf A,2010,359(3):82-87.
[24]ROMO-URIBE A,SANTIAGO-SANTIAGO K,ZAVALA-PADILLA G,et al.Waterborne layered silicate/acrylate nano-composites by in-situ emulsion polymerization:Thermal and mechanical reinforcement[J].Prog Org Coat,2016,101(46):59-70.
[25]SONG X G,LOU H T,ZHAO L N.Study on organosilicone modified waterborne UV-cured epoxy resin[J].Guangzhou Chem,2013,89(45):268-270.
[26]LIU M,MAO X,ZHU H,et al.Water and corrosion resistance of epoxy-acrylic-amine waterborne coatings:Effects of resin molecular weight,polar group and hydrophobic segment[J].Corros Sci,2013,75(7):106-113.
[27]陈松.高性能水性光固化涂料的合成研究[D].北京:北京化工大学,2008.
[28]何游.水性UV固化含氟聚合物及涂料的制备及性能研究[D].广州:广东工业大学,2013.