腰果酚缩水甘油醚改性碱溶性酚醛环氧丙烯酸酯的制备及应用
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摘要
利用腰果酚缩水甘油醚与经酸酐酸化后的酚醛环氧丙烯酸酯反应,得到改性碱溶性酚醛环氧丙烯酸酯树脂,并将其应用到感光型阻焊油墨中。实验通过红外以及核磁氢谱证明了目标产物的成功合成。该改性树脂所制得的涂层具有优异的感光性、耐热性以及力学强度,同时柔韧性得到提升。将其应用到感光型阻焊油墨中,与用未改性碱溶性酚醛环氧丙烯酸酯树脂制得的油墨相比,在保持良好显影性和感光性的同时,解析度由140μm提高到了85μm,显影线条的最小侧蚀由37.1μm降低到10.4μm,展现了优异的抗蚀刻能力。
An o-cresol formaldehyde epoxy acrylates resin modified by cardanol glycidyl ether(EATC)was prepared and used in solder resist ink.The synthesis of EATC was studied and characterized in detail by IR spectroscopy and ~1HNMR spectrum.The coating made of modified resin exhibited good photosensitive,thermal and mechanical properties.Besides,the flexibility of the film became better.Compared to unmodified o-cresol formaldehyde epoxy acrylates resin,the solder resist ink which consist of EATC has good performance in photosensitivity.The resolution increased from 140 to 85 μm,and the minimal etching resistance decrease from 37.1 to 10.4μm.
An o-cresol formaldehyde epoxy acrylates resin modified by cardanol glycidyl ether(EATC)was prepared and used in solder resist ink.The synthesis of EATC was studied and characterized in detail by IR spectroscopy and ~1HNMR spectrum.The coating made of modified resin exhibited good photosensitive,thermal and mechanical properties.Besides,the flexibility of the film became better.Compared to unmodified o-cresol formaldehyde epoxy acrylates resin,the solder resist ink which consist of EATC has good performance in photosensitivity.The resolution increased from 140 to 85 μm,and the minimal etching resistance decrease from 37.1 to 10.4μm.
引文
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[20]金银,王德峰,朱小飞,王炳才,朱红军.新型改性环氧丙烯酸酯预聚物合成及性能研究[J].涂料工业,2012,42(11):13-17.Jin Y,Wang D F,Zhu X F,Wang B C,Zhu H J.Synthesis and properties of novel modified epoxy acrylate prepolymers[J].Paint&Coatings Industry,2012,42(11):13-17.
[2]Crama Y,van de Klundert J,Spieksma F C R.Production planning problems in printed circuit board assembly[J].Discrete Applied Mathematics,2002,123(1-3):339-361.
[3]Zeng G,McDonald S,Nogita K.Development of high-temperature solders[J].Microelectronics Reliability,2012,52(7):1306-1322.
[4]Shirai M.Reworkable UV curing materials[J].Progress in Organic Coatings,2007,58(2-3):158-165.
[5]周亮.环氧丙烯酸酯光固化体系及积层电路板用感光成像油墨的研究[D].广州:华南理工大学,2003.Zhou L.Study on photosensitive image ink for epoxy acrylate light curing system and laminated circuit board[D].Guangzhou:South China University of Technology,2003.
[6]王斋民.高密度多层线路板用改性邻甲酚醛环氧树脂的固化行为及性能[D].广州:华南理工大学,2007.Wang Z M.Curing behavior and properties of modified ocresol novolac epoxy resin for high density multilayer circuit boards[D].Guangzhou:South China University of Technology,2003.
[7]王斋民,彭炳初,皮丕辉.酸改性邻甲酚醛环氧丙烯酸酯的合成及应用[J].华南理工大学学报(自然科学版),2005,33(10):5-8.Wang Z M,Peng B C,Pi P H.Synthesis and application of acid modified o-cresol aldehyde epoxy acrylate[J].Journal of South China University of Technology(Natural Science Edition),2005,33(10):5-8.
[8]杨建文,罗晓文,曾兆华,陈用烈.羧基化环氧丙烯酸酯合成及在光成像阻焊油墨中的应用[J].应用化学,2001,18(8):606-609.Yang J W,Luo X W,Zeng Z H,Chen Y L.Synthesis of carboxylated epoxy acrylate and its application in photoimageable solder mask ink[J].Chinese Journal of Applied Chemistry,2001,18(8):606-609.
[9]吴建兵,马国章.环氧丙烯酸酯的改性及其性能的研究进展[J].精细与专用化学品,2010,18(11):37-40.Wu J B,Ma G Z.Research progress on modification of epoxy acrylate and its properties[J].Fine and Specialty Chemicals,2010,18(11):37-40.
[10]Karata爧S,Klzllkaya C,Kayaman-Apohan N,Güng9r A.Preparation and characterization of sol-gel derived UV-curable organo-silica-titania hybrid coatings[J].Progress in Organic Coatings,2007,60(2):140-147.
[11]Bayramolu G,Kahraman M V,Kayaman-Apohan N,Güng9r A.Synthesis and characterization of UV-curable dual hybrid oligomers based on epoxy acrylate containing pendant alkoxysilane groups[J].Progress in Organic Coatings,2006,57(1):50-55.
[12]Kardar P,Ebrahimi M,Bastani S.Study the effect of nano-alumina particles on physical-mechanical properties of UV cured epoxy acrylate via nano-indentation[J].Progress in Organic Coatings,2008,62(3):321-325.
[13]侣庆法,唐中华,范晓东.紫外光固化环氧丙烯酸酯/蒙脱土纳米复合材料的合成与表征[J].高分子材料科学与工程,2004,20(4):206-209.Lv Q F,Tang Z H,Fan X D.Synthesis and characterization of UV-curable epoxy acrylate/montmorillonite nanocomposites[J].Polymer Materials Science&Engineering,2004,20(4):206-209.
[14]Oprea S,Vlad S,Stanciu A,Macoveanu M.Epoxy urethane acrylate[J].European Polymer Journal,2000,36(2):373-378.
[15]Chen C Y,Huang C K,Lin S P,Han J L,Hsieh K H,Lin C P.Low-shrinkage visible-light-curable urethanemodified epoxy acrylate/SiO2composites as dental restorative materials[J].Composites Science and Technology,2008,68(13):2811-2817.
[16]Wang W.Synthesis and characterization of UV-curable polydimethylsiloxane epoxy acrylate[J].European Polymer Journal,2003,39(6):1117-1123.
[17]Wang X,Wang X,Song L,Xing W,Tang G,Hu W,Hu Y.Preparation and thermal stability of UV-cured epoxybased coatings modified with octamercaptopropyl POSS[J].Thermochimica Acta,2013,568(20):130-139.
[18]Chattopadhyay D K,Panda S S,Raju K.Thermal and mechanical properties of epoxy acrylate/methacrylates UVcured coatings[J].Progress in Organic Coatings,2005,54(1):10-19.
[19]Xu G,Zhao Y,Shi W.Properties and morphologies of UV-cured epoxy acrylate blend films containing hyperbranched polyurethane acrylate/hyperbranched polyester[J].Journal of Polymer Science Part B:Polymer Physics,2005,43(22):3159-3170.
[20]金银,王德峰,朱小飞,王炳才,朱红军.新型改性环氧丙烯酸酯预聚物合成及性能研究[J].涂料工业,2012,42(11):13-17.Jin Y,Wang D F,Zhu X F,Wang B C,Zhu H J.Synthesis and properties of novel modified epoxy acrylate prepolymers[J].Paint&Coatings Industry,2012,42(11):13-17.