基于核废物固化应用的铁磷酸盐材料研究进展
|
摘要
铁磷酸盐材料是一类新型的核废物固化材料,铁磷酸盐玻璃具有较高的化学稳定性和较低的熔融温度,独居石、磷灰石等是固化核素优选的晶体,铁磷酸盐玻璃陶瓷固化兼有玻璃基体对多种元素的包容性和陶瓷固化对特定放射性核素抗辐射能力的优势。综述了铁磷酸盐玻璃、陶瓷及玻璃陶瓷的特点及其在高放废物固化方面的研究现状及进展,比较了用于核废物固化的铁磷酸盐固化体的体系及特点。
Iron phosphate material is a new type of material for nuclear waste solidification. Iron phosphate glass shows better corrosive-resistant and lower melting temperature. Monazite, apatite are optimized crystals of curing nuclide. Immobilization as a Iron phosphate glass-ceramic wastform has advantages both high Immobilization capacity of glass for multiple elements and radiation resistance of ceramic for curing specific radionuclide. In this paper some features and the research progress of the iron phosphate glass, ceramic and glass-ceramic in nuclear waste solidification were discussed. The system and characteristics of the iron phosphate solidified body for nuclear waste solidification were compared.
Iron phosphate material is a new type of material for nuclear waste solidification. Iron phosphate glass shows better corrosive-resistant and lower melting temperature. Monazite, apatite are optimized crystals of curing nuclide. Immobilization as a Iron phosphate glass-ceramic wastform has advantages both high Immobilization capacity of glass for multiple elements and radiation resistance of ceramic for curing specific radionuclide. In this paper some features and the research progress of the iron phosphate glass, ceramic and glass-ceramic in nuclear waste solidification were discussed. The system and characteristics of the iron phosphate solidified body for nuclear waste solidification were compared.
引文
[1]Sales B C,Boatner L A.Lead-Iron Phosphate Glass:AStable Storage Medium for High-Level Nuclear Waste[J].Science,1984,(226):45-48.
[2]Greaves G N,Gurman S J,Gladen L F,et al.A structural basis for the corrosion resistance of lead-iron-phosphate glasses:An X-ray absorption spectroscopy study[J].Philosophical Magazine Part B,1988,58(3):271-283.
[3]梁晓峰,任慧.铁磷酸盐玻璃固化材料研究进展[J].玻璃,2014(2):8-11.
[4]陈明周,张瑞峰,吕永红,等.放射性固体废物玻璃固化技术综述[J].热力发电,2012,41(3):1-6.
[5]Day D E,Wu Z,Ray C S,et al.Chemically durable iron phosphate glass wasteforms[J].Journal of Non-Crystalline Solids,1998,241:1-12.
[6]Huang W,Day D E,Ray C S,et a1.Vitrification of high chrome oxide nuclear waste in iron Phosphate glasses[J].Journal of Nuclear Materials,2004,327:46-57.
[7]Karabulut M,Yuksek M,Marasinghe G K,Day D E.Structural features of hafnium iron hosphate glasses[J].Journal of Non-Crystalline Solids,2009,355:1571-1573.
[8]Govindan Kutty K V,Kitheri J,Asuvathraman R,et al.Development of glass and ceramic matrices for the immobilization of high level radioactive waste from fast reactors,Global 2009,Paris,France,September 611,2009:402-410.
[9]Pinheiro A S,da Costa Z M,Bell M J V,et al.Thermal characterization of iron phosphate glasses for nuclear waste disposal[J].Optical Materials,2011,33(12):1975-1979.
[10]Huang W H,Day D E,Ray C S,et al.Vitri cation of high chrome oxide nuclear waste in iron phosphate glasses[J].Journal of Nuclear Materials,2004,1(327):46-57.
[11]黄文,周萘,Day D E,Ray C S.磷酸盐玻璃固化体化学耐蚀性研究[J].硅酸盐学报,2004,32(4):460-470.
[12]Joseph K,Govindan Kutty K V,Chandramohan P,Vasudeva Rao P R.Studies on the synthesis and characterization of cesium-containing iron phosphateglasses[J].Journal of Nuclear Materials.2009,384(3):262-267.
[13]Joseph K,Premila M,Amarendra G,Govindan Kutty KV,Sundar C S,Vasudeva Rao P R.Structure of cesium loaded iron phosphate glasses:an infrared and Raman spectroscopy study[J].Journal of Nuclear Materials,2012,420(1-3):49-53.
[14]Joseph K,Govindan Kutty K V,Goswami M C,Vasudeva Rao P R.Viscosity and crystallization mechanism of cesium loaded ironphosphate glasses[J].Thermochimica Acta,2014,587:42-47.
[15]Joseph K,Ghosh S,Govindan Kutty K V,Vasudeva Rao P R,Crystallization kinetics,stability and glass forming ability of iron phosphate and cesium loaded iron phosphate glasses[J].Journal of Nuclear Materials,2012,426(1-3):233-239.
[16]Joseph K,Asuvathraman R,Venkata Krishnan R,Joseph J,Govindan Kutty K V,Vasudeva Rao P R.Investigation of thermal expansion and specific heat of cesium loaded iron phosphate glasses[J].Journal of Nuclear Materials,2012,429(1-3):1-6.
[17]Day D E,Brow R K,Ray C S,et al.Iron Phosphate Glass for Vitrifying Hanford AZ102 LAW in Joule Heated and Cold Crucible Induction Melters-12240.Waste Manage,Conference Process,2012.
[18]Jen-Hsien Hsu,Joseph W,Newkirk,et al.The performance of Inconel 693 electrodes for processing an iron phosphate glass melt containing 26 wt%of a simulated low activity waste[J].Journal of Nuclear Materials,2014,444(1-3):323-330.
[19]胡唐华,徐世平,鲍卫民等.模拟锶铯废物铁磷酸盐玻璃固化及化学稳定性[J].硅酸盐通报,2003,22(2):86-92.
[20]Ojovan M I,Lee W E.Glassy Wasteforms for Nuclear Waste Immobilization[J].Metallurgical and Materials Transactions A,2011,42(4):837-851.
[21]张振涛,王雷,甘学英等.放射性废物处理与处置-高放废液和锕系核素玻璃-陶瓷固化技术研究简况[R].北京:中国原子能科学研究院,2007.
[22]Jongkwon Choi,Wooyong Um,Sungwook Choung.Development of iron phosphate ceramic waste form to immobilize radioactive waste solution[J].Journal of Nuclear Materials,2014,452(1-3):16-23.
[23]杨建文,汤宝龙,罗上庚.富烧绿石型人造岩石固化模拟锕系元素废液的研究[J].核化学与放射化学,2000,22(3):178-182.
[24]廖其龙,廖春娟,向光华等.Al2O3对独居石玻璃陶瓷固化体的影响[J].原子能科学术,2014,48(1):23-27.
[25]何涌.高放射性废物矿物固化体的特性[J].地质科技情报,2000,19(3):73-76.
[26]Borzunov A I,D’yakov S V,Poluéktov P P.Immobilization of Radioactive Wastes by Embedding in Phosphate Ceramic[J].Atomic Energy,2004,96(2).
[27]Colorado H A,Dileep Singh.High-sodium waste streams stabilized with inorganic acid-base phosphate ceramics fabricated at room temperature[J].Ceramics International,2014,40(7):10621-10631.
[28]马辉,陈泉水,梁磐仪,等.掺杂钕的磷酸铈独居石固化体合成研究[J].陶瓷学报,2012,33(1):1-5.
[29]Loiseau P,Caurant D,Baffier N,et al.Glass-ceramic nuclear waste forms obtained from Si O2-Al2O3-Ca O-Zr O2-Ti O2 glasses containing lanthanides(Ce,Nd,Eu,Gd,Yb)and actinides(Th):study of internal crystallization[J].Journal of Nuclear Materials,2004,335:14-32.
[30]章为夷.混合烧结法在玻璃陶瓷制备中的应用[J].硅酸盐通报,2011,30(5):1110-1113.
[31]姜伟,蔡舒,张文娟.CaO-P2O5-SrO-MgO-Na2O玻璃陶瓷的析晶控制和微观结构的研究[J].稀有金属材料与工程,2009,38(2):814-817.
[32]He Y,LüY J,Zhang Q.Characterization of monazite glass-ceramics as waste forms for simulatedα-HLLW[J].Journal of Nuclear Materials,2008,376(2):201-206.
[33]吕彦杰.模拟α-高放废液独居石磷酸盐玻璃陶瓷固化体的研究[D].武汉:中国地质大学硕士论文,2008.
[34]向光华.独居石-磷灰石玻璃陶瓷固化体的制备与性能研究[D].绵阳:西南科技大学,2012.
[35]Zhang Y,Zhang Z,Thorogood G,Vance E R.Pyrochlore based glass-ceramics for the immobilization of actiniderich nuclear wastes:From concept to reality[J].Journal of Nuclear Materials,2013,432:545-547.
[36]Loiseau P,Caurant D.Glass-ceramic nuclear waste forms obtained by crystallization of SiO 2-A12O3-CaO-ZrO 2-TiO 2glasses containing lanthanides(Ce,Nd,Eu,Gd,Yb)and actinides(Th):Study of the crystallization from the surface[J].Journal of Nuclear Materials,2010,402(1):38-54.
[2]Greaves G N,Gurman S J,Gladen L F,et al.A structural basis for the corrosion resistance of lead-iron-phosphate glasses:An X-ray absorption spectroscopy study[J].Philosophical Magazine Part B,1988,58(3):271-283.
[3]梁晓峰,任慧.铁磷酸盐玻璃固化材料研究进展[J].玻璃,2014(2):8-11.
[4]陈明周,张瑞峰,吕永红,等.放射性固体废物玻璃固化技术综述[J].热力发电,2012,41(3):1-6.
[5]Day D E,Wu Z,Ray C S,et al.Chemically durable iron phosphate glass wasteforms[J].Journal of Non-Crystalline Solids,1998,241:1-12.
[6]Huang W,Day D E,Ray C S,et a1.Vitrification of high chrome oxide nuclear waste in iron Phosphate glasses[J].Journal of Nuclear Materials,2004,327:46-57.
[7]Karabulut M,Yuksek M,Marasinghe G K,Day D E.Structural features of hafnium iron hosphate glasses[J].Journal of Non-Crystalline Solids,2009,355:1571-1573.
[8]Govindan Kutty K V,Kitheri J,Asuvathraman R,et al.Development of glass and ceramic matrices for the immobilization of high level radioactive waste from fast reactors,Global 2009,Paris,France,September 611,2009:402-410.
[9]Pinheiro A S,da Costa Z M,Bell M J V,et al.Thermal characterization of iron phosphate glasses for nuclear waste disposal[J].Optical Materials,2011,33(12):1975-1979.
[10]Huang W H,Day D E,Ray C S,et al.Vitri cation of high chrome oxide nuclear waste in iron phosphate glasses[J].Journal of Nuclear Materials,2004,1(327):46-57.
[11]黄文,周萘,Day D E,Ray C S.磷酸盐玻璃固化体化学耐蚀性研究[J].硅酸盐学报,2004,32(4):460-470.
[12]Joseph K,Govindan Kutty K V,Chandramohan P,Vasudeva Rao P R.Studies on the synthesis and characterization of cesium-containing iron phosphateglasses[J].Journal of Nuclear Materials.2009,384(3):262-267.
[13]Joseph K,Premila M,Amarendra G,Govindan Kutty KV,Sundar C S,Vasudeva Rao P R.Structure of cesium loaded iron phosphate glasses:an infrared and Raman spectroscopy study[J].Journal of Nuclear Materials,2012,420(1-3):49-53.
[14]Joseph K,Govindan Kutty K V,Goswami M C,Vasudeva Rao P R.Viscosity and crystallization mechanism of cesium loaded ironphosphate glasses[J].Thermochimica Acta,2014,587:42-47.
[15]Joseph K,Ghosh S,Govindan Kutty K V,Vasudeva Rao P R,Crystallization kinetics,stability and glass forming ability of iron phosphate and cesium loaded iron phosphate glasses[J].Journal of Nuclear Materials,2012,426(1-3):233-239.
[16]Joseph K,Asuvathraman R,Venkata Krishnan R,Joseph J,Govindan Kutty K V,Vasudeva Rao P R.Investigation of thermal expansion and specific heat of cesium loaded iron phosphate glasses[J].Journal of Nuclear Materials,2012,429(1-3):1-6.
[17]Day D E,Brow R K,Ray C S,et al.Iron Phosphate Glass for Vitrifying Hanford AZ102 LAW in Joule Heated and Cold Crucible Induction Melters-12240.Waste Manage,Conference Process,2012.
[18]Jen-Hsien Hsu,Joseph W,Newkirk,et al.The performance of Inconel 693 electrodes for processing an iron phosphate glass melt containing 26 wt%of a simulated low activity waste[J].Journal of Nuclear Materials,2014,444(1-3):323-330.
[19]胡唐华,徐世平,鲍卫民等.模拟锶铯废物铁磷酸盐玻璃固化及化学稳定性[J].硅酸盐通报,2003,22(2):86-92.
[20]Ojovan M I,Lee W E.Glassy Wasteforms for Nuclear Waste Immobilization[J].Metallurgical and Materials Transactions A,2011,42(4):837-851.
[21]张振涛,王雷,甘学英等.放射性废物处理与处置-高放废液和锕系核素玻璃-陶瓷固化技术研究简况[R].北京:中国原子能科学研究院,2007.
[22]Jongkwon Choi,Wooyong Um,Sungwook Choung.Development of iron phosphate ceramic waste form to immobilize radioactive waste solution[J].Journal of Nuclear Materials,2014,452(1-3):16-23.
[23]杨建文,汤宝龙,罗上庚.富烧绿石型人造岩石固化模拟锕系元素废液的研究[J].核化学与放射化学,2000,22(3):178-182.
[24]廖其龙,廖春娟,向光华等.Al2O3对独居石玻璃陶瓷固化体的影响[J].原子能科学术,2014,48(1):23-27.
[25]何涌.高放射性废物矿物固化体的特性[J].地质科技情报,2000,19(3):73-76.
[26]Borzunov A I,D’yakov S V,Poluéktov P P.Immobilization of Radioactive Wastes by Embedding in Phosphate Ceramic[J].Atomic Energy,2004,96(2).
[27]Colorado H A,Dileep Singh.High-sodium waste streams stabilized with inorganic acid-base phosphate ceramics fabricated at room temperature[J].Ceramics International,2014,40(7):10621-10631.
[28]马辉,陈泉水,梁磐仪,等.掺杂钕的磷酸铈独居石固化体合成研究[J].陶瓷学报,2012,33(1):1-5.
[29]Loiseau P,Caurant D,Baffier N,et al.Glass-ceramic nuclear waste forms obtained from Si O2-Al2O3-Ca O-Zr O2-Ti O2 glasses containing lanthanides(Ce,Nd,Eu,Gd,Yb)and actinides(Th):study of internal crystallization[J].Journal of Nuclear Materials,2004,335:14-32.
[30]章为夷.混合烧结法在玻璃陶瓷制备中的应用[J].硅酸盐通报,2011,30(5):1110-1113.
[31]姜伟,蔡舒,张文娟.CaO-P2O5-SrO-MgO-Na2O玻璃陶瓷的析晶控制和微观结构的研究[J].稀有金属材料与工程,2009,38(2):814-817.
[32]He Y,LüY J,Zhang Q.Characterization of monazite glass-ceramics as waste forms for simulatedα-HLLW[J].Journal of Nuclear Materials,2008,376(2):201-206.
[33]吕彦杰.模拟α-高放废液独居石磷酸盐玻璃陶瓷固化体的研究[D].武汉:中国地质大学硕士论文,2008.
[34]向光华.独居石-磷灰石玻璃陶瓷固化体的制备与性能研究[D].绵阳:西南科技大学,2012.
[35]Zhang Y,Zhang Z,Thorogood G,Vance E R.Pyrochlore based glass-ceramics for the immobilization of actiniderich nuclear wastes:From concept to reality[J].Journal of Nuclear Materials,2013,432:545-547.
[36]Loiseau P,Caurant D.Glass-ceramic nuclear waste forms obtained by crystallization of SiO 2-A12O3-CaO-ZrO 2-TiO 2glasses containing lanthanides(Ce,Nd,Eu,Gd,Yb)and actinides(Th):Study of the crystallization from the surface[J].Journal of Nuclear Materials,2010,402(1):38-54.