新型光催化水处理反应器的研究进展及展望
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摘要
介绍各类典型光催化反应器,光催化与膜组件、超声波、微波及磁化技术的联用工艺。通过对现有光催化反应器的降解性能进行分析、归纳、总结,结合笔者所在课题组用3D打印技术研发出的新型鼓泡式光催化反应器,提出了光催化反应器在水污染治理方面进一步发展的方向。
This article introduced the typical process of various types of photocatalytic reactor,photocatalytic and membrane module,ultrasonic,microwave and magnetization technology.The degradation performance of the photocatalytic reactor was analyzed and summarized.Combined the new type of bubbling type photocatalytic reactor developed by3 Dprinting technology which incented by the author's group,the direction of the further development of the photocatalytic reactor in water pollution control was put forward.
This article introduced the typical process of various types of photocatalytic reactor,photocatalytic and membrane module,ultrasonic,microwave and magnetization technology.The degradation performance of the photocatalytic reactor was analyzed and summarized.Combined the new type of bubbling type photocatalytic reactor developed by3 Dprinting technology which incented by the author's group,the direction of the further development of the photocatalytic reactor in water pollution control was put forward.
引文
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[3]Wu X Y,Wang J T,Zhang G K,et al.Series of MxWO3/ZnO(M=K,Rb,NH4)Nanocompoites:Combination of Energy Saving and Environmental Decontamination Functions[J].Applied Catalysis B:Environmental,2017,201:128-136.
[4]Lu D,Zhang GK,Wang JT.Facile Synthesis of Anatase Titania Microspheres by a Novel Pyrolysis Method and Their Photocatalytic Properties[J].Materials Science in Semiconductor Processing,2014,27:985-993.
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[14]解立平,王能亮.一体式光催化氧化-膜分离三相流化床反应器[J].化学工程,2009,37(8):36-38,54.
[15]张宏忠,张钰,王明花,等.二氧化钛光催化膜分离耦合技术在水处理中的应用[J].无机盐工业,2017,49(7):50-54.
[16]Ma N,Quan X,Zhang Y,et al.Integration of Separation and Photocatalysis Using an Inorganic Membrane Modified with Si-doped Ti02for Water Purification[J].Journal of Membrane Science,2009,335(1-2):58-67.
[17]张萃,李亚峰,田西满.超声波辅助光催化氧化技术在废水处理中的研究进展[J].工业用水与废水,2009,40(3):16-18,22.
[18]Bae TH,Tak TM.Preparation of TiO2 Self-assembled Polymeric Nanocomposite Membranes and Examination of Their Fouling Mitigation Effects in a Membrane Bioreactor System[J].Journal of Membrane Science,2005(266):1-5.
[19]姜伟娟,张睿,许霞,等.超声/光催化氧化组合工艺对湖泊型原水藻类去除研究[A].中国环境科学学会.2010中国环境科学学会学术年会论文集(第三卷)[C].北京:中国环境科学学会,2010:4.
[20]李莉,张秀芬,马禹,等.微波增强TiO2光催化降解染料和水杨酸[J].化工学报,2008(12):3067-3072.
[21]郑坤,吴春笃,解清杰.旋转磁场光磁耦合多效污水处理装置[P].江苏:CN203741083U,2014-07-30.
[22]吴国枝,吴纯德,张捷鑫,等.超声、臭氧、光催化及其组合工艺处理苯酚废水[J].工业用水与废水,2007(5):38-41.
[23]赵硕伟,储金宇,顾立勇,李宁.超声波、臭氧协同复合氧化物体系光催化甲基橙的研究[J].安徽农业科学,2010,38(30):16735-16737.
[24]刘清香,雷雨晴,孙頔洋,等.微波辅助光催化-膜蒸馏降解活性黑的研究[J].水处理技术,2013,39(11):77-82.
[25]Kato H,Asakura K,Kudo A.Highly efficient water splitting into H2and O2over lanthanum-doped NaTaO3Photocatalysts with High Crystallinity and Surface Nanostructure[J].Journal of the American Chemical Society,2003,125(10):3082-3089.
[26]Wan Z,Zhang GK,Wang JT,Zhang YL.Synthesis,Characterization and Visible-light Photocatalytic Activity of Bi24Al2O39 Mesoporous Hollow Spheres[J].RSC Advances,2013,3(42):19617-19623.
[2]Wang J T,Xiao C,Wu X Y,et al.Potassium Tantalate K6Ta10.8O30with Tungsten Bronze Structure and Its Photocatalytic Property[J].Chinese Journal ofChemistry,2017,32(2):189-195.
[3]Wu X Y,Wang J T,Zhang G K,et al.Series of MxWO3/ZnO(M=K,Rb,NH4)Nanocompoites:Combination of Energy Saving and Environmental Decontamination Functions[J].Applied Catalysis B:Environmental,2017,201:128-136.
[4]Lu D,Zhang GK,Wang JT.Facile Synthesis of Anatase Titania Microspheres by a Novel Pyrolysis Method and Their Photocatalytic Properties[J].Materials Science in Semiconductor Processing,2014,27:985-993.
[5]Fujishima A,Honda K.Electrochemical Photolysis of Water at a Semiconductor Electrode[J].Nature,1972,238:37-38.
[6]Carey JH,Lawrence J,Tosine HM.Photo Dechlorination of PCB's in the Presence of Titanium Dioxide Inaqueous Suspensions[J].Bulletin of Environmental Contamination and Toxicology,1976,16:697-706.
[7]石金娥.具有光催化性能的几种半导体材料的制备、表征与应用[D].长春:东北师范大学,2008.
[8]桑雪梅,赵清华,王敏,等.旋转薄膜式光催化反应器降解水中有机污染物[J].环境科学与技术,2008(4):107-109,115.
[9]Puma G L,Yue P L.A Novel Fountain Photocatalytic Reactor:Model Development and Experimental Validation[J].Chemical Engineering Science,2001,56(8):2733-2744.
[10]陈作雁,安兴才,刘刚,等.多功能复合抛物面太阳能光催化反应器研制[J].太阳能学报,2015,36(2):447-451.
[11]顾宗梁,林少华.固定膜双层薄板反应器去除苯酚研究[J].森林工程,2011,27(6):51-53.
[12]童惠君,程黎放.深度处理有机废水的光催化装置[P].江苏:CN104261510A,2015-01-07.
[13]刘波,姚吉伦,庞治邦,等.TiO2光催化技术及其组合技术在水处理中的应用[J].兵器装备工程学报,2016,37(1):155-160.
[14]解立平,王能亮.一体式光催化氧化-膜分离三相流化床反应器[J].化学工程,2009,37(8):36-38,54.
[15]张宏忠,张钰,王明花,等.二氧化钛光催化膜分离耦合技术在水处理中的应用[J].无机盐工业,2017,49(7):50-54.
[16]Ma N,Quan X,Zhang Y,et al.Integration of Separation and Photocatalysis Using an Inorganic Membrane Modified with Si-doped Ti02for Water Purification[J].Journal of Membrane Science,2009,335(1-2):58-67.
[17]张萃,李亚峰,田西满.超声波辅助光催化氧化技术在废水处理中的研究进展[J].工业用水与废水,2009,40(3):16-18,22.
[18]Bae TH,Tak TM.Preparation of TiO2 Self-assembled Polymeric Nanocomposite Membranes and Examination of Their Fouling Mitigation Effects in a Membrane Bioreactor System[J].Journal of Membrane Science,2005(266):1-5.
[19]姜伟娟,张睿,许霞,等.超声/光催化氧化组合工艺对湖泊型原水藻类去除研究[A].中国环境科学学会.2010中国环境科学学会学术年会论文集(第三卷)[C].北京:中国环境科学学会,2010:4.
[20]李莉,张秀芬,马禹,等.微波增强TiO2光催化降解染料和水杨酸[J].化工学报,2008(12):3067-3072.
[21]郑坤,吴春笃,解清杰.旋转磁场光磁耦合多效污水处理装置[P].江苏:CN203741083U,2014-07-30.
[22]吴国枝,吴纯德,张捷鑫,等.超声、臭氧、光催化及其组合工艺处理苯酚废水[J].工业用水与废水,2007(5):38-41.
[23]赵硕伟,储金宇,顾立勇,李宁.超声波、臭氧协同复合氧化物体系光催化甲基橙的研究[J].安徽农业科学,2010,38(30):16735-16737.
[24]刘清香,雷雨晴,孙頔洋,等.微波辅助光催化-膜蒸馏降解活性黑的研究[J].水处理技术,2013,39(11):77-82.
[25]Kato H,Asakura K,Kudo A.Highly efficient water splitting into H2and O2over lanthanum-doped NaTaO3Photocatalysts with High Crystallinity and Surface Nanostructure[J].Journal of the American Chemical Society,2003,125(10):3082-3089.
[26]Wan Z,Zhang GK,Wang JT,Zhang YL.Synthesis,Characterization and Visible-light Photocatalytic Activity of Bi24Al2O39 Mesoporous Hollow Spheres[J].RSC Advances,2013,3(42):19617-19623.