水力空化在水处理领域的应用研究进展
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摘要
水力空化作为一种新型的废水物化处理技术具有潜在的应用前景,目前已开始应用于化工环保和能源环境领域。从理论研究与实际应用的角度出发,主要阐述了水力空化的概念与形成机理、空化效应以及该项技术在水处理领域的降解和杀菌原理,并对近年来水力空化在水处理方面的国内外技术应用与最新研究进展进行综述介绍。同时提出了目前该领域存在的问题,并对今后的发展方向与研究趋势做出预测和展望,对于进一步研究水力空化现象及应用具有一定的参考价值。
As a potentially promising new-type wastewater physicochemical treatment technology, hydrodynamic cavitation has been applied in the fields of chemical engineering, environment protection and energy environment at present. From the perspectives of theoretical research and practical application, the concept and mechanism of hydrodynamic cavitation, cavitation effect and the degradation and sterilization mechanism of hydrodynamic cavitation in water treatment field are expounded. Meanwhile, the updated progress in the research and application of hydraulic cavitation at home and abroad in the recent years are reviewed. Some main existing problems for now are put forward. Moreover, the developmental direction and tendency in this research field in the future are predicted and prospected. It is helpful for further study on hydrodynamic cavitation phenomenon and application.
As a potentially promising new-type wastewater physicochemical treatment technology, hydrodynamic cavitation has been applied in the fields of chemical engineering, environment protection and energy environment at present. From the perspectives of theoretical research and practical application, the concept and mechanism of hydrodynamic cavitation, cavitation effect and the degradation and sterilization mechanism of hydrodynamic cavitation in water treatment field are expounded. Meanwhile, the updated progress in the research and application of hydraulic cavitation at home and abroad in the recent years are reviewed. Some main existing problems for now are put forward. Moreover, the developmental direction and tendency in this research field in the future are predicted and prospected. It is helpful for further study on hydrodynamic cavitation phenomenon and application.
引文
[1]王西奎,邢乃军,王金刚,等.水力空化技术在有机废水处理中的应用[J].济南大学学报(自然科学版),2009, 23(1):38-41.
[2]魏群,高孟理,曾立云.水力空化技术及其研究进展[J].甘肃水利水电技术,2004, 40(4):334-336.
[3] GOGATE P R, PANDIT A B. A review and assessment of hydrodynamic cavitation as a technology for the future[J]. Ultrasonics Sonochemistry, 2005, 12(1-2):21-27.
[4] JYOTI K K, PANDIT A B. Ozone and cavitation for water disinfection[J]. Biochemical Engineering Journal, 2004, 18(1):9-19.
[5]李永峰,陈宜俍,郭士岭,等.超声波降解氯苯水溶液的研究[J].高校化学工程学报,2002, 16(1):93-96.
[6] GOGATE P R. Cavitation:An auxiliary technique in wastewater treatment schemes[J]. Advances in Environmental Research,2002, 6(3):335-358.
[7] VOGEL A, LAUTERBORN W, TIMM R. Optical and acoustic investigation of the dynamics of laser produce cavitation bubbles neara solid boundary[J]. Journal of Fluid Mechanics, 1989, 206:299-338.
[8] PANDIT A B, KUMAR P S, KUMAR M S. Improve reaction with hydrodynamic cavitation[J].Chemical Engineering Progress,1999, 95(5):43-50.
[9]张克危.流体机械原理(上册)[M].北京:机械工业出版社,2010.
[10]柯乃普RT,戴利JW,哈密脱FG.空化与空蚀[M].水利水电科学研究院,译.北京:水利出版社,1981.
[11] PANDIT A B, JOSHI J B. Hydrolysis of fatty oils:Effect of cavitation[J]. Chemical Engineering Science, 1993, 48(19):3440-3442.
[12]朱孟府,曾艳,邓橙,等.水力空化在水处理中的应用与研究进展[J].环境科学与技术,2010, 33(s2):445-449.
[13]古颖龙,王海燕,吴羽,等.空化微流体在生物医学方面的应用[J].激光生物学报,2014, 23(4):289-293.
[14]刘小兵,程良骏.空泡在任意流场中的运动研究[J].水动力学研究与进展,1994, 9(2):150-162.
[15]古孜扎尔·米吉提,地力拜·马力克,马忠庭,等.空化射流技术处理含油废水的应用研究进展[J].中国石油和化工标准与质量,2016, 36(19):121-122.
[16]王福霞,赵丽,付显威,等.空化初生研究综述[J].中国石油大学胜利学院学报,2006, 20(3):3-6.
[17] DIDENKO Y T, SUSLICK K S. The energy efficiency of formation of photons, radicals and ions during single-bubble cavitation[J].Nature, 2002, 418:394-397.
[18] HAMMITT F G. Cavitation and multiphase flow phenomena[M].New York:McGraw-Hill, 1980.
[19] GOGATE P R, PANDIT A B. Hydrodynamic cavitation reactors:A state of the art review[J]. Reviews in Chemical Engineering,2001, 17(1):1-85.
[20]管金发,邓松圣,雷飞东,等.空化水射流理论和应用研究[J].石油化工应用,2010, 29(12):15-19.
[21]冯中营.空化及其在杀菌中的应用[J].科学技术与工程,2010,10(5):1208-1210.
[22]王惠敏,孙三祥.水力空化及其研究现状[J].甘肃科技,2005,21(12):150-151,168.
[23]李虹霞,淮秀兰,李勋锋,等.水力空化防除垢实验研究[J].工程热物理学报,2010, 31(9):1531-1534.
[24]张宏伟,李大尉,宫禹,等.水的空化技术及其应用[J].黑龙江科学,2013, 4(5):21-23,46.
[25]张晓冬,杨会中,李志义.水力空化强度与空化自由基产量的关系[J].化工学报,2007,58(1):27-32.
[26] PRASAD NAIDU D V, RAJAN R, KUMAR R, et al. Modelling of a batch sonochemical reactor[J]. Chemical Engineering Science, 1994, 49(6):877-888.
[27]钱梦騄,彭若龙.单泡声致发光现象——气泡的稳定性[J].声学技术,2003, 22(2):130-135.
[28]白晓慧.超声波技术与污水污泥及难降解废水处理[J].工业水处理,2000, 20(12):8-10,14.
[29]张绍园.臭氧氧化在降解废水中有机污染物的应用[J].国外环境科学技术,1997(2):32-34.
[30]陈伟,范瑾初.超声降解水体中有机污染物技术综述[J].上海环境科学,1999, 18(10):457-460.
[31]魏群,肖波.水力空化技术在废水处理中的研究与应用进展[J].中国给水排水,2007, 23(2):13-16.
[32] BOTHA C J, BUCKLEY C A. Disinfection of potable water:The role of hydrodynamic cavitation[J]. Water Supply, 1995, 13(2):219-229.
[33] KALUMUCK K M, CHAHINE G L. The use of cavitating jets to oxidize organic compounds in water[J]. Journal of Fluids Engineering, 2000, 122(3):465-470.
[34] SIVAKUMAR M, PANDIT A B. Wastewater treatment:A novel energy efficient hydrodynamic cavitational technique[J]. Ultrasonics Sonochemistry, 2002, 9(3):123-131.
[35]陈利军,吴纯德,张捷鑫,等.水力空化强化H202氧化降解水中苯酚的研究[J].环境科学研究,2006, 19(3):67-70.
[36]乔慧琼,孙三祥,张健东.水力空化技术降解含苯酚、二甲苯废水的实验研究[J].能源环境保护,2007, 21(2):18-20,24.
[37] CHAKINALA A G, GOGATE P R, BURGESS A E, et al. Treatment of industrial wastewater effluents using hydrodynamic cavitation and the advanced Fenton process[J]. Ultrasonics Sonochemistry, 2008, 15(1):49-54.
[38]翟磊,董守平,冯高坡,等.水力空化与臭氧联合降解油田污水初步试验研究[J].科技导报,2009, 27(6):38-42.
[39]姚锐豪,董志勇,张凯.多孔板水力空化对降解化工废水的影响[J].环境污染与防治,2015, 37(9):5-8.
[40]张凯,董志勇,姚锐豪.力空化去除水中难降解亲水性和疏水性污染物[J].水力发电学报,2017, 36(8):50-57.
[41]李奎,朱孟府,邓橙,等.水力空化去除水中石油污染物实验研究[J].水处理技术,2017, 43(7):115-118.
[42]黄永春,李晴,邓冬梅,等.水力空化深度处理焦化废水的实验研究[J].工业水处理,2017, 37(4):53-57.
[43] SAVE S S, PANDIT A B, JOSHI J B. Use of hydrodynamic cavitation for large scale microbial cell disruption[J]. Food and Bioproducts Processing, 1997, 75(1):41-49.
[44] JYOTI K K, PANDIT A B. Water disinfection by acoustic and hydrodynamic cavitation[J]. Biochemical Engineering Journal,2001, 7(3):201-212.
[45]陈利军,吴纯德,张捷鑫.水力空化技术在饮用水消毒中的应用[J].水处理技术,2007, 33(3):45-48.
[46] MEZULE L, TSYFANSKY S, YAKUSHEVICH V, et al. A simple technique for water disinfection with hydrodynamic cavitation:Effect on survival of Escherichia coli[J]. Desalination, 2009, 248(1-3):152-159.
[47]王磊,董志勇,秦兆雨,等.变扩散角文丘里式水力空化杀灭原水中病原微生物试验研究[J].水力发电学报,2017, 36(9):75-81.
[48]陈乐,董志勇,刘昶,等.方孔多孔板水力空化杀灭大肠杆菌的实验研究[J].水力发电学报,2016, 35(9):48-54.
[49]刘昶,董志勇,陈乐,等.圆孔多孔板水力空化杀灭大肠杆菌的实验研究[J].中国环境科学,2016, 36(8):2364-2370.
[50]邓洁,许仕荣,张伟.水力空化强化效应的实验研究[J].兰州理工大学学报,2008, 34(5):72-76.
[51]邓洁,许仕荣.水力空化装置空化效果的最佳条件[J].四川建材,2007, 33(6):301-302,305.
[2]魏群,高孟理,曾立云.水力空化技术及其研究进展[J].甘肃水利水电技术,2004, 40(4):334-336.
[3] GOGATE P R, PANDIT A B. A review and assessment of hydrodynamic cavitation as a technology for the future[J]. Ultrasonics Sonochemistry, 2005, 12(1-2):21-27.
[4] JYOTI K K, PANDIT A B. Ozone and cavitation for water disinfection[J]. Biochemical Engineering Journal, 2004, 18(1):9-19.
[5]李永峰,陈宜俍,郭士岭,等.超声波降解氯苯水溶液的研究[J].高校化学工程学报,2002, 16(1):93-96.
[6] GOGATE P R. Cavitation:An auxiliary technique in wastewater treatment schemes[J]. Advances in Environmental Research,2002, 6(3):335-358.
[7] VOGEL A, LAUTERBORN W, TIMM R. Optical and acoustic investigation of the dynamics of laser produce cavitation bubbles neara solid boundary[J]. Journal of Fluid Mechanics, 1989, 206:299-338.
[8] PANDIT A B, KUMAR P S, KUMAR M S. Improve reaction with hydrodynamic cavitation[J].Chemical Engineering Progress,1999, 95(5):43-50.
[9]张克危.流体机械原理(上册)[M].北京:机械工业出版社,2010.
[10]柯乃普RT,戴利JW,哈密脱FG.空化与空蚀[M].水利水电科学研究院,译.北京:水利出版社,1981.
[11] PANDIT A B, JOSHI J B. Hydrolysis of fatty oils:Effect of cavitation[J]. Chemical Engineering Science, 1993, 48(19):3440-3442.
[12]朱孟府,曾艳,邓橙,等.水力空化在水处理中的应用与研究进展[J].环境科学与技术,2010, 33(s2):445-449.
[13]古颖龙,王海燕,吴羽,等.空化微流体在生物医学方面的应用[J].激光生物学报,2014, 23(4):289-293.
[14]刘小兵,程良骏.空泡在任意流场中的运动研究[J].水动力学研究与进展,1994, 9(2):150-162.
[15]古孜扎尔·米吉提,地力拜·马力克,马忠庭,等.空化射流技术处理含油废水的应用研究进展[J].中国石油和化工标准与质量,2016, 36(19):121-122.
[16]王福霞,赵丽,付显威,等.空化初生研究综述[J].中国石油大学胜利学院学报,2006, 20(3):3-6.
[17] DIDENKO Y T, SUSLICK K S. The energy efficiency of formation of photons, radicals and ions during single-bubble cavitation[J].Nature, 2002, 418:394-397.
[18] HAMMITT F G. Cavitation and multiphase flow phenomena[M].New York:McGraw-Hill, 1980.
[19] GOGATE P R, PANDIT A B. Hydrodynamic cavitation reactors:A state of the art review[J]. Reviews in Chemical Engineering,2001, 17(1):1-85.
[20]管金发,邓松圣,雷飞东,等.空化水射流理论和应用研究[J].石油化工应用,2010, 29(12):15-19.
[21]冯中营.空化及其在杀菌中的应用[J].科学技术与工程,2010,10(5):1208-1210.
[22]王惠敏,孙三祥.水力空化及其研究现状[J].甘肃科技,2005,21(12):150-151,168.
[23]李虹霞,淮秀兰,李勋锋,等.水力空化防除垢实验研究[J].工程热物理学报,2010, 31(9):1531-1534.
[24]张宏伟,李大尉,宫禹,等.水的空化技术及其应用[J].黑龙江科学,2013, 4(5):21-23,46.
[25]张晓冬,杨会中,李志义.水力空化强度与空化自由基产量的关系[J].化工学报,2007,58(1):27-32.
[26] PRASAD NAIDU D V, RAJAN R, KUMAR R, et al. Modelling of a batch sonochemical reactor[J]. Chemical Engineering Science, 1994, 49(6):877-888.
[27]钱梦騄,彭若龙.单泡声致发光现象——气泡的稳定性[J].声学技术,2003, 22(2):130-135.
[28]白晓慧.超声波技术与污水污泥及难降解废水处理[J].工业水处理,2000, 20(12):8-10,14.
[29]张绍园.臭氧氧化在降解废水中有机污染物的应用[J].国外环境科学技术,1997(2):32-34.
[30]陈伟,范瑾初.超声降解水体中有机污染物技术综述[J].上海环境科学,1999, 18(10):457-460.
[31]魏群,肖波.水力空化技术在废水处理中的研究与应用进展[J].中国给水排水,2007, 23(2):13-16.
[32] BOTHA C J, BUCKLEY C A. Disinfection of potable water:The role of hydrodynamic cavitation[J]. Water Supply, 1995, 13(2):219-229.
[33] KALUMUCK K M, CHAHINE G L. The use of cavitating jets to oxidize organic compounds in water[J]. Journal of Fluids Engineering, 2000, 122(3):465-470.
[34] SIVAKUMAR M, PANDIT A B. Wastewater treatment:A novel energy efficient hydrodynamic cavitational technique[J]. Ultrasonics Sonochemistry, 2002, 9(3):123-131.
[35]陈利军,吴纯德,张捷鑫,等.水力空化强化H202氧化降解水中苯酚的研究[J].环境科学研究,2006, 19(3):67-70.
[36]乔慧琼,孙三祥,张健东.水力空化技术降解含苯酚、二甲苯废水的实验研究[J].能源环境保护,2007, 21(2):18-20,24.
[37] CHAKINALA A G, GOGATE P R, BURGESS A E, et al. Treatment of industrial wastewater effluents using hydrodynamic cavitation and the advanced Fenton process[J]. Ultrasonics Sonochemistry, 2008, 15(1):49-54.
[38]翟磊,董守平,冯高坡,等.水力空化与臭氧联合降解油田污水初步试验研究[J].科技导报,2009, 27(6):38-42.
[39]姚锐豪,董志勇,张凯.多孔板水力空化对降解化工废水的影响[J].环境污染与防治,2015, 37(9):5-8.
[40]张凯,董志勇,姚锐豪.力空化去除水中难降解亲水性和疏水性污染物[J].水力发电学报,2017, 36(8):50-57.
[41]李奎,朱孟府,邓橙,等.水力空化去除水中石油污染物实验研究[J].水处理技术,2017, 43(7):115-118.
[42]黄永春,李晴,邓冬梅,等.水力空化深度处理焦化废水的实验研究[J].工业水处理,2017, 37(4):53-57.
[43] SAVE S S, PANDIT A B, JOSHI J B. Use of hydrodynamic cavitation for large scale microbial cell disruption[J]. Food and Bioproducts Processing, 1997, 75(1):41-49.
[44] JYOTI K K, PANDIT A B. Water disinfection by acoustic and hydrodynamic cavitation[J]. Biochemical Engineering Journal,2001, 7(3):201-212.
[45]陈利军,吴纯德,张捷鑫.水力空化技术在饮用水消毒中的应用[J].水处理技术,2007, 33(3):45-48.
[46] MEZULE L, TSYFANSKY S, YAKUSHEVICH V, et al. A simple technique for water disinfection with hydrodynamic cavitation:Effect on survival of Escherichia coli[J]. Desalination, 2009, 248(1-3):152-159.
[47]王磊,董志勇,秦兆雨,等.变扩散角文丘里式水力空化杀灭原水中病原微生物试验研究[J].水力发电学报,2017, 36(9):75-81.
[48]陈乐,董志勇,刘昶,等.方孔多孔板水力空化杀灭大肠杆菌的实验研究[J].水力发电学报,2016, 35(9):48-54.
[49]刘昶,董志勇,陈乐,等.圆孔多孔板水力空化杀灭大肠杆菌的实验研究[J].中国环境科学,2016, 36(8):2364-2370.
[50]邓洁,许仕荣,张伟.水力空化强化效应的实验研究[J].兰州理工大学学报,2008, 34(5):72-76.
[51]邓洁,许仕荣.水力空化装置空化效果的最佳条件[J].四川建材,2007, 33(6):301-302,305.