弱相互作用调控表面活性剂自组装(V)——在纳米材料制备方面的应用
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摘要
通过调节表面活性剂之间,表面活性剂与前驱体之间以及表面活性剂与溶剂之间的弱相互作用,可以制备形貌和功能多样的介孔二氧化硅、贵金属纳米材料和超分子材料。除了传统的以表面活性剂形成的聚集体(胶束、囊泡、液晶等)作为模板制备纳米材料外,还可以利用表面活性剂中引入的响应性基团简化制备过程,提高材料的循环使用。采用有机-无机共组装的方法制备超分子材料更是具有广阔的应用前景。
Mesoporous silica, noble metal nanomaterials and supramolecular materials with various morphologies and functions can be prepared by adjusting the weak interactions between surfactants, surfactants and precursors or surfactants and solvents. In addition to the traditional surfactant-forming aggregates(micelles, vesicles, liquid crystals, etc.)as templates for the preparation of nanomaterials, the responsive groups introduced in the molecule can be used to simplify the preparation process and improve the recycling of the materials. The preparation of composite nanomaterials by organic-inorganic co-assembly method has broad application prospects.
Mesoporous silica, noble metal nanomaterials and supramolecular materials with various morphologies and functions can be prepared by adjusting the weak interactions between surfactants, surfactants and precursors or surfactants and solvents. In addition to the traditional surfactant-forming aggregates(micelles, vesicles, liquid crystals, etc.)as templates for the preparation of nanomaterials, the responsive groups introduced in the molecule can be used to simplify the preparation process and improve the recycling of the materials. The preparation of composite nanomaterials by organic-inorganic co-assembly method has broad application prospects.
引文
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[31]Li Jingfang,Chen Zhijun,Zhou Mengcheng,et al.Polyoxometalate-driven self-assembly of short peptides into multivalent nanofibers with enhanced antibacterial activity[J].Angew.Chem.Int.Ed.,2016,55(7):2592-2595.
[32]Gong Yanjun,Guo Yongxian,Hu Qiongzheng,et al.pH-Responsive polyoxometalate-based supramolecular hybrid nanomaterials and application as renewable catalyst for dyes[J].ACS Sustain.Chem.Eng.,2017,5(5):3650-3658.
[2]Xiao Junyan,Qi Limin.Surfactant-assisted,shape-controlled synthesis of gold nanocrystals[J].Nanoscale,2011,3(4):1383-1396.
[3]Yoo H,Sharma J,Yeh H C,et al.Solution-phase synthesis of Au fibers using rod-shaped micelles as shape directing agents[J].Chem.Commun.,2010,46(36):6813-6815.
[4]Yoo H,Jang M H.Size-controlled synthesis of gold bipyramids using an aqueous mixture of CTAC and salicylate anions as the soft template[J].Nanoscale,2013,5(15):6708-6712.
[5]Zhu C,Peng H C,Zeng J,et al.Facile synthesis of gold wavy nanowires and investigation of their growth mechanism[J].J.Am.Chem.Soc.,2012,134(50):20234-20237.
[6]Gai Fangyuan,Zhou Tianlei,Chu Guang,et al.Mixed anionic surfactant-templated mesoporous silica nanoparticles for fluorescence detection of Fe3+[J].Dalton T.,2016,45(2):508-514.
[7]Lokupitiya H N,Jones A,Reid B,et al.Ordered mesoporous to macroporous oxides with tunable isomorphic architectures:solution criteria for persistent micelle templates[J].Chem.Mater.,2016,28(6):1653-1667.
[8]Gao Xinpei,Lu Fei,Shi Lijuan,et al.Nanostructured aqueous lithium-ion conductors formed by the self-assembly of imidazoliumtype zwitterions[J].ACS Appl.Mater.Inter.,2013,5(24):13312-13317.
[9]Gao Xinpei,Lu Fei,Dong Bin,et al.Facile synthesis of gold and gold-based alloy nanowire networks using wormlike micelles as soft templates[J].Chem.Commun.,2015,51(5):843-846.
[10]Gao Xinpei,Lu Fei,Yang Wenjiang,et al.Wormlike micelle templated synthesis of monoand bi-metallic nanochain networks with adjustable structure and constituents[J].RSC Adv.,2016,6(72):67495-67501.
[11]Mesa G L,Sesta B,Bonicelli M G,et al.Phase diagram of the binary system water-(dodecyldimethylammonio)propanesulfonate[J].Langmuir,1990,6(4):728-731.
[12]Dong Renhao,Liu Weimin,Hao Jingcheng.Soft vesicles in the synthesis of hard materials[J].Accounts Chem.Res.,2012,45(4):504-513.
[13]Hubert D H W,Jung M,Frederik P M,et al.Vesicle-directed growth of silica[J].Adv.Mater.,2000,12(17):1286-1290.
[14]Wang Wentao,Han Yuchun,Tian Maozhang,et al.Cationic Gemini surfactant-assisted synthesis of hollow Au nanostructures by stepwise reductions[J].ACS Appl.Mater.Inter.,2013,5(12):5709-5716.
[15]Gao Xinpei,Lu Fei,Dong Bin,et al.Zwitterionic vesicles with AuCl4-counterions as soft templates for the synthesis of gold nanoplates and nanospheres[J].Chem.Commun.,2014,50(63):8783-8786.
[16]Akbar S,Elliott J M,Rittman M,et al.Facile production of ordered3D platinum nanowire networks with“single diamond”bicontinuous cubic morphology[J].Adv.Mater.,2013,25(8):1160-1164.
[17]Yamauchi Y,Tonegawa A,Komatsu M,et al.Electrochemical synthesis of mesoporous Pt-Au binary alloys with tunable compositions for enhancement of electrochemical performance[J].J.Am.Chem.Soc.,2012,134(11):5100-5109.
[18]Li Anhu,Zhou Yonggui,Dai Lixin,et al.Asymmetric aziridination over ylides:highly stereoselective synthesis of acetylenyl-N-sulfonylaziridines[J].Angew.Chem.Int.Ed.,1997,36(12):1317-1319.
[19]Liang Y C,Juan Y W,Lu K T,et al.Formation process of mesostructured PtRu nanoparticles electrodeposited on a microemulsion lyotropic liquid crystalline template as revealed by in situ XRD,SAXS,and XANES[J].J.Phys.Chem.C,2012,116(50):26649-26655.
[20]Lu Xili,Zhang Hu,Fei Guoxia,et al.Liquid-crystalline dynamic networks doped with gold nanorods showing enhanced photocontrol of actuation[J].Adv.Mater.,2018,30(14):1706597.
[21]Zhang Yongmin,Feng Yujun,Wang Yuejiao,et al.CO2 switchable viscoelastic fluids based on a pseudogemini surfactant[J].Langmuir,2013,29(13):4187-4192.
[22]Jessop P G,Mercera S M,Heldebrant D J.CO2-triggered switchable solvents,surfactants,and other materials[J].Energ.Environ.Sci.,2012,5(6):7240-7253.
[23]Wei Jing,Liu Yuyun,Chen Jia,et al.Azobenzene-derived surfactants as phototriggered recyclable templates for the synthesis of ordered mesoporous silica nanospheres[J].Adv.Mater.,2014,26(11):1782-1787.
[24]Liu Yingxin,Jessop P G,Cunningham M,et al.Switchable surfactants[J].Science,2006,313(5789):954-958.
[25]Jiang Jianzhong,Yin Jinchao,Dai Li,et al.Facile synthesis of mesoporous silica by CO2/N2 switchable templates using a convenient compound[J].RSC Adv.,2017,7(40):25066-25069.
[26]Rana R K,Murthy V S,Yu Jie,et al.Nanoparticle self-assembly of hierarchically ordered microcapsule structure[J].J.Mater.Chem.,2005,17(9):1145-1150.
[27]Zhao Zhongkui,Wang Xianhui,Jiao Yanhua,et al.Facile,lowcost,and scalable fabrication of particle size and pore structure tuneable monodisperse mesoporous silica nanospheres as supports for advanced solid acid catalysts[J].RSC Adv.,2016,6(11):9072-9081.
[28]Zhang Jing,Chen Xiaofei,Li Wen,et al.Solvent dielectricitymodulated helical assembly and morphologic transformation of achiral surfactant-inorganic cluster ionic complexes[J].Langmuir,2017,33(44):12750-12758.
[29]Shen Jinglin,Wang Zhi,Sun Di.Self-assembly of water-soluble silver nanoclusters:superstructure formation and morphological evolution[J].Nanoscale,2017,9(48):19191-19200.
[30]Nisar A,Lu Yao,Zhuang Jing,et al.Polyoxometalate nanocone nanoreactors:magnetic manipulation and enhanced catalytic performance[J].Angew.Chem.Int.Ed.,2011,50(14):3187-3192.
[31]Li Jingfang,Chen Zhijun,Zhou Mengcheng,et al.Polyoxometalate-driven self-assembly of short peptides into multivalent nanofibers with enhanced antibacterial activity[J].Angew.Chem.Int.Ed.,2016,55(7):2592-2595.
[32]Gong Yanjun,Guo Yongxian,Hu Qiongzheng,et al.pH-Responsive polyoxometalate-based supramolecular hybrid nanomaterials and application as renewable catalyst for dyes[J].ACS Sustain.Chem.Eng.,2017,5(5):3650-3658.