石墨烯/碳纳米管增强氧化铝陶瓷涂层的耐腐蚀性能研究

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英文篇名：Study on Corrosion Resistance of Graphene/Carbon Nanotubes Reinforced Alumina Ceramic Coatings 作者：黄华栋 ; 卞达 ; 秦卢梦 ; 赵永武 ; 关集俱 英文作者：HUANG Huadong;BIAN Da;QIN Lumeng;ZHAO Yongwu;GUAN Jiju;Suzhou Institute of Industrial Technology;School of Mechanical Engineering, Jiangnan University; 关键词：石墨烯 ; 碳纳米管 ; 氧化铝陶瓷涂层 ; 耐腐蚀性 英文关键词：Graphene;;Carbon nanotubes;;Alumina ceramic coating;;Corrosion resistance 中文刊名：ZGTC 英文刊名：China Ceramics 机构：苏州工业职业技术学院;江南大学机械工程学院; 出版日期：2019-05-05 出版单位：中国陶瓷 年：2019 期：v.55;No.366 基金：国家自然科学基金(51675232,51805345);; 江苏省自然科学基金(BK20170373);; 江苏高校品牌专业建设工程基金(PPZY2015B186);; 苏州市重点实验室资助基金(SZS201815) 语种：中文; 页：ZGTC201905001 页数：6 CN：05 ISSN：36-1090/TQ 分类号：6-11

摘要

为了提高氧化铝陶瓷涂层性能,将碳纳米管及石墨烯的一种或两种材料植入涂层中。并对氧化铝陶瓷涂层开展电化学试验进行耐腐蚀性能研究,研究结果表明:添加0.2%石墨烯和0.2%混杂功能化碳纳米管的复合涂层的耐腐蚀性能最优异,电流密度从2.890×10~(-6) A/cm~2下降到1.536×10~(-6) A/cm~2,电阻抗从11388Ω提高到28079Ω,耐腐蚀效率最大46.85%。微观结构表明,相比于纯的氧化铝涂层,碳纳米管和石墨烯的植入能提高陶瓷涂层的致密性,同时,碳纳米管和石墨烯的结构能够有效阻断裂纹扩散,从而起到保护基体的作用。
        To improve the corrosion resistance of the alumina ceramic coating, the carbon nanotube and gaphene are selected as the reinforcement. The corrosion behavior was investigaed based on the electrochemical experiment. The result shows that, the ceramic coating reinforced with both carbon nanotubes and graphene shows the best corrosion resistances among all samples. The corrosion current density of this coating decreases from 2.890×10~(-6) A/cm~2(the corrosion current density of pure substrate)to 1.536×10~(-6) A/cm~2. Besides, the electrical impedance increases from 11388 Ω to 28079 Ω, and corrosion resistant efficiency reaches to 46.85%. The Micro-structure investigation shows that, compared with pure alumina coating, The addition of carbon nanotubes and graphene can improve the compactness of the ceramic coating. In addition, the structure of carbon nanotubes and graphene can effectively block the crack diffusion, thus protecting the matrix.

引文

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