聚合物基纳米复合材料的界面作用研究进展
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摘要
将聚合物与纳米粒子复合制备性能优异的聚合物基纳米复合材料是近20年来科学界的研究热点,其中聚合物与纳米粒子间的界面作用对复合材料的性能起着关键性作用。从界面结构、力学性能、热性能及计算机仿真模拟等方面综述了聚合物基纳米复合材料的界面研究进展,并对这一领域的研究进行了展望。
Polymer matrix nanocomposites with excellent properties which are prepared from polymer and nanoparticles is a hot research topic during the past two decades,and the interfacial interaction between polymer and nanoparticles is of key importance for the properties of the composites.Based on a rich amount of literatures,the progress of interfacial interaction about polymer based nanocomposites is reviewed from the perspectives interface structure,mechanical properties,thermal properties,and computer simulation in this paper,and meanwhile,the research prospect of this field is discussed.
Polymer matrix nanocomposites with excellent properties which are prepared from polymer and nanoparticles is a hot research topic during the past two decades,and the interfacial interaction between polymer and nanoparticles is of key importance for the properties of the composites.Based on a rich amount of literatures,the progress of interfacial interaction about polymer based nanocomposites is reviewed from the perspectives interface structure,mechanical properties,thermal properties,and computer simulation in this paper,and meanwhile,the research prospect of this field is discussed.
引文
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9 Lizundia E,Ruiz Rubio L,Vilas J L,et al.Poly(l-lactide)/ZnO nanocomposites as efficient UV-shielding coatings for packaging applications[J].Journal of Applied Polymer Science,2016,133(2):42426.
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26 Gennes P G D.Polymers at an interface:A simple view[J].Advances in Colloid&Interface Science,1987,27(3-4):189.
27 Guiselin O.First measurement of the discontinuity jump in a reflectivity curve near total reflection edge[J].Europhysics Letters,1992,17:57.
28 Semenov A N,Bonet-Avalas J,Johner A,et al.Adsorption of polymer solutions onto a flat surface[J].Macromolecules,1996,29(6):2179.
29 Theodorou D N.Lattice models for bulk polymers at interfaces[J].Macromolecules,1988,21(5):1391.
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36 Li Y,Yang T,Yu T,et al.Synergistic effect of hybrid carbon nanotube-graphene oxide as a nanofiller in enhancing the mechanical properties of PVA composites[J].Journal of Materials Chemistry,2011,21(29):10844.
37 Hwang S H,Kang D,Ruoff R S,et al.Poly(vinyl alcohol)reinforced and toughened with poly(dopamine)-treated graphene oxide,and its use for humidity sensing[J].ACS Nano,2014,8(7):6739.
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39 Zaman I,Phan T T,Kuan H C,et al.Epoxy/graphene platelets nanocomposites with two levels of interface strength[J].Polymer,2011,52(7):1603.
40 Cheng Guojun,Song Ruijuan,Miao Jibin,et al.Characterization of interfacial structure of polymer nanocomposites[J].Materials Review A:Review Papers,2012,26(6):130(in Chinese).程国君,宋瑞娟,苗继斌,等.聚合物纳米复合材料界面结构的表征[J].材料导报:综述篇,2012,26(6):130.
41 Hoshino J,Limpanart S,Khunthon S,et al.Adsorption of singlestrand alkylammonium salts on bentonite,surface properties of the modified clay and polymer nanocomposites formation by a two-roll mill[J].Materials Chemistry&Physics,2010,123(2-3):706.
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43 Zhang Li,Shen Shijie.The research of fiber reinforced polymer interface[J].Fiber Composites,2011,28(4):30(in Chinese).张莉,申士杰.纤维增强树脂基复合材料界面结合机理研究现状[J].纤维复合材料,2011,28(4):30.
44 Hong S,Leroueil P R,Janus E K,et al.Interaction of polycationic polymers with supported lipid bilayers and cells:Nanoscale hole formation and enhanced membrane permeability[J].Bioconjugate Chemistry,2006,17(3):728.
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46 Peetla C,Labhasetwar V.Effect of molecular structure of cationic surfactants on biophysical interactions of surfactant-modified nanoparticles with a model membrane and cellular uptake[J].Langmuir,2009,25(4):2369.
47 Jing B,Hutin M,Connor E,et al.Polyoxometalate macroion induced phase and morphology instability of lipid membrane[J].Chemical Science,2013,4(10):3818.
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52 Wu L,Jiang X.Recent developments in methodology employed to study the interactions between nanomaterials and model lipid membranes[J].Analytical and Bioanalytical Chemistry,2016,408(11):1.
53 Zhang L,Luo M,Sun S,et al.Effect of surface structure of nanoCaCO3particles on mechanical and rheological properties of PVC composites[J].Journal of Macromolecular Science Part B,2010,49(5):970.
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58 Jiang C,He H,Jiang H,et al.Nano-lignin filled natural rubber composites:Preparation and characterization[J].Express Polymer Letters,2013,7(5):480.
59 Zhang S,Guo M,Chen Z,et al.Grafting photosensitive polyurethane onto colloidal silica for use in UV-curing polyurethane nanocomposites[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,443(4):525.
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2 Zhang W,Ma J,Gao D,et al.Preparation of amino-functionalized graphene oxide by Hoffman rearrangement and its performances on polyacrylate coating latex[J].Progress in Organic Coatings,2016,94:9.
3 Merkel T C,Freeman B D,Spontak R J,et al.Sorption,transport,and structural evidence for enhanced free volume in poly(4-methyl-2-pentyne)/fumed silica nanocomposite membranes[J].Chemistry of Materials,2016,15(1):109.
4 Shaohui L,Jiwei Z,Jinwen W,et al.Enhanced energy storage density in poly(vinylidene fluoride)nanocomposites by a small loading of suface-hydroxylated Ba0.6Sr0.4TiO3 nanofibers[J].ACS Applied Materials&Interfaces,2016,6(3):1533.
5 Bodakhe S,Verma S,Garkhal K,et al.Injectable photocrosslinkable nanocomposite based on poly(glycerol sebacate)fumarate and hydroxyapatite:Development,biocompatibility and bone regeneration in a rat calvarial bone defect model[J].Nanomedicine,2017,8(11):1777.
6 Subramani N K,Nagaraj S K,Shivanna S,et al.Highly flexible and visibly transparent poly(vinyl alcohol)/calcium zincate nanocomposite films for UVA shielding applications as assessed by novel ultraviolet photon induced fluorescence quenching[J].Macromolecules,2016,49(7):2791.
7 Jeon H,Park S,Nam S,et al.Spin self-assembled clay nanocomposite passivation layers made from a photocrosslinkable poly(vinyl alcohol)and Na+-montmorillonite enhance the environmental stability of organic thin-film transistors[J].Chinese Journal of Chemistry,2016,34(11):1103.
8 Imran S M,Shao G N,Haider M S,et al.Carbon nanotube-based thermoplastic polyurethane-poly(methyl methacrylate)nanocomposites for pressure sensing applications[J].Polymer Engineering&Science,2016,56(9):1031.
9 Lizundia E,Ruiz Rubio L,Vilas J L,et al.Poly(l-lactide)/ZnO nanocomposites as efficient UV-shielding coatings for packaging applications[J].Journal of Applied Polymer Science,2016,133(2):42426.
10 Lei J,Tao Y,Yan L,et al.Preparation of Au-polydopamine functionalized carbon encapsulated Fe3O4 magnetic nanocomposites and their application for ultrasensitive detection of carcino-embryonic antigen[J].Scientific Reports,2016,6:21017.
11 Liu C,Yan H,Lv Q,et al.Enhanced tribological properties of aligned reduced graphene oxide-Fe3O4@polyphosphazene/bismaleimides composites[J].Carbon,2016,102:145.
12 Bao Y,Shi C,Ma J,et al.Double in-situ synthesis of polyacrylate/nano-TiO2composite latex[J].Progress in Organic Coatings,2015,85:101.
13 Ma J,Xu Q,Zhou J,et al.Nano-scale core-shell structural casein based coating latex:Synthesis,characterization and its biodegradability[J].Progress in Organic Coatings,2013,76(10):1346.
14 Bao Y,Ma J,Li N.Synthesis and swelling behaviors of sodium carboxymethyl cellulose-g-poly(AA-co-AM-co-AMPS)/MMT superabsorbent hydrogel[J].Carbohydrate Polymers,2011,84(1):76.
15 Xue C H,Ma J Z.Long-lived superhydrophobic surfaces[J].Journal of Materials Chemistry A,2013,1(13):4146.
16 Xu Q,Fan Q,Ma J,et al.Facile synthesis of casein-based TiO2nanocomposite for self-cleaning and high covering coatings:Insights from TiO2dosage[J].Progress in Organic Coatings,2016,99:223.
17 Petrella A,Tamborra M,Curri M L,et al.Colloidal TiO2nanocrystals/MEH-PPV nanocomposites:Photo(electro)chemical study[J].Journal of Physical Chemistry B,2005,109(4):1554.
18 Zhang J,Wang B J,Ju X,et al.New observations on the optical properties of PPV/TiO2nanocomposites[J].Polymer,2001,42(8):3697.
19 Savenije T J,Warman J M,Goossens A.Visible light sensitisation of titanium dioxide using aphenylene vinylene polymer[J].Chemical Physics Letters,1998,287(1):148.
20 Salafsky J S.Exciton dissociation,charge transport,and recombination in ultrathin,conjugated polymer-TiO2 nanocrystal intermixed composites[J].Physical Review B,1999,59(16):293.
21 Chamis C C.Computerized multilevel analysis for multilayered fiber composites[J].Computers&Structures,1973,3(3):467.
22 Adams D F,Walrath D E.Iosipescu shear properties of SMC composite materials[C]∥Composite Materials:Testing and Design(6th Conference).ASTM International,1982:19.
23 Gent A N,Wang C.Fracture mechanics and cavitation in rubber-like solids[J].Journal of Materials Science,1991,26(12):3392.
24 Zhou L M,Mai Y W,Ye L.Analyses of fibre push-out test based on the fracture mechanics approach[J].Composites Engineering,1995,5(10-11):1199.
25 Scheutjens J M H M,Fleer G J.Statistical theory of the adsorption of interacting chain molecules.2.Train,loop,and tail size distribution[J].Journal of Physical Chemistry,1980,84(2):178.
26 Gennes P G D.Polymers at an interface:A simple view[J].Advances in Colloid&Interface Science,1987,27(3-4):189.
27 Guiselin O.First measurement of the discontinuity jump in a reflectivity curve near total reflection edge[J].Europhysics Letters,1992,17:57.
28 Semenov A N,Bonet-Avalas J,Johner A,et al.Adsorption of polymer solutions onto a flat surface[J].Macromolecules,1996,29(6):2179.
29 Theodorou D N.Lattice models for bulk polymers at interfaces[J].Macromolecules,1988,21(5):1391.
30 Tannenbaum R,Zubris M,David K,et al.FTIR characterization of the reactive interface of cobalt oxide nanoparticles embedded in polymeric matrices[J].Journal of Physical Chemistry B,2006,110(5):2227.
31 Lou Yuanhua,Liu Meihong,Wang Xinping.Study on the interfacial structure of inorganic particles polymer nanocomposites[J].Polymer Bulletin,2009(4):38(in Chinese).娄渊华,刘梅红,王新平.纳米无机粒子/聚合物复合材料界面结构的研究[J].高分子通报,2009(4):38.
32 Doganay D,Coskun S,Kaynak C,et al.Electrical,mechanical and thermal properties of aligned silver nanowire/polylactide nanocomposite films[J].Composites Part B Engineering,2016,99:288.
33 Goumri M,Venturini J W,Bakour A,et al.Tuning the luminescence and optical properties of graphene oxide and reduced graphene oxide functionnalized with PVA[J].Applied Physics A,2016,122(3):212.
34 She X,He C,Peng Z,et al.Molecular-level dispersion of graphene into epoxidized natural rubber:Morphology,interfacial interaction and mechanical reinforcement[J].Polymer,2014,55(26):6803.
35 Shao L,Li J,Yu G,et al.PVA/polyethyleneimine-functionalized graphene composites with optimized properties[J].Materials&Design,2016,99:235.
36 Li Y,Yang T,Yu T,et al.Synergistic effect of hybrid carbon nanotube-graphene oxide as a nanofiller in enhancing the mechanical properties of PVA composites[J].Journal of Materials Chemistry,2011,21(29):10844.
37 Hwang S H,Kang D,Ruoff R S,et al.Poly(vinyl alcohol)reinforced and toughened with poly(dopamine)-treated graphene oxide,and its use for humidity sensing[J].ACS Nano,2014,8(7):6739.
38 Lin Y,Liu L,Xu G,et al.Interfacial interactions and segmental dynamics of poly(vinyl acetate)/silica nanocomposites[J].Journal of Physical Chemistry C,2015,119(23):12956.
39 Zaman I,Phan T T,Kuan H C,et al.Epoxy/graphene platelets nanocomposites with two levels of interface strength[J].Polymer,2011,52(7):1603.
40 Cheng Guojun,Song Ruijuan,Miao Jibin,et al.Characterization of interfacial structure of polymer nanocomposites[J].Materials Review A:Review Papers,2012,26(6):130(in Chinese).程国君,宋瑞娟,苗继斌,等.聚合物纳米复合材料界面结构的表征[J].材料导报:综述篇,2012,26(6):130.
41 Hoshino J,Limpanart S,Khunthon S,et al.Adsorption of singlestrand alkylammonium salts on bentonite,surface properties of the modified clay and polymer nanocomposites formation by a two-roll mill[J].Materials Chemistry&Physics,2010,123(2-3):706.
42 Wilson K S,Washburn A N R.Interphase effects in dental nanocomposites investigated by small-angle neutron scattering[J].Journal of Biomedical Materials Research Part A,2007,81(1):113.
43 Zhang Li,Shen Shijie.The research of fiber reinforced polymer interface[J].Fiber Composites,2011,28(4):30(in Chinese).张莉,申士杰.纤维增强树脂基复合材料界面结合机理研究现状[J].纤维复合材料,2011,28(4):30.
44 Hong S,Leroueil P R,Janus E K,et al.Interaction of polycationic polymers with supported lipid bilayers and cells:Nanoscale hole formation and enhanced membrane permeability[J].Bioconjugate Chemistry,2006,17(3):728.
45 Leroueil P R,Berry S A,Duthie K,et al.Wide varieties of cationic nanoparticles induce defects in supported lipid bilayers[J].Nano Letters,2008,8(2):420.
46 Peetla C,Labhasetwar V.Effect of molecular structure of cationic surfactants on biophysical interactions of surfactant-modified nanoparticles with a model membrane and cellular uptake[J].Langmuir,2009,25(4):2369.
47 Jing B,Hutin M,Connor E,et al.Polyoxometalate macroion induced phase and morphology instability of lipid membrane[J].Chemical Science,2013,4(10):3818.
48 van Lehn R C,Ricci M,Silva P H,et al.Lipid tail protrusions mediate the insertion of nanoparticles into model cell membranes[J].Nature Communications,2014,5:4482.
49 Roiter Y,Ornatska M,Rammohan A R,et al.Interaction of nanoparticles with lipid membrane[J].Nano Letters,2008,8(3):941.
50 Xiao X,Monta1o G A,Edwards T L,et al.Surface charge dependent nanoparticle disruption and deposition of lipid bilayer assemblies[J].Langmuir,2012,28(50):17396.
51 Dong H,Ye P,Zhong M,et al.Superhydrophilic surfaces via polymer-SiO2nanocomposites[J].Langmuir the ACS Journal of Surfaces&Colloids,2010,26(19):15567.
52 Wu L,Jiang X.Recent developments in methodology employed to study the interactions between nanomaterials and model lipid membranes[J].Analytical and Bioanalytical Chemistry,2016,408(11):1.
53 Zhang L,Luo M,Sun S,et al.Effect of surface structure of nanoCaCO3particles on mechanical and rheological properties of PVC composites[J].Journal of Macromolecular Science Part B,2010,49(5):970.
54 Ashida M,Noguchi T,Mashimo S.Dynamic moduli for short fiberCR composites[J].Journal of Applied Polymer Science,1984,29(2):661.
55 Richard A,Vaia A,Giannelis E P.Polymer melt intercalation in organically-modified layered silicates:Model predictions and experiment[J].Macromolecules,1997,30(25):8000.
56 Pukánszky B,Fekete E.Adhesion and surface modification[J].1999,139:109.
57 Diao H,Si Y,Zhu A,et al.Surface modified nano-hydroxyapatite/poly(lactide acid)composite and its osteocyte compatibility[J].Materials Science&Engineering C,2012,32(7):1796.
58 Jiang C,He H,Jiang H,et al.Nano-lignin filled natural rubber composites:Preparation and characterization[J].Express Polymer Letters,2013,7(5):480.
59 Zhang S,Guo M,Chen Z,et al.Grafting photosensitive polyurethane onto colloidal silica for use in UV-curing polyurethane nanocomposites[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,443(4):525.
60 Hosseini S M,Torbati-Fard N,Kiyani H,et al.Comparative role of interface in reinforcing mechanisms of nano silica modified by silanes and liquid rubber in SBR composites[J].Journal of Polymer Research,2016,23(9):203.
61 Zhan Y,Fan Y,Pan Y,et al.Construction of advanced poly(arylene ether nitrile)/multi-walled carbon nanotubes nanocompo-sites by controlling the precise interface[J].Journal of Materials Science,2016,51(4):2090.
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