Ni-Mo脱芳催化剂在变压器油加氢改质上的工业应用

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英文篇名：Industrial Application of Ni-Mo Dearomatization Catalyst in Transformer Oil Hydroupgrading 作者：周欣 英文作者：ZHOU Xin;Sinopec Jinling Company; 关键词：催化剂 ; 加氢脱芳 ; 变压器油 ; 异构装置 英文关键词：catalyst;;hydrodearomatization;;transformer oil;;isomerization unit 中文刊名：JXSI 英文刊名：Advances in Fine Petrochemicals 机构：中国石油化工股份有限公司金陵分公司; 出版日期：2019-04-28 出版单位：精细石油化工进展 年：2019 期：v.20 语种：中文; 页：JXSI201902013 页数：4 CN：02 ISSN：32-1601/TE 分类号：47-50

摘要

金陵分公司现有工艺生产的变压器油因多环芳烃含量高,氧化安定性差,无法达到合格产品质量标准,销售困难。公司利用闲置的尾油异构装置(WSI装置),选用Ni-Mo脱芳催化剂对变压油进行二次脱芳,通过工艺技术攻关优化进行工业应用,结果表明:在反应温度170℃,反应压力3.0 MPa,空速2.57 h~(-1),氢油体积比290∶1的工况下,变压油的总芳烃含质量降至5%以下,多环芳烃降至1%以下,产品外观清澈透亮,符合指标要求。
        Because of the high content of polycyclic aromatic hydrocarbons and poor oxidation stability of the transformer oil produced in the existing transformer oil process of Sinopec Jinling Company, the product of transformer oil cannot meet quality specification and thus is difficult to be sold. The tail oil isomerization unit that had been put out of operation was used together with a Ni-Mo dearomatization catalyst to carry out secondary dearomatization of the transformer oil, and this technology has been put into commercial application after research and optimization. The results of application have shown that total aromatics content of transformer oil can be reduced to less than 5% and the content of polycyclic aromatic hydrocarbons can be reduced to less than 1% when the reaction temperature is 170 ℃, the reaction pressure is 3.0 MPa, the space velocity is 2.57 h~(-1), and the hydrogen-oil ratio is 290 : 1. The product is clear and transparent in appearance, and meets quality specification at these conditions.

引文

[1] 杨明辉.加氢裂化变压器油提质探索及工业应用[J],当代化工,2017,46(8):1614-1618.