Mn(Ⅱ) Based Coordination Polymer Involving 1,2,4,5-Benzenetetraboxylic Acid and 4,4-Bis(imidazol-1-ylmethyl)biphenyl: Synthetic, Structure and Magnetic Property
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摘要
A novel Mn(Ⅱ)coordination polymer(CP),[Mn(BBA)_(0.5)(BIYB)]_n(1),was gained by the 1,2,4,5-benzenetetracarboxylic acid(H_4BBA),4,4-bis(imidazol-1-ylmethyl)biphenyl(BIYB),and Mn(CH_3COO)_2·4H_2O under hydrothermal reaction.CP 1 was characterized and structurally determined by elemental analyses,PXRD,IR spectra,thermal behaviors,and X-ray single-crystal diffraction.The framework structure of 1 shows a novel(2,5,6)-connected 3Dnetwork with a Schlafli symbol of(4~3.6~6.8)~2(4~6.6~9)(6)~2.It crystallizes in triclinic system,space group ■,with a=7.5898(5),b=9.8201(6),c=14.1307(9)?,α=97.5850(10),β=99.6810(10),γ=111.6580(10)o,V=943.01(10)?~3,Z=2,C_(23)H_(15)MnN _4O_4,M_r=466.33,D_c=1.462 g/cm~3,F(000)=476,S=1.082,R=0.0361 and wR=0.1008.The magnetic property of CP 1 was investigated.The weak antiferromagnetic interactions are observed between the Mn(Ⅱ)ions.
A novel Mn(Ⅱ)coordination polymer(CP),[Mn(BBA)_(0.5)(BIYB)]_n(1),was gained by the 1,2,4,5-benzenetetracarboxylic acid(H_4BBA),4,4-bis(imidazol-1-ylmethyl)biphenyl(BIYB),and Mn(CH_3COO)_2·4H_2O under hydrothermal reaction.CP 1 was characterized and structurally determined by elemental analyses,PXRD,IR spectra,thermal behaviors,and X-ray single-crystal diffraction.The framework structure of 1 shows a novel(2,5,6)-connected 3Dnetwork with a Schlafli symbol of(4~3.6~6.8)~2(4~6.6~9)(6)~2.It crystallizes in triclinic system,space group ■,with a=7.5898(5),b=9.8201(6),c=14.1307(9)?,α=97.5850(10),β=99.6810(10),γ=111.6580(10)o,V=943.01(10)?~3,Z=2,C_(23)H_(15)MnN _4O_4,M_r=466.33,D_c=1.462 g/cm~3,F(000)=476,S=1.082,R=0.0361 and wR=0.1008.The magnetic property of CP 1 was investigated.The weak antiferromagnetic interactions are observed between the Mn(Ⅱ)ions.
A novel Mn(Ⅱ)coordination polymer(CP),[Mn(BBA)_(0.5)(BIYB)]_n(1),was gained by the 1,2,4,5-benzenetetracarboxylic acid(H_4BBA),4,4-bis(imidazol-1-ylmethyl)biphenyl(BIYB),and Mn(CH_3COO)_2·4H_2O under hydrothermal reaction.CP 1 was characterized and structurally determined by elemental analyses,PXRD,IR spectra,thermal behaviors,and X-ray single-crystal diffraction.The framework structure of 1 shows a novel(2,5,6)-connected 3Dnetwork with a Schlafli symbol of(4~3.6~6.8)~2(4~6.6~9)(6)~2.It crystallizes in triclinic system,space group ■,with a=7.5898(5),b=9.8201(6),c=14.1307(9)?,α=97.5850(10),β=99.6810(10),γ=111.6580(10)o,V=943.01(10)?~3,Z=2,C_(23)H_(15)MnN _4O_4,M_r=466.33,D_c=1.462 g/cm~3,F(000)=476,S=1.082,R=0.0361 and wR=0.1008.The magnetic property of CP 1 was investigated.The weak antiferromagnetic interactions are observed between the Mn(Ⅱ)ions.
引文
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(25)Ma, L. F.; Wang, L. Y.; Du, M. A novel 3D Mn coordination polymer involving 4,4-dipyridylsulfide and 4,4-dipyridyltrisulfide obtained by in situ ligand formation from 4,4-dipyridyldisulfide. CrystEngComm. 2009, 11, 2593–2596.
(2)Ji,W.J.;Hao,R.Q.;Pei,W.W.;Feng,L.;Zhai,Q.G.DesignoftwoisoreticularCd-biphenyltetracarboxylateframeworksfordyeadsorption,separation and photocatalytic degradation. Dalton Transactions 2018, 47, 700–707.
(3)Li, D. S.; Wu, Y. P.; Zhao, J.; Zhang, J.; Lu, J. Y. Metal-organic frameworks based upon non-zeotype 4-connected topology. Coord. Chem. Rev. 2014,261, 1–27.
(4)Michele, S.; Matteo, M.; Lorenzo, P.; Emilio, V.; Brunetto, C.; Philippe, S.; Donella, R.; Andrea, C.; Roberta, S. Low-temperature magnetic force microscopy on single molecule magnet-based microarrays. Nano. Lett. 2017, 17, 1899–1905.
(5)Hou, X. Y.; Wang, X.; Hou, X. F.; Tang, L.; Wang, J. J.; Kang, W. W.; Liu, X. L. Synthesis, structure, and properties of{[Mn(ADA)(Phen)]·(H2O)2}n constructed from azobenzene-4,4?-dicarboxylic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 2017, 36, 1125–1132.
(6)Zhang, J. W.; Li, S. N.; Jiang, Y. C.; Qu, P.; Zhai, Q. G. Assembly of[Cu2(COO)4] and[M3(μ3-O)(COO)6](M=Sc, Fe, Ga, and In)building blocks into porous frameworks towards ultra-high C2H2/CO2 and C2H2/CH4 separation performance. Chem. Commun. 2018, 54, 2012–2015.
(7)Wang, X.; Wang, H.; Hou, X. Y.; Lv, L.; Cao, J.; Chen, X. L.; Wang, J. J.; Fu, F. Alternating double trinucleate[Yb3(μ3-OH)2O]2 chain bridged byμ3-OH mode in a 3D Yb3+-CP and its near infrared luminescent properties. Chin. J. Struct. Chem. 2016, 35, 1615–1621.
(8)Kong,Z.G.;Liu,D.X.;Li,R.;Jiang,Y.;Wang,L.J.;Hu,B.Anewone-dimensionalcoordinationpolymerbasedon3,5-dinitrosalicylicacid:synthesis, crystal structure, luminescent property and theoretical calculation. Chin. J. Struct. Chem. 2017, 36, 841–847.
(9)Stubbs,A.W.;Braglia,L.;Borfecchia,E.;Meyer,R.J.Leshkov,Y.;Lamberti,C.;Dinca,M.SelectivecatalyticolefinepoxidationwithMnII exchanged MOF-5. ACS Catal. 2018, 8, 596–601.
(10)Liu, X. Y.; Cen, P. P.; Zhou, H. L.; Jin, X. Y.; Hu, Q. L.; Ji, Y. Q.; Hu, Q. L.; Ji, Y. Q. A new 3D Cd(II)metal-organic framework with discrete(H2O)6 clusters based on flexible cyclohexane-1,2,4,5-tetracarboxylic acid ligand. Inorg. Chem. Commun. 2015, 53, 11–14.
(11)Madrahimov,S.T.;Gallagher,J.R.;Zhang,G.H.;Meinhart,Z.;Garibay,S.J.;Delferro,M.;Miller,J.T.;Farha,O.K.;Hu,J.T.Gas-phase dimerization of ethylene under mild conditions catalyzed by MOF materials containing(bpy)NiII complexes. ACS Catal. 2015, 5, 6713–6718.
(12)Lei,B.;Wang,M.F.;Jiang,Z.;Qi,W.;Su,R.;He,Z.Constructingredox-responsivemetal-organicframeworknanocarriersforanticancerdrug delivery. ACS Appl. Mater. Inter. 2018, 10, 16698–16706.
(13)Chen, W. X.; Wu, S. T.; Long, L. S.; Huang, R. B.; Zheng, L. S. Construction of a three-fold parallel interpenetration network and bilayer structure based on copper(II)and trimesic acid. Cryst. Growth Des. 2007, 7, 1171–1175.
(14)Fang, R. Q.; Zhang, X. M. Diversity of coordination architecture of metal 4,5-dicarboxyimidazole. Inorg. Chem. 2006, 45, 4801–4810.
(15)Hunger,J.; Krautscheid,H.;Sieler,J. Hydrothermalsynthesis and structure ofcoordinationpolymers bycombination ofbipyrazole andaromatic dicarboxylate ligands. Cryst. Growth Des. 2009, 9, 4613–4625.
(16)Zhai,Q.G.;Lin,Q.P.;Wu,T.;Zheng,S.T.;Bu,X.H.;Feng,P.Y.Inductionoftrimeric[Mg3(OH)(CO2)6]inaporousframeworkbya desymmetrized tritopic ligand. Dalton Trans. 2012, 41, 2866–2868.
(17)Pedersen, K. S.; Bendix, J.; Clerac, R. Single-molecule magnet engineering:building-block approaches. Chem. Commun. 2014, 50, 4396–4415.
(18)Herchel,R.;Vahovska,L.;Potocnak,I.;Travnicek,Z.Slowmagneticrelaxationinoctahedralcobalt(II)field-inducedsingle-ionmagnetwith positive axial large rhombic anisotropy. Inorg. Chem. 2014, 53, 5896–5898.
(19)Fataftah, M. S.; Zadrozny, J. M.; Rogers, D. M.; Freedman, D. E. Amononuclear transition metal single-molecule magnet in a nuclear spin-free ligand environment. Inorg. Chem. 2014, 53, 10716–10721.
(20)Zhang,P.;Guo,Y.N.;Tang,J.K.Recentadvancesin dysprosium-basedsinglemoleculemagnets:Structuraloverviewandsynthetic strategies.Coord. Chem. Rev. 2013, 257, 1728–1763.
(21)Sheldrick, G. M. SHELXS-2014/7, Program for Crystal Structure Determination. University of Gottingen, Germany 2014.
(22)Sheldrick, G. M. SHELXL-2014/7, Program for Crystal Structure Refinement. University of Gottingen, Germany 2014.
(23)Chen, X.; Zhang, M. X.; Huang, K. L. A 3D homochiral Mn(II)coordination polymer based on the ligand 2,2?-(ethane-1,2-diylbis(oxy))dicinnamic acid. Chin. J. Struct. Chem. 2018, 37, 966–972.
(24)He,Y.F.;Chen,D.M.;Xu,H.;Chen,P.Structuraldiversityofluminescentlanthanidemetal-organicframeworksbasedonaV-shapedligand.Cryst. Eng. Comm. 2015, 17, 2471–2478.
(25)Ma, L. F.; Wang, L. Y.; Du, M. A novel 3D Mn coordination polymer involving 4,4-dipyridylsulfide and 4,4-dipyridyltrisulfide obtained by in situ ligand formation from 4,4-dipyridyldisulfide. CrystEngComm. 2009, 11, 2593–2596.