纳米纤维素环保高效制备研究进展?
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摘要
概述了纳米纤维素的制备研究现状及环保化发展趋势。重点对通过多物理场耦合蒸爆可控解离天然植物纤维素获得结构和性质可调的纳米纤维素进行了展望,指出了蒸爆技术应用于纳米纤维素高效环保制备需解决的主要问题,提出新型纳米纤维素制备技术朝着高效、环保的方向发展。
The advances in nanocellulose preparation as well as the environmentally friendly development trend are reviewed. Nanocellulose products with controllable structure and property are expected to obtain by disassociation under multi-physics coupling mechanical field. The main problems in the preparation of nanocellulose with high efficiency and environmental protection are introduced. It's believed that the development of effective and environmentally friendly methods will be the main trend for nanocellulose preparation.
The advances in nanocellulose preparation as well as the environmentally friendly development trend are reviewed. Nanocellulose products with controllable structure and property are expected to obtain by disassociation under multi-physics coupling mechanical field. The main problems in the preparation of nanocellulose with high efficiency and environmental protection are introduced. It's believed that the development of effective and environmentally friendly methods will be the main trend for nanocellulose preparation.
引文
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[6]Wu M,Kuga S,Huang Y.Quasi-one-dimensional arrangement of silver nanoparticles templated by cellulose microfibrils[J].Langmuir the Acs Journal of Surfaces&Colloids,2008,24(18):10494-10497.
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[13]Lourdin D,Peixinho J,Bréard J,et al.Concentration driven cocrystallisation and percolation in all-cellulose nanocomposites[J].Cellulose,2016,23(1):529-543.
[14]Pullawan T,Wilkinson A N,Zhang L N,et al.Deformation micromechanics of all-cellulose nanocomposites:Comparing matrix and reinforcing components[J].Carbohydr Polym,2014,100(2):31-39.
[15]Yousefi H,Mashkour M,Yousefi R.Direct solvent nanowelding of cellulose fibers to make all-cellulose nanocomposite[J].Cellulose,2015,22(2):1189-1200.
[16]Pullawan T,Wilkinson A N,Eichhorn S J.Discrimination of matrix-fibre interactions in all-cellulose nanocomposites[J].Composites Science&Technology,2010,70(16):2325-2330.
[17]Qi H S,Cai J,Zhang L,et al.Properties of films composed of cellulose nanowhiskers and a cellulose matrix regenerated from alkali/urea solution[J].Biomacromolecules,2009,10(6):1597-1602.
[18]Ma H,Zhou B,Li H S,et al.Green composite films composed of nanocrystalline cellulose and a cellulose matrix regenerated from functionalized ionic liquid solution[J].Carbohydrate Polymers,2011,84(1):383-389.
[19]Zhao J Q,He X,Wang Y R,et al.Reinforcement of all-cellulose nanocomposite films using native cellulose nanofibrils[J].Carbohydrate Polymers,2014,104(1):143-150.
[20]Xu H,Feng Z X,Xie L,et al.Graphene oxide-driven design of strong and flexible biopolymer barrier films:From smart crystallization control to affordable engineering[J].Acs Sustainable Chemistry&Engineering,2016,4(1):4417-4430.
[21]Soykeabkaew N,Nishino T,Peijs T.All-cellulose composites of regenerated cellulose fibres by surface selective dissolution[J].Composites Part A Applied Science&Manufacturing,2009,40(4):321-328.
[22]Pullawan T,Wilkinson A N,Eichhorn S J.Influence of magnetic field alignment of cellulose whiskers on the mechanics of all-cellulose nanocomposites[J].Biomacromolecules,2012,13(8):2528-2536.
[23]Li D,Liu Z,Al-Haik M,et al.Magnetic alignment of cellulose nanowhiskers in an all-cellulose composite[J].Polymer Bulletin,2010,65(6):635-642.
[24]Pullawan T,Wilkinson A N,Eichhorn S J.Orientation and deformation of wet-stretched all-cellulose nanocomposites[J].Journal of Materials Science,2013,48(22):7847-7855.
[25]Torstensen J?,Johnsen P O,Riis H,et al.Preparation of cellulose nanofibrils for imaging purposes:Comparison of liquid cryogens for rapid vitrification[J].Cellulose,2018,25(8):4269-4274.
[26]Huang P,Wu M,Kuga S,et al.One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent[J].Chemsuschem,2012,5(12):2319-2322.
[27]Kccc B,Hjc V,Moh C,et al.Preparation of nanocellulose from Imperata brasiliensis grass using Taguchi method[J].Carbohydrate Polymers,2018,192:337-346.
[28]Torlopov M A,Udoratina E V,Martakov I S,et al.Cellulose nanocrystals prepared in H3PW12O40-acetic acid system[J].Cellulose,2017,24(5):2153-2162.
[29]Liu C,Li B,Du H,et al.Properties of nanocellulose isolated from corncob residue using sulfuric acid,formic acid,oxidative and mechanical methods[J].Carbohydrate Polymers,2016,151:716-724.
[30]Du H,Liu C,Mu X,et al.Preparation and characterization of thermally stable cellulose nanocrystals via a sustainable approach of FeCl3-catalyzed formic acid hydrolysis[J].Cellulose,2016,23(4):2389-2407.
[31]卢麒麟,唐丽荣,游惠娟,等.氯化铁体系绿色高效催化制备纳米纤维素[J].科技导报,2014,32(z1):56-60.
[32]游惠娟,曾常伟,卢麒麟,等.炭基磷钨酸催化制备纳米纤维素的研究[J].西南林业大学学报(自然科学),2014(2):100-103.
[33]Wang D,Liu Y,Ngo H H,et al.Approach of describing dynamic production of volatile fatty acids from sludge alkaline fermentation[J].Bioresource Technology,2017,238:343-351.
[34]冯欣,苗苗,施利毅,等.荧光特性的透明纳米纤维素纸的制备方法:CN,104130429 A[P].2014.
[35]Mari?o M A,Rezende C A,Tasic L.A multistep mild process for preparation of nanocellulose from orange bagasse[J].Cellulose,2018,25(10):5739-5750.
[36]Satyamurthy P,Vigneshwaran N.A novel process for synthesis of spherical nanocellulose by controlled hydrolysis of microcrystalline cellulose using anaerobic microbial consortium[J].Enzyme&Microbial Technology,2013,52(1):20-25.
[37]李强,徐术娟,季更生,等.一种纳米微晶纤维素的制备方法:CN,103755817 A[P].2014-04-30.
[38]Pullawan T,Wilkinson A N,Zhang L N,et al.Deformation micromechanics of all-cellulose nanocomposites:Comparing matrix and reinforcing components[J].Carbohydr Polym,2014,100(2):31-39.
[39]Zhao M,Kuga S,Wu M,et al.Hydrophobic nanocoating of cellulose by solventless mechanical milling[J].Green Chemistry,2016,18(10):3006-3012.
[40]Ivanov A S,Kar T,Boldyrev A I.Nanoscale stabilization of zintl compounds:1D ionic Li-P double helix confined inside a carbon nanotube[J].Nanoscale,2016,8(6):3454-3460.
[41]Rao X,Kuga S,Wu M,et al.Influence of solvent polarity on surface-fluorination of cellulose nanofiber by ball milling[J].Cellulose,2015,22(4):2341-2348.
[42]Huang P,Wu M,Kuga S,et al.Aqueous pretreatment for reactive ball milling of cellulose[J].Cellulose,2013,20(4):2175-2178.
[43]33Torstensen J?,Johnsen P O,Riis H,et al.Preparation of cellulose nanofibrils for imaging purposes:Comparison of liquid cryogens for rapid vitrification[J].Cellulose,2018,25(8):1-6.
[44]Huang Lijie,Zhang Xiaoxiao,Xu Mingzi.Preparation and mechanical properties of modified nanocellulose/PLA composites from cassava residue[J].AIP Advances,2018,8(2):2158-3226.
[45]Barbash V A,Yaschenko O V,Shniruk O M.Preparation and properties of nanocellulose from organosolv straw pulp[J].Nanoscale Research Letters,2017,12(1):241-249.
[46]Barbash V A,Yaschenko O V,Alushkin S V,et al.The effect of mechanochemical treatment of the cellulose on characteristics of nanocellulose films[J].Nanoscale Research Letters,2016,11(1):410-418.
[47]Chen H Z,Qiu W H.Key technologies for bioethanol production from lignocellulose[J].Biotechnology Advances,2010,28(5):556-562.
[48]牛成,潘勤鹤,王芙香,等.一种高分散纳米纤维素胶的制备方法及所得产品和应用:CN,106065081 A[P].2016-11-02.
[49]Wang L,Chen H Z.Increased fermentability of enzymatically hydrolyzed steam-exploded corn stover for butanol production by removal of fermentation inhibitors[J].Process Biochemistry,2011,46(2):604-607.
[50]Atalla R H,Vanderhart D L.Native cellulose:a composite of two distinct crystalline forms[J].Science,1984,223(4633):283-285.
[51]刘琪,何文清,郭瑞,等.小麦秸秆纤维素纳米纤维的制备与表征[C].北京:中国农学会耕作制度分会2016年学术年会论文摘要集,2016:10.
[52]Abraham E,Deepa B,Pothan L A,et al.Extraction of nanocellulose fibrils from lignocellulosic fibres:A novel approach[J].Carbohydrate Polymers,2011,86(4):1468-1478.
[53]Cherian B M,Le?o A L,Souza S F D,et al.Isolation of nanocellulose from pineapple leaf fibres by steam explosion[J].Carbohydrate Polymers,2010,81(3):720-725.
[54]Yu Z D,Zhang B L,Yu F Q,et al.A real explosion:The requirement of steam explosion pretreatment[J].Bioresource Technology,2012,121(121):335-341.
[55]Ma P T,Lan J S,Feng Y H,et al.Effects of continuous steam explosion on the microstructure and properties of eucalyptus fibers[J].Bioresources,2016,11(1):1417-1428.
[56]Abraham E,Elbi P A,Deepa B,et al.X-ray diffraction and biodegradation analysis of green composites of natural rubber/nanocellulose[J].Polymer Degradation&Stability,2012,97(11):2378-2387.
[57]Rani A,Monga S,Bansal M,et al.Bionanocomposites reinforced with cellulose nanofibers derived from sugarcane bagasse[J].Polymer Composites,2016,39(13):E55-E64.
[58]Fortunati E,Luzi F,Jiménez A,et al.Revalorization of sunflower stalks as novel sources of cellulose nanofibrils and nanocrystals and their effect on wheat gluten bionanocomposite properties[J].Carbohydrate Polymers,2016,149:357-368.
[59]Bansal M,Chauhan G S,Kaushik A,et al.Extraction and functionalization of bagasse cellulose nanofibres to Schiff-base based antimicrobial membranes[J].International Journal of Biological Macromolecules,2016,91:887-894.
[60]Gou G J,Wang Q,Xie W,et al.Assessment of instant catapult steam explosion treatment on rice straw for isolation of high quality cellulose[J].BioResources,2018,13(2):2328-2341.
[2]Rathod M,Moradeeya P G,Haldar S,et al.Nanocellulose/TiO2 composites:Preparation,characterization and application in the photocatalytic degradation of a potential endocrine disruptor,mefenamic acid,in aqueous media[J].Photochemical&Photobiological Sciences,2018,17(10):1301-1309.
[3]潘媛媛,杨旖旎,滕佑超,等.纳米纤维素/碳纳米管/纳米银线柔性电极的制备[J].包装工程,2018,39(7):80-85.
[4]Moon R J,Martini A,Nairn J,et al.Cellulose nanomaterials review:Structure,properties and nanocomposites[J].Chemical Society Reviews,2011,42(42):3941-3994.
[5]Atalla R H,Vanderhart D L.Native cellulose:A composite of two distinct crystalline forms[J].Science,1984,223(4633):283-285.
[6]Wu M,Kuga S,Huang Y.Quasi-one-dimensional arrangement of silver nanoparticles templated by cellulose microfibrils[J].Langmuir the Acs Journal of Surfaces&Colloids,2008,24(18):10494-10497.
[7]Tian Y,Wu M,Liu R,et al.Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment[J].Carbohydrate Polymers,2011,83(2):743-748.
[8]Sun P,Kuga S,Wu M,et al.Exfoliation of graphite by dry ball milling with cellulose[J].Cellulose,2014,21(4):2469-2478.
[9]Durán N,Lemes A P,Seabra A B.Review of cellulose nanocrystals patents:Preparation,composites and general applications[J].Recent Patents on Nanotechnology,2012,6(1):16-28.
[10]Hooshmand S,Aitom?ki Y,Skrifvars M,et al.All-cellulose nanocomposite fibers produced by melt spinning cellulose acetate butyrate and cellulose nanocrystals[J].Cellulose,2014,21(4):2665-2678.
[11]Soykeabkaew N,Sian C,Gea S,et al.All-cellulose nanocomposites by surface selective dissolution of bacterial cellulose[J].Cellulose,2009,16(3):435-444.
[12]Yang Q,Saito T,Berglund L A,et al.Cellulose nanofibrils improve the properties of all-cellulose composites by the nano-reinforcement mechanism and nanofibril-induced crystallization[J].Nanoscale,2015,7(42):17957-17963.
[13]Lourdin D,Peixinho J,Bréard J,et al.Concentration driven cocrystallisation and percolation in all-cellulose nanocomposites[J].Cellulose,2016,23(1):529-543.
[14]Pullawan T,Wilkinson A N,Zhang L N,et al.Deformation micromechanics of all-cellulose nanocomposites:Comparing matrix and reinforcing components[J].Carbohydr Polym,2014,100(2):31-39.
[15]Yousefi H,Mashkour M,Yousefi R.Direct solvent nanowelding of cellulose fibers to make all-cellulose nanocomposite[J].Cellulose,2015,22(2):1189-1200.
[16]Pullawan T,Wilkinson A N,Eichhorn S J.Discrimination of matrix-fibre interactions in all-cellulose nanocomposites[J].Composites Science&Technology,2010,70(16):2325-2330.
[17]Qi H S,Cai J,Zhang L,et al.Properties of films composed of cellulose nanowhiskers and a cellulose matrix regenerated from alkali/urea solution[J].Biomacromolecules,2009,10(6):1597-1602.
[18]Ma H,Zhou B,Li H S,et al.Green composite films composed of nanocrystalline cellulose and a cellulose matrix regenerated from functionalized ionic liquid solution[J].Carbohydrate Polymers,2011,84(1):383-389.
[19]Zhao J Q,He X,Wang Y R,et al.Reinforcement of all-cellulose nanocomposite films using native cellulose nanofibrils[J].Carbohydrate Polymers,2014,104(1):143-150.
[20]Xu H,Feng Z X,Xie L,et al.Graphene oxide-driven design of strong and flexible biopolymer barrier films:From smart crystallization control to affordable engineering[J].Acs Sustainable Chemistry&Engineering,2016,4(1):4417-4430.
[21]Soykeabkaew N,Nishino T,Peijs T.All-cellulose composites of regenerated cellulose fibres by surface selective dissolution[J].Composites Part A Applied Science&Manufacturing,2009,40(4):321-328.
[22]Pullawan T,Wilkinson A N,Eichhorn S J.Influence of magnetic field alignment of cellulose whiskers on the mechanics of all-cellulose nanocomposites[J].Biomacromolecules,2012,13(8):2528-2536.
[23]Li D,Liu Z,Al-Haik M,et al.Magnetic alignment of cellulose nanowhiskers in an all-cellulose composite[J].Polymer Bulletin,2010,65(6):635-642.
[24]Pullawan T,Wilkinson A N,Eichhorn S J.Orientation and deformation of wet-stretched all-cellulose nanocomposites[J].Journal of Materials Science,2013,48(22):7847-7855.
[25]Torstensen J?,Johnsen P O,Riis H,et al.Preparation of cellulose nanofibrils for imaging purposes:Comparison of liquid cryogens for rapid vitrification[J].Cellulose,2018,25(8):4269-4274.
[26]Huang P,Wu M,Kuga S,et al.One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent[J].Chemsuschem,2012,5(12):2319-2322.
[27]Kccc B,Hjc V,Moh C,et al.Preparation of nanocellulose from Imperata brasiliensis grass using Taguchi method[J].Carbohydrate Polymers,2018,192:337-346.
[28]Torlopov M A,Udoratina E V,Martakov I S,et al.Cellulose nanocrystals prepared in H3PW12O40-acetic acid system[J].Cellulose,2017,24(5):2153-2162.
[29]Liu C,Li B,Du H,et al.Properties of nanocellulose isolated from corncob residue using sulfuric acid,formic acid,oxidative and mechanical methods[J].Carbohydrate Polymers,2016,151:716-724.
[30]Du H,Liu C,Mu X,et al.Preparation and characterization of thermally stable cellulose nanocrystals via a sustainable approach of FeCl3-catalyzed formic acid hydrolysis[J].Cellulose,2016,23(4):2389-2407.
[31]卢麒麟,唐丽荣,游惠娟,等.氯化铁体系绿色高效催化制备纳米纤维素[J].科技导报,2014,32(z1):56-60.
[32]游惠娟,曾常伟,卢麒麟,等.炭基磷钨酸催化制备纳米纤维素的研究[J].西南林业大学学报(自然科学),2014(2):100-103.
[33]Wang D,Liu Y,Ngo H H,et al.Approach of describing dynamic production of volatile fatty acids from sludge alkaline fermentation[J].Bioresource Technology,2017,238:343-351.
[34]冯欣,苗苗,施利毅,等.荧光特性的透明纳米纤维素纸的制备方法:CN,104130429 A[P].2014.
[35]Mari?o M A,Rezende C A,Tasic L.A multistep mild process for preparation of nanocellulose from orange bagasse[J].Cellulose,2018,25(10):5739-5750.
[36]Satyamurthy P,Vigneshwaran N.A novel process for synthesis of spherical nanocellulose by controlled hydrolysis of microcrystalline cellulose using anaerobic microbial consortium[J].Enzyme&Microbial Technology,2013,52(1):20-25.
[37]李强,徐术娟,季更生,等.一种纳米微晶纤维素的制备方法:CN,103755817 A[P].2014-04-30.
[38]Pullawan T,Wilkinson A N,Zhang L N,et al.Deformation micromechanics of all-cellulose nanocomposites:Comparing matrix and reinforcing components[J].Carbohydr Polym,2014,100(2):31-39.
[39]Zhao M,Kuga S,Wu M,et al.Hydrophobic nanocoating of cellulose by solventless mechanical milling[J].Green Chemistry,2016,18(10):3006-3012.
[40]Ivanov A S,Kar T,Boldyrev A I.Nanoscale stabilization of zintl compounds:1D ionic Li-P double helix confined inside a carbon nanotube[J].Nanoscale,2016,8(6):3454-3460.
[41]Rao X,Kuga S,Wu M,et al.Influence of solvent polarity on surface-fluorination of cellulose nanofiber by ball milling[J].Cellulose,2015,22(4):2341-2348.
[42]Huang P,Wu M,Kuga S,et al.Aqueous pretreatment for reactive ball milling of cellulose[J].Cellulose,2013,20(4):2175-2178.
[43]33Torstensen J?,Johnsen P O,Riis H,et al.Preparation of cellulose nanofibrils for imaging purposes:Comparison of liquid cryogens for rapid vitrification[J].Cellulose,2018,25(8):1-6.
[44]Huang Lijie,Zhang Xiaoxiao,Xu Mingzi.Preparation and mechanical properties of modified nanocellulose/PLA composites from cassava residue[J].AIP Advances,2018,8(2):2158-3226.
[45]Barbash V A,Yaschenko O V,Shniruk O M.Preparation and properties of nanocellulose from organosolv straw pulp[J].Nanoscale Research Letters,2017,12(1):241-249.
[46]Barbash V A,Yaschenko O V,Alushkin S V,et al.The effect of mechanochemical treatment of the cellulose on characteristics of nanocellulose films[J].Nanoscale Research Letters,2016,11(1):410-418.
[47]Chen H Z,Qiu W H.Key technologies for bioethanol production from lignocellulose[J].Biotechnology Advances,2010,28(5):556-562.
[48]牛成,潘勤鹤,王芙香,等.一种高分散纳米纤维素胶的制备方法及所得产品和应用:CN,106065081 A[P].2016-11-02.
[49]Wang L,Chen H Z.Increased fermentability of enzymatically hydrolyzed steam-exploded corn stover for butanol production by removal of fermentation inhibitors[J].Process Biochemistry,2011,46(2):604-607.
[50]Atalla R H,Vanderhart D L.Native cellulose:a composite of two distinct crystalline forms[J].Science,1984,223(4633):283-285.
[51]刘琪,何文清,郭瑞,等.小麦秸秆纤维素纳米纤维的制备与表征[C].北京:中国农学会耕作制度分会2016年学术年会论文摘要集,2016:10.
[52]Abraham E,Deepa B,Pothan L A,et al.Extraction of nanocellulose fibrils from lignocellulosic fibres:A novel approach[J].Carbohydrate Polymers,2011,86(4):1468-1478.
[53]Cherian B M,Le?o A L,Souza S F D,et al.Isolation of nanocellulose from pineapple leaf fibres by steam explosion[J].Carbohydrate Polymers,2010,81(3):720-725.
[54]Yu Z D,Zhang B L,Yu F Q,et al.A real explosion:The requirement of steam explosion pretreatment[J].Bioresource Technology,2012,121(121):335-341.
[55]Ma P T,Lan J S,Feng Y H,et al.Effects of continuous steam explosion on the microstructure and properties of eucalyptus fibers[J].Bioresources,2016,11(1):1417-1428.
[56]Abraham E,Elbi P A,Deepa B,et al.X-ray diffraction and biodegradation analysis of green composites of natural rubber/nanocellulose[J].Polymer Degradation&Stability,2012,97(11):2378-2387.
[57]Rani A,Monga S,Bansal M,et al.Bionanocomposites reinforced with cellulose nanofibers derived from sugarcane bagasse[J].Polymer Composites,2016,39(13):E55-E64.
[58]Fortunati E,Luzi F,Jiménez A,et al.Revalorization of sunflower stalks as novel sources of cellulose nanofibrils and nanocrystals and their effect on wheat gluten bionanocomposite properties[J].Carbohydrate Polymers,2016,149:357-368.
[59]Bansal M,Chauhan G S,Kaushik A,et al.Extraction and functionalization of bagasse cellulose nanofibres to Schiff-base based antimicrobial membranes[J].International Journal of Biological Macromolecules,2016,91:887-894.
[60]Gou G J,Wang Q,Xie W,et al.Assessment of instant catapult steam explosion treatment on rice straw for isolation of high quality cellulose[J].BioResources,2018,13(2):2328-2341.