变压器绝缘油吸附净化材料的研究进展
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摘要
吸附处理技术是一种重要的绝缘油再生处理技术,也是绝缘油处理领域的研究热点。本文综述了变压器绝缘油在吸附净化过程中所用吸附材料的研究进展,包括传统吸附剂以及近年来出现的新型吸附剂,并指出了变压器绝缘油吸附剂领域的发展趋势。
Adsorption treatment technology is an important regeneration technology of insulating oil and has been a research hotspot in the field of insulating oil treatment. The research progress of absorption materials applied in the adsorption-purification process of transformer insulating oil was reviewed in this paper, which included conventional adsorbents and new types of adsorbents appeared in recent years.Meanwhile, the development trend in the adsorption field of transformer insulating oil was proposed.
Adsorption treatment technology is an important regeneration technology of insulating oil and has been a research hotspot in the field of insulating oil treatment. The research progress of absorption materials applied in the adsorption-purification process of transformer insulating oil was reviewed in this paper, which included conventional adsorbents and new types of adsorbents appeared in recent years.Meanwhile, the development trend in the adsorption field of transformer insulating oil was proposed.
引文
[1]万涛,钱晖.变压器油老化研究进展[C]//2011电力行业电力用油、气应用技术研讨会.西安,2011.
[2]李睿,曹顺安,钱艺华,等.变压器油中腐蚀性硫的研究现状[J].变压器,2009,46(2):19-22.
[3]马蕊燕,甄新平,张静,等.变压器油生产技术及国内外产品介绍[J].润滑油,2017,32(6):56-60.
[4]QIAN Y H,HUANG Y B,FU Q,et al.Comparative study on the impurities content of hydrogenated transformer oil under static condition[J].Advanced Materials Research,2011,421(1):129-135.
[5]任双赞,钟力生,于钦学,等.变压器油中腐蚀性硫的检测标准及测量方法研究[J].高压电器,2011,47(7):40-43.
[6]李臻,万涛,龚尚昆.变压器油中腐蚀性硫问题研究进展[J].湖南电力,2016,36(4):5-8.
[7]万涛,周舟,冯兵,等.变压器油中腐蚀性硫与铜离子综合处理研究[J].绝缘材料,2016,49(2):70-74.
[8]陈剑光,陈艺丹.变压器油中铜离子和氨基吡啉对绝缘电阻的影响和处理[J].变压器,2017,54(10):75-76.
[9]林永平,周杰华,何冰,等.大型变压器油介质损耗因数异常的原因分析[J].中国电力,2000,33(7):65-68.
[10]颜道容.微生物对变压器油的污染机理及净化[J].电工技术,2001(3):9-9.
[11]刘晓东,吕宪俊,邱俊.活性白土研究探讨[J].山东化工,2004,33(4):16-19.
[12]董幼斐,孟明,孟忠.膨润土基新型绝缘油净化吸附剂研究[J].非金属矿,1995(5):37-39.
[13]ZHANG H,TONG Z,WEI T,et al.Removal characteristics of Zn(II)from aqueous solution by alkaline Ca-bentonite[J].Desalination,2011,276(1):103-108.
[14]NASRAT L,ABDELWAHAB M,ISMAILl G.Improvement of used transformer oils with activated bentonite[J].Engineering,2011(6):764-767.
[15]RAYMON A,KARTHIK R.Reclaiming aged transformer oil with activated bentonite and enhancing reclaimed and fresh transformer oils with antioxidants[J].IEEE Transactions on Dielectrics and Electrical Insulation,2015,22(1):548-555.
[16]许俊瑞.801吸附剂接触精制法-再生劣质变压器油的应用[J].华北电力技术,1987,17(5):44-47.
[17]孙少平,赵德义.劣化变压器油再生处理方法[J].河北电力技术,1986,6(4):41,39.
[18]ZOUGAGH M,CANO PAVON J,GARCIA D.Chelating sorbents based on silica gel and their application in atomic spectrometry[J].Analytical and Bioanalytical Chemistry,2005,381(6):1103-1113.
[19]王瑞珍,何清,袁平.硅胶进入变压器后的影响分析[J].湖北电力,2012,36(6):33-34.
[20]杨鸿森.用球型硅胶处理水分介质损耗因数异常的变压器油[C]//输配电技术国际会议.北京,2005:1310-1313.
[21]诸红玉,吴春华.不同固体吸附剂对变压器油的再生处理[J].上海电力学院学报,1998,14(4):39-42.
[22]刘杰.“801-硅胶组合吸附剂”处理劣质变压器油工艺及效果评定[J].贵州电力技术,2003,46(4):30-31.
[23]刘作霖.活性氧化铝的性能及其用途[J].化学世界,1966(5):9-11.
[24]HOUSLEY J.Reconditioning of insulating oils by activated alumina[J].Electrical Engineering,1939,58(4):172-178.
[25]刘祥茂.防止变压器油老化剂“铝素”[J].变压器,1981(2):40-41.
[26]胡大为,杨清河,聂红,等.活性氧化铝载体的扩孔及改性[J].石油炼制与化工,2004,35(8):46-49.
[27]AL-ZAHRANI A,DAOUS M.Recycling of spent bleaching clay and oil recovery[J].Process Safety and Environmental Protection,2000,78(3):224-228.
[28]李智,李良智.高效吸附剂再生劣化变压器油的试验[J].华东电力,1996,25(11):34-35.
[29]叶华,刘爱菊.802分子筛高效吸附剂在变压器油再生中的应用[J].华北电力技术,1996,26(12):64-65.
[30]张安志.使用高铝微球处理变压器油的实践[J].山西电力,1994,14(1):54-55.
[31]罗运柏,任乔林,周作成,等.高效吸附剂再生劣化电力用油的试验研究[J].润滑油,1995,10(2):19-22.
[32]任乔林,卢理成.XDK型高效吸附剂在大亚湾核电站超高压变压器油处理中的应用[J].变压器,2000,37(2):34-37.
[33]唐金伟,李烨峰,刘永洛,等.微孔硅铝吸附剂用于矿物变压器油再生处理[J].热力发电,2015,44(10):107-111.
[34]赵耀洪,钱艺华,苏伟,等.变压器油中二苄基二硫醚的脱除研究[J].绝缘材料,2016,49(11):75-79.
[35]MAJANO G,MINTOVA S.Mineral oil regeneration using selective molecular sieves as sorbents[J].Chemosphere,2010,78(5):591-598.
[36]孙晓琳.关于石油化工技术中分子筛的影响分析[J].中国化工贸易,2014,6(2):214-214.
[37]LAURENTINO A,PARIZE A,LARANJEIRA M,et al.Regeneration of insulating mineral oil by carbonated amorphous calcium phosphate-chitosan adsorbent[J].Process Safety and Environmental Protection,2007,85(4):327-331.
[38]VANITHA M,NARMADHAI N,KARTHIK M.Investigation of critical characteristics of mineral oil with activated carbon[J].Circuits and Systems,2016,7(9):2521-2529.
[39]AL-ZUHAIR S,NOURA H,FARDOUN A.Using activated carbon from waste date-pits as an adsorbent for transformer oil regeneration[C]//2011 World Congress on Sustainable Technologies(WCST).London,UK:IEEE,2011:69-72.
[40]ZHANG H X,HUANG H L,LI C X,et al.Adsorption behavior of metal-organic frameworks for thiophenic sulfur from diesel oil[J].Industrial&Engineering Chemistry Research,2012,51(38):12449-12455.
[41]于凤丽,张高飞,王睿,等.碳材料负载型杂多化合物油品脱硫催化剂及其脱硫方法:CN101474569A[P].2009-07-08.
[2]李睿,曹顺安,钱艺华,等.变压器油中腐蚀性硫的研究现状[J].变压器,2009,46(2):19-22.
[3]马蕊燕,甄新平,张静,等.变压器油生产技术及国内外产品介绍[J].润滑油,2017,32(6):56-60.
[4]QIAN Y H,HUANG Y B,FU Q,et al.Comparative study on the impurities content of hydrogenated transformer oil under static condition[J].Advanced Materials Research,2011,421(1):129-135.
[5]任双赞,钟力生,于钦学,等.变压器油中腐蚀性硫的检测标准及测量方法研究[J].高压电器,2011,47(7):40-43.
[6]李臻,万涛,龚尚昆.变压器油中腐蚀性硫问题研究进展[J].湖南电力,2016,36(4):5-8.
[7]万涛,周舟,冯兵,等.变压器油中腐蚀性硫与铜离子综合处理研究[J].绝缘材料,2016,49(2):70-74.
[8]陈剑光,陈艺丹.变压器油中铜离子和氨基吡啉对绝缘电阻的影响和处理[J].变压器,2017,54(10):75-76.
[9]林永平,周杰华,何冰,等.大型变压器油介质损耗因数异常的原因分析[J].中国电力,2000,33(7):65-68.
[10]颜道容.微生物对变压器油的污染机理及净化[J].电工技术,2001(3):9-9.
[11]刘晓东,吕宪俊,邱俊.活性白土研究探讨[J].山东化工,2004,33(4):16-19.
[12]董幼斐,孟明,孟忠.膨润土基新型绝缘油净化吸附剂研究[J].非金属矿,1995(5):37-39.
[13]ZHANG H,TONG Z,WEI T,et al.Removal characteristics of Zn(II)from aqueous solution by alkaline Ca-bentonite[J].Desalination,2011,276(1):103-108.
[14]NASRAT L,ABDELWAHAB M,ISMAILl G.Improvement of used transformer oils with activated bentonite[J].Engineering,2011(6):764-767.
[15]RAYMON A,KARTHIK R.Reclaiming aged transformer oil with activated bentonite and enhancing reclaimed and fresh transformer oils with antioxidants[J].IEEE Transactions on Dielectrics and Electrical Insulation,2015,22(1):548-555.
[16]许俊瑞.801吸附剂接触精制法-再生劣质变压器油的应用[J].华北电力技术,1987,17(5):44-47.
[17]孙少平,赵德义.劣化变压器油再生处理方法[J].河北电力技术,1986,6(4):41,39.
[18]ZOUGAGH M,CANO PAVON J,GARCIA D.Chelating sorbents based on silica gel and their application in atomic spectrometry[J].Analytical and Bioanalytical Chemistry,2005,381(6):1103-1113.
[19]王瑞珍,何清,袁平.硅胶进入变压器后的影响分析[J].湖北电力,2012,36(6):33-34.
[20]杨鸿森.用球型硅胶处理水分介质损耗因数异常的变压器油[C]//输配电技术国际会议.北京,2005:1310-1313.
[21]诸红玉,吴春华.不同固体吸附剂对变压器油的再生处理[J].上海电力学院学报,1998,14(4):39-42.
[22]刘杰.“801-硅胶组合吸附剂”处理劣质变压器油工艺及效果评定[J].贵州电力技术,2003,46(4):30-31.
[23]刘作霖.活性氧化铝的性能及其用途[J].化学世界,1966(5):9-11.
[24]HOUSLEY J.Reconditioning of insulating oils by activated alumina[J].Electrical Engineering,1939,58(4):172-178.
[25]刘祥茂.防止变压器油老化剂“铝素”[J].变压器,1981(2):40-41.
[26]胡大为,杨清河,聂红,等.活性氧化铝载体的扩孔及改性[J].石油炼制与化工,2004,35(8):46-49.
[27]AL-ZAHRANI A,DAOUS M.Recycling of spent bleaching clay and oil recovery[J].Process Safety and Environmental Protection,2000,78(3):224-228.
[28]李智,李良智.高效吸附剂再生劣化变压器油的试验[J].华东电力,1996,25(11):34-35.
[29]叶华,刘爱菊.802分子筛高效吸附剂在变压器油再生中的应用[J].华北电力技术,1996,26(12):64-65.
[30]张安志.使用高铝微球处理变压器油的实践[J].山西电力,1994,14(1):54-55.
[31]罗运柏,任乔林,周作成,等.高效吸附剂再生劣化电力用油的试验研究[J].润滑油,1995,10(2):19-22.
[32]任乔林,卢理成.XDK型高效吸附剂在大亚湾核电站超高压变压器油处理中的应用[J].变压器,2000,37(2):34-37.
[33]唐金伟,李烨峰,刘永洛,等.微孔硅铝吸附剂用于矿物变压器油再生处理[J].热力发电,2015,44(10):107-111.
[34]赵耀洪,钱艺华,苏伟,等.变压器油中二苄基二硫醚的脱除研究[J].绝缘材料,2016,49(11):75-79.
[35]MAJANO G,MINTOVA S.Mineral oil regeneration using selective molecular sieves as sorbents[J].Chemosphere,2010,78(5):591-598.
[36]孙晓琳.关于石油化工技术中分子筛的影响分析[J].中国化工贸易,2014,6(2):214-214.
[37]LAURENTINO A,PARIZE A,LARANJEIRA M,et al.Regeneration of insulating mineral oil by carbonated amorphous calcium phosphate-chitosan adsorbent[J].Process Safety and Environmental Protection,2007,85(4):327-331.
[38]VANITHA M,NARMADHAI N,KARTHIK M.Investigation of critical characteristics of mineral oil with activated carbon[J].Circuits and Systems,2016,7(9):2521-2529.
[39]AL-ZUHAIR S,NOURA H,FARDOUN A.Using activated carbon from waste date-pits as an adsorbent for transformer oil regeneration[C]//2011 World Congress on Sustainable Technologies(WCST).London,UK:IEEE,2011:69-72.
[40]ZHANG H X,HUANG H L,LI C X,et al.Adsorption behavior of metal-organic frameworks for thiophenic sulfur from diesel oil[J].Industrial&Engineering Chemistry Research,2012,51(38):12449-12455.
[41]于凤丽,张高飞,王睿,等.碳材料负载型杂多化合物油品脱硫催化剂及其脱硫方法:CN101474569A[P].2009-07-08.
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