丙烯-1-丁烯共聚物的研究进展
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摘要
综述了丙烯-1-丁烯共聚物的研究进展,并总结了催化剂对共聚物性能的影响。其中,Ti/MgCl_2催化剂活性和效率较高,而茂金属催化剂能够对聚合物结构进行设计。介绍了丙烯-1-丁烯共聚物的聚合方法,主要包括液相本体聚合、气相聚合和悬浮聚合等。其中,液相本体聚合和气相聚合技术相对成熟,在现今的研究和生产中运用居多。对丙烯-1-丁烯共聚物结晶行为以及力学性能进行了分析。最后,针对丙烯-1-丁烯共聚物的未来发展做出展望。
A comprehensive overview of propylene/1-butene copolymers is presented. The effect of catalysts on polymerization properties of the copolymers is introduced. It is found that the activity and efficiency of the Ti/MgCl_2 catalyst are high,and the metallocene catalyst can be used for designing the polymer structure.The polymerization methods of propylene/1-butene copolymers are introduced,including liquid phase bulk polymerization,gas phase polymerization and suspension polymerization,among which liquid phase bulk polymerization and gas phase polymerization are relatively mature and are used in current research and production. The crystallization behavior and physical properties of the copolymers are summarized. Finally,the future development of the copolymers is explored.
A comprehensive overview of propylene/1-butene copolymers is presented. The effect of catalysts on polymerization properties of the copolymers is introduced. It is found that the activity and efficiency of the Ti/MgCl_2 catalyst are high,and the metallocene catalyst can be used for designing the polymer structure.The polymerization methods of propylene/1-butene copolymers are introduced,including liquid phase bulk polymerization,gas phase polymerization and suspension polymerization,among which liquid phase bulk polymerization and gas phase polymerization are relatively mature and are used in current research and production. The crystallization behavior and physical properties of the copolymers are summarized. Finally,the future development of the copolymers is explored.
引文
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[25]Daniela M,RenéA,Evgeny Z,et al.Formation and reorganization of the mesophase of random copolymers of propylene and1-butene[J].Polymer,2011,52(4):1107-1115.
[26]陈雪生.聚乙烯醇-b-聚苯乙烯星形嵌段聚合物的制备及丙烯-1-丁烯无规共聚物的研究[D].北京:北京化工大学,2005.
[27]刘立新,赵晓非,谭小红,等.丙烯/1-丁烯无规共聚树脂等温结晶动力学研究[J].中国塑料,2009,23(7):44-48.
[28]刘立新,贾相臣,刘永卫,等.丙烯/1-丁烯无规共聚物的非等温结晶行为研究[J].中国塑料,2009,23(10):36-39.
[29]Carolina R O,Rufina G A.Show more morphological and kinetic partitioning of comonomer in random propylene1-butene copolymers[J].Polymer,2012,53(3):810-822.
[30]张从容.丙烯-丁烯共聚物首次出现于PP膜市场[J].石油化工动态,1994(5):47.
[31]Kasgoz A,Tamer M,Kocyigit C,et al.Effect of the comonomer content on the solid-state mechanical and viscoelastic properties of poly(propylene-co-1-butene)films[J].J Appl Polym Sci,2018,135(23):46350-46360.
[32]胡雄.丙烯/1-丁烯无规共聚透明聚丙烯研究[J].广东化工,2010,37(7):51-52.
[33]陈国康,高国强,胡雄.丙烯/丁烯-1无规共聚产品的工业化开发[J].石油化工技术与经济,2011,27(5):48-51.
[34]蒋文军,李国飞.丙烯/丁烯-1共聚透明聚丙烯的生产开发[J].广东化工,2013,40(17):71-72.
[2]洪定一.聚丙烯--原理、工艺与技术[M].北京:中国石化出版社,2005:200.
[3]埃克森美孚化学专利公司.丙烯抗冲共聚物:中国,1398272A[P].2003-02-19.
[4]徐伟.苄基醚型树枝状二亚胺吡啶铁系催化剂的合成、表征及其在丙烯聚合中的应用[D].厦门:厦门大学,2007.
[5]赵敏.改性聚丙烯新材料[M].2版.北京:化学工业出版社,2010:7-8.
[6]Fabricio M,Enrique L L,JoséC P,et al.In situ preparation of polypropylene-1-butene alloys using a MgCl2-supported Ziegler-Natta catalyst[J].Eur Polym J,2008,14(4):1130-1139.
[7]Silva F M,Lima E L,Pinto J C,et al.Synthesis of propylene-1-butene copolymers with Ziegler-Natta catalyst in gas-phase copolymerizations:kinetics and macromolecular properties[J].Macromol Chem Phys,2005,206(23):2333-2341.
[8]Silva F M,Melo P A,Nele M,et al.Liquid pool copolymerization of propylene-1-butene with a MgCl2-supported Ziegler-Natta catalyst[J].Macromol Mater Eng,2006,291(5):540-551.
[9]Xu Junting,Feng Linxian,Yang Shilin,et al.Influence of electron donors on the tacticityand the composition distribution of propylene-butene copolymers produced by supported Ziegler-Natta catalysts[J].Macromolecules,1997,30(25):7655-7660.
[10]秦亚伟,牛慧,董金勇.Ziegler-Natta催化体系催化丙烯/1-丁烯共聚及其共聚物的表征[J].石油化工,2013,42(10):1159-1164.
[11]任合刚,李振友,闫义彬,等.球形聚丙烯/聚丁烯-1合金粒子制备和性能[J].材料研究学报,2018,32(7):518-524.
[12]李雪,刘宣伯,张丽英.成核剂对丙烯-1-丁烯无规共聚物结构与性能的影响[J].合成树脂及塑料,2012,29(3):66-68.
[13]丁健桦,乐长高,李建强.有机过渡金属络合物均相催化发展及展望[J].化工生产与技术,1999(2):35-39;42.
[14]de Rosa C,Auriemma F,de Ballesteros O R,et al.Crystallization behavior of isotactic propylene-ethylene and propylenebutene copolymers:effects of commoners versus sereodefects on crystallization properties of isotactic polypropylene[J].Macromolecules,2007,40(18):6600-6616.
[15]Nedorezova P M,Chapurina A V,Koval’chuk A A,et al.Copolymerization of propylene with 1-butene and 1-pentene with the isospecific catalytic system rac-Me2Si(4-Ph-2-MeInd)2ZrCl2-MAO[J].Polym Sci Series B,2012,54(1/2):1-14.
[16]刘永卫,刘建国,兰永良.丙烯/1-丁烯共聚物的研究进展[J].精细石油化工进展,2009,10(8):46-49.
[17]Basell Poliolefine Italia s.r.l.Catalyst component for the polymerization of olefins:WO,2007147740[P].2007-12-27.
[18]张春雨,董博,张贺新,等.本体共聚合制备丙烯/1-丁烯合金及表征[J].高等学校化学学报,2014,35(9):2014-2018.
[19]中国石油化工股份有限公司.一种丙烯/1-丁烯无规共聚物的生产方法:中国,201310085576.8[P].2013-06-05.
[20]埃克森化学专利公司.改进的丙烯共聚物热密封树脂及其制品:中国,95193772.3[P]1997-06-18.
[21]Binsbergen F L,de Lange B G M.Morphology of polypropylene crystallized from the melt[J].Polymer,1968,9(68):23-40.
[22]Turner J.Development of theγ-crystal form in random copolymers of propylene and their analysis by dsc and X-ray methods[J].Polymer,1971,12(8):487-508.
[23]Daniela M,Qamer Z,RenéA,et al.Mesophase formation in poly(propylene-ran-1-butene)by rapid cooling[J].Polyme,2009,50(23):5482-5489.
[24]Daniela M,RenéA,Sergio S,et al.X-ray study of crystallization of random copolymers of propylene and 1-butene via a mesophase[J].Polymer,2010,51(22):5212-5220.
[25]Daniela M,RenéA,Evgeny Z,et al.Formation and reorganization of the mesophase of random copolymers of propylene and1-butene[J].Polymer,2011,52(4):1107-1115.
[26]陈雪生.聚乙烯醇-b-聚苯乙烯星形嵌段聚合物的制备及丙烯-1-丁烯无规共聚物的研究[D].北京:北京化工大学,2005.
[27]刘立新,赵晓非,谭小红,等.丙烯/1-丁烯无规共聚树脂等温结晶动力学研究[J].中国塑料,2009,23(7):44-48.
[28]刘立新,贾相臣,刘永卫,等.丙烯/1-丁烯无规共聚物的非等温结晶行为研究[J].中国塑料,2009,23(10):36-39.
[29]Carolina R O,Rufina G A.Show more morphological and kinetic partitioning of comonomer in random propylene1-butene copolymers[J].Polymer,2012,53(3):810-822.
[30]张从容.丙烯-丁烯共聚物首次出现于PP膜市场[J].石油化工动态,1994(5):47.
[31]Kasgoz A,Tamer M,Kocyigit C,et al.Effect of the comonomer content on the solid-state mechanical and viscoelastic properties of poly(propylene-co-1-butene)films[J].J Appl Polym Sci,2018,135(23):46350-46360.
[32]胡雄.丙烯/1-丁烯无规共聚透明聚丙烯研究[J].广东化工,2010,37(7):51-52.
[33]陈国康,高国强,胡雄.丙烯/丁烯-1无规共聚产品的工业化开发[J].石油化工技术与经济,2011,27(5):48-51.
[34]蒋文军,李国飞.丙烯/丁烯-1共聚透明聚丙烯的生产开发[J].广东化工,2013,40(17):71-72.