氢氧稳定同位素对东平湖枯水期水环境的指示作用
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摘要
为掌握东平湖枯水期水环境质量,采集氢氧稳定同位素样品分析了氢氧同位素分布、氘盈余(d值)和富营养化状况,揭示了枯水期蒸发作用和人为因素对湖泊水质的影响,结果表明:(1)单因子评价法反映出东平湖枯水期富营养化现象严重,水体中COD、TN和TP含量平均值分别为16.92mg/L、0.80mg/L和0.31mg/L,接近重富营养化;(2)枯水期δD和δ18 O呈现出从湖区的东南向西北逐渐增加的规律,而氘盈余值则表现出与δD和δ18 O比值相反的空间分布。湖水的氘盈余在-4.77‰～-12.48‰之间,d值严重偏负,说明水体的蒸发作用较强烈;(3)枯水期湖水的δ18 O、δD与COD、pH、EC、呈显著相关性,反映出蒸发分馏对COD等含量的影响;而水中TN、TP含量与δD和δ18 O比值无显著相关性,其含量的大小一定程度是受人为因素影响的。
To learn about the quality of water environment of Dongping Lake in dry period,we collected hydrogen and oxygen stable isotopes samples and analyzed the distribution of hydrogen and oxygen isotopes,deuterium surplus,and eutrophication conditions in Dongping Lake.We revealed the effect of evaporation and human factors on water quality during dry period.The results showed that:(1)The single-factor evaluation showed serious eutrophication in Dongping Lake during dry period.The average concentrations of COD,TN and TP in Dongping Lake were 16.92mg/L,0.80mg/L and 0.31mg/L,respectively.They were close to heavy eutrophication in the dry period.(2)The spatial distributions ofδD andδ18 O showed a gradual increasing trend from the southeast to the northwest of the lake area,while the d value showed an opposite distribution trend to that ofδD andδ18 O.The d value of lake water is negative between-4.77‰ and-12.48‰,indicating that the evaporation of water is strong.(3)In the dry period,δ18 O andδD of lake water showed a significant correlation with the COD,pH and EC,which reflected the effect of evaporation fractionation on the content of COD.However,TN and TP had no significant correlation withδD andδ18 O isotopic values because the content of TN and TP was affected by human factors.
To learn about the quality of water environment of Dongping Lake in dry period,we collected hydrogen and oxygen stable isotopes samples and analyzed the distribution of hydrogen and oxygen isotopes,deuterium surplus,and eutrophication conditions in Dongping Lake.We revealed the effect of evaporation and human factors on water quality during dry period.The results showed that:(1)The single-factor evaluation showed serious eutrophication in Dongping Lake during dry period.The average concentrations of COD,TN and TP in Dongping Lake were 16.92mg/L,0.80mg/L and 0.31mg/L,respectively.They were close to heavy eutrophication in the dry period.(2)The spatial distributions ofδD andδ18 O showed a gradual increasing trend from the southeast to the northwest of the lake area,while the d value showed an opposite distribution trend to that ofδD andδ18 O.The d value of lake water is negative between-4.77‰ and-12.48‰,indicating that the evaporation of water is strong.(3)In the dry period,δ18 O andδD of lake water showed a significant correlation with the COD,pH and EC,which reflected the effect of evaporation fractionation on the content of COD.However,TN and TP had no significant correlation withδD andδ18 O isotopic values because the content of TN and TP was affected by human factors.
引文
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