利用咖啡渣制取咖啡油及活性炭等综合利用技术
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摘要
以咖啡渣为原料制备咖啡油、活性炭以及以肥皂为代表的日用洗护品。咖啡油以咖啡渣为原料用乙醇萃取、超声处理及抽滤旋蒸得。活性炭采用物理化学活化法制备,能够制备出兼得两者优点的高性能活性炭,并通过对其进行重金属离子的吸附效果测定,确定其良好的吸附能力。以肥皂为代表的日用化学采用了咖啡油制备,加入高性能活性炭,具有良好的去角质能力和吸附重金属离子能力,作为创新产品具有良好的可行性和实际生活效益。
Coffee oil, activated carbon and daily-use toiletries represented by soap are prepared from coffee grounds. The coffee oil is extracted from coffee grounds by ethanol extraction, ultrasonication and suction filtration. Activated carbon is prepared by physical chemical activation method, and can produce highperformance activated carbon with both advantages, and determine its good adsorption capacity by measuring the adsorption effect of heavy metal ions. The daily chemistry represented by soap is prepared by using coffee oil, adding high-performance activated carbon, having good exfoliating ability and absorbing heavy metal ions, and has good feasibility and practical life benefits as an innovative product.
Coffee oil, activated carbon and daily-use toiletries represented by soap are prepared from coffee grounds. The coffee oil is extracted from coffee grounds by ethanol extraction, ultrasonication and suction filtration. Activated carbon is prepared by physical chemical activation method, and can produce highperformance activated carbon with both advantages, and determine its good adsorption capacity by measuring the adsorption effect of heavy metal ions. The daily chemistry represented by soap is prepared by using coffee oil, adding high-performance activated carbon, having good exfoliating ability and absorbing heavy metal ions, and has good feasibility and practical life benefits as an innovative product.
引文
[1]Zuo S L,Liu J L,Yang J X,et al.Effects of the crystallinity oflignocellulosic material on the porosity of phosphoric acid-activatedcarbon[J].Carbon,2009,47:3574-3584.
[2]Namane A,Mekarzia A,Benrachedi K,et al.Determination of the adsorption capacity of activated carbon made from coffee grounds by chemical activation with ZnCl2and H3PO4[J].Hazard.Mat.,2005,B119:189-194.
[3]董宇,申哲民,申哲民,等.亚临界水解预处理稻草秸秆制备活性炭及表征[J].环境科学,2012,33(5):1753-1759.
[4]Eguirim M,Limousy L,Dutournie P.Pyrolysis kinetics andphysicochemical properties of agropellets produced from spent ground coffee blended with conventional biomass[J].Chemical Research,2014,92(10):1876-1882.
[5]立本英穖,安部郁夫.活性炭的应用技术其维持管理及存在问题[M].南京:东南大学出版社,2002.
[6]刘斌,杨继亮,马叶,等.磷酸活化法制备梧桐叶活性炭及表征[J].林产工业,2013,(6):35-40.
[7]Monser L,Adhoum N.Removal of Cr(Ⅵ)from aqueous solutionusing activated carbon modified with nitric acid[J].Chemical Engineering Journal,2009,152:434-439.
[8]Mussatto S I,Ballesteros L F,Martins S,et al.Extraction of antioxidant phenolic compounds from spent coffee grounds[J].Separation and Purification Technology,2011,83:173-179.
[9]沈曾明,张文辉,张学军,等.活性炭材料的制备与应用[M].北京:化学工业出版社,2006.
[10]Valix M,Cheung W H,Mc Kay G.Preparation of activated carbonusing low temperature carbonisation and physical activation of highash raw bagasse for acid dye adsorption[J].Chemosphere,2004,56:493-501.
[11]谢新苹,孟中磊,蒋剑春,等.磷酸活化桉木屑制备活性炭的影响因素及表征[J].东北林业大学学报,2013,41(4):116-119.
[12](a)朱光真,邓先伦.磷酸法制备活性炭活化机理研究[J].安徽农业科技,2011,39(30):18653-18655(b)周曰,潘卫国,郭瑞堂,等.用磷酸活化法制备甘蔗渣活性炭及其吸附性能研究[J].上海电力学院学报,2013,29(1):97-100.
[13](a)Emad N Q,Allen S J,Walker G M.Adsorption of methylene blueonto activated carbon produced from steam activated bituminouscoal:A study of equilibrium adsorption isotherm[J].(b)ChemicalEngineering Journal,2006,124:103-110.Gong G Z,Xie Q,Zheng Y F,et al.Regulation pore sizedistribution in coal-based activated carbon[J].New Carbon Materials,2009,24(2):141-145.
[14]何永涛.利用农林废弃物联产生物油和生物炭[D].杭州:浙江工业大学,2012:22-23.
[15]cibi M C,Jeanne-Rose V,Mahjoub B,et al.Preparation andcharacterisation of raw chars and physically activated carbons derived from marine Posidonia oceanica(L)fibres[J].Journal of Hazardous Materials,2009,165(3):240-249.
[16]Okhovat A,Ahmadpour A.A Comparative study of the effects ofdifferent chemical agents on the pore size distributions of macadamianutshell based activated carbons using different models[J].Adsorption Science&Technology,2011,30(2):159-169.
[17]Patnukao P,Pavasant P.Activated carbon from Eucalyptuscamaldulensis Dehn dark using phosphoric acid activation[J].Bioresource Technology,2008,99(17):8540-8543.
[18]Puziy A M,Poddubnaya O L,Martnez-Alonso A,et al.Surface chemistry of phosphorus containing carbons of lignocellubsic origin[J].Carbon,2005,43(14):2857-2868.
[19]Ucar S,Murat E,Tay T,et al.Preparation and characterization ofactivated carbon produced from pomegranate seeds by ZnCl2activation[J].Applied Surface Science,2009,255(21):8890-8896.
[20]王新征,李梦青,居萌轩,等.制备方法对活性炭孔结构的影响[J].炭素技术,2002,6:25-29.
[21]王洋,刘守新.木质素对H3PO4法活性炭孔隙结构的影响[J].林产化学与工业,2011,31(3):33-38.
[2]Namane A,Mekarzia A,Benrachedi K,et al.Determination of the adsorption capacity of activated carbon made from coffee grounds by chemical activation with ZnCl2and H3PO4[J].Hazard.Mat.,2005,B119:189-194.
[3]董宇,申哲民,申哲民,等.亚临界水解预处理稻草秸秆制备活性炭及表征[J].环境科学,2012,33(5):1753-1759.
[4]Eguirim M,Limousy L,Dutournie P.Pyrolysis kinetics andphysicochemical properties of agropellets produced from spent ground coffee blended with conventional biomass[J].Chemical Research,2014,92(10):1876-1882.
[5]立本英穖,安部郁夫.活性炭的应用技术其维持管理及存在问题[M].南京:东南大学出版社,2002.
[6]刘斌,杨继亮,马叶,等.磷酸活化法制备梧桐叶活性炭及表征[J].林产工业,2013,(6):35-40.
[7]Monser L,Adhoum N.Removal of Cr(Ⅵ)from aqueous solutionusing activated carbon modified with nitric acid[J].Chemical Engineering Journal,2009,152:434-439.
[8]Mussatto S I,Ballesteros L F,Martins S,et al.Extraction of antioxidant phenolic compounds from spent coffee grounds[J].Separation and Purification Technology,2011,83:173-179.
[9]沈曾明,张文辉,张学军,等.活性炭材料的制备与应用[M].北京:化学工业出版社,2006.
[10]Valix M,Cheung W H,Mc Kay G.Preparation of activated carbonusing low temperature carbonisation and physical activation of highash raw bagasse for acid dye adsorption[J].Chemosphere,2004,56:493-501.
[11]谢新苹,孟中磊,蒋剑春,等.磷酸活化桉木屑制备活性炭的影响因素及表征[J].东北林业大学学报,2013,41(4):116-119.
[12](a)朱光真,邓先伦.磷酸法制备活性炭活化机理研究[J].安徽农业科技,2011,39(30):18653-18655(b)周曰,潘卫国,郭瑞堂,等.用磷酸活化法制备甘蔗渣活性炭及其吸附性能研究[J].上海电力学院学报,2013,29(1):97-100.
[13](a)Emad N Q,Allen S J,Walker G M.Adsorption of methylene blueonto activated carbon produced from steam activated bituminouscoal:A study of equilibrium adsorption isotherm[J].(b)ChemicalEngineering Journal,2006,124:103-110.Gong G Z,Xie Q,Zheng Y F,et al.Regulation pore sizedistribution in coal-based activated carbon[J].New Carbon Materials,2009,24(2):141-145.
[14]何永涛.利用农林废弃物联产生物油和生物炭[D].杭州:浙江工业大学,2012:22-23.
[15]cibi M C,Jeanne-Rose V,Mahjoub B,et al.Preparation andcharacterisation of raw chars and physically activated carbons derived from marine Posidonia oceanica(L)fibres[J].Journal of Hazardous Materials,2009,165(3):240-249.
[16]Okhovat A,Ahmadpour A.A Comparative study of the effects ofdifferent chemical agents on the pore size distributions of macadamianutshell based activated carbons using different models[J].Adsorption Science&Technology,2011,30(2):159-169.
[17]Patnukao P,Pavasant P.Activated carbon from Eucalyptuscamaldulensis Dehn dark using phosphoric acid activation[J].Bioresource Technology,2008,99(17):8540-8543.
[18]Puziy A M,Poddubnaya O L,Martnez-Alonso A,et al.Surface chemistry of phosphorus containing carbons of lignocellubsic origin[J].Carbon,2005,43(14):2857-2868.
[19]Ucar S,Murat E,Tay T,et al.Preparation and characterization ofactivated carbon produced from pomegranate seeds by ZnCl2activation[J].Applied Surface Science,2009,255(21):8890-8896.
[20]王新征,李梦青,居萌轩,等.制备方法对活性炭孔结构的影响[J].炭素技术,2002,6:25-29.
[21]王洋,刘守新.木质素对H3PO4法活性炭孔隙结构的影响[J].林产化学与工业,2011,31(3):33-38.