质子交换膜燃料电池中膜电极衰减机理综述
|
摘要
膜电极是质子交换膜燃料电池的核心部件,由质子交换膜、催化层、气体扩散层组成,对电池的性能有决定性的影响。分别分析了质子交换膜、催化层与气体扩散层的衰减机理,为提高质子交换膜燃料电池的耐久性提供参考。
The MEA is the core component of the PEMFC. It consists of proton exchange membrane, catalyst layer, and gas diffusion layer, which have a decisive impact to the performance of the battery. The attenuation mechanism of proton exchange membrane, catalyst layer and gas diffusion layer was analyzed respectively,which provided a reference for enhancement of the durability of PEMFC.
The MEA is the core component of the PEMFC. It consists of proton exchange membrane, catalyst layer, and gas diffusion layer, which have a decisive impact to the performance of the battery. The attenuation mechanism of proton exchange membrane, catalyst layer and gas diffusion layer was analyzed respectively,which provided a reference for enhancement of the durability of PEMFC.
引文
[1]CURTIN S,GANGI J.Fuel Cell Technologies Market Report 2015[R].Washington:U.S.Department of Energy,2016.
[2]邸志岗.玻璃基质子交换膜的制备与性能研究[D].上海:上海交通大学,2014.
[3]王诚,王树博,张剑波,等.车用燃料电池耐久性研究[J].化学进展,2015,27(4):424-435.
[4]INABA M,KINUMOTO T,KIRIAKE M,et al.Gas Crossover and Membrane Degradation in Polymer Electrolyte Fuel Cells[J].Electrochimica Acta,2006,51(26):5746-5753.
[5]LIU W,ZUCKERBROD D.In Situ Detection of Hydrogen Peroxide in PEM Fuel Cells[J].Journal of the Electrochemical Society,2005,152(6):A1165-A1170.
[6]CURTIN D E,LOUSENBERG R D,HENRY T J,et al.Advanced Materials for Improved PEMFC Performance and Life[J].Journal of Power Sources,2004,131(1-2):41-48.
[7]SETHURAMAN V A,WEIDNER J W,HAUG A T,et al.Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode Effect of Humidity and Temperature[J].Journal of the Electrochemical Society,2008,155(1):B50-B57.
[8]CHEN C,FULLER T F.Modeling of H2O2Formation in PEMFCs[J].Electrochimica Acta,2009,54(16):3984-3995.
[9]ZHAO M,SHI W Y,WU B B,et al.Influence of Membrane Thickness on Membrane Degradation and Platinum Agglomeration under Long-term Open Circuit Voltage Conditions[J].Electrochimica Acta,2015,153:254-262.
[10]TANG H L,PEIKANG S,JIANG S P,et al.A Degradation Study of Nafion Proton Exchange Membrane of PEM Fuel Cells[J].Journal of Power Sources,2007,170(1):85-92.
[11]KREITMEIER S,SCHULER G A,WOKAUN A,et al.Investigation of Membrane Degradation in Polymer Electrolyte Fuel Cells Using Local Gas Permeation Analysis[J].Journal of Power Sources,2012,212:139-147.
[12]ENDOH E,TERAZONO S,WIDJAJA H,et al.Degradation Study of MEA for PEMFCs under Low Humidity Conditions[J].Electrochemical and Solid-State Letters,2004,7(7):A209-A211.
[13]UCHIYAMA T,KATO M,YOSHIDA T.Buckling Deformation of Polymer Electrolyte Membrane and Membrane Electrode Assembly under Humidity Cycles[J].Journal of Power Sources,2012,206:37-46.
[14]MCDONALD R C,MITTELSTEADT C K,THOMPSON E L.Effects of Deep Temperature Cycling on Nafion112Membranes and Membrane Electrode Assemblies[J].Fuel Cells,2004,4(3):208-213.
[15]SUROWIEC J,BOGOCZEK R.Studies on the Thermal Stability of the Perfluorinated Cation-exchange Membrane Nafion-417[J].Journal of Thermal Analysis,1988,33(4):1097-1102.
[16]WILKIE C A,THOMSEN J R,MITTLEMAN M L.Interaction of Poly(Methyl Methacrylate)and Nafions[J].Journal of Applied Polymer Science,1991,42(4):901-909.
[17]BORUP R,MEYERS J,PIVOVAR B,et al.Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation[J].Chemical Reviews,2007,107(10):3904-3951.
[18]WATANABE M,TSURUMI K,MIZUKAMI T,et al.Activity and Stability of Ordered and Disordered Co-Pt Alloys for Phosphoric Acid Fuel Cells[J].Journal of the Electrochemical Society,1994,141(10):2659-2668.
[19]AKITA T,TANIGUCHI A,MAEKAWA J,et al.Analytical TEM Study of Pt Particle Deposition in the Proton-exchange Membrane of a Membrane-electrodeassembly[J].Journal of Power Sources,2006,159(1):461-467.
[20]SHAO Y Y,YIN G P,GAO Y Z.Understanding and Approaches for the Durability Issues of Pt-based Catalysts for PEM Fuel Cell[J].Journal of Power Sources,2007,171(2):558-566.
[21]WU J F,YUAN X Z,MARTIN J J,et al.A Review of PEM Fuel Cell Durability:Degradation Mechanisms and Mitigation Strategies[J].Journal of Power Sources,2008,184(1):104-119.
[22]REISER C A,BREGOLI L,PATTERSON T W,et al.AReverse-Current Decay Mechanism for Fuel Cells[J].Electrochemical and Solid-State Letters,2005,8(6):A273-A276.
[23]MILLINGTON B,WHIPPLE V,POLLET B G.A Novel Method for Preparing Proton Exchange Membrane Fuel Cell Electrodes by the Ultrasonic-spray Technique[J].Journal of Power Sources,2011,196(20):8500-8508.
[24]XIAO S H,ZHANG H M.The Investigation of Resin Degradation in Catalyst Layer of Proton Exchange Membrane Fuel Cell[J].Journal of Power Sources,2014,246:858-861.
[25]ST-PIERRE J,JIA N Y.Successful Demonstration of Ballard PEMFCS for Space Shuttle Applications[J].Journal of New Materials for Electrochemical Systems,2002,5(4):263-271.
[26]BORUP R,DAVEY J,WOOD D,et al.PEM Fuel Cell Durability[R]∥FY 2005 Progress Report:DOE Hydrogen Program.
[27]SCHULZE M,WAGNER N,KAZ T,et al.Combined Electrochemical and Surface Analysis Investigation of Degradation Processes in Polymer Electrolyte Membrane Fuel Cells[J].Electrochimica Acta,2007,52(6):2328-2336.
[28]PARK J M,OH H Y,HA T H,et al.A Review of the Gas Diffusion Layer in Proton Exchange Membrane Fuel Cells:Durability and Degradation[J].Applied Energy,2015,155:866-880.
[29]FRISK J W,HICKS M T,ATANASOSKI R T,et al.MEAComponent Durability[C].2004 Fuel Cell Seminar,San Autonio,2004.
[30]BORUP R L,DAVEY J R,GARZON F H,et al.PEMFuel Cell Electrocatalyst Durability Measurements[J].Journal of Power Sources,2006,163(1):76-81.
[2]邸志岗.玻璃基质子交换膜的制备与性能研究[D].上海:上海交通大学,2014.
[3]王诚,王树博,张剑波,等.车用燃料电池耐久性研究[J].化学进展,2015,27(4):424-435.
[4]INABA M,KINUMOTO T,KIRIAKE M,et al.Gas Crossover and Membrane Degradation in Polymer Electrolyte Fuel Cells[J].Electrochimica Acta,2006,51(26):5746-5753.
[5]LIU W,ZUCKERBROD D.In Situ Detection of Hydrogen Peroxide in PEM Fuel Cells[J].Journal of the Electrochemical Society,2005,152(6):A1165-A1170.
[6]CURTIN D E,LOUSENBERG R D,HENRY T J,et al.Advanced Materials for Improved PEMFC Performance and Life[J].Journal of Power Sources,2004,131(1-2):41-48.
[7]SETHURAMAN V A,WEIDNER J W,HAUG A T,et al.Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode Effect of Humidity and Temperature[J].Journal of the Electrochemical Society,2008,155(1):B50-B57.
[8]CHEN C,FULLER T F.Modeling of H2O2Formation in PEMFCs[J].Electrochimica Acta,2009,54(16):3984-3995.
[9]ZHAO M,SHI W Y,WU B B,et al.Influence of Membrane Thickness on Membrane Degradation and Platinum Agglomeration under Long-term Open Circuit Voltage Conditions[J].Electrochimica Acta,2015,153:254-262.
[10]TANG H L,PEIKANG S,JIANG S P,et al.A Degradation Study of Nafion Proton Exchange Membrane of PEM Fuel Cells[J].Journal of Power Sources,2007,170(1):85-92.
[11]KREITMEIER S,SCHULER G A,WOKAUN A,et al.Investigation of Membrane Degradation in Polymer Electrolyte Fuel Cells Using Local Gas Permeation Analysis[J].Journal of Power Sources,2012,212:139-147.
[12]ENDOH E,TERAZONO S,WIDJAJA H,et al.Degradation Study of MEA for PEMFCs under Low Humidity Conditions[J].Electrochemical and Solid-State Letters,2004,7(7):A209-A211.
[13]UCHIYAMA T,KATO M,YOSHIDA T.Buckling Deformation of Polymer Electrolyte Membrane and Membrane Electrode Assembly under Humidity Cycles[J].Journal of Power Sources,2012,206:37-46.
[14]MCDONALD R C,MITTELSTEADT C K,THOMPSON E L.Effects of Deep Temperature Cycling on Nafion112Membranes and Membrane Electrode Assemblies[J].Fuel Cells,2004,4(3):208-213.
[15]SUROWIEC J,BOGOCZEK R.Studies on the Thermal Stability of the Perfluorinated Cation-exchange Membrane Nafion-417[J].Journal of Thermal Analysis,1988,33(4):1097-1102.
[16]WILKIE C A,THOMSEN J R,MITTLEMAN M L.Interaction of Poly(Methyl Methacrylate)and Nafions[J].Journal of Applied Polymer Science,1991,42(4):901-909.
[17]BORUP R,MEYERS J,PIVOVAR B,et al.Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation[J].Chemical Reviews,2007,107(10):3904-3951.
[18]WATANABE M,TSURUMI K,MIZUKAMI T,et al.Activity and Stability of Ordered and Disordered Co-Pt Alloys for Phosphoric Acid Fuel Cells[J].Journal of the Electrochemical Society,1994,141(10):2659-2668.
[19]AKITA T,TANIGUCHI A,MAEKAWA J,et al.Analytical TEM Study of Pt Particle Deposition in the Proton-exchange Membrane of a Membrane-electrodeassembly[J].Journal of Power Sources,2006,159(1):461-467.
[20]SHAO Y Y,YIN G P,GAO Y Z.Understanding and Approaches for the Durability Issues of Pt-based Catalysts for PEM Fuel Cell[J].Journal of Power Sources,2007,171(2):558-566.
[21]WU J F,YUAN X Z,MARTIN J J,et al.A Review of PEM Fuel Cell Durability:Degradation Mechanisms and Mitigation Strategies[J].Journal of Power Sources,2008,184(1):104-119.
[22]REISER C A,BREGOLI L,PATTERSON T W,et al.AReverse-Current Decay Mechanism for Fuel Cells[J].Electrochemical and Solid-State Letters,2005,8(6):A273-A276.
[23]MILLINGTON B,WHIPPLE V,POLLET B G.A Novel Method for Preparing Proton Exchange Membrane Fuel Cell Electrodes by the Ultrasonic-spray Technique[J].Journal of Power Sources,2011,196(20):8500-8508.
[24]XIAO S H,ZHANG H M.The Investigation of Resin Degradation in Catalyst Layer of Proton Exchange Membrane Fuel Cell[J].Journal of Power Sources,2014,246:858-861.
[25]ST-PIERRE J,JIA N Y.Successful Demonstration of Ballard PEMFCS for Space Shuttle Applications[J].Journal of New Materials for Electrochemical Systems,2002,5(4):263-271.
[26]BORUP R,DAVEY J,WOOD D,et al.PEM Fuel Cell Durability[R]∥FY 2005 Progress Report:DOE Hydrogen Program.
[27]SCHULZE M,WAGNER N,KAZ T,et al.Combined Electrochemical and Surface Analysis Investigation of Degradation Processes in Polymer Electrolyte Membrane Fuel Cells[J].Electrochimica Acta,2007,52(6):2328-2336.
[28]PARK J M,OH H Y,HA T H,et al.A Review of the Gas Diffusion Layer in Proton Exchange Membrane Fuel Cells:Durability and Degradation[J].Applied Energy,2015,155:866-880.
[29]FRISK J W,HICKS M T,ATANASOSKI R T,et al.MEAComponent Durability[C].2004 Fuel Cell Seminar,San Autonio,2004.
[30]BORUP R L,DAVEY J R,GARZON F H,et al.PEMFuel Cell Electrocatalyst Durability Measurements[J].Journal of Power Sources,2006,163(1):76-81.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |