正丁烷氧化制顺酐反应器技术进展
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摘要
对正丁烷氧化制顺酐传统反应器技术如固定床反应器、流化床反应器进行了评述,指出了传统反应器技术存在的问题,并从工业角度介绍了近几年新的反应器技术的研究进展情况。结合我国顺酐生产现状,认为固定床反应器技术是我国顺酐行业现阶段研究重点,并针对该技术存在的问题提出了解决方案。
The commercial reactor technologies for oxidation of n-butane to maleic anhydride are reviewed,including fixed-bed reactor technology and fluidized-bed reactor technology. The advantages and disadvantages of two different reactor technologies are analyzed. From the perspective of industrial application,the new reactor technology is introduced in detail. Based on the current situation of maleic anhydride production in China,the fixed-bed reactor technology is focused at present. The solutions of the existing problem in the fixed-bed reactor technology are also put forward.
The commercial reactor technologies for oxidation of n-butane to maleic anhydride are reviewed,including fixed-bed reactor technology and fluidized-bed reactor technology. The advantages and disadvantages of two different reactor technologies are analyzed. From the perspective of industrial application,the new reactor technology is introduced in detail. Based on the current situation of maleic anhydride production in China,the fixed-bed reactor technology is focused at present. The solutions of the existing problem in the fixed-bed reactor technology are also put forward.
引文
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[2]TrifiròF,Grasselli R K.How the yield of maleic anhydride in n-butane oxidation,using VPO catalysts,was improved over the years[J].Topics in Catalysis,2014,57(14/15/16):1188-1195.
[3]鲁文质,滕丽华,肖文德.流化床/浆态床反应器耐磨催化剂的研究[C].北京:全国催化学术会议,2005.
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[5]王俐.顺酐生产技术进展及经济性分析[J].化学工业,2015,(5):27-34.
[6]岳鹏,翁心林.顺酐市场分析与发展趋势[J].现代化工,2002,22(8):50-52.
[7]师慧敏.正丁烷氧化法制顺酐钒磷氧催化剂的研究进展[J].石油化工,2013,42(9):1044-1055.
[8]陈真真,张立芬,李勇,等.正丁烷氧化制取顺酐的Huntsman工艺技术进展[J].化学工程,2011,(11):92-98.
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[11]Diedenhoven J,Reitzmann A,Mestl G,et al.A model for the phosphorus dynamics of VPO catalysts during the selective oxidation of n-butane to maleic anhydride in a tubular reactor[J].Chemie Ingenieur Technik,2012,84(4):517-523.
[12]Dente M,Pierucci S,Tronconi E,et al.Selective oxidation of n-butane to maleic anhydride in fluid bed reactors:detailed kinetic investigation and reactor modelling[J].Chemical Engineering Science,2003,58(3/4/5/6):643-648.
[13]Alonso M,Patience G,Fernndez J R,et al.Heat transfer studies in an inorganic membrane reactor at pilot plant scale[J].Catalysis Today,2006,118(1/2):32-38.
[14]Mallada R,Pedernera M,Menéndez N,et al.Synthesis of maleic anhydride in an inert membrane reactor.Effect of reactor configuration[J].Industrial&Engineering Chemistry Research,2000,39(3):620-625.
[15]Garagounis I,Kyriakou V,Anagnostou C,et al.Solid Electrolytes:Applications in heterogeneous catalysis and chemical cogeneration[J].Industrial&Engineering Chemistry Research,2011,50(2):431-472.
[16]Chalakov L,Rihko-Struckmann L K,Munder B,et al.Reaction induced current generation by butane oxidation in high temperature electrochemical membrane reactor[J].Chemical Engineering Journal,2007,131(1/2/3):15-22.
[17]Emig G,Liauw M A.New reaction engineering concepts for selective oxidation reactions[J].Topics in Catalysis,2002,21(1):11-24.
[18]Alonso M,Lorences M J,Pina M P,et al.Butane partial oxidation in an externally fluidized bed-membrane reactor[J].Catalysis Today,2001,67(1/2/3):151-157.
[19]Alonso M,Lorences M J,Patience G S,et al.Membrane pilot reactor applied to selective oxidation reactions[J].Catalysis Today,2005,104(2/3/4):177-184.
[20]SRI International.Permix efficient chemical reactor[EB/OL].[2014-01-09].http://www.sri.com/engage/products-solutions/permix-efficient-chemical-reactor.
[21]陈楠.固定床正丁烷制顺酐的动力学和工艺研究[D].杭州:浙江大学,2014.
[22]Becker C.Katalytische wandreaktorkonzepte für MSA-synthese und methanol-dampfreformierung[D].Stuttgart:Universitt Stuttgart,2002.
[23]Lintz H G,Reitzmann A.Alternative reaction engineering concepts in partial oxidations on oxidic catalysts[J].Catalysis Reviews,2007,49(1):1-32.
[24]Herguido J,Menéndez M,Santamaría J.On the use of fluidized bed catalytic reactors where reduction and oxidation zones are present simultaneously[J].Catalysis Today,2005,100(1/2):181-189.
[25]Gascón J,Téllez C,Herguido J,et al.Fluidized bed reactors with two-zones for maleic anhydride production:Different configurations and effect of scale[J].Industrial&engineering chemistry research,2005,44(24):8945-8951.
[26]Rubio O,Mallada R,Herguido J,et al.Experimental study on the oxidation of butane to maleic anhydride in a two-zone fluidized bed reactor[J].Industrial&Engineering Chemistry Research,2002,41(21):5181-5186.
[27]Julin I,Herguido J,Menéndez M.Experimental and simulated solids mixing and bubbling behavior in a scaled two-section two-zone fluidized bed reactor[J].Chemical Engineering Science,2016,143:240-255.
[2]TrifiròF,Grasselli R K.How the yield of maleic anhydride in n-butane oxidation,using VPO catalysts,was improved over the years[J].Topics in Catalysis,2014,57(14/15/16):1188-1195.
[3]鲁文质,滕丽华,肖文德.流化床/浆态床反应器耐磨催化剂的研究[C].北京:全国催化学术会议,2005.
[4]Gascón J,Valenciano R,Téllez C,et al.A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions[J].Chemical Engineering Science,2006,61(19):6385-6394.
[5]王俐.顺酐生产技术进展及经济性分析[J].化学工业,2015,(5):27-34.
[6]岳鹏,翁心林.顺酐市场分析与发展趋势[J].现代化工,2002,22(8):50-52.
[7]师慧敏.正丁烷氧化法制顺酐钒磷氧催化剂的研究进展[J].石油化工,2013,42(9):1044-1055.
[8]陈真真,张立芬,李勇,等.正丁烷氧化制取顺酐的Huntsman工艺技术进展[J].化学工程,2011,(11):92-98.
[9]韩刚,杨伯伦.正丁烷氧化制顺丁烯二酸酐吸收精制工艺分析[J].现代化工,2006,26(s2):353-356.
[10]Lesser D,Mestl G,Turek T.Transient behavior of vanadyl pyrophosphate catalysts during the partial oxidation of n-butane in industrialsized,fixed bed reactors[J].Applied Catalysis A:General,2016,510:1-10.
[11]Diedenhoven J,Reitzmann A,Mestl G,et al.A model for the phosphorus dynamics of VPO catalysts during the selective oxidation of n-butane to maleic anhydride in a tubular reactor[J].Chemie Ingenieur Technik,2012,84(4):517-523.
[12]Dente M,Pierucci S,Tronconi E,et al.Selective oxidation of n-butane to maleic anhydride in fluid bed reactors:detailed kinetic investigation and reactor modelling[J].Chemical Engineering Science,2003,58(3/4/5/6):643-648.
[13]Alonso M,Patience G,Fernndez J R,et al.Heat transfer studies in an inorganic membrane reactor at pilot plant scale[J].Catalysis Today,2006,118(1/2):32-38.
[14]Mallada R,Pedernera M,Menéndez N,et al.Synthesis of maleic anhydride in an inert membrane reactor.Effect of reactor configuration[J].Industrial&Engineering Chemistry Research,2000,39(3):620-625.
[15]Garagounis I,Kyriakou V,Anagnostou C,et al.Solid Electrolytes:Applications in heterogeneous catalysis and chemical cogeneration[J].Industrial&Engineering Chemistry Research,2011,50(2):431-472.
[16]Chalakov L,Rihko-Struckmann L K,Munder B,et al.Reaction induced current generation by butane oxidation in high temperature electrochemical membrane reactor[J].Chemical Engineering Journal,2007,131(1/2/3):15-22.
[17]Emig G,Liauw M A.New reaction engineering concepts for selective oxidation reactions[J].Topics in Catalysis,2002,21(1):11-24.
[18]Alonso M,Lorences M J,Pina M P,et al.Butane partial oxidation in an externally fluidized bed-membrane reactor[J].Catalysis Today,2001,67(1/2/3):151-157.
[19]Alonso M,Lorences M J,Patience G S,et al.Membrane pilot reactor applied to selective oxidation reactions[J].Catalysis Today,2005,104(2/3/4):177-184.
[20]SRI International.Permix efficient chemical reactor[EB/OL].[2014-01-09].http://www.sri.com/engage/products-solutions/permix-efficient-chemical-reactor.
[21]陈楠.固定床正丁烷制顺酐的动力学和工艺研究[D].杭州:浙江大学,2014.
[22]Becker C.Katalytische wandreaktorkonzepte für MSA-synthese und methanol-dampfreformierung[D].Stuttgart:Universitt Stuttgart,2002.
[23]Lintz H G,Reitzmann A.Alternative reaction engineering concepts in partial oxidations on oxidic catalysts[J].Catalysis Reviews,2007,49(1):1-32.
[24]Herguido J,Menéndez M,Santamaría J.On the use of fluidized bed catalytic reactors where reduction and oxidation zones are present simultaneously[J].Catalysis Today,2005,100(1/2):181-189.
[25]Gascón J,Téllez C,Herguido J,et al.Fluidized bed reactors with two-zones for maleic anhydride production:Different configurations and effect of scale[J].Industrial&engineering chemistry research,2005,44(24):8945-8951.
[26]Rubio O,Mallada R,Herguido J,et al.Experimental study on the oxidation of butane to maleic anhydride in a two-zone fluidized bed reactor[J].Industrial&Engineering Chemistry Research,2002,41(21):5181-5186.
[27]Julin I,Herguido J,Menéndez M.Experimental and simulated solids mixing and bubbling behavior in a scaled two-section two-zone fluidized bed reactor[J].Chemical Engineering Science,2016,143:240-255.