阻燃技术在制浆造纸工业中的应用研究进展
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摘要
综述了近年来阻燃技术在制浆造纸工业中的应用研究进展,介绍了阻燃剂在造纸行业中的发展过程、阻燃纸类的应用、阻燃剂的作用机理和阻燃评价方法。从纤维的阻燃改性、难燃纤维阻燃、填料阻燃和涂料阻燃等方面论述了阻燃技术在制浆造纸工业中的应用,并对以上方法进行分析与比较。
In this paper,the application of flame retardant technology in paper industry in recent years was reviewed,including the development process of flame retardants in paper industry,the applications of flame retardant paper,the function mechanism of flame retardants and several current evaluation indexes of flame retardancy. The application of flame retardant technology in pulp and paper industry was discussed in terms of fiber flame retardant modification,adding refractory fiber,filler flame retardant and coatings flame retardant,finally the above methods were analyzed and compared.
In this paper,the application of flame retardant technology in paper industry in recent years was reviewed,including the development process of flame retardants in paper industry,the applications of flame retardant paper,the function mechanism of flame retardants and several current evaluation indexes of flame retardancy. The application of flame retardant technology in pulp and paper industry was discussed in terms of fiber flame retardant modification,adding refractory fiber,filler flame retardant and coatings flame retardant,finally the above methods were analyzed and compared.
引文
[1] Liu R P,Zhu S C,Sun Q H,et al. Application of new phosphorus nitrogen flame retardant in engineering wallpaper[J].China Pulp&Paper Industry,2016,37(23):75.刘蕊平,朱守诚,孙庆红,等.新型磷-氮系阻燃剂在工程墙纸上的应用[J].中华纸业,2016,37(23):75.
[2] Bao K. Trial production of fireproof wrapping paper[J]. China Pulp&Paper Industry,2008,29(10):84.鲍坤.防火包装纸的试制[J].中华纸业,2008,29(10):84.
[3] Chen F F,Zhu Y J,Xiong Z C,et al. Hydroxyapatite nanowirebased all-weather flexible electrically conductive paper with superhydrophobic and flame-retardant properties[J]. Acs. Appl. Mater. Interfaces,2017,9(45):39534.
[4] Chen J W. Development of environment-friendly flame retardant insulating paperboard[J]. Paper Science&Technology,2016(6):31.陈继伟.环保阻燃绝缘纸板的研制[J].造纸科学与技术,2016(6):31.
[5] Pan Q L,Xu C C,Liu M Y,et al. The Development and Application of Flame Retardant Agent in Papermaking[J]. China Pulp&Paper,2006,25(5):39.潘泉利,徐程程,刘明友,等.阻燃剂在造纸中的应用与发展[J].中国造纸,2006,25(5):39.
[6] Wang Q G,Zhang J,Zhang F. Working principle and application of cone calorimeter[J]. Chinese Journal of Mechanical Engineering,2003(6):36.王庆国,张军,张峰.锥形量热仪的工作原理及应用[J].现代科学仪器,2003(6):36.
[7] Costes L,Laoutid F,Khelifa F,et al. Cellulose/phosphorus combinations for sustainable fire retarded polylactide[J]. European Polymer Journal,2016,74:218.
[8] Gaan S,Sun G. Effect of phosphorus and nitrogen on flame retardant cellulose:A study of phosphorus compounds[J]. Journal of Analytical&Applied Pyrolysis,2007,78(2):371.
[9] Katsuura K,Inagaki N. Flame-retardant properties of cellulose phenylthiophosphonate[J]. Journal of Applied Polymer Science,2010,22(3):679.
[10] Ghanadpour M,Carosio F,W?gberg L. Ultrastrong and flame-resistant freestanding films from nanocelluloses,self-assembled using a layer-by-layer approach[J]. Applied Materials Today,2017,9:229.
[11] Zhang K,Zong L,Tan Y,et al. Improve the flame retardancy of cellulose fibers by grafting zinc ion[J]. Carbohydrate Polymer,2016,136:121.
[12] Shi R,Tan L,Zong L,et al. Influence of Na+and Ca2+on flame retardancy,thermal degradation,and pyrolysis behavior of cellulose fibers[J]. Carbohydrate Polymer,2017,157:1594.
[13] Xu D,Ji Q,Tan L,et al. Influence of alkaline metal ions on flame retardancy and thermal degradation of cellulose fibers[J]. Fibers&Polymers,2014,15(2):220.
[14] Gao Z,Yao T,Ma T,et al. Flame retardant cellulose fibers modified by K+or Na+[J]. Polymer Materials Science&Engineering,2013,29(5):146.
[15] Raabe J,De Souza Fonseca A,Bufalino L,et al. Evaluation of reaction factors for deposition of silica(SiO2)nanoparticles on cellulose fibers[J]. Carbohydrate Polymer,2014,114:424.
[16] Song H Z,Luo Z Q,Wang C Z,et al. Preparation and characterization of bionanocomposite fiber based on cellulose and nano-SiO2using ionic liquid[J]. Carbohydrate Polymer,2013,98(1):161.
[17] Wang Z H,Han E H,Liu F C,et al. Thermal behavior of NanoTiO2in fire-resistant coating[J]. Journal of Materials Science&Technology,2007,23(4):547.
[18] Li X,Zhang K,Shi R,et al. Enhanced flame-retardant properties of cellulose fibers by incorporation of acid-resistant magnesium-oxide microcapsules[J]. Carbohydrate Polymer,2017,176:246.
[19] Nechyporchuk O,Bordes R,K?hnke T. Wet spinning of flame-retardant cellulosic fibers supported by interfacial complexation of cellulose nanofibrils with silica nanoparticles[J]. Acs. Appl. Mater.Interfaces,2017,9(44):69.
[20] Zhang H,Chang Z,Qian X,et al. In situ preparation,characterization and performance of magnesium carbonate whiskers/cellulose fibers hybrid paper[J]. Cellulose,2014,21(6):4633.
[21] Chen F,Zhang J,Li N,et al. Heat insulating,fire retardant and flexible inorganic nanocomposite paper[J]. Materials&Design,2018,144:281.
[22] Dong L Y,Zhu Y J. A new kind of fireproof,flexible,inorganic,nanocomposite paper and its application to the protection layer in flameretardant fiberoptic cables[J]. Chemistry-A European Journal,2017,23(19):4597.
[23] Chen X,Qian X,An X. Preparation of flame-retardant paper using magnesium salt whiskers as filler[J]. Appita Journal of the Technical Association of the Australian&New Zealand Pulp&Paper Industry,2012,65(1):87.
[24] Hou Y,Liu M,Li Y. Feasibility and influence of flame retardant Mg(OH)2as a part of cigarette paper filler on reducing harmful smoke[C]//International Conference on Paper and Environment,Tianjin,2008.
[25] Chen H,Chen K,Yang R,et al. Use of aluminum trihydrate filler to improve the strength properties of cellulosic paper exposed to high temperature treatment[J]. Bioresources,2011,6(3):2399.
[26] Wang S L,Song X M. Synthesis of Mg-Al hydrotalcite and application in flame retardancy of paper[J]. China Printing and Packaging Study,2010,27(s1):18.王松林,宋晓明.镁铝类水滑石的合成及其在纸张阻燃中的应用[J].中国印刷与包装研究,2010,27(s1):18.
[27] LI Xianhui,QIAN Xueren. Study of Mg-Al Hydrotalcite as Flame Retardant Filler for Papermaking[J]. China Pulp&Paper,2008,27(12):16.李贤慧,钱学仁.镁铝水滑石用作造纸阻燃填料的研究[J].中国造纸,2008,27(12):16.
[28] LIU Yuejun,HAO Zongxian,LIU Yiwu. Multilayered Layered Double Hydroxides Metal Oxide Composite Used as Flame Retardant Filler to Prepare Flame-retardant Paper[J]. China Pulp&Paper,2012,31(7):17.刘跃军,郝宗贤,刘亦武.多元层状双羟基金属复合氧化物用作阻燃填料制备阻燃纸[J].中国造纸,2012,31(7):17.
[29] Li C,Liu Z,Hui L F. Study on the preparation of flame-retardant paper by Mg-Al hydrotalcite[J]. China Pulp&Paper Industry,2011,32(2):39.李超,刘忠,惠岚峰.镁铝水滑石制备阻燃纸的研究[J].中华纸业,2011,32(2):39.
[30] Tang X. Application of new calcium silicate filler in flame-retardant paper[D]. Tianjin:Tianjin University of Science&Technology,2014.唐鑫.新型硅酸钙填料在阻燃纸中的应用研究[D].天津:天津科技大学,2014.
[31] Lin H,Sha L Z,Zhao H F. Synthesis of Ammonium polyphosphate/diatomite composite filler and effect on flame retardancy of paper[J]. Paper and Paper Making,2017,36(2):30.林宏,沙力争,赵会芳.聚磷酸铵/硅藻土复合填料的合成及对纸页阻燃性能的影响[J].纸和造纸,2017,36(2):30.
[32] Cayla A,Rault F,Giraud S,et al. Interest of wood wastes(lignin)as flame retardant fillers in bio-based polymers(PA11 and PLA)[C]//Eurofillers Polymer Blends,Montpellier,France,2015.
[33] Yang W G,Yang F,Yang R D,et al. Study on melamine cyanurate as paper flame retardant[J]. Paper Science&Technology,2016(1):57.杨文光,杨飞,杨仁党,等.三聚氰胺氰尿酸盐用作纸张阻燃剂的研究[J].造纸科学与技术,2016(1):57.
[34] Hong L,Hu J,Huang C,et al. Effect of flame retardants on paper fiber by BL-flame retardant[J]. Paper and Paper Making,2010,29(6):28.洪莉,胡健,黄铖,等. BL-阻燃剂对纸张纤维阻燃的效果[J].纸和造纸,2010,29(6):28.
[35] Jindasuwan S,Sukmanee N,Supanpong C,et al. Preparation of water-repellent and flame-retardant coating on mulberry paper[J].Advanced Materials Research,2013,770:100.
[36] Naksata W,Naksata M. Sulphate-based flame-retardant for handmade mulberry paper[J]. Advanced Materials Research,2008,55/57:833.
[37] YANG Jun,LIANG Yun,XU Guilong,et al. Development of Flame Retardant Air Filter Paper for Internal Combustion Engines[J]. China Pulp&Paper,2010,29(6):6.杨军,梁云,徐桂龙,等.内燃机用阻燃型空气过滤纸的研制[J].中国造纸,2010,29(6):6.
[38] Vasiljevi?J,Had?i?S,Jerman I,et al. Study of flame-retardant finishing of cellulose fibres:organic-inorganic hybrid versus conventional organophosphonate[J]. Polymer Degradation and Stability,2013,98(12):2602.
[39] ZHOU Hui,LIU Zhong,WEI Yajing. Preparation of Flame Retardant Paper with Magnesium Hydroxide as Flame Retardant[J]. China Pulp&Paper,2009,28(1):13.周辉,刘忠,魏亚静.以氢氧化镁为阻燃剂制备阻燃纸的研究[J].中国造纸,2009,28(1):13.
[40] Edwards B,Hauser P,El-Shafei A. Nonflammable cellulosic substrates by application of novel radiation-curable flame retardant monomers derived from cyclotriphosphazene[J]. Cellulose,2014,22(1):275.
[41] Liu Y,Pan Y-T,Wang X,et al. Effect of phosphorus-containing inorganic-organic hybrid coating on the flammability of cotton fabrics:synthesis,characterization and flammability[J]. Chemical Engineering Journal,2016,294:167.
[42] Januszewski R,Dutkiewicz M,Maciejewski H,et al. Synthesis and characterization of phosphorus-containing, silicone rubber based flame retardant coatings[J]. Reactive and Functional Polymers,2018,123:1.
[43] Parvinzadeh G M,Almasian A. UV radiation induced flame retardant cellulose fiber by using polyvinylphosphonic acid/carbon nanotube composite coating[J]. Composites Part B:Engineering,2013,45(1):282.
[44] Vasiljevi?J,Jerman I,Jak?a G,et al. Functionalization of cellulose fibres with DOPO-polysilsesquioxane flame retardant nanocoating[J]. Cellulose,2015,22(3):1893.
[45] Wang Y C,Zhao J P,Tong Y Y,et al. Comparative study on flame retardancy of NaOH and Na2SiO3for fiberboard[J]. Bulletin of The Chinese Ceramic Society,2017,36(3):1085.王亚超,赵江平,童媛媛,等. NaOH和Na2SiO3对纤维板阻燃性能的比较研究[J].硅酸盐通报,2017,36(3):1085.
[46] Hribernik S,Smole M S,Kleinschek K S,et al. Flame retardant activity of SiO2-coated regenerated cellulose fibres[J]. Polymer Degradation and Stability,2007,92(11):1957.
[47] Zeng S H,Wei C,Tan Y Y,et al. Modification of sisal fiber microcrystalline with renewable CH/PA flame retardant coating[J]. Chinese Journal of Materials Research,2014,28(2):121.曾思华,韦春,谭玉园,等.可再生CH/PA阻燃涂层对剑麻纤维素微晶的改性[J].材料研究学报,2014,28(2):121.
[48] Pan H,Wang W,Pan Y,et al. Construction of layer-by-layer assembled chitosan/titanate nanotubes based nanocoating on cotton fabrics:flame retardant performance and combustion behavior[J].Cellulose,2015,22(1):911.
[49] Wang N,Liu Y,Liu Y,et al. Properties and mechanisms of different guanidine flame retardant wood pulp paper[J]. Journal of Analytical and Applied Pyrolysis,2017,128:224.
[50] Wang N,Liu Y,Xu C,et al. Acid-base synergistic flame retardant wood pulp paper with high thermal stability[J]. Carbohydrate Polymer,2017,178:123.
[2] Bao K. Trial production of fireproof wrapping paper[J]. China Pulp&Paper Industry,2008,29(10):84.鲍坤.防火包装纸的试制[J].中华纸业,2008,29(10):84.
[3] Chen F F,Zhu Y J,Xiong Z C,et al. Hydroxyapatite nanowirebased all-weather flexible electrically conductive paper with superhydrophobic and flame-retardant properties[J]. Acs. Appl. Mater. Interfaces,2017,9(45):39534.
[4] Chen J W. Development of environment-friendly flame retardant insulating paperboard[J]. Paper Science&Technology,2016(6):31.陈继伟.环保阻燃绝缘纸板的研制[J].造纸科学与技术,2016(6):31.
[5] Pan Q L,Xu C C,Liu M Y,et al. The Development and Application of Flame Retardant Agent in Papermaking[J]. China Pulp&Paper,2006,25(5):39.潘泉利,徐程程,刘明友,等.阻燃剂在造纸中的应用与发展[J].中国造纸,2006,25(5):39.
[6] Wang Q G,Zhang J,Zhang F. Working principle and application of cone calorimeter[J]. Chinese Journal of Mechanical Engineering,2003(6):36.王庆国,张军,张峰.锥形量热仪的工作原理及应用[J].现代科学仪器,2003(6):36.
[7] Costes L,Laoutid F,Khelifa F,et al. Cellulose/phosphorus combinations for sustainable fire retarded polylactide[J]. European Polymer Journal,2016,74:218.
[8] Gaan S,Sun G. Effect of phosphorus and nitrogen on flame retardant cellulose:A study of phosphorus compounds[J]. Journal of Analytical&Applied Pyrolysis,2007,78(2):371.
[9] Katsuura K,Inagaki N. Flame-retardant properties of cellulose phenylthiophosphonate[J]. Journal of Applied Polymer Science,2010,22(3):679.
[10] Ghanadpour M,Carosio F,W?gberg L. Ultrastrong and flame-resistant freestanding films from nanocelluloses,self-assembled using a layer-by-layer approach[J]. Applied Materials Today,2017,9:229.
[11] Zhang K,Zong L,Tan Y,et al. Improve the flame retardancy of cellulose fibers by grafting zinc ion[J]. Carbohydrate Polymer,2016,136:121.
[12] Shi R,Tan L,Zong L,et al. Influence of Na+and Ca2+on flame retardancy,thermal degradation,and pyrolysis behavior of cellulose fibers[J]. Carbohydrate Polymer,2017,157:1594.
[13] Xu D,Ji Q,Tan L,et al. Influence of alkaline metal ions on flame retardancy and thermal degradation of cellulose fibers[J]. Fibers&Polymers,2014,15(2):220.
[14] Gao Z,Yao T,Ma T,et al. Flame retardant cellulose fibers modified by K+or Na+[J]. Polymer Materials Science&Engineering,2013,29(5):146.
[15] Raabe J,De Souza Fonseca A,Bufalino L,et al. Evaluation of reaction factors for deposition of silica(SiO2)nanoparticles on cellulose fibers[J]. Carbohydrate Polymer,2014,114:424.
[16] Song H Z,Luo Z Q,Wang C Z,et al. Preparation and characterization of bionanocomposite fiber based on cellulose and nano-SiO2using ionic liquid[J]. Carbohydrate Polymer,2013,98(1):161.
[17] Wang Z H,Han E H,Liu F C,et al. Thermal behavior of NanoTiO2in fire-resistant coating[J]. Journal of Materials Science&Technology,2007,23(4):547.
[18] Li X,Zhang K,Shi R,et al. Enhanced flame-retardant properties of cellulose fibers by incorporation of acid-resistant magnesium-oxide microcapsules[J]. Carbohydrate Polymer,2017,176:246.
[19] Nechyporchuk O,Bordes R,K?hnke T. Wet spinning of flame-retardant cellulosic fibers supported by interfacial complexation of cellulose nanofibrils with silica nanoparticles[J]. Acs. Appl. Mater.Interfaces,2017,9(44):69.
[20] Zhang H,Chang Z,Qian X,et al. In situ preparation,characterization and performance of magnesium carbonate whiskers/cellulose fibers hybrid paper[J]. Cellulose,2014,21(6):4633.
[21] Chen F,Zhang J,Li N,et al. Heat insulating,fire retardant and flexible inorganic nanocomposite paper[J]. Materials&Design,2018,144:281.
[22] Dong L Y,Zhu Y J. A new kind of fireproof,flexible,inorganic,nanocomposite paper and its application to the protection layer in flameretardant fiberoptic cables[J]. Chemistry-A European Journal,2017,23(19):4597.
[23] Chen X,Qian X,An X. Preparation of flame-retardant paper using magnesium salt whiskers as filler[J]. Appita Journal of the Technical Association of the Australian&New Zealand Pulp&Paper Industry,2012,65(1):87.
[24] Hou Y,Liu M,Li Y. Feasibility and influence of flame retardant Mg(OH)2as a part of cigarette paper filler on reducing harmful smoke[C]//International Conference on Paper and Environment,Tianjin,2008.
[25] Chen H,Chen K,Yang R,et al. Use of aluminum trihydrate filler to improve the strength properties of cellulosic paper exposed to high temperature treatment[J]. Bioresources,2011,6(3):2399.
[26] Wang S L,Song X M. Synthesis of Mg-Al hydrotalcite and application in flame retardancy of paper[J]. China Printing and Packaging Study,2010,27(s1):18.王松林,宋晓明.镁铝类水滑石的合成及其在纸张阻燃中的应用[J].中国印刷与包装研究,2010,27(s1):18.
[27] LI Xianhui,QIAN Xueren. Study of Mg-Al Hydrotalcite as Flame Retardant Filler for Papermaking[J]. China Pulp&Paper,2008,27(12):16.李贤慧,钱学仁.镁铝水滑石用作造纸阻燃填料的研究[J].中国造纸,2008,27(12):16.
[28] LIU Yuejun,HAO Zongxian,LIU Yiwu. Multilayered Layered Double Hydroxides Metal Oxide Composite Used as Flame Retardant Filler to Prepare Flame-retardant Paper[J]. China Pulp&Paper,2012,31(7):17.刘跃军,郝宗贤,刘亦武.多元层状双羟基金属复合氧化物用作阻燃填料制备阻燃纸[J].中国造纸,2012,31(7):17.
[29] Li C,Liu Z,Hui L F. Study on the preparation of flame-retardant paper by Mg-Al hydrotalcite[J]. China Pulp&Paper Industry,2011,32(2):39.李超,刘忠,惠岚峰.镁铝水滑石制备阻燃纸的研究[J].中华纸业,2011,32(2):39.
[30] Tang X. Application of new calcium silicate filler in flame-retardant paper[D]. Tianjin:Tianjin University of Science&Technology,2014.唐鑫.新型硅酸钙填料在阻燃纸中的应用研究[D].天津:天津科技大学,2014.
[31] Lin H,Sha L Z,Zhao H F. Synthesis of Ammonium polyphosphate/diatomite composite filler and effect on flame retardancy of paper[J]. Paper and Paper Making,2017,36(2):30.林宏,沙力争,赵会芳.聚磷酸铵/硅藻土复合填料的合成及对纸页阻燃性能的影响[J].纸和造纸,2017,36(2):30.
[32] Cayla A,Rault F,Giraud S,et al. Interest of wood wastes(lignin)as flame retardant fillers in bio-based polymers(PA11 and PLA)[C]//Eurofillers Polymer Blends,Montpellier,France,2015.
[33] Yang W G,Yang F,Yang R D,et al. Study on melamine cyanurate as paper flame retardant[J]. Paper Science&Technology,2016(1):57.杨文光,杨飞,杨仁党,等.三聚氰胺氰尿酸盐用作纸张阻燃剂的研究[J].造纸科学与技术,2016(1):57.
[34] Hong L,Hu J,Huang C,et al. Effect of flame retardants on paper fiber by BL-flame retardant[J]. Paper and Paper Making,2010,29(6):28.洪莉,胡健,黄铖,等. BL-阻燃剂对纸张纤维阻燃的效果[J].纸和造纸,2010,29(6):28.
[35] Jindasuwan S,Sukmanee N,Supanpong C,et al. Preparation of water-repellent and flame-retardant coating on mulberry paper[J].Advanced Materials Research,2013,770:100.
[36] Naksata W,Naksata M. Sulphate-based flame-retardant for handmade mulberry paper[J]. Advanced Materials Research,2008,55/57:833.
[37] YANG Jun,LIANG Yun,XU Guilong,et al. Development of Flame Retardant Air Filter Paper for Internal Combustion Engines[J]. China Pulp&Paper,2010,29(6):6.杨军,梁云,徐桂龙,等.内燃机用阻燃型空气过滤纸的研制[J].中国造纸,2010,29(6):6.
[38] Vasiljevi?J,Had?i?S,Jerman I,et al. Study of flame-retardant finishing of cellulose fibres:organic-inorganic hybrid versus conventional organophosphonate[J]. Polymer Degradation and Stability,2013,98(12):2602.
[39] ZHOU Hui,LIU Zhong,WEI Yajing. Preparation of Flame Retardant Paper with Magnesium Hydroxide as Flame Retardant[J]. China Pulp&Paper,2009,28(1):13.周辉,刘忠,魏亚静.以氢氧化镁为阻燃剂制备阻燃纸的研究[J].中国造纸,2009,28(1):13.
[40] Edwards B,Hauser P,El-Shafei A. Nonflammable cellulosic substrates by application of novel radiation-curable flame retardant monomers derived from cyclotriphosphazene[J]. Cellulose,2014,22(1):275.
[41] Liu Y,Pan Y-T,Wang X,et al. Effect of phosphorus-containing inorganic-organic hybrid coating on the flammability of cotton fabrics:synthesis,characterization and flammability[J]. Chemical Engineering Journal,2016,294:167.
[42] Januszewski R,Dutkiewicz M,Maciejewski H,et al. Synthesis and characterization of phosphorus-containing, silicone rubber based flame retardant coatings[J]. Reactive and Functional Polymers,2018,123:1.
[43] Parvinzadeh G M,Almasian A. UV radiation induced flame retardant cellulose fiber by using polyvinylphosphonic acid/carbon nanotube composite coating[J]. Composites Part B:Engineering,2013,45(1):282.
[44] Vasiljevi?J,Jerman I,Jak?a G,et al. Functionalization of cellulose fibres with DOPO-polysilsesquioxane flame retardant nanocoating[J]. Cellulose,2015,22(3):1893.
[45] Wang Y C,Zhao J P,Tong Y Y,et al. Comparative study on flame retardancy of NaOH and Na2SiO3for fiberboard[J]. Bulletin of The Chinese Ceramic Society,2017,36(3):1085.王亚超,赵江平,童媛媛,等. NaOH和Na2SiO3对纤维板阻燃性能的比较研究[J].硅酸盐通报,2017,36(3):1085.
[46] Hribernik S,Smole M S,Kleinschek K S,et al. Flame retardant activity of SiO2-coated regenerated cellulose fibres[J]. Polymer Degradation and Stability,2007,92(11):1957.
[47] Zeng S H,Wei C,Tan Y Y,et al. Modification of sisal fiber microcrystalline with renewable CH/PA flame retardant coating[J]. Chinese Journal of Materials Research,2014,28(2):121.曾思华,韦春,谭玉园,等.可再生CH/PA阻燃涂层对剑麻纤维素微晶的改性[J].材料研究学报,2014,28(2):121.
[48] Pan H,Wang W,Pan Y,et al. Construction of layer-by-layer assembled chitosan/titanate nanotubes based nanocoating on cotton fabrics:flame retardant performance and combustion behavior[J].Cellulose,2015,22(1):911.
[49] Wang N,Liu Y,Liu Y,et al. Properties and mechanisms of different guanidine flame retardant wood pulp paper[J]. Journal of Analytical and Applied Pyrolysis,2017,128:224.
[50] Wang N,Liu Y,Xu C,et al. Acid-base synergistic flame retardant wood pulp paper with high thermal stability[J]. Carbohydrate Polymer,2017,178:123.
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