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重金属污染土壤修复技术研究进展
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  • 英文篇名:Research Progress in Remediation Technology of Heavy Metal Contaminated Soil
  • 作者:王兴利 ; 王晨野 ; 吴晓晨 ; 王晶博 ; 穆晓东 ; 杨晓姝 ; 胡小飞 ; 高静
  • 英文作者:WANG Xingli;WANG Chenye;WU Xiaochen;WANG Jingbo;MU Xiaodong;YANG Xiaoshu;HU Xiaofei;GAO Jing;Hainan Institute of Environmental Sciences;College of Chemistry,Jilin University;
  • 关键词:重金属 ; 污染土壤 ; 修复技术
  • 英文关键词:heavy metal;;contaminated soil;;remediation technology
  • 中文刊名:HBHG
  • 英文刊名:Chemistry & Bioengineering
  • 机构:海南省环境科学研究院;吉林大学化学学院;
  • 出版日期:2019-01-31
  • 出版单位:化学与生物工程
  • 年:2019
  • 期:v.36;No.265
  • 基金:海南省自然科学基金项目(218QN305);; 海南省重点研发计划项目(ZDYF2018208);海南省重点研究计划项目(ZDYF2018201)
  • 语种:中文;
  • 页:HBHG201902001
  • 页数:8
  • CN:02
  • ISSN:42-1710/TQ
  • 分类号:4-10+14
摘要
随着工农业的快速发展,我国面临着严峻的土壤重金属污染。重金属污染土壤修复已经成为当今生态环境领域面临的重要课题,受到广泛关注。立足于国内外重金属污染土壤修复技术的前沿,对土壤重金属污染的主要来源进行了简单介绍,同时详细阐述和分析了重金属污染土壤的主要修复技术,如物理修复技术、化学修复技术、生物修复技术等,针对各种修复技术的特点和缺点,提出了重金属污染土壤修复技术领域的改进和发展方向,为土壤修复技术研究提供借鉴。
        With the rapid development of industry and agriculture,China is facing a severe situation of soil heavy metal pollution.The remediation of heavy metal contaminated soil has become an important issue in the field of ecological environment,which has attracted extensive attention.On the basis of the frontier of remediation technology for heavy metal contaminated soil at home and abroad,we shortly introduce the main sources of soil heavy metal pollution.Meanwhile,we expound and analyze the main remediation technologies of heavy metal contaminated soil in detail,such as physical remediation,chemical remediation,and biological remediation,etc.Aiming at the characteristics and disadvantages of various remediation technologies,we put forward the improvement and development directions of remediation technologies for heavy metal contaminated soil in the future,which provide a reference for the research of soil remediation.
引文
[1]陈怀满.环境土壤学[M].北京:科学出版社,2006:216-217.
    [2]冯凤玲,成杰民,王德霞.蚯蚓在植物修复重金属污染土壤中的应用前景[J].土壤通报,2006,37(4):808-814.FENG F L,CHENG J M,WANG D X.Potential application of earthworm for the phytoremediation of soils contaminated by heavy metals[J].Chinese Journal of Soil Science,2006,37(4):808-814.
    [3]余志,黄代宽.重金属污染土壤修复治理技术概述[J].环保科技,2013,19(4):46-48.YU Z,HUANG D K.Overview of remediation of heavy metal pollution in soil[J].Environmental Protection and Technology,2013,19(4):46-48.
    [4]吴燕玉,陈涛,张学询.沈阳张士灌区Cd污染生态研究[J].生态学报,1989,9(1):21-26.WU Y Y,CHEN T,ZHANG X X.Pollution ecology of Cd in the Zhangshi irrigation area of Shenyang[J].Acta Ecologica Sinica,1989,9(1):21-26.
    [5]佟洪金,涂仕华,赵秀兰.土壤重金属污染的治理措施[J].西南农业学报,2003,16(S1):33-37.TONG H J,TU S H,ZHAO X L.Countermeasure technology in heavy metal contaminated soils[J].Southwest China Journal of Agricultural Sciences,2003,16(S1):33-37.
    [6]肖楚,李礼,查忠勇.铅污染土壤的修复技术研究进展[J].重庆工商大学学报(自然科学版),2012,29(3):99-104.XIAO C,LI L,ZHA Z Y.Research progress in lead contaminated soil remediation technology[J].Journal of Chongqing Technology and Business University(Natural Science Edition),2012,29(3):99-104.
    [7] KUNKEL A M,SEIBERT J J,ELLIOTT L J,et al.Remediation of elemental mercury using in situthermal desorption(ISTD)[J].Environmental Science and Technology,2006,40(7):2384-2389.
    [8]瞿丽雅,付舜珍,刘鹂,等.汞污染土壤的改善研究[J].贵州师范大学学报(自然科学版),2004,22(2):49-51.QU L Y,FU S Z,LIU L,et al.A study on the soil improvement palluted by mercury[J].Journal of Guizhou Normal University(Natural Science Edition),2004,22(2):49-51.
    [9]乔志香,金春姬,贾永刚,等.重金属污染土壤电动力学修复技术[J].环境污染治理技术与设备,2004,5(6):80-83.QIAO Z X,JIN C J,JIA Y G,et al.Technology of electrokinetic remediation of heavy metals-contaminated soils[J].Techniques and Equipment for Environmental Pollution Control,2004,5(6):80-83.
    [10]于颖,周启星.污染土壤化学修复技术研究与进展[J].环境污染治理技术与设备,2005,6(7):1-7.YU Y,ZHOU Q X.A review on chemical remediation technology of contaminated soils[J].Techniques and Equipment for Environmental Pollution Control,2005,6(7):1-7.
    [11]苗旭锋,肖细元,郭朝晖,等.矿冶区重金属污染土壤肥力特征及生态修复潜力分析[J].环境科学与技术,2010,33(7):115-119.MIAO X F,XIAO X Y,GUO Z H,et al.Fertility characteristics and ecological restoration potential analysis for metal contaminated soils from vicinity of typical mining and smelting areas in Hunan Province[J].Environmental Science and Technology,2010,33(7):115-119.
    [12]韦树燕,黄宇妃,宋波.重金属污染土壤化学钝化剂应用研究进展[J].资源节约与环保,2013(6):143-144.
    [13]王碧玲,谢正苗,孙叶芳,等.磷肥对铅锌矿污染土壤中铅毒的修复作用[J].环境科学学报,2005,25(9):1189-1194.WANG B L,XIE Z M,SUN Y F,et al.Effects of phosphorus fertilizers on remediation of lead toxicity in a soil contaminated by lead and zinc mining[J].Acta Scientiae Circumstantiae,2005,25(9):1189-1194.
    [14]彭建,蒋一军,吴健生,等.我国矿山开采的生态环境效应及土地复垦典型技术[J].地理科学进展,2005,24(2):38-48.PENG J,JIANG Y J,WU J S,et al.Eco-environmental effects of mining and related land reclamation technologies in China[J].Progress in Geography,2005,24(2):38-48.
    [15] SHRESTHA G,TRAINA S J,SWANSTON C W.Black carbon′s properties and role in the environment:a comprehensive review[J].Sustainability,2010,2(1):294-320.
    [16]何绪生,耿增超,佘雕,等.生物炭生产与农用的意义及国内外动态[J].农业工程学报,2011,27(2):1-7.HE X S,GENG Z C,SHE D,et al.Implications of production and agricultural utilization of biochar and its international dynamic[J].Transactions of the Chinese Society of Agricultural Engineering,2011,27(2):1-7.
    [17]王萌萌,周启星.生物炭的土壤环境效应及其机制研究[J].环境化学,2013,32(5):768-780.WANG M M,ZHOU Q X.Environmental effects and their mechanisms of biochar applied to soils[J].Environmental Chemistry,2013,32(5):768-780.
    [18] NAVARRO A,MARTINEZ F.The use of soil-flushing to remediate metal contamination in a smelting slag dumping area:column and pilot-scale experiments[J].Engineering Geology,2010,115(1/2):16-27.
    [19] CHIANG K Y,HU Y H.Water washing effects on metals emission reduction during municipal solid waste incinerator(MSWI)fly ash melting process[J].Waste Management,2010,30(5):831-838.
    [20]刘磊,胡少平,陈英旭,等.淋洗法修复化工厂遗留地重金属污染土壤的可行性[J].应用生态学报,2010,21(6):1537-1541.LIU L,HU S P,CHEN Y X,et al.Feasibility of washing as a remediation technology for the heavy metals-polluted soils left by chemical plant[J].Chinese Journal of Applied Ecology,2010,21(6):1537-1541.
    [21] MOUTSATSOU A,GREGOU M,MATSAS D,et al.Washing as a remediation technology applicable in soils heavily polluted by mining-metallurgical activities[J].Chemosphere,2006,63(10):1632-1640.
    [22] KO I W,LEE C H,LEE K P,et al.Remediation of soil contaminated with arsenic,zinc,and nickel by pilot-scale soil washing[J].Environmental Progress,2006,25(1):39-48.
    [23] MAKINO T,KAMIYA T,TAKANO H,et al.Remediation of cadmium-contaminated paddy soils by washing with calcium chloride:verification of on-site washing[J].Environmental Pollution,2007,147(1):112-119.
    [24]MAKINO T,TAKANO H,KAMIYA T,et al.Restoration of cadmium-contaminated paddy soils by washing with ferric chloride:Cd extraction mechanism and bench-scale verification[J].Chemosphere,2008,70(6):1035-1043.
    [25] SUBIRES-MUNOZ J D,GARCIA-RUBIO A,VEREDA-ALONSO C,et al.Feasibility study of the use of different extractant agents in the remediation of a mercury contaminated soil from Almaden[J].Separation and Purification Technology,2011,79(2):151-156.
    [26]周健民.土壤学大辞典[M].北京:科学出版社,2013:41-48.
    [27]李玉双,胡晓钧,孙铁珩,等.污染土壤淋洗修复技术研究进展[J].生态学杂志,2011,30(3):596-602.LI Y S,HU X J,SUN T H,et al.Soil washing/flushing of contaminated soil:a review[J].Chinese Journal of Ecology,2011,30(3):596-602.
    [28] MAO X H,JIANG R,XIAO W,et al.Use of surfactants for the remediation of contaminated soils:a review[J].Journal of Hazardous Materials,2015,285:419-435.
    [29] UDOVIC M,LESTAN D.Pb,Zn and Cd mobility,availability and fractionation in aged soil remediated by EDTA leaching[J].Chemosphere,2009,74(10):1367-1373.
    [30]董汉英,仇荣亮,赵芝灏,等.EDTA淋洗修复Cu污染土壤的去除效率与适宜淋洗剂用量的选取[J].中山大学学报(自然科学版),2010,49(3):135-139.DONG H Y,QIU R L,ZHAO Z H,et al.Washing of Cu-contaminated soil using EDTA-removal efficiency and the optimization of EDTA dosage[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2010,49(3):135-139.
    [31]赵娜,崔岩山,付彧,等.乙二胺四乙酸(EDTA)和乙二胺二琥珀酸(EDDS)对污染土壤中Cd、Pb的浸提效果及其风险评估[J].环境化学,2011,30(5):958-963.ZHAO N,CUI Y S,FU Y,et al.Leaching of Cd and Pb from a contaminationated soil with EDTA and EDDS:effectiveness and health risk assessment[J].Environmental Chemistry,2011,30(5):958-963.
    [32]冯静,张增强,李念,等.铅锌厂重金属污染土壤的螯合剂淋洗修复及其应用[J].环境工程学报,2015,9(11):5617-5625.FENG J,ZHANG Z Q,LI N,et al.Washing of heavy metal contaminated soil around a lead-zinc smelter by several chelating agents and the leached soil utilization[J].Chinese Journal of Environmental Engineering,2015,9(11):5617-5625.
    [33]祝方,陈雨,刘文庆.螯合剂对用芥菜型油菜修复镉污染土壤镉形态转化的影响[J].能源环境保护,2013(1):25-28,31.ZHU F,CHEN Y,LIU W Q.The effect of chelator on distribution of cadmium from contaminated soil by Brassica juncea L.[J].Energy Environmental Protection,2013(1):25-28,31.
    [34]可欣,张昀,李培军,等.利用酒石酸土柱淋洗法修复重金属污染土壤[J].深圳大学学报(理工版),2009,26(3):240-245.KE X,ZHANG Y,LI P J,et al.Leaching remediation of a heavy metal contaminated soil using tartaric acid[J].Journal of Shenzhen University(Science&Engineering),2009,26(3):240-245.
    [35]许超,夏北城,林颖.柠檬酸对中低污染土壤中重金属的淋洗动力学[J].生态环境学报,2009,18(2):507-510.XU C,XIA B C,LIN Y.Kinetics of heavy metals in medium and slight pollution load soils under effects of citric washing[J].Ecology and Environment,2009,18(2):507-510.
    [36]梁丽丽,郭书海,李刚,等.柠檬酸/柠檬酸钠淋洗铬污染土壤效果及弱酸可提取态铬含量的变化[J].农业环境科学学报,2011,30(5):881-885.LIANG L L,GUO S H,LI G,et al.The effects of Cr removal from contaminated soil and the content changes of acid extractable fraction by citric/sodium citrate leaching[J].Journal of Agro-Environment Science,2011,30(5):881-885.
    [37]董汉英,仇荣亮,赵芝灏,等.工业废弃地多金属污染土壤组合淋洗修复技术研究[J].土壤学报,2010,47(6):1126-1133.DONG H Y,QIU R L,ZHAO Z H,et al.Sequential elution technique for remediation of multi-metal contaminated brownfield soils[J].Acta Pedologica Sinica,2010,47(6):1126-1133.
    [38] GHEJU M,PODE R,MANEAA F.Comparative heavy metal chemical extraction from anaerobically digested biosolids[J].Hydrometallurgy,2011,108(1/2):115-121.
    [39] DEBELA F,AROCENA J M,THRING R W,et al.Organic acidinduced release of lead from pyromorphite and its relevance to reclamation of Pb-contaminated soils[J].Chemosphere,2010,80(4):450-456.
    [40]吕青松,蒋煜峰,杨帆,等.重金属污染土壤淋洗技术研究进展[J].甘肃农业科技,2010(3):33-37.LV Q S,JIANG Y F,YANG F,et al.Research progress on the flushing remediation of heavy metal contaminated soils[J].Gansu Agricultural Science and Technology,2010(3):33-37.
    [41] TORRES L G,LOPEZ R B,BELTRAN M.Removal of As,Cd,Cu,Ni,Pb and Zn from a highly contaminated industrial soil u-sing surfactant enhanced soil washing[J].Physics and Chemistry of the Earth,2012,37/38/39:30-36.
    [42] FRANZETTI A,CAREDDA P,RUGGERI C,et al.Potential applications of surface active compounds by Gordonia sp.strain BS29in soil remediation technologies[J].Chemosphere,2009,75(6):801-807.
    [43] HJ 682-2014[S].污染场地术语.
    [44]李飞宇.土壤重金属污染的生物修复技术[J].环境科学与技术,2011,34(S2):148-151.LI F Y.Bioremediation in heavy metals contaminated soils[J].Environmental Science and Technology,2011,34(S2):148-151.
    [45]张从,夏立江.污染土壤生物修复技术[M].北京:中国环境科学出版社,2000:148-151.
    [46]鲍桐,廉梅花,孙丽娜,等.重金属污染土壤植物修复研究进展[J].生态环境,2008,17(2):858-865.BAO T,LIAN M H,SUN L N,et al.Research progress on the phytoremediation of soils contaminated by heavy metals[J].Ecology and Environment,2008,17(2):858-865.
    [47] CHANEY R L.Plant uptake of in organic waste constituents[C]//PARR J F.Land treatment of hazardous wastes.New Jersey:Park Ridge,Noyes Data Corporation,1983:50-76.
    [48] CHEN T B,WEI C Y.Arsenic hyperaccumulator in some plant species in South China[C]//Proceedings of International Conference of Soil Remediation,2000:194-195.
    [49]陈同斌,韦朝阳,黄泽春,等.砷超富集植物蜈蚣草及其对砷的富集特征[J].科学通报,2002,47(3):207-210.
    [50]谢景千,雷梅,陈同斌,等.蜈蚣草对污染土壤中As、Pb、Zn、Cu的原位去除效果[J].环境科学学报,2010,30(1):165-171.XIE J Q,LEI M,CHEN T B,et al.Phytoremediation of soil cocontaminated with arsenic,lead,zinc and copper using Pteris vittata L.:a field study[J].Acta Scientiae Circumstantiae,2010,30(1):165-171.
    [51]杨肖娥,龙新宪,倪吾钟,等.东南景天(Sedum alfredii H.)——一种新的锌超富集植物[J].科学通报,2002,47(13):1003-1006.
    [52]黄闺,孟桂元,陈跃进,等.苎麻对重金属铅耐受性及其修复铅污染土壤潜力研究[J].中国农学通报,2013,29(20):148-152.HUANG G,MENG G Y,CHEN Y J,et al.Study on Pb tolerance and remediation potential of lead-contaminated soil of ramie[J].Chinese Agricultural Science Bulletin,2013,29(20):148-152.
    [53]廖晓勇,陈同斌,阎秀兰,等.提高植物修复效率的技术途径与强化措施[J].环境科学学报,2007,27(6):881-893.LIAO X Y,CHEN T B,YAN X L,et al.Enhancement of heavy metal removal in phytoremediation of soils contaminated with heavy metals[J].Acta Scientiae Circumstantiae,2007,27(6):881-893.
    [54]赵颖,刘利军,党晋华,等.污灌区复合污染土壤的植物修复研究[J].生态环境学报,2013,22(7):1208-1213.ZHAO Y,LIU L J,DANG J H,et al.Phytoremediation of combined pollution soil in a sewage irrigation area[J].Ecology and Environmental Sciences,2013,22(7):1208-1213.
    [55]金勇,付庆灵,郑进,等.超富集植物修复铜污染土壤的研究现状[J].中国农业科技导报,2012,14(4):93-100.JIN Y,FU Q L,ZHENG J,et al.Research status on phytoremediation of copper contaminated soil with hyperaccumulator[J].Journal of Agricultural Science and Technology,2012,14(4):93-100.
    [56]唐浩,朱江,黄沈发,等.蚯蚓在土壤重金属污染及其修复中的应用研究进展[J].土壤,2013,45(1):17-25.TANG H,ZHU J,HUANG S F,et al.Review on application of earthworm in soil heavy metal pollution and remediation[J].Soils,2013,45(1):17-25.
    [57]滕应,骆永明,李振高.污染土壤的微生物修复原理与技术进展[J].土壤,2007,39(4):497-502.TENG Y,LUO Y M,LI Z G.Principles and techniques of microbial remediation of polluted soils[J].Soils,2007,39(4):497-502.
    [58]杨靖.铬污染土壤的微生物修复技术研究进展[J].资源节约与环保,2013(7):241-242.
    [59]王洪祚,刘世勇.酶和细胞的固定化[J].化学通报,1997(2):22-27.
    [60] SU D,LI P J,FRANK S,et al.Biodegradation of benzo[a]pyrene in soil by Mucor sp.SF06and Bacillus sp.SB02co-immobilized on vermiculite[J].Journal of Environmental Sciences,2006,18(6):1204-1209.
    [61] ALMUTAIRI M.Monitoring bioremediation in oil contaminated soils using toxicity analysis[C]//Society of Petroleum Engineers-9th International Conference on Health,Safety and Environment in Oil and Gas Exploration and Production 2008-'In Search of Sustainable Excellence',2008:1-7.
    [62]李华,刘永军,刘金光.固定化Acinetobacter sp.XA05和Sphingomonas sp.FG03降解苯酚[J].化工环保,2010,30(1):12-15.LI H,LIU Y J,LIU J G.Biodegradation of phenol by using free and immobilized cells of Acinetobacter sp.XA05and Sphingomonas sp.FG03[J].Environmental Protection of Chemical Industry,2010,30(1):12-15.
    [63]苏丹,李培军,鞠京丽,等.非流体介质中多环芳烃污染的微生物固定化修复技术[J].应用生态学报,2006,17(8):1530-1534.SU D,LI P J,JU J L,et al.Remediation of polycyclic aromatic hydrocarbons in non-fluid medium with immobilized microorganism technique[J].Chinese Journal of Applied Ecology,2006,17(8):1530-1534.
    [64]司友斌,彭军.固定化微生物技术及其在污染土壤修复中的应用[J].土壤,2007,39(5):673-676.SI Y B,PENG J.Advances in immobilized microorganism and its application in contaminated soil remediation[J].Soils,2007,39(5):673-676.
    [65]胡广军,梁成华,李培军,等.固定化微生物对多环芳烃污染土壤的降解[J].生态学杂志,2008,27(5):745-750.HU G J,LIANG C H,LI P J,et al.Degradation of soil polycyclic aromatic hydrocarbons by immobilized microbes[J].Chinese Journal of Ecology,2008,27(5):745-750.
    [66] WANG L,HUANG L J,YUN L J,et al.Removal of nitrogen,phosphorus,and organic pollutants from water using seeding type immobilized microorganisms[J].Biomedical and Environmental Sciences,2008,21(2):150-156.
    [67]曹阳,宋菁.固定化微生物技术对受污染缓流水体底泥生态修复的研究[J].黄石理工学院学报,2009,25(3):11-14.CAO Y,SONG J.Study on effects of immobilized microorganism technology on ecological restoration of contaminated slow-flow water sediments[J].Journal of Huangshi Institute of Technology,2009,25(3):11-14.
    [68]张秀霞,白雪晶,徐娜娜,等.固定化微生物修复石油污染土壤影响因素研究[J].环境工程学报,2013,7(3):1156-1162.ZHANG X X,BAI X J,XU N N,et al.Study on influencing factors of immobilized microorganisms for remedying oil-contaminated soil[J].Chinese Journal of Environmental Engineering,2013,7(3):1156-1162.
    [69] JANOUSKOVA M,PAVLIKOVA D,VOSATKA M.Potential contribution of arbuscular mycorrhiza to cadmium immobilisation in soil[J].Chemosphere,2006,65(11):1959-1965.
    [70] GONZALEZ-CHAVEZ M C,CARRILLO-GONZALEZ R,WRIGHT S F,et al.The role of glomalin,aprotein produced by arbuscular mycorrhizal fungi,in sequestering potentially toxic elements[J].Environmental Pollution,2004,130(3):317-323.
    [71] CHERN E C,TSAI D W,OGUNSEITAN O A.Deposition of glomalin-related soil protein and sequestered toxic metals into watersheds[J].Environmental Science and Technology,2007,41(10):3566-3572.
    [72]串丽敏,赵同科,郑怀国,等.土壤重金属污染修复技术研究进展[J].环境科学与技术,2014,37(S2):213-222.CHUAN L M,ZHAO T K,ZHENG H G,et al.Research advances in remediation of heavy metal contaminated soils[J].Environmental Science and Technology,2014,37(S2):213-222.
    [73]廖强,刘爱菊.土壤重金属污染状况与修复技术研究进展[J].山东理工大学学报(自然科学版),2018,32(4):7-11.LIAO Q,LIU A J.The state of art in soil heavy metal contamination and remediation technology[J].Journal of Shandong University of Technology(Natural Science Edition),2018,32(4):7-11.

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