腐蚀产物膜对石油管材腐蚀行为影响的研究进展
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摘要
在实际服役过程中,石油专用管内壁往往被腐蚀产物覆盖,腐蚀产物膜的形成与腐蚀过程密切相关,而腐蚀产物膜的结构与性能又严重影响着管材的进一步腐蚀行为。综述了石油专用管腐蚀产物膜形成机制,重点阐述了影响腐蚀产物膜形成的主要因素、腐蚀产物膜的结构和性能,并简述了石油专用管内防护措施,最后对腐蚀产物膜的研究方向进行了展望。
In actual service process,the inner walls of petroleum pipes are usually covered by corrosion products.The formation of corrosion scale is closely related to corrosion process,and the structure and properties of corrosion scale affect the corrosion behavior of petroleum pipe seriously.The formation mechanism of corrosion scale on petroleum pipes is reviewed,and the main factors affecting the formation of corrosion scale,the structure and properties of corrosion scale are highlighted.The protection measures for petroleum pipes are briefly described.Finally,the research direction of corrosion scale is prospected.
In actual service process,the inner walls of petroleum pipes are usually covered by corrosion products.The formation of corrosion scale is closely related to corrosion process,and the structure and properties of corrosion scale affect the corrosion behavior of petroleum pipe seriously.The formation mechanism of corrosion scale on petroleum pipes is reviewed,and the main factors affecting the formation of corrosion scale,the structure and properties of corrosion scale are highlighted.The protection measures for petroleum pipes are briefly described.Finally,the research direction of corrosion scale is prospected.
引文
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[5]张瑾,许立宁,朱金阳,等.高温高压CO2腐蚀环境中含Cr低合金钢耐蚀机理的研究进展[J].腐蚀与防护,2017,38(6):456-461.
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[8]张江江,张志宏,羊东明,等.油气田地面集输碳钢管线内腐蚀检测技术应用[C]//2013中国油气田腐蚀与防护技术科技创新大会.贵阳:石油工业出版社,2013.
[9]PALACIOS C A,SHADLEY J R.Characteristics of corrosion scales on steels in a CO2sub-saturated NaCl brine[J].Corrosion,1991,47:122-127.
[10]林冠发,白真权,赵新伟,等.CO2腐蚀产物膜形态结构与温度和压力的关系[J].石油机械,2005,33:1-4.
[11]张国安,路民旭,吴荫顺.CO2腐蚀产物膜的微观形貌和结构特征[J].材料研究学报,2005,19(5):537-548.
[12]高立新,谷坛,闫静,等.高酸性条件下元素硫对碳钢腐蚀的影响[J].天然气工业,2015,35:94-98.
[13]ZHANG Y,XIE Y,LU M,et al.Corrosion behavior of Cr bearing low alloy steel with different Cr content in CO2top-of-line corrosion environment[J].Comparative Immunology Microbiology&Infectious Diseases,2014,36(1):9-16.
[14]常炜,胡丽华.温度对X65和3%Cr管线钢CO2腐蚀行为的影响[J].腐蚀与防护,2012,33(S2):100-105.
[15]蔡乾锋,薛晨,朱世东,等.低铬油套管H2S/CO2腐蚀研究进展[J].表面技术,2016,45(8):7-13.
[16]MOLCHAN I S,THOMPSON G E,LINDSAY R,et al.Corrosion behaviour of mild steel in 1-alkyl-3-methylimidazolium tricyanomethanide ionic liquids for CO2capture applications[J].Royal Society of Chemistry Advances,2014,4:5300-5311.
[17]李勇.油气田腐蚀环境中N80钢和3Cr钢的腐蚀行为[J].腐蚀与防护,2016,37(6):494-497.
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[20]刘艳朝,赵国仙,薛艳,等.超级13Cr钢在高温高压下的抗CO2腐蚀性能[J].全面腐蚀控制,2011,25(11):29-34.
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[22]周卫军,郭瑞,张勇.温度对SM80SS套管钢在CO2/H2S共存环境中的高温高压腐蚀行为影响[J].全面腐蚀控制,2009,23(7):39-41,29.
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