Ti(C,N)基金属陶瓷性能影响因素及发展趋势
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摘要
Ti(C,N)基金属陶瓷作为一种新型的工具材料,具有密度低、室温硬度和高温硬度都优于WC基硬质合金、化学稳定性和抗氧化性好、耐磨性好等优点。介绍了Ti(C,N)基金属陶瓷的基本组成和结构,组织性能及其影响因素,综述了Ti(C,N)基金属陶瓷的研究现状,指出了其未来的发展方向和应用。
Ti(C,N)-based cermets,as a new tool material,have the advantages of low density,excellent hardness at room temperature and high temperature,superior to WC-based cemented carbide,good chemical and oxidation resistance and good abrasion resistance.The basic composition and structure of Ti(C,N)-based cermets and their microstructures and their influencing factors were introduced.The current research status of Ti(C,N)-based cermets was reviewed.Future development directions and applications were also pointed out.
Ti(C,N)-based cermets,as a new tool material,have the advantages of low density,excellent hardness at room temperature and high temperature,superior to WC-based cemented carbide,good chemical and oxidation resistance and good abrasion resistance.The basic composition and structure of Ti(C,N)-based cermets and their microstructures and their influencing factors were introduced.The current research status of Ti(C,N)-based cermets was reviewed.Future development directions and applications were also pointed out.
引文
1 Liu N,Xu Y D,Li Z H,et al.Influence of molybdenum addition on the microstructure and mechanical properties of TiC-based cermets with nano-TiN modification.Ceram Inter,2003,29(8):919~925
2 Humenik M,Parikh N M.Cermets:Ⅰ,fundamental concepts related to microstructure and physical properties of cermet system.J Am Ceram Soc,1956,39(2):60~63
3 Parikh N M,Humenik M J.Cermets:Ⅱwettability and microstructure studies in liquid phase sintering.J Am Ceram Soc,1957,40(9):315~320
4王零森.特种陶瓷.长沙:中南工业大学出版社,1996
5陆庆忠,张福润,余立新.Ti(C,N)基金属陶瓷的研究现状及发展趋势.武汉科技学院学报,2002,15(5):43~46
6李荣久.陶瓷-金属复合材料.北京:冶金工业出版社,2004
7 Moskowitz D,Termer L.Ti(C,N)cermets and its application.RM&HM,1986(3):13~15
8 Chen L M,Walter L,Klaus D.Advances in modern nitrogen-containing hardmetals and cermets.Int J Refr Hard Met,2000,18:153~161
9黄金昌.碳氮化钛基金属陶瓷.稀有金属与硬质合金,1994,119:43~49
10贺从训,夏志华,汪有明,等.Ti(C,N)基金属陶瓷的研究.稀有金属,1999(1):4~12
11 Qi F,Kang S.A study on microstructural changes in Ti(CN)-NbC-Ni cermets.Materials Science and Engineeirng,1998,A25l:276~285
12 Fredeirc Monteverde,Vlaentina Medir,Alida Bellosi.Microstructural of hot-pressed Ti(C,N)-based cermets.Journal of the European Ceramic Society,2002,22:2 587~2 593
13谢峰,张崇高,刘宁,等.Ti(C,N)基金属陶瓷刀具与纳米改性.中国机械工程,2002,13(12):1 062~1 065
14张杰,刘灿楼,胡镇华.碳量对Ti(C,N)基金属陶瓷组织和性能的影响.粉末冶金技术,1997,15(2):122~125
15刘宁,等.添加碳对Ti(C,N)基金属陶瓷组织和性能的影响.理化检验-物理分册,1995,31(2):13~15
16刘宁,崔崑,胡镇华.SiC晶须对金属陶瓷抗弯强度和断裂韧性的影响.稀有金属材料与工程,1996,25(5):12~15
17刘宁,姜勇,吕庆荣.化学成分对Ti(C,N)基金属陶瓷断裂韧性的影响.粉末冶金技术,1999,17(4):269~272
18刘宁,崔崑,胡镇华.SiC晶须对金属陶瓷抗弯强度和断裂韧性的影响.稀有金属材料与工程,1996,25(5):12~15
19熊惟皓,胡镇华,崔昆.Ti(C,N)基金属陶瓷中碳化物的界面行为.材料导报,1998(4):14~16
20铃木寿.超微WC-Co硬质台盒的结构与抗弯强度.粉体与粉末冶盒,1985,32(4):152~157
2 Humenik M,Parikh N M.Cermets:Ⅰ,fundamental concepts related to microstructure and physical properties of cermet system.J Am Ceram Soc,1956,39(2):60~63
3 Parikh N M,Humenik M J.Cermets:Ⅱwettability and microstructure studies in liquid phase sintering.J Am Ceram Soc,1957,40(9):315~320
4王零森.特种陶瓷.长沙:中南工业大学出版社,1996
5陆庆忠,张福润,余立新.Ti(C,N)基金属陶瓷的研究现状及发展趋势.武汉科技学院学报,2002,15(5):43~46
6李荣久.陶瓷-金属复合材料.北京:冶金工业出版社,2004
7 Moskowitz D,Termer L.Ti(C,N)cermets and its application.RM&HM,1986(3):13~15
8 Chen L M,Walter L,Klaus D.Advances in modern nitrogen-containing hardmetals and cermets.Int J Refr Hard Met,2000,18:153~161
9黄金昌.碳氮化钛基金属陶瓷.稀有金属与硬质合金,1994,119:43~49
10贺从训,夏志华,汪有明,等.Ti(C,N)基金属陶瓷的研究.稀有金属,1999(1):4~12
11 Qi F,Kang S.A study on microstructural changes in Ti(CN)-NbC-Ni cermets.Materials Science and Engineeirng,1998,A25l:276~285
12 Fredeirc Monteverde,Vlaentina Medir,Alida Bellosi.Microstructural of hot-pressed Ti(C,N)-based cermets.Journal of the European Ceramic Society,2002,22:2 587~2 593
13谢峰,张崇高,刘宁,等.Ti(C,N)基金属陶瓷刀具与纳米改性.中国机械工程,2002,13(12):1 062~1 065
14张杰,刘灿楼,胡镇华.碳量对Ti(C,N)基金属陶瓷组织和性能的影响.粉末冶金技术,1997,15(2):122~125
15刘宁,等.添加碳对Ti(C,N)基金属陶瓷组织和性能的影响.理化检验-物理分册,1995,31(2):13~15
16刘宁,崔崑,胡镇华.SiC晶须对金属陶瓷抗弯强度和断裂韧性的影响.稀有金属材料与工程,1996,25(5):12~15
17刘宁,姜勇,吕庆荣.化学成分对Ti(C,N)基金属陶瓷断裂韧性的影响.粉末冶金技术,1999,17(4):269~272
18刘宁,崔崑,胡镇华.SiC晶须对金属陶瓷抗弯强度和断裂韧性的影响.稀有金属材料与工程,1996,25(5):12~15
19熊惟皓,胡镇华,崔昆.Ti(C,N)基金属陶瓷中碳化物的界面行为.材料导报,1998(4):14~16
20铃木寿.超微WC-Co硬质台盒的结构与抗弯强度.粉体与粉末冶盒,1985,32(4):152~157