微波法制备生物柴油研究进展
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摘要
基于微波的选择性、瞬时性及体积性加热的特点,可以有效提高反应分子的平均能量、分子的碰撞频率,加快反应速率,采用微波辅助催化酯交换反应制备生物柴油近几年得到了国内外学者的广泛关注。将微波能应用于生物柴油制备过程具有显著的优势,与传统加热方式相比,采用微波辐射加热,反应时间明显缩短,产物组成也有所变化。因此主要从酸碱催化剂催化酯交换反应和酯化反应的角度,综述了国内外对微波辅助生物柴油制备的研究进展,并对微波优势及未来发展趋势进行了展望。
Due to the characteristics of selectivity, instantaneity and volumetric heating, microwaves can increase the reaction rate by increasing the average energy of organic reaction molecules and increasing their collision frequency. Microwave assisted preparation of biodiesel through catalytic transesterification has attracted more and more attention from the scholars. The application of microwave in the preparation of biodiesel has significant advantages compared to the traditional heating method the reaction time is obviously shortened and the products compositions are changed as well. This paper reviews the research progress of biodiesel preparation through acidic/basic catalytic transesterification using microwave heating, and the future trend is also prospected.
Due to the characteristics of selectivity, instantaneity and volumetric heating, microwaves can increase the reaction rate by increasing the average energy of organic reaction molecules and increasing their collision frequency. Microwave assisted preparation of biodiesel through catalytic transesterification has attracted more and more attention from the scholars. The application of microwave in the preparation of biodiesel has significant advantages compared to the traditional heating method the reaction time is obviously shortened and the products compositions are changed as well. This paper reviews the research progress of biodiesel preparation through acidic/basic catalytic transesterification using microwave heating, and the future trend is also prospected.
引文
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[6]中华人民共和国国家质量监督检查检疫总局,中国国家标准化管理委员会. B5柴油:GB 25199—2017[S].北京:中国标准出版社, 2017.General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China, Standardization Administration of the Peoples Republic of China. B5 diesel:GB25199—2017[S]. Beijing:Standards Press of China, 2017.
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[8]魏红明,赵华.生物柴油制备方法及应用现状[J].当代化工,2006, 35(4):246-249.Wei H M, Zhao H. Preparation methods of application situation of biodiesel fuels[J]. Contemporary Chemical Industry, 2006, 35(4):246-249.
[9]张萍波,韩秋菊,范明明,等.酯交换法制备生物柴油反应机理的研究进展[J].石油化工, 2012, 41(9):1081-1086.Zhang P B, Han Q J, Fan M M, et al. Progresses in study on the mechanism of transesterification for biodiesel fuel[J].Petrochemical Technology, 2012, 41(9):1081-1086.
[10]张秋云,杨松,李虎.制备生物柴油的固体酸催化剂研究进展[J].化工进展, 2013, 32(3):575-583.Zhang Q Y, Yang S, Li H. Research progress in the preparation of biodiesel with solid acid as the catalyst[J]. Chemical Industry and Engineering Progress, 2013, 32(3):575-583.
[11] Gedye R, Smith F, Westaway K, et al. The use of microwave ovens for rapid organic synthesis[J]. Tetrahedron Letter, 1986, 27(3):279-282.
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[13] Meredith R J. Engineers Handbook of Industrial Microwave Heating[M]. London:Institute of Electrical Engineers, 1998.
[14] Amais R S, Donati G L, Schiavo D, et al. A simple dilute-andshoot procedure for Si determination in diesel and biodiesel by microwave-induced plasma optical emission spectrometry[J].Microchemical Journal, 2013, 106:318-322.
[15] Azcan N, Danisman A. Microwave assisted transesterification of rapeseed oil[J]. Fuel, 2008, 87(10/11):1781-1788.
[16] Azcan N, Yilmaz O. Microwave assisted transesterification of waste frying oil and concentrate methyl ester content of biodiesel by molecular distillation[J]. Fuel, 2013, 104:614-619.
[17] Boldor D, Kanitkar A, Terigar B G, et al. Microwave assisted extraction of biodiesel feedstock from the seeds of invasive Chinese tallow tree[J]. Environmental Science Technology, 2010,44(10):4019-4025.
[18] Cheng J, Huang R, Yu T, et al. Biodiesel production from lipids in wet microalgae with microwave irradiation and bio-crude production from algal residue through hydrothermal liquefaction[J]. Bioresource Technology, 2014, 151:415-418.
[19] Choedkiatsakul I, Ngaosuwan K, Assabumrungrat S, et al.Biodiesel production in a novel continuous flow microwave reactor[J]. Renewable Energy, 2015, 83:25-29.
[20] da Rós P C, de Castro H F, Carvalho A K, et al. Microwaveassisted enzymatic synthesis of beef tallow biodiesel[J]. Journal of Industrial Microbiology, 2012, 39(4):529-536.
[21] Dai Y M, Chen K T, Chen C C. Study of the microwave lipid extraction from microalgae for biodiesel production[J]. Chemical Engineering Journal, 2014, 250:267-273.
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