过渡金属在石油脱硫技术中的催化作用
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摘要
含硫有机物的脱硫是石油冶炼工艺中的难点。对比了传统的除硫方法和过渡金属活性配合物除硫的方法,重点阐述了过渡金属Pd、Pt、Ru、Fe等与含硫有机物发生的各种具体反应,推导了当代脱硫技术中过渡金属活动性为Pd>Pt>Ru>Fe,这对石油冶炼技术和脱硫工艺的发展具有指导作用。
The desulfurization of sulfur compounds is a difficult problem of petroleum refining process. It was compared that there were many differences between the sulfur traditional method and active transition metal complexes of sulfur removal method. We have focused on a variety of transition metal Pd, Pt, Ru, Fe and organic sulfur compounds in the specific reaction pathways. The transition of contemporary desulfurization technology of metal activity was Pd>Pt>Ru>Fe, which has made important instruction for the petroleum refining technology and the development of desulfurization technology.
The desulfurization of sulfur compounds is a difficult problem of petroleum refining process. It was compared that there were many differences between the sulfur traditional method and active transition metal complexes of sulfur removal method. We have focused on a variety of transition metal Pd, Pt, Ru, Fe and organic sulfur compounds in the specific reaction pathways. The transition of contemporary desulfurization technology of metal activity was Pd>Pt>Ru>Fe, which has made important instruction for the petroleum refining technology and the development of desulfurization technology.
引文
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[29]徐文媛,徐娜娜,唐静,等.肟和环戊烯杂Diels-Alder反应的理论计算[J].吉首大学学报:自然科学版,2012,33(2):89-92.
[30]薛伟,龚华玉,赵洪菊,等.含苯并噻唑基双酰胺衍生物的合成与生物活性[J].吉首大学学报:自然科学版,2012,33(5):92-97.
[31]刘景锋,李凌燕.虚部光子晶体掺杂介质色散模型[J].吉首大学学报:自然科学版,2012,33(5):51-55.
[32]王清才,王岩,王光怀.一维函数光子晶体的禁带特性理论[J].吉首大学学报:自然科学版,2012,33(1):36-40.
[33]蒋剑波,罗冬明,钱东.聚吡咯/氧化石墨复合材料的电化学电容性能[J].吉首大学学报:自然科学版,2012,33(2):93-98.
[34]BIANCHINI C,MEALLI C,MELI A,et al.Genesis of tetrathiooxalate-like C2S4 and C2Se 4units.A multiform experimental study and the relevant theoretical implications for the role of transition-metal fragments[J].Journal of the American Chemical Society,1987,109(1):185-198.
[2]STANISLAUS A,MARAFI A,RANA M S.Recent advances in the science and technology of ultra low sulfur diesel(ULSD)production[J].Catal Today,2010,153:61-68.
[3]龙剑友.湘西自治州农村环境污染的防治——基于社会主义新农村建设的思考[J].吉首大学学报:自然科学版,2012,33(1):116-119.
[4]钱伯章.欧洲炼厂实施二氧化碳减排方案[J].天然气与石油,2009,27(4):37.
[5]张一方.经济危机和非线性经济增长理论及其3个定理[J].吉首大学学报:自然科学版,2012,33(3):94-99.
[6]夏青虹.柴油机排放标准发展研究[C]//中国石油学会第六届石油炼制学术年会会议论文集.北京:中国石化出版社,2010.
[7]LIU Z,ZHANG Q,ZHENG Y,et al.Effects of Nitrogen and Aromatics on Hydrodesulfurization of Light Cycle Oil Predicted by a System Dynamics Model[J].Energy Fuels,2008,22(2):860-866.
[8]ALI M F,AL-MALKI A,EL-ALI B,et al.Deep desulphurization of gasoline and diesel fuels using non-hydrogen consuming techniques[J].Fuel,2006,85(3):1354-1363.
[9]李建源,周新锐,赵德丰.苯并噻吩及其衍生物[J].化学通报,2005,68(5):1-7.
[10]顾仁勇,银永忠.超临界CO2萃取栝楼籽油工艺条件优化[J].吉首大学学报:自然科学版,2012,33(2):99-102.
[11]孙志娟,余谟鑫,张心亚,等.油品中噻吩类硫化物脱除技术研究进展[J].化工进展,2005,24(9):1002-1005.
[12]杨林,李春虎,李秀平,等.活性半焦在FCC柴油吸附脱硫中的应用研究[J].工业催化,2007,15(1):24-28.
[13]宋鹏俊,闫锋,张影,等.FCC柴油氧气氧化萃取法脱硫研究[J].化工科技,2010,18(2):43-47.
[14]黄庆云,徐瑞秋.菇烯环氧化反应的研究(Ⅰ)烃基过氧化氢非均相催化菇烯环氧化反应的研究[J].北京大学学报:自然科学版,1989,25(4):427-430.
[15]童晓滨.乙醇提取雷竹叶芳香油及其红外光谱分析[J].吉首大学学报:自然科学版,2012,33(3):66-70.
[16]易成高,于寒颖,赵欢,等.石油和天然气生物脱硫技术分析和展望[J].石油化工,2010,39(6):681-687.
[17]邢金仙,刘晨光.FCC柴油中硫、氮化合物的馏分和类型分布[J].石油与天然气化工,2003,32(8):246-249.
[18]WANG L D,HE W,YU Z K.Transition-metal mediated carbon-sulfur bond activation and transformations[J].Chem Soc Rev,2013,42(2),599-621.
[19]GOH L Y,WENG Z,LEONG W K,et al.C-S Bond Cleavage and C-C Coupling in Cyclopentadienyl Chromium Complexes to Give the First Dithiooxamide-Bridged and Doubly Dithiocarbamate-Bridged Double Cubanes:[Cp6Cr8S8{(C(S)NEt2)2}]and[Cp6Cr8S8(S2CNEt2)2][J].Angewandte Chemie International Edition,2001,40(17):3236-3239.
[20]GUYON F,KNORR M,GARILLON A,et al.Platinum(Ⅱ)Complexes Bearing a Thiolate/Thioether Ligand Hemilability vs Dealkylation[J].European Journal of Inorganic Chemistry,2012(2):282-291.
[21]TORRES-NIETO J,AR E′VALO A,GARC I′A-GUTI E′RREZ P,et al.Catalytic desulfurization of dibenzothiophene and 4,6-dimethyl dibenzo thiophene with nickel compounds[J].Organometallics,2004,23(20):4534-4536.
[22]DEWHURST R D,HILL A F,RAE A D,et al.Reactions of bis(tricarbido)mercurials and dimetallaoctatetraynes with[Ru(CO)2(PPh3)3]:scission of a Csp-Csp single bond[J].Organometallics,2005,24(20):4703-4706.
[23]ORTEGA-ALFARO M C,ALCANTARA O,ORRALA M,et al.C-S Bond Activation of Two Novel AsymmetricA-azo-Ketenedithioacetals Using Fe2(CO)9[J].Organometallics,2007,26(8):1895-1899.
[24]苏培峰,谭凯,吴安安,等.理论与计算化学研究进展[J].厦门大学学报:自然科学版,2011,50(2):311-318.
[25]徐昕,王南钦,吕鑫,等.量子化学的研究现状、发展趋势与展望[J].化学进展,1996,7(1):30-42.
[26]龙威.H2理论研究中的量子化学计算方法[J].宁夏师范学院学报,2010,31(3):43-47.
[27]徐文媛,周洁霞,龙威,等.H2在催化剂上的吸附行为[J].吉首大学学报:自然科学版,2012,33(5):88-91.
[28]龙威.镍基上甲烷—超临界CO2重整反应机理研究[D].上海:华东交通大学,2011.
[29]徐文媛,徐娜娜,唐静,等.肟和环戊烯杂Diels-Alder反应的理论计算[J].吉首大学学报:自然科学版,2012,33(2):89-92.
[30]薛伟,龚华玉,赵洪菊,等.含苯并噻唑基双酰胺衍生物的合成与生物活性[J].吉首大学学报:自然科学版,2012,33(5):92-97.
[31]刘景锋,李凌燕.虚部光子晶体掺杂介质色散模型[J].吉首大学学报:自然科学版,2012,33(5):51-55.
[32]王清才,王岩,王光怀.一维函数光子晶体的禁带特性理论[J].吉首大学学报:自然科学版,2012,33(1):36-40.
[33]蒋剑波,罗冬明,钱东.聚吡咯/氧化石墨复合材料的电化学电容性能[J].吉首大学学报:自然科学版,2012,33(2):93-98.
[34]BIANCHINI C,MEALLI C,MELI A,et al.Genesis of tetrathiooxalate-like C2S4 and C2Se 4units.A multiform experimental study and the relevant theoretical implications for the role of transition-metal fragments[J].Journal of the American Chemical Society,1987,109(1):185-198.