河北蔡家营铅锌多金属矿地电化学提取有效性及提取条件试验
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摘要
通过干旱-半干旱风成砂覆盖区蔡家营铅锌多金属矿315勘探线上地电化学有效性及条件性试验发现:在该景观区及矿床条件下,地电化学测量较常规土壤测量异常显示效果更佳,具有更大的勘查适用性。在测量条件方面:(1)随电提取时间的增加,Pb、Zn等主成矿元素异常显示效果有变好的趋势,埋藏更深的矿体上方逐步出现较明显的地电化学元素异常,但Cd、Cu等元素在不同的提取时间条件下均可取得较为一致的提取效果;(2)使用人工外电场和在提取极土壤中添加井水等提取液可保证地电化学测量获得较好的异常显示效果,是电提取过程的必要条件。
According the research of effectiveness and conditions of geo-electrochemistry( CHIM) in the drought-semiarid aeolian shallow overburden area of Caijiayin Pb-Zn polymetallic mining area,we found that CHIM was more efficient and applicable than traditional soil survey. The results of conditions texts show:(1)With the increase of electric extraction time,the abnormal curve of main ore-forming elements such as Pb and Zn had a tendency to become better. More obvious electrochemical elemental anomalies appear gradually above the buried ore body. But Cd,Cu and other elements could be achieved more consistent extraction effect in different extraction time conditions.(2)The use of artificial external electric field and extractant could ensure geo-electrochemical measurement to obtain better anomalies of indicator elements. Thus these are necessary conditions for geo-electrochemical extraction process.
According the research of effectiveness and conditions of geo-electrochemistry( CHIM) in the drought-semiarid aeolian shallow overburden area of Caijiayin Pb-Zn polymetallic mining area,we found that CHIM was more efficient and applicable than traditional soil survey. The results of conditions texts show:(1)With the increase of electric extraction time,the abnormal curve of main ore-forming elements such as Pb and Zn had a tendency to become better. More obvious electrochemical elemental anomalies appear gradually above the buried ore body. But Cd,Cu and other elements could be achieved more consistent extraction effect in different extraction time conditions.(2)The use of artificial external electric field and extractant could ensure geo-electrochemical measurement to obtain better anomalies of indicator elements. Thus these are necessary conditions for geo-electrochemical extraction process.
引文
Fei Xi-quan.1984.The result of experiment with method of partial metal extraction in several mining areas[J].Geophysical and Geochemical Exploration,8(3):162-166(in Chinese with English abstract)
Hu Xue-wen,Zhang Jiang-man,Quan Hen.1996.Isotopic age of Hongqiyingzi Gr in northern Hebei and its time attribution[J].Geological Bulletin of China,(s1):186-192(in Chinese)
Hu Xiao-die,Shen Bao-feng,Mao De-bao,Zhong Chang-ting.2005.On metallogeny of the Caijiaying Pb-Zn deposit[J].Geological Survey and Research,28(4):221-227(in Chinese with English abstract)
Huang Dian-hao,Ding Xiao-shi,Wu Cheng-yu,Zhang Chang-jiang.1991.Mineral characteristics and occurrence of gold,silver and bismuth of the Caijiaying lead-zinc-silver deposit,Hebei Province[J].Acta Geologica Sinica,(2):127-140(in Chinese with English abstract)
Kang Ming,Ceng Kuang,Luo Xian-rong.2006.Applcation of“dipole CHIM”electrified by low voltage dipole[J].Geology and Prospecting,42(4):81-85(in Chinese with English abstract)
Kang Ming,Luo Xian-rong.2003.Improvement and applied results of geoelectrical chemistry methods[J].Geology and Prospecting,39(5):63-66(in Chinese with English abstract)
Li Jiang,Gao Min-hai,Wang Shi-mei,Wang Dian-yun.1989.Electrogeochemical extraction techniques using in exploration for gold[J].Geology and Prospecting,(1):52-54(in Chinese with English abstract)
Li Jin-ming,Lu Jun.1998.Theoretical and experimental study for geoelectrochemical extraction menthod[J].Earth Science Frontiers,5(1):208-216(in Chinese with English abstract)
Liu Zhan-yuan,Liu Ji-min,Cui Ai-min.1997.A discussion on the action conditions of CHIM process[J].Geophysical and Geochemical Exploration21(2),115-122(in Chinese with English abstract)
Liu Zhan-yuan,Zhou Guo-hua.2002.Some new advances method and techniques of CHIM[J].Geology and Prospecting,38(s1):173-177(in Chinese with English abstract)
Luo Xian-rong.1994.Secondary discussion on prospecting buried ore by geoelectrochemical method[J].Journal of Guilin University of Technology,14(3):295-302(in Chinese with English abstract)
Luo Xian-rong.2005.The mechanism of electrogechemical halo-formation and the application of electrogeochemical method to exploration of metallic ore deposits[D].Hefei:Hefei University of Technology:61-71(in Chinese with English abstract)
Mao Ning,Zhou Lin-cheng,Li Yan-feng.2011.Application of polyurethane foam in metal lons monitoring and wastewater treatment[J].Chemistry Bulltein,74(9):797-802(in Chinese with English abstract)
Рысс,Ю·С,Zhang Zhao-yuan,Cui Lin-pei.1986.Geoelectrochemical exploration method[M].Beijing:Geological Publishing House:1-30(in Chinese)
Qiu Yu-min.1988.Experimental study of geoelectrical-chemistry for gold deposits and its effects[J].Gold,(6):22-26(in Chinese with English abstract)
Shen Wu-jun,Bai Chun-dong,Chen Yuan-yuan.2017.Geochemical exploration of concealed deposits in Caijiaying area of Hebei Province[J].Geophysical and Geochemical Exploration,41(2):210-218(in Chinese with English abstract)
Sun Bin-bin,Liu Zhan-yuan,Zhou Guo-hua.2011.The development of the solid carrier elements extractor[J].Geophysical and Geochemical Exploration,35(3):375-378(in Chinese with English abstract)
Sun Bin-bin,Zhang Xue-jun,Liu Zhan-yuan,Zhou Guo-hua,Zhang Bimin,Chen Ya-dong.2015.A preliminary study of the formation mechanism of the geoelectric chemistry anomaly[J].Geophysical and Geochemical Exploration,39(6):1183-1187(in Chinese with English abstract)
Xie Bang-ting,Sun Bin-bin,He Ling,Liu Zhan-yuan,Ye Rong,Liu Yinfei,Wang Teng-yun.2016.Geoelectrochemical Exploration at a scale1∶50 000 in the Periphery of the Chaobuleng polymetallic deposit[J].Geology and Exploration,52(5):885-892(in Chinese with English abstract)
Xiong Chang-lin,Li Hui-ling.2003.On the mechanism of the geoelectric and chemical extraction method[J].Geology of Fujian,22(4):187-194(in Chinese with English abstract)
Yang Fang-fang,Lu Zong-liu,Lu Yi-gan.2006.Efficiency of electric absorption prospecting method in capturing anomalies hard to be found by routine geochemical methods[J].Mineral Resources and Geology,20(4):479-483(in Chinese with English abstract)
Zhang Chang-jiang.1990.Geological characteristics of the Caijiaying lead-zinc(gold-silver)deposit in Hebei Province[J].Mineral Deposits,9(4):301-308(in Chinese with English abstract)
费锡铨.1984.电提取离子法在几个矿区的试验结果[J].物探与化探,8(3):162-166
胡学文,张江满,权桓.1996.冀北红旗营子群同位素年龄及其时代归属[J].地质通报,(s1):186-192
胡小蝶,沈保丰,毛德宝,钟长汀.2005.冀北蔡家营铅锌矿床成因探讨[J].地质调查与研究,28(4):221-227
黄典豪,丁孝石,吴澄宇,张长江.1991.河北蔡家营铅-锌-银矿床矿物特征和金、银、铋赋存状态的研究[J].地质学报,(2):127-140
康明,岑况,罗先熔.2006.低电压偶极子供电方式下的“偶极CHIM”应用效果[J].地质与勘探,42(4):81-85
康明,罗先熔.2003.地电化学方法的改进及应用效果[J].地质与勘探,39(5):63-66
雷斯(Рысс,Ю·С),张肇元,崔霖沛译.1986.地电化学勘探法[M].北京:地质出版社:1-30
李江,高明海.1989.地电化学提取法在找金矿中的应用[J].地质与勘探,(1):52-54
李金铭,卢军.1998.地电化学提取法的理论与实验研究[J].地学前缘,5(1):208-216
刘占元,刘吉敏,崔爱民.1997.电提取过程作用条件问题讨论[J].物探与化探,21(2):115-122
刘占元,周国华.2002.地电化学方法技术改进的思路与进展[J].地质与勘探,38(s1):173-177
罗先熔.1994.再论地球电化学测量法寻找隐伏矿床[J].桂林理工大学学报,14(3):295-302
罗先熔.2005.地电化学成晕机制、方法技术及找矿研究[D].合肥:合肥工业大学:61-71
毛宁,周林成,李彦锋.2011.聚氨酯泡沫材料用于环境中金属离子监测及污染物去除的研究进展[J].化学通报,74(9):797-802
邱玉民.1988.地电化学找金矿的试验研究及其效果[J].黄金,(6):22-26
申伍军,白春东,陈圆圆.2017.冀北蔡家营地区隐伏矿地球化学勘查方法[J].物探与化探,41(2):210-218
孙彬彬,刘占元,周国华.2011.固体载体型元素提取器研制[J].物探与化探,35(3):375-378
孙彬彬,张学君,刘占元,周国华,张必敏,陈亚东.2015.地电化学异常形成机理初探[J].物探与化探,39(6):1183-1187
谢邦廷,孙彬彬,贺灵,刘占元,叶荣,刘银飞,王腾云.2016.朝不楞多金属矿外围1∶5万地电化学勘查应用[J].地质与勘探,52(5):885-892
熊长林,李惠玲.2003.地电化学提取法机理研究[J].福建地质,22(4):187-194
杨芳芳,卢宗柳,周奇明,陆一敢.2006.电吸附找矿法在捕获常规化探方法难以发现的异常时的有效性[J].矿产与地质,20(4):479-483
张长江.1990.河北蔡家营铅锌(金银)矿床地质特征[J].矿床地质,9(4):301-308
Hu Xue-wen,Zhang Jiang-man,Quan Hen.1996.Isotopic age of Hongqiyingzi Gr in northern Hebei and its time attribution[J].Geological Bulletin of China,(s1):186-192(in Chinese)
Hu Xiao-die,Shen Bao-feng,Mao De-bao,Zhong Chang-ting.2005.On metallogeny of the Caijiaying Pb-Zn deposit[J].Geological Survey and Research,28(4):221-227(in Chinese with English abstract)
Huang Dian-hao,Ding Xiao-shi,Wu Cheng-yu,Zhang Chang-jiang.1991.Mineral characteristics and occurrence of gold,silver and bismuth of the Caijiaying lead-zinc-silver deposit,Hebei Province[J].Acta Geologica Sinica,(2):127-140(in Chinese with English abstract)
Kang Ming,Ceng Kuang,Luo Xian-rong.2006.Applcation of“dipole CHIM”electrified by low voltage dipole[J].Geology and Prospecting,42(4):81-85(in Chinese with English abstract)
Kang Ming,Luo Xian-rong.2003.Improvement and applied results of geoelectrical chemistry methods[J].Geology and Prospecting,39(5):63-66(in Chinese with English abstract)
Li Jiang,Gao Min-hai,Wang Shi-mei,Wang Dian-yun.1989.Electrogeochemical extraction techniques using in exploration for gold[J].Geology and Prospecting,(1):52-54(in Chinese with English abstract)
Li Jin-ming,Lu Jun.1998.Theoretical and experimental study for geoelectrochemical extraction menthod[J].Earth Science Frontiers,5(1):208-216(in Chinese with English abstract)
Liu Zhan-yuan,Liu Ji-min,Cui Ai-min.1997.A discussion on the action conditions of CHIM process[J].Geophysical and Geochemical Exploration21(2),115-122(in Chinese with English abstract)
Liu Zhan-yuan,Zhou Guo-hua.2002.Some new advances method and techniques of CHIM[J].Geology and Prospecting,38(s1):173-177(in Chinese with English abstract)
Luo Xian-rong.1994.Secondary discussion on prospecting buried ore by geoelectrochemical method[J].Journal of Guilin University of Technology,14(3):295-302(in Chinese with English abstract)
Luo Xian-rong.2005.The mechanism of electrogechemical halo-formation and the application of electrogeochemical method to exploration of metallic ore deposits[D].Hefei:Hefei University of Technology:61-71(in Chinese with English abstract)
Mao Ning,Zhou Lin-cheng,Li Yan-feng.2011.Application of polyurethane foam in metal lons monitoring and wastewater treatment[J].Chemistry Bulltein,74(9):797-802(in Chinese with English abstract)
Рысс,Ю·С,Zhang Zhao-yuan,Cui Lin-pei.1986.Geoelectrochemical exploration method[M].Beijing:Geological Publishing House:1-30(in Chinese)
Qiu Yu-min.1988.Experimental study of geoelectrical-chemistry for gold deposits and its effects[J].Gold,(6):22-26(in Chinese with English abstract)
Shen Wu-jun,Bai Chun-dong,Chen Yuan-yuan.2017.Geochemical exploration of concealed deposits in Caijiaying area of Hebei Province[J].Geophysical and Geochemical Exploration,41(2):210-218(in Chinese with English abstract)
Sun Bin-bin,Liu Zhan-yuan,Zhou Guo-hua.2011.The development of the solid carrier elements extractor[J].Geophysical and Geochemical Exploration,35(3):375-378(in Chinese with English abstract)
Sun Bin-bin,Zhang Xue-jun,Liu Zhan-yuan,Zhou Guo-hua,Zhang Bimin,Chen Ya-dong.2015.A preliminary study of the formation mechanism of the geoelectric chemistry anomaly[J].Geophysical and Geochemical Exploration,39(6):1183-1187(in Chinese with English abstract)
Xie Bang-ting,Sun Bin-bin,He Ling,Liu Zhan-yuan,Ye Rong,Liu Yinfei,Wang Teng-yun.2016.Geoelectrochemical Exploration at a scale1∶50 000 in the Periphery of the Chaobuleng polymetallic deposit[J].Geology and Exploration,52(5):885-892(in Chinese with English abstract)
Xiong Chang-lin,Li Hui-ling.2003.On the mechanism of the geoelectric and chemical extraction method[J].Geology of Fujian,22(4):187-194(in Chinese with English abstract)
Yang Fang-fang,Lu Zong-liu,Lu Yi-gan.2006.Efficiency of electric absorption prospecting method in capturing anomalies hard to be found by routine geochemical methods[J].Mineral Resources and Geology,20(4):479-483(in Chinese with English abstract)
Zhang Chang-jiang.1990.Geological characteristics of the Caijiaying lead-zinc(gold-silver)deposit in Hebei Province[J].Mineral Deposits,9(4):301-308(in Chinese with English abstract)
费锡铨.1984.电提取离子法在几个矿区的试验结果[J].物探与化探,8(3):162-166
胡学文,张江满,权桓.1996.冀北红旗营子群同位素年龄及其时代归属[J].地质通报,(s1):186-192
胡小蝶,沈保丰,毛德宝,钟长汀.2005.冀北蔡家营铅锌矿床成因探讨[J].地质调查与研究,28(4):221-227
黄典豪,丁孝石,吴澄宇,张长江.1991.河北蔡家营铅-锌-银矿床矿物特征和金、银、铋赋存状态的研究[J].地质学报,(2):127-140
康明,岑况,罗先熔.2006.低电压偶极子供电方式下的“偶极CHIM”应用效果[J].地质与勘探,42(4):81-85
康明,罗先熔.2003.地电化学方法的改进及应用效果[J].地质与勘探,39(5):63-66
雷斯(Рысс,Ю·С),张肇元,崔霖沛译.1986.地电化学勘探法[M].北京:地质出版社:1-30
李江,高明海.1989.地电化学提取法在找金矿中的应用[J].地质与勘探,(1):52-54
李金铭,卢军.1998.地电化学提取法的理论与实验研究[J].地学前缘,5(1):208-216
刘占元,刘吉敏,崔爱民.1997.电提取过程作用条件问题讨论[J].物探与化探,21(2):115-122
刘占元,周国华.2002.地电化学方法技术改进的思路与进展[J].地质与勘探,38(s1):173-177
罗先熔.1994.再论地球电化学测量法寻找隐伏矿床[J].桂林理工大学学报,14(3):295-302
罗先熔.2005.地电化学成晕机制、方法技术及找矿研究[D].合肥:合肥工业大学:61-71
毛宁,周林成,李彦锋.2011.聚氨酯泡沫材料用于环境中金属离子监测及污染物去除的研究进展[J].化学通报,74(9):797-802
邱玉民.1988.地电化学找金矿的试验研究及其效果[J].黄金,(6):22-26
申伍军,白春东,陈圆圆.2017.冀北蔡家营地区隐伏矿地球化学勘查方法[J].物探与化探,41(2):210-218
孙彬彬,刘占元,周国华.2011.固体载体型元素提取器研制[J].物探与化探,35(3):375-378
孙彬彬,张学君,刘占元,周国华,张必敏,陈亚东.2015.地电化学异常形成机理初探[J].物探与化探,39(6):1183-1187
谢邦廷,孙彬彬,贺灵,刘占元,叶荣,刘银飞,王腾云.2016.朝不楞多金属矿外围1∶5万地电化学勘查应用[J].地质与勘探,52(5):885-892
熊长林,李惠玲.2003.地电化学提取法机理研究[J].福建地质,22(4):187-194
杨芳芳,卢宗柳,周奇明,陆一敢.2006.电吸附找矿法在捕获常规化探方法难以发现的异常时的有效性[J].矿产与地质,20(4):479-483
张长江.1990.河北蔡家营铅锌(金银)矿床地质特征[J].矿床地质,9(4):301-308