CO_2绿色化合成低碳烯烃Fe基催化剂研究进展
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摘要
综述了CO2催化加氢合成低碳烯烃反应的研究进展,具体从总反应机理和Fe基催化剂的副活性组分、助剂、载体及制备超细化等方面进行了系统阐述,并分析各因素与催化活性间的关系。指明当前研究的不足之处,并展望了今后可行的研究方向。
The recent progress of synthesizing light olefins from CO2 hydrogenation is reviewed. The overall reaction mechanism,secondary active components,the promoters,the supporters and novel methods for preparing of Fe-based catalyst,as well as the relationship between these factors and the activity of catalysts are described in detail. The shortcomings in this field yet to be solved are presented. The significant and predictive trends in the future are proposed as well.
The recent progress of synthesizing light olefins from CO2 hydrogenation is reviewed. The overall reaction mechanism,secondary active components,the promoters,the supporters and novel methods for preparing of Fe-based catalyst,as well as the relationship between these factors and the activity of catalysts are described in detail. The shortcomings in this field yet to be solved are presented. The significant and predictive trends in the future are proposed as well.
引文
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[16]任冬梅,周亚松.铁含量对Fe-Mn-K催化剂上CO2加氢反应性能的影响[J].工业催化,2004,12(7):32-35.
[17]刘歆颖,邓国才.铁镍双金属催化剂用于二氧化碳加氢合成低碳烯烃的研究[J].燃料化学学报,1999,27(5):447-450.
[18]Pandey D,Deo G.Promotional effects in alumina and silica supported bimetallic Ni-Fe catalysts during CO2hydrogenation[J].Journal of Molecular Catalysis A:Chemical,2014,382:23-30.
[19]Tang Q,Chen Y,Zhou C J,et al.Statistical modelling and analysis of the aerobic oxidation of benzyl alcohol over K-Mn/C catalysts[J].Catalysis Letters,2009,128(1/2):210-220.
[20]Prasad P S,Bae J W,Jun K-W,et al.Fischer-Tropsch synthesis by carbon dioxide hydrogenation on Fe-based catalysts[J].Catalysis Surveys from Asia,2008,12(3):170-183.
[21]Choi P H,Jun K-W,Lee S-J,et al.Hydrogenation of carbon dioxide over alumina supported Fe-K catalysts[J].Catalysis Letters,1996,40(1/2):115-118.
[22]赵卓.稀土催化材料在环境保护中的应用[M].北京:化学工业出版社,2013:25-47.
[23]邓国才,李梦青.稀土对二氧化碳加氢合成低碳烯烃催化剂活性的影响[J].中国稀土学报,1997,15(3):278-280.
[24]Dorner R W,Hardy D R,Williams F W,et al.C2-C5+olefin production from CO2hydrogenation using ceria modified Fe/Mn/K catalysts[J].Catalysis Communications,2011,15(1):88-92.
[25]Pettigrew D,Trimm D,Cant N.The effects of rare earth oxides on the reverse water-gas shift reaction on palladium/alumina[J].Catalysis Letters,1994,28(2/3/4):313-319.
[26]Nam S S,Kishan G,Lee M W,et al.Effect of lanthanum loading in Fe-K/La-Al2O3catalysts for CO2hydrogenation to hydrocarbons[J].Applied Organometallic Chemistry,2000,14(12):794-798.
[27]郑斌.二氧化碳加氢制烃类铁基催化剂的制备及性能[D].大连:大连理工大学,2012:28-62.
[28]李梦青,邓国才,陈荣悌,等.Fe Co Mn K/Be O催化剂上二氧化碳加氢合成低碳烯烃的反应性能和原位FT-IR研究[J].催化学报,2000,21(1):71-74.
[29]苏春彦,檀建群,王承学.铁基催化剂上二氧化碳加氢合成低碳烯烃的研究[J].天然气化工:C1化学与化工,2013,38(3):34-38.
[30]郑斌,张安峰,刘民,等.纳米铁基催化剂在CO2加氢制烃中的性能[J].物理化学学报,2012,28(8):1943-1950.
[2]Torrente-Murciano L,Mattia D,Jones M D,et al.Formation of hydrocarbons via CO2hydrogenation—A thermodynamic study[J].Journal of CO2Utilization,2014,6:34-39.
[3]王维佳,李金林,罗明生.硅对铁基费-托合成催化剂的影响[J].催化学报,2007,28(10):925-930.
[4]定明月,杨勇,相宏伟,等.费托合成Fe基催化剂中铁物相与活性的关系[J].催化学报,2010,31(9):1145-1150.
[5]Hu B,Frueh S,Garces H F,et al.Selective hydrogenation of CO2and CO to useful light olefins over octahedral molecular sieve manganese oxide supported iron catalysts[J].Applied Catalysis B:Environmental,2013,132:54-61.
[6]Wang J,You Z,Zhang Q,et al.Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts[J].Catalysis Today,2013,215:186-193.
[7]You Z,Deng W,Zhang Q,et al.Hydrogenation of carbon dioxide to light olefins over non-supported iron catalyst[J].Chinese Journal of Catalysis,2013,34(5):956-963.
[8]Ando H,Matsumura Y,Souma Y.A comparative study on hydrogenation of carbon dioxide and carbon monoxide over iron catalyst[J].Journal of Molecular Catalysis A:Chemical,2000,154(1):23-29.
[9]Kummer J,Dewitt T,Emmett P.Some mechanism studies on the Fischer-Tropsch synthesis using C14[J].Journal of the American Chemical Society,1948,70(11):3632-3643.
[10]Smit De E,Cinquini F,Beale A M,et al.Stability and reactivity of∈-χ-θiron carbide catalyst phases in fischer-tropsch synthesis:ControllingμC[J].Journal of the American Chemical Society,2010,132(42):14928-14941.
[11]Saeidi S,Amin N a S,Rahimpour M R.Hydrogenation of CO2to value-added products—A review and potential future developments[J].Journal of CO2Utilization,2014,5:66-81.
[12]李梦青,邓国才.Fe Co K催化剂上二氧化碳加氢合成低碳烯烃的研究[J].河北工业大学学报,2000,29(2):39-43.
[13]Satthawong R,Koizumi N,Song C,et al.Bimetallic Fe-Co catalysts for CO2hydrogenation to higher hydrocarbons[J].Journal of CO2Utilization,2013,3/4:102-106.
[14]Li T,Yang Y,Zhang C,et al.Effect of manganese on an iron-based Fischer-Tropsch synthesis catalyst prepared from ferrous sulfate[J].Fuel,2007,86(7):921-928.
[15]Dorner R W,Hardy D R,Williams F W,et al.K and Mn doped iron-based CO2hydrogenation catalysts:Detection of KAl H4as part of the catalyst's active phase[J].Applied Catalysis A:General,2010,373(1):112-121.
[16]任冬梅,周亚松.铁含量对Fe-Mn-K催化剂上CO2加氢反应性能的影响[J].工业催化,2004,12(7):32-35.
[17]刘歆颖,邓国才.铁镍双金属催化剂用于二氧化碳加氢合成低碳烯烃的研究[J].燃料化学学报,1999,27(5):447-450.
[18]Pandey D,Deo G.Promotional effects in alumina and silica supported bimetallic Ni-Fe catalysts during CO2hydrogenation[J].Journal of Molecular Catalysis A:Chemical,2014,382:23-30.
[19]Tang Q,Chen Y,Zhou C J,et al.Statistical modelling and analysis of the aerobic oxidation of benzyl alcohol over K-Mn/C catalysts[J].Catalysis Letters,2009,128(1/2):210-220.
[20]Prasad P S,Bae J W,Jun K-W,et al.Fischer-Tropsch synthesis by carbon dioxide hydrogenation on Fe-based catalysts[J].Catalysis Surveys from Asia,2008,12(3):170-183.
[21]Choi P H,Jun K-W,Lee S-J,et al.Hydrogenation of carbon dioxide over alumina supported Fe-K catalysts[J].Catalysis Letters,1996,40(1/2):115-118.
[22]赵卓.稀土催化材料在环境保护中的应用[M].北京:化学工业出版社,2013:25-47.
[23]邓国才,李梦青.稀土对二氧化碳加氢合成低碳烯烃催化剂活性的影响[J].中国稀土学报,1997,15(3):278-280.
[24]Dorner R W,Hardy D R,Williams F W,et al.C2-C5+olefin production from CO2hydrogenation using ceria modified Fe/Mn/K catalysts[J].Catalysis Communications,2011,15(1):88-92.
[25]Pettigrew D,Trimm D,Cant N.The effects of rare earth oxides on the reverse water-gas shift reaction on palladium/alumina[J].Catalysis Letters,1994,28(2/3/4):313-319.
[26]Nam S S,Kishan G,Lee M W,et al.Effect of lanthanum loading in Fe-K/La-Al2O3catalysts for CO2hydrogenation to hydrocarbons[J].Applied Organometallic Chemistry,2000,14(12):794-798.
[27]郑斌.二氧化碳加氢制烃类铁基催化剂的制备及性能[D].大连:大连理工大学,2012:28-62.
[28]李梦青,邓国才,陈荣悌,等.Fe Co Mn K/Be O催化剂上二氧化碳加氢合成低碳烯烃的反应性能和原位FT-IR研究[J].催化学报,2000,21(1):71-74.
[29]苏春彦,檀建群,王承学.铁基催化剂上二氧化碳加氢合成低碳烯烃的研究[J].天然气化工:C1化学与化工,2013,38(3):34-38.
[30]郑斌,张安峰,刘民,等.纳米铁基催化剂在CO2加氢制烃中的性能[J].物理化学学报,2012,28(8):1943-1950.
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