FeAl/Al_2O_3复合阻氚涂层制备技术的研究进展
|
摘要
FeAl/Al_2O_3复合膜层是聚变堆氚增殖包层及辅助涉氚系统结构材料首选的阻氚涂层。其制备过程通常需要铝化和氧化2个步骤,铝化是Al原子与基体Fe原子通过相互扩散在基体表面形成铁铝固溶体(Fe,Al)或Fe-Al金属间化合物过渡层;氧化是使铝化涂层表面选择性氧化形成Al_2O_3膜。该阻氚涂层的制备可采用物理气相沉积(PVD)、化学气相沉积(CVD)、热浸铝化(HDA)、包埋渗铝(PC)、等离子体喷涂(PS)和电化学沉积(ECD)等技术。相对而言,CVD、HDA和PC等3种技术有较好的应用前景,有望成为聚变堆中FeAl/Al_2O_3阻氚涂层工程化制备的候选技术而ECD技术因其制备过程容易控制、涂层性能稳定、可涂镀复杂结构件等特点在FeAl/Al_2O_3阻氚涂层制备方面颇具吸引力。
FeAl/Al_2O_3 composite coating is the most promising candidate for the tritium permeation barrier(TPB) of structural materials in the tritium breading blanket and auxiliary tritium handling system in fusion reactors.The preparation process of the FeAl/Al_2O_3 coating generally involves two steps of aluminization and oxidation.Interdiffusion occurs between Al atoms and Fe atoms on the base surface to form(Fe,Al) solid solution or Fe-Al intermetallic transition layer in the aluminization step.In the oxidation step,the aluminide layer surface is selectively oxidized to form Al_2O_3 film.FeAl/Al_2O_3 coating can be prepared by the technique of physical vapor deposition(PVD),chemical vapor deposition(CVD),hot-dipping aluminization(HDA),packing cementation(PC),plasma sputtering(PS) and electro-chemical deposition(ECD) et al.Relatively speaking,CVD,HDA and PC techniques are promising in coating preparation,and have potentials to be selected as the candidate engineering preparation technique of FeAl/Al_2O_3 composite TPB coating in fusion reactors.Meanwhile,ECD technique is rather appealing for the preparation of FeAl/Al_2O_3 TPB coating because of its easy process controlling,stable coat performance and availability of coating complex-shaped structure.
FeAl/Al_2O_3 composite coating is the most promising candidate for the tritium permeation barrier(TPB) of structural materials in the tritium breading blanket and auxiliary tritium handling system in fusion reactors.The preparation process of the FeAl/Al_2O_3 coating generally involves two steps of aluminization and oxidation.Interdiffusion occurs between Al atoms and Fe atoms on the base surface to form(Fe,Al) solid solution or Fe-Al intermetallic transition layer in the aluminization step.In the oxidation step,the aluminide layer surface is selectively oxidized to form Al_2O_3 film.FeAl/Al_2O_3 coating can be prepared by the technique of physical vapor deposition(PVD),chemical vapor deposition(CVD),hot-dipping aluminization(HDA),packing cementation(PC),plasma sputtering(PS) and electro-chemical deposition(ECD) et al.Relatively speaking,CVD,HDA and PC techniques are promising in coating preparation,and have potentials to be selected as the candidate engineering preparation technique of FeAl/Al_2O_3 composite TPB coating in fusion reactors.Meanwhile,ECD technique is rather appealing for the preparation of FeAl/Al_2O_3 TPB coating because of its easy process controlling,stable coat performance and availability of coating complex-shaped structure.
引文
[1]Causey R A,Karnesky R A,Marchi C S.Comprehensive Nucl Mater[J],2012,4:511
[2]Krauss W,Konys J,Holstein N et al.J Nucl Mater[J],2011,417:1233
[3]Zhang G K,Chen C A,Luo D L et al.Fusion Eng Des[J],2012,87:1370
[4]Yang F,Wu P,Yan D et al.Surf Coat Technol[J],2014,238:174
[5]Kumar E R,Danani C,Sandeep I et al.Fusion Eng Des[J],2008,83:1169
[6]Luo D L,Song J F,Huang G Q et al.Fusion Eng Des[J],2012,87:1261
[7]Wong C P C,Salavy J F,Kim Y et al.Fusion Eng Des[J],2008,83:850
[8]Chang Hua(常华),Tao Jie(陶杰),Luo Xinyi(骆心怡)et al.Mater Mecha Eng(机械工程材料)[J],2007,31:1
[9]Zhang G K,Wang X L,Yang F L et al.Int J Hydrogen Energy[J],2013,38:5557
[10]Zhang G K,Wang X L,Xiong YFet al.Int J Hydrogen Energy[J],2013,38:1157
[11]Zhang G K,Dou S P,Lu Y J et al.Int J Hydrogen Energy[J],2014,39:610
[12]Zywitzki O,Hoetzsch G.Surf Coat Technol[J],1997,94-95:303
[13]Serra E,Kelly P J,Ross DK et al.J Nucl Mater[J],1998,257:194
[14]Hao Jiakun(郝嘉琨),Shan Changqi(山常起),Jin Zhujing(金柱京)et al.Nucl Fusion Plasma Phys(核聚变与等离子体物理)[J],1996,16:62
[15]Liu H B,Tao J,Xu J et al.Appl Surf Sci[J],2010,256:5939
[16]Yin Lei(尹磊).Thesis for Masterate(硕士论文)[D].Nanjing:Nanjing University of Aeronautics and Astronautics,2011
[17]Zhang Guikai(张桂凯),Li Ju(李炬),Chen Chang'an(陈长安)et al.Mater Mecha Eng(机械工程材料)[J],2010,34:5
[18]Ruppi S,Larsson A.Int J Refract Met Hard Mater[J],2005,23:306
[19]Natali M,Carta G,Rigato V et al.Electrochimica Acta[J],2005,50:4615
[20]Li S,He D,Liu X P et al.J Nucl Mater[J],2012,420:405
[21]Leal J,Alcala G,Bolivar F J et al.Corro Sci[J],2008,50:1833
[22]Sanchez L,Bolivar F J,Hierro M P et al.Surf Coat Technol[J],2007,201:7626
[23]Glasbrenner H,Wedemeyer O.J Nucl Mater[J],1998,257:274
[24]Yao Z Y,Chini M,Aiello A et al.Acta Metallurgica Sinica[J],2001,14:435
[25]Glasbrenner H,Nold E,Voss Z.J Nucl Mater[J],1997,249:39
[26]Konys J,Aiello A,Benamati G et al.Fusion Sci Technol[J],2005,47:844
[27]Glasbrenner H,Stein-Fechner K,Konys J.J Nucl Mater[J],2000,283-287:1302
[28]Zhang W,Fan Z K,Hu P F et al.J Iron Steel Research Int[J],2006,13:60
[29]Forcey K S,Ross D K.J Nucl Mater[J],1991,182:36
[30]Zhan Qin(占勤),Yang Hongguang(杨洪广),Zhao Weiwei(赵崴巍)et al.Trans Mater Heat Treat(材料热处理学报)[J],2008,29:158
[31]Yang H G,Zhan Q,Zhao W W.J Nucl Mater[J],2011,417:1237
[32]Nickel H,Koizlik K.Thin Solid Films[J],1983,18:401
[33]Fazio C,Stein-Fechner K,Serra E.J Nucl Mater[J],1999,273:233
[34]Guo Z H,Huang Q Y,Yan Z L et al.Fusion Eng Des[J],2010,85:1469
[35]Yan Z L,Huang Q Y,Guo Z H et al.Fusion Eng Des[J],2010,85:1542
[36]Tian L H,Li C X,Yang G J et al.Rare Met Mater Eng[J],2012,41(S1):467
[37]Konys J,Krauss W,Holstein N.Fusion Eng Des[J],2010,85:2141
[38]Liu Q X,Zein El Abedin S,Endres F.Surf Coat Technol[J],2006,201:1352
[39]Zhang G K,Li J,Chen C A et al.J Nucl Mater[J],2011,417:1245
[40]Uekia Y,Kunugia T,Morleyb N B et al.Fusion Eng Des[J],2010,85:1824
[41]Wang T S,Pu J,Bo C et al.Fusion Eng Des[J],2010,85:1068
[42]Zhang D X,Kondo M,Tanaka T et al.Fusion Eng Des[J],2011,86:2508
[43]Tanaka T,Muroga T.Fusion Eng Des[J],2013,88:2569
[44]Kuisartov T V,Hayashi K,Nakamichi M et al.Fusion Eng Des[J],2006,81:701
[45]Yao Zhenyu(姚振宇),Chini M,Aiello A et al.Nuclear Science and Engineering(核科学与工程)[J],2003,22:36
[46]Luis A,Sedano C R,Michael A.J Nucl Mater[J],1996,233:1411
[47]Liu Xinyue(刘歆粤).Thesis for Master Degree(硕士论文)[D].Harbin:Harbin Engineering University,2006
[48]Glasbrenner H,Stein-Fechner K,Konys J.Fusion Eng Des[J],2000,51-52:105
[49]Hollenberg G W.Fusion Eng Des[J],1995,28:190
[50]Levchuk D,Koch F,Maier H et al.J Nucl Mater[J],2004,328:103
[51]Han S,Li H,Wang S et al.Int J Hydrogen Energy[J],2010,35:2689
[52]Cheng W J,Wang C J.Surf Coat Technol[J],2011,205:4726
[2]Krauss W,Konys J,Holstein N et al.J Nucl Mater[J],2011,417:1233
[3]Zhang G K,Chen C A,Luo D L et al.Fusion Eng Des[J],2012,87:1370
[4]Yang F,Wu P,Yan D et al.Surf Coat Technol[J],2014,238:174
[5]Kumar E R,Danani C,Sandeep I et al.Fusion Eng Des[J],2008,83:1169
[6]Luo D L,Song J F,Huang G Q et al.Fusion Eng Des[J],2012,87:1261
[7]Wong C P C,Salavy J F,Kim Y et al.Fusion Eng Des[J],2008,83:850
[8]Chang Hua(常华),Tao Jie(陶杰),Luo Xinyi(骆心怡)et al.Mater Mecha Eng(机械工程材料)[J],2007,31:1
[9]Zhang G K,Wang X L,Yang F L et al.Int J Hydrogen Energy[J],2013,38:5557
[10]Zhang G K,Wang X L,Xiong YFet al.Int J Hydrogen Energy[J],2013,38:1157
[11]Zhang G K,Dou S P,Lu Y J et al.Int J Hydrogen Energy[J],2014,39:610
[12]Zywitzki O,Hoetzsch G.Surf Coat Technol[J],1997,94-95:303
[13]Serra E,Kelly P J,Ross DK et al.J Nucl Mater[J],1998,257:194
[14]Hao Jiakun(郝嘉琨),Shan Changqi(山常起),Jin Zhujing(金柱京)et al.Nucl Fusion Plasma Phys(核聚变与等离子体物理)[J],1996,16:62
[15]Liu H B,Tao J,Xu J et al.Appl Surf Sci[J],2010,256:5939
[16]Yin Lei(尹磊).Thesis for Masterate(硕士论文)[D].Nanjing:Nanjing University of Aeronautics and Astronautics,2011
[17]Zhang Guikai(张桂凯),Li Ju(李炬),Chen Chang'an(陈长安)et al.Mater Mecha Eng(机械工程材料)[J],2010,34:5
[18]Ruppi S,Larsson A.Int J Refract Met Hard Mater[J],2005,23:306
[19]Natali M,Carta G,Rigato V et al.Electrochimica Acta[J],2005,50:4615
[20]Li S,He D,Liu X P et al.J Nucl Mater[J],2012,420:405
[21]Leal J,Alcala G,Bolivar F J et al.Corro Sci[J],2008,50:1833
[22]Sanchez L,Bolivar F J,Hierro M P et al.Surf Coat Technol[J],2007,201:7626
[23]Glasbrenner H,Wedemeyer O.J Nucl Mater[J],1998,257:274
[24]Yao Z Y,Chini M,Aiello A et al.Acta Metallurgica Sinica[J],2001,14:435
[25]Glasbrenner H,Nold E,Voss Z.J Nucl Mater[J],1997,249:39
[26]Konys J,Aiello A,Benamati G et al.Fusion Sci Technol[J],2005,47:844
[27]Glasbrenner H,Stein-Fechner K,Konys J.J Nucl Mater[J],2000,283-287:1302
[28]Zhang W,Fan Z K,Hu P F et al.J Iron Steel Research Int[J],2006,13:60
[29]Forcey K S,Ross D K.J Nucl Mater[J],1991,182:36
[30]Zhan Qin(占勤),Yang Hongguang(杨洪广),Zhao Weiwei(赵崴巍)et al.Trans Mater Heat Treat(材料热处理学报)[J],2008,29:158
[31]Yang H G,Zhan Q,Zhao W W.J Nucl Mater[J],2011,417:1237
[32]Nickel H,Koizlik K.Thin Solid Films[J],1983,18:401
[33]Fazio C,Stein-Fechner K,Serra E.J Nucl Mater[J],1999,273:233
[34]Guo Z H,Huang Q Y,Yan Z L et al.Fusion Eng Des[J],2010,85:1469
[35]Yan Z L,Huang Q Y,Guo Z H et al.Fusion Eng Des[J],2010,85:1542
[36]Tian L H,Li C X,Yang G J et al.Rare Met Mater Eng[J],2012,41(S1):467
[37]Konys J,Krauss W,Holstein N.Fusion Eng Des[J],2010,85:2141
[38]Liu Q X,Zein El Abedin S,Endres F.Surf Coat Technol[J],2006,201:1352
[39]Zhang G K,Li J,Chen C A et al.J Nucl Mater[J],2011,417:1245
[40]Uekia Y,Kunugia T,Morleyb N B et al.Fusion Eng Des[J],2010,85:1824
[41]Wang T S,Pu J,Bo C et al.Fusion Eng Des[J],2010,85:1068
[42]Zhang D X,Kondo M,Tanaka T et al.Fusion Eng Des[J],2011,86:2508
[43]Tanaka T,Muroga T.Fusion Eng Des[J],2013,88:2569
[44]Kuisartov T V,Hayashi K,Nakamichi M et al.Fusion Eng Des[J],2006,81:701
[45]Yao Zhenyu(姚振宇),Chini M,Aiello A et al.Nuclear Science and Engineering(核科学与工程)[J],2003,22:36
[46]Luis A,Sedano C R,Michael A.J Nucl Mater[J],1996,233:1411
[47]Liu Xinyue(刘歆粤).Thesis for Master Degree(硕士论文)[D].Harbin:Harbin Engineering University,2006
[48]Glasbrenner H,Stein-Fechner K,Konys J.Fusion Eng Des[J],2000,51-52:105
[49]Hollenberg G W.Fusion Eng Des[J],1995,28:190
[50]Levchuk D,Koch F,Maier H et al.J Nucl Mater[J],2004,328:103
[51]Han S,Li H,Wang S et al.Int J Hydrogen Energy[J],2010,35:2689
[52]Cheng W J,Wang C J.Surf Coat Technol[J],2011,205:4726