幔源岩浆氧化还原状态及对岩浆矿床成矿的制约
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摘要
岩浆的氧化还原状态是控制许多基本地质过程的关键热动力学参数之一。估算玄武质岩浆和源区岩石氧化还原状态的常用方法主要包括多价元素的价态、多价元素的分配系数、共存矿物对的化学平衡和全岩化学比值。岩石学实验的深入和分析技术手段的快速发展使精确估算岩浆氧逸度成为可能。这有力地促进了对地幔源区成分、岩浆的部分熔融程度和熔融方式与分异演化历史,以及岩浆矿床的成因机制及成矿过程的研究。幔源岩浆的氧化还原状态复杂多变,不仅与构造背景有关,还与地幔深度(压力)、交代作用和部分熔融有着密切联系。而在岩浆到达浅部地壳后,结晶分异、岩浆去气和同化混染等过程也能不同程度地改变岩浆的氧逸度。因此,即使来自同一构造背景的幔源岩浆也呈现出明显的氧逸度不均一性。氧逸度的高低对源区部分熔融过程中金属元素的地球化学行为、岩浆的分异演化趋势、Fe-Ti-V氧化物饱和时间的早晚和S在岩浆中的溶解度具有明显的控制作用。因此,岩浆的氧逸度对钒钛磁铁矿矿床和汇聚板块边缘的岩浆硫化物矿床的成矿过程具有显著的影响。
The redox state of mantle-derived basaltic magma is one of the key thermodynamic parameters controlling many basic geological processes. Methods commonly used to estimate redox state of basaltic magmas and its source rocks include valence state of multivalent elements,partition coefficient of multivalent elements,chemical equilibrium of coexisting mineral pairs and whole-rock chemical ratios. With the rapid development of petrological experiments and the advances in analytical techniques,it is possible to accurately estimate the oxygen fugacity of mantle-derived basaltic magma and source rocks. This has greatly promoted the studies on composition of mantle source,evolutional history of partial melting,differentiation of mantle-derived basaltic magma,genesis of magmatic deposits,and metallogenic processes. The variable redox state of the mantle-derived magma is not only related to the tectonic settings,but also closely related to the mantle depth( pressure),metasomatism,and partial melting. Fractional crystallization,degassing and contamination of the magma can also change the oxygen fugacity of the magma in variable degrees at the shallow crust.Therefore,the mantle-derived magma exhibits variable oxygen fugacity even from the same geodynamic background. The oxygen fugacity of mantle-derived magma exerts critical controls on geochemical behavior of metals( e. g.,PGE,Au,Cu) during partial melting of the source region,magma differentiation trends,relative saturation time of Fe-Ti-V oxide and its V content,and sulfur solubility in the magma. Thus,the ore-forming processes of Fe-Ti-V oxide deposits and Ni-Cu-( PGE) sulfide deposits are significantly influenced by the oxygen fugacity of magma.
The redox state of mantle-derived basaltic magma is one of the key thermodynamic parameters controlling many basic geological processes. Methods commonly used to estimate redox state of basaltic magmas and its source rocks include valence state of multivalent elements,partition coefficient of multivalent elements,chemical equilibrium of coexisting mineral pairs and whole-rock chemical ratios. With the rapid development of petrological experiments and the advances in analytical techniques,it is possible to accurately estimate the oxygen fugacity of mantle-derived basaltic magma and source rocks. This has greatly promoted the studies on composition of mantle source,evolutional history of partial melting,differentiation of mantle-derived basaltic magma,genesis of magmatic deposits,and metallogenic processes. The variable redox state of the mantle-derived magma is not only related to the tectonic settings,but also closely related to the mantle depth( pressure),metasomatism,and partial melting. Fractional crystallization,degassing and contamination of the magma can also change the oxygen fugacity of the magma in variable degrees at the shallow crust.Therefore,the mantle-derived magma exhibits variable oxygen fugacity even from the same geodynamic background. The oxygen fugacity of mantle-derived magma exerts critical controls on geochemical behavior of metals( e. g.,PGE,Au,Cu) during partial melting of the source region,magma differentiation trends,relative saturation time of Fe-Ti-V oxide and its V content,and sulfur solubility in the magma. Thus,the ore-forming processes of Fe-Ti-V oxide deposits and Ni-Cu-( PGE) sulfide deposits are significantly influenced by the oxygen fugacity of magma.
引文
Alderman OLG,Wilding MC,Tamalonis A,Sendelbach S,Heald SM,Benmore CJ,Johnson CE,Johnson JA,Hah HY and Weber JKR.2017.Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses.Chemical Geology,453:169-185
Arndt NT,Czamanske GK,Walker RJ,Chauvel C and Fedorenko VA.2003.Geochemistry and origin of the intrusive hosts of the Noril’skTalnakh Cu-Ni-PGE sulfide deposits.Economic Geology,98(3):495-515
Arndt NT,Lesher CM and Czamanske GK.2005.Mantle-derived magmas and magmatic Ni-Cu-(PGE)deposits.In:Hedenquist JW,Thompson JFH,Goldfarb RJ and Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,5-23
Balan E,De Villiers JPR,Eeckhout SG,Glatzel P,Toplis MJ,Fritsch E,Allard T,Galoisy L and Calas G.2006.The oxidation state of vanadium in titanomagnetite from layered basic intrusions.American Mineralogist,91(5-6):953-956
Ballhaus C,Berry RF and Green DH.1990.Oxygen fugacity controls in the Earth’s upper mantle.Nature,348(6300):437-440
Ballhaus C,Berry RF and Green DH.1991.High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer:Implications for the oxidation state of the upper mantle.Contributions to Mineralogy and Petrology,107(1):27-40
Ballhaus C.1993.Redox states of lithospheric and asthenospheric upper mantle.Contributions to Mineralogy and Petrology,114(3):331-348
Barnes SJ and Lightfoot PC.2005.Formation of magmatic nickel-sulfide ore deposits and processes affecting their copper and platinum-group element contents.In:Hedenquist JW,Thompson JFH,Goldfarb RJand Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,179-214
Berry AJ,Stewart GA,O’Neill HSC,Mallmann G and Mosselmans JFW.2018.A re-assessment of the oxidation state of iron in MORBglasses.Earth and Planetary Science Letters,483:114-123
Bézos A and Humler E.2005.The Fe3+/∑Fe ratios of MORB glasses and their implications for mantle melting.Geochimica et Cosmochimica Acta,69(3):711-725
Bowen NL.1928.The Evolution of the Igneous Rocks.Princeton:Princeton University Press
Brandon AD and Draper DS.1996.Constraints on the origin of the oxidation state of mantle overlying subduction zones:An example from Simcoe,Washington,USA.Geochimica et Cosmochimica Acta,60(10):1739-1749
Brounce M,Stolper E and Eiler J.2017.Redox variations in Mauna Kea lavas,the oxygen fugacity of the Hawaiian plume,and the role of volcanic gases in Earth’s oxygenation.Proceedings of the National Academy of Sciences of the United States of America,114(34):8997-9002
Brounce MN,Kelley KA and Cottrell E.2014.Variations in Fe3+/∑Fe of mariana arc basalts and mantle wedge fO2.Journal of Petrology,55(12):2513-2536
Buddington AF and Lindsley DH.1964.Iron-titanium oxide minerals and synthetic equivalents.Journal of Petrology,5(2):310-357
Canil D.1997.Vanadium partitioning and the oxidation state of Archaean komatiite magmas.Nature,389(6653):842-845
Canil D.1999.Vanadium partitioning between orthopyroxene,spinel and silicate melt and the redox states of mantle source regions for primary magmas.Geochimica et Cosmochimica Acta,63(3-4):557-572
Carmichael ISE and Ghiorso MS.1986.Oxidation-reduction relations in basic magma:A case for homogeneous equilibria.Earth and Planetary Science Letters,78(2-3):200-210
Carmichael ISE.1991.The redox states of basic and silicic magmas:Areflection of their source regions?Contributions to Mineralogy and Petrology,106(2):129-141
Cawthorn RG,Barnes SJ,Ballhaus C and Malitch K.2005.Platinum group element,chromium,and vanadium deposits in mafic and ultramafic rocks.In:Hedenquist JW,Thompson JFH,Goldfarb RJand Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,215-249
Cottrell E,Kelley KA,Lanzirotti A and Fischer RA.2009.Highprecision determination of iron oxidation state in silicate glasses using XANES.Chemical Geology,268(3-4):167-179
Cottrell E and Kelley KA.2011.The oxidation state of Fe in MORBglasses and the oxygen fugacity of the upper mantle.Earth and Planetary Science Letters,305(3-4):270-282
Crabtree SM and Lange RA.2012.An evaluation of the effect of degassing on the oxidation state of hydrous andesite and dacite magmas:A comparison of pre-and post-eruptive Fe2+concentrations.Contributions to Mineralogy and Petrology,163(2):209-224
Creighton S,Stachel T,Matveev S,H9fer H,Mc Cammon C and Luth RW.2008.Oxidation of the Kaapvaal lithospheric mantle driven by metasomatism.Contributions to Mineralogy and Petrology,157(4):491-504
de Hoog JCM,Mason PRD and van Bergen MJ.2001.Sulfur and chalcophile elements in subduction zones:Constraints from a laser ablation ICP-MS study of melt inclusions from Galunggung Volcano,Indonesia.Geochimica et Cosmochimica Acta,65(18):3147-3164
Dixon JE,Clague DA,Wallace P and Poreda R.1997.Volatiles in alkalic basalts form the North arch volcanic field,Hawaii:Extensive degassing of deep submarine-erupted alkalic series lavas.Journal of Petrology,38(7):911-939
Evans KA,Elburg MA and Kamenetsky VS.2012.Oxidation state of subarc mantle.Geology,40(9):783-786
Fenner CN.1929.The crystallization of basalts.American Journal of Science,18(105):225-253
Foley SF.2011.A reappraisal of redox melting in the earth’s mantle as a function of tectonic setting and time.Journal of Petrology,52(7-8):1363-1391
Frost BR,Lindsley DH and Andersen DJ.1988.Fe-Ti oxide-silicate equilibrium:Assemblages with fayalitic olivine.American Mineralogist,73(7-8):727-740
Frost BR and Lindsley DH.1992.Equilibria among Fe-Ti oxides,pyroxenes,olivine,and quartz:PartⅡ.Application.American Mineralogist,77(9-10):1004-1020
Gaetani GA and Grove TL.1997.Partitioning of moderately siderophile elements among olivine,silicate melt,and sulfide melt:Constraints on core formation in the Earth and Mars.Geochimica et Cosmochimica Acta,61(9):1829-1846
Gaetani GA.2016.The behavior of Fe3+/∑Fe during partial melting of spinel lherzolite.Geochimica et Cosmochimica Acta,185:64-77
Gaillard F,Scaillet B,Pichavant M and Iacono-Marziano G.2015.The redox geodynamics linking basalts and their mantle sources through space and time.Chemical Geology,418:217-233
Ganino C,Arndt NT,Zhou MF,Gaillard F and Chauvel C.2008.Interaction of magma with sedimentary wall rock and magnetite ore genesis in the Panzhihua mafic intrusion,SW China.Mineralium Deposita,43(6):677-694
Ganino C,Harris C,Arndt NT,Prevec SA and Howarth GH.2013.Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit(SW China):Evidence from stable isotopes.Geoscience Frontiers,4(5):547-554
Ghiorso MS and Sack O.1991.Fe-Ti oxide geothermometry:Thermodynamic formulation and the estimation of intensive variables in silicic magmas.Contributions to Mineralogy and Petrology,108(4):485-510
Goncharov AG,Ionov DA,Doucet LS and Pokhilenko LN.2012.Thermal state,oxygen fugacity and C-O-H fluid speciation in cratonic lithospheric mantle:New data on peridotite xenoliths from the Udachnaya kimberlite,Siberia.Earth and Planetary Science Letters,357-358:99-110
Grocke SB,Cottrell E,de Silva S and Kelley KA.2016.The role of crustal and eruptive processes versus source variations in controlling the oxidation state of iron in Central Andean magmas.Earth and Planetary Science Letters,440:92-104
Hao HD,Campbell IH,Park JW and Cooke DR.2017.Platinum-group element geochemistry used to determine Cu and Au fertility in the Northparkes igneous suites,New South Wales,Australia.Geochimica et Cosmochimica Acta,216:372-392
Head E,Lanzirotti A,Newville M and Sutton S.2018.Vanadium,sulfur,and iron valences in melt inclusions as a window into magmatic processes:A case study at Nyamuragira volcano,Africa.Geochimica et Cosmochimica Acta,226:149-173
Iacono-Marziano G,Gaillard F,Scaillet B,Polozov AG,Marecal V,Pirre M and Arndt NT.2012.Extremely reducing conditions reached during basaltic intrusion in organic matter-bearing sediments.Earth and Planetary Science Letters,357-358:319-326
Jayasuriya KD,O’Neill HSC,Berry AJ and Campbell SJ.2004.AM9ssbauer study of the oxidation state of Fe in silicate melts.American Mineralogist,89(11-12):1597-1609
Jugo PJ.2009.Sulfur content at sulfide saturation in oxidized magmas.Geology,37(5):415-418
Jugo PJ,Wilke M and Botcharnikov RE.2010.Sulfur K-edge XANESanalysis of natural and synthetic basaltic glasses:Implications for Sspeciation and S content as function of oxygen fugacity.Geochimica et Cosmochimica Acta,74(20):5926-5938
Karner JM,Papike JJ,Shearer CK,Mckay G,Le L and Burger P.2007.Valence state partitioning of Cr and V between pyroxene-melt:Estimates of oxygen fugacity for martian basalt QUE 94201.American Mineralogist,92(7):1238-1241
Karner JM,Papike JJ,Sutton SR,Shearer CK,Burger P,Mc Kay G and Le L.2008.Valence state partitioning of V between pyroxene-melt:Effects of pyroxene and melt composition,and direct determination of V valence states by XANES.Application to Martian basalt QUE94201 composition.Meteoritics&Planetary Science,43(8):1275-1285
Keays RR.1995.The role of komatiitic and picritic magmatism and S-saturation in the formation of ore deposits.Lithos,34(1-3):1-18
Kelley KA and Cottrell E.2012.The influence of magmatic differentiation on the oxidation state of Fe in a basaltic arc magma.Earth and Planetary Science Letters,329-330:109-121
Kress VC and Carmichael ISE.1991.The compressibility of silicate liquids containing Fe2O3and the effect of composition,temperature,oxygen fugacity and pressure on their redox states.Contributions to Mineralogy and Petrology,108(1-2):82-92
Lai SC and Zhou TZ.1993.Study on the oxygen fugacity of magmas and its advance.Qinghai Geology,2(2):64-69(in Chinese with English abstract)
Lanzirotti A,Dyar MD,Sutton S,Newville M,Head E,Carey CJ,Mc Canta M,Lee L,King PL and Jones J.2018.Accurate predictions of microscale oxygen barometry in basaltic glasses using VK-edge X-ray absorption spectroscopy:A multivariate approach.American Mineralogist 103(8):1282-1297.
Laubier M,Grove TL and Langmuir CH.2014.Trace element mineral/melt partitioning for basaltic and basaltic andesitic melts:An experimental and laser ICP-MS study with application to the oxidation state of mantle source regions.Earth and Planetary Science Letters,392:265-278
Lazarov M,Woodland AB and Brey GP.2009.Thermal state and redox conditions of the Kaapvaal mantle:A study of xenoliths from the Finsch mine,South Africa.Lithos,112(Suppl.2):913-923
Lee CA.1996.A review of mineralization in the bushveld complex and some other layered intrusions.In:Cawthorn RG(ed.).Layered Intrusions.Amsterdam:Elsevier,103-145
Lee CTA,Leeman WP,Canil D and Li ZXA.2005.Similar V/Sc systematics in MORB and arc basalts:Implications for the oxygen fugacities of their mantle source regions.Journal of Petrology,46(11):2313-2336
Lee CTA,Luffi P,Le Roux V,Dasgupta R,Albaréde F and Leeman WP.2010.The redox state of arc mantle using Zn/Fe systematics.Nature,468(7324):681-685
Lee CTA,Luffi P,Chin EJ,Bouchet R,Dasgupta R,Morton DM,Le Roux V,Yin QZ and Jin D.2012.Copper systematics in arc magmas and implications for crust-mantle differentiation.Science,336(6077):64-68
Li C and Ripley EM.2011.The giant Jinchuan Ni-Cu-(PGE)deposit:Tectonic setting,magma evolution,ore genesis,and exploration implications.In:Li C and Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry,and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,163-180
Li ZXA and Lee CTA.2004.The constancy of upper mantle fO2through time inferred from V/Sc ratios in basalts.Earth and Planetary Science Letters,228(3-4):483-493
Lindsley DH and Frost BR.1992.“Equilibria among Fe-Ti oxides,pyroxenes,olivine,and quartz;PartⅠ,Theory.”American Mineralogist 77(9-10):987-1003
Liu CQ,Li HP,Huang ZL and Su GL.2001.A review of studies on oxygen fugacity of the earth mantle.Earth Science Frontiers,8(3):73-82(in Chinese with English abstract)
Mallmann G and O’Neill HSC.2009.The crystal/melt partitioning of Vduring mantle melting as a function of oxygen fugacity compared with some other elements(Al,P,Ca,Sc,Ti,Cr,Fe,Ga,Y,Zr and Nb).Journal of Petrology,50(9):1765-1794
Mallmann G and O’Neill HSC.2013.Calibration of an empirical thermometer and oxybarometer based on the partitioning of Sc,Y and V between olivine and silicate melt.Journal of Petrology,54(5):933-949
Marks MAW,Scharrer M,Ladenburger S and Markl G.2016.“Comment on“Apatite:A new redox proxy for silicic magmas?”[Geochimica et Cosmochimica Acta 132(2014)101-119].”Geochimica et Cosmochimica Acta 183:267-270
Matjuschkin V,Blundy JD and Brooker RA.2016.The effect of pressure on sulphur speciation in mid-to deep-crustal arc magmas and implications for the formation of porphyry copper deposits.Contributions to Mineralogy and Petrology,171(7):66
Mc Cammon C and Kopylova MG.2004.A redox profile of the Slave mantle and oxygen fugacity control in the cratonic mantle.Contributions to Mineralogy and Petrology,148(1):55-68
Mc Cammon CA,Griffin WL,Shee SR and O’Neill HSC.2001.Oxidation during metasomatism in ultramafic xenoliths from the Wesselton kimberlite,South Africa:Implications for the survival of diamond.Contributions to Mineralogy and Petrology,141(3):287-296
Miles AJ,Graham CM,Hawkesworth CJ,Gillespie MR,Hinton RW and Bromiley GD.2014.Apatite:A new redox proxy for silicic magmas?Geochimica et Cosmochimica Acta,132:101-119
Molyneux TG.1974.A geological investigation of the Bushveld Complex in Sekhukhuneland and part of the Steelpoort Valley.South African Journal of Geology,77(3):329-338
Morse SA.1981.Kiglapait geochemistryⅣ:The major elements.Geochimica et Cosmochimica Acta,45(3):461-479
Morse SA.2015.Kiglapait intrusion,labrador.In:Charlier B,Namur O,Latypov R and Tegner C(eds.).Layered Intrusions.Dordrecht:Springer,589-648
Moussallam Y,Oppenheimer C,Scaillet B,Gaillard F,Kyle P,Peters N,Hartley M,Berlo K and Donovan A.2014.Tracking the changing oxidation state of Erebus magmas,from mantle to surface,driven by magma ascent and degassing.Earth and Planetary Science Letters,393:200-209
Moussallam Y,Edmonds M,Scaillet B,Peters N,Gennaro E,Sides Iand Oppenheimer C.2016.The impact of degassing on the oxidation state of basaltic magmas:A case study of Kīlauea volcano.Earth and Planetary Science Letters,450:317-325
Mungall JE,Hanley JJ,Arndt NT and Debecdelievre A.2006.Evidence from meimechites and other low-degree mantle melts for redox controls on mantle-crust fractionation of platinum-group elements.Proceedings of the National Academy of Sciences of the United States of America,103(34):12695-12700
Naldrett AJ.2011.Fundamentals of magmatic sulfide deposits.In:Li Cand Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,1-50
Naslund HR.1983.The effect of oxygen fugacity on liquid immiscibility in iron-bearing silicate melts.American Journal of Science,283(10):1034-1059
O’Neill HSC,Berry AJ,Mc Cammon CC,Jayasuriya KD,Campbell SJand Foran G.2006.An experimental determination of the effect of pressure on the Fe3+/∑Fe ratio of an anhydrous silicate melt to 3.0GPa.American Mineralogist,91(2-3):404-412
O’Neill HSC and Wall VJ.1987.The olivine-orthopyroxene-spinel oxygen geobarometer,the nickel precipitation curve,and the oxygen fugacity of the Earth’s upper mantle.Journal of Petrology,28(6):1169-1191
Palme H and O’Neill HSC.2014.Cosmochemical estimates of mantle composition.In:Holland HD and Turekian KK(ed.).Treatise on Geochemistry.2ndEdition.Amsterdam:Elsevier,1-39
Pang KN,Zhou MF,Lindsley D,Zhao DG and Malpas J.2008.Origin of Fe-Ti oxide ores in mafic intrusions:Evidence from the panzhihua intrusion,SW China.Journal of Petrology,49(2):295-313
Papike JJ,Burger PV,Bell AS,Le L,Shearer CK,Sutton SR,Jones Jand Newville M.2013.Developing vanadium valence state oxybarometers(spinel-melt,olivine-melt,spinel-olivine)and V/(Cr+Al)partitioning(spinel-melt)for martian olivine-phyric basalts.American Mineralogist,98(11-12):2193-2196
Papike JJ,Simon SB,Burger PV,Bell AS,Shearer CK and Karner JM.2016.Chromium,vanadium,and titanium valence systematics in Solar System pyroxene as a recorder of oxygen fugacity,planetary provenance,and processes.American Mineralogist,101(4):907-918
Park JW,Campbell IH,Kim J and Moon JW.2015.The role of late sulfide saturation in the formation of a Cu-and Au-rich Magma:Insights from the platinum group element geochemistry of NiuatahiMotutahi Lavas,Tonga Rear Arc.Journal of Petrology,56(1):59-81
Philpotts AR and Doyle CD.1983.Effect of magma oxidation state on the extent of silicate liquid immiscibility in a tholeiitic basalt.American Journal of Science,283(9):967-986
Putirka KD.2008.Thermometers and barometers for volcanic systems.Reviews in Mineralogy and Geochemistry,69(1):61-120
Putirka K.2016.Rates and styles of planetary cooling on Earth,Moon,Mars,and Vesta,using new models for oxygen fugacity,ferricferrous ratios,olivine-liquid Fe-Mg exchange,and mantle potential temperature.American Mineralogist,101(4):819-840
Righter K,Sutton SR,Newville M,Le L,Schwandt CS,Uchida H,Lavina B and Downs RT.2006.An experimental study of the oxidation state of vanadium in spinel and basaltic melt with implications for the origin of planetary basalt.American Mineralogist,91(10):1643-1656
Ripley EM and Li C.2011.A review of conduit-related Ni-Cu-(PGE)sulfide mineralization at the Voiseys Bay Deposit,Labrador,and the Eagle Deposit,northern Michigan.In:Li C and Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry,and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,181-197
Rowe MC,Kent AJR and Nielsen RL.2009.Subduction influence on oxygen fugacity and trace and volatile elements in basalts across the cascade volcanic arc.Journal of Petrology,50(1):61-91
Shishkina T,Portnyagin M,Botcharnikov R,Almeev R,Simonyan A,Garbe-Sch9nberg D,Schuth S,Oeser M and Holtz F.2018.Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas.American Mineralogist,103(3):369-383
Sisson TW.2003.Native gold in a Hawaiian alkalic magma.Economic Geology,98(3):643-648
Smythe DJ and Brenan JM.2016.Magmatic oxygen fugacity estimated using zircon-melt partitioning of cerium.Earth and Planetary Science Letters,453:260-266
Song XY,Qi HW,Hu RZ,Chen LM,Yu SY and Zhang JF.2013.Formation of thick stratiform Fe-Ti oxide layers in layered intrusion and frequent replenishment of fractionated mafic magma:Evidence from the Panzhihua intrusion,SW China.Geochemistry,Geophysics,Geosystems,14(3):712-732
Song XY,Yi JN,Chen LM,She YW,Liu CZ,Dang XY,Yang QA and Wu SK.2016.The giant Xiarihamu Ni-Co sulfide deposit in the East Kunlun orogenic belt,Northern Tibet Plateau,China.Economic Geology,111(1):29-55
Sun WD,Arculus RJ,Kamenetsky VS and Binns RA.2004.Release of gold-bearing fluids in convergent margin magmas prompted by magnetite crystallization.Nature,431(7011):975-978
Sutton SR,Karner J,Papike J,Delaney JS,Shearer C,Newville M,Eng P,Rivers M and Dyar MD.2005.Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry.Geochimica et Cosmochimica Acta,69(9):2333-2348
Tegner C and Cawthorn RG.2010.Iron in plagioclase in the Bushveld and Skaergaard intrusions:Implications for iron contents in evolving basic magmas.Contributions to Mineralogy and Petrology,159(5):719-730
Thakurta J,Ripley EM and Li C.2008.Geochemical constraints on the origin of sulfide mineralization in the Duke Island Complex,southeastern Alaska.Geochemistry,Geophysics,Geosystems,9(7):Q07003
Tomkins AG,Rebryna KC,Weinberg RF and Schaefer BF.2012.Magmatic sulfide formation by reduction of oxidized arc basalt.Journal of Petrology,53(8):1537-1567
Toplis MJ and Carroll MR.1995.An experimental study of the influence of oxygen fugacity on Fe-Ti oxide stability,phase relations,and mineral-melt equilibria in ferro-basaltic systems.Journal of Petrology,36(5):1137-1170
Toplis MJ and Corgne A.2002.An experimental study of element partitioning between magnetite,clinopyroxene and iron-bearing silicate liquids with particular emphasis on vanadium.Contributions to Mineralogy and Petrology,144(1):22-37
Trail D,Bruce Watson E and Tailby ND.2012.Ce and Eu anomalies in zircon as proxies for the oxidation state of magmas.Geochimica et Cosmochimica Acta,97:70-87
Vigouroux N,Wallace PJ and Kent AJR.2008.Volatiles in high-Kmagmas from the western trans-Mexican volcanic belt:Evidence for fluid fluxing and extreme enrichment of the mantle wedge by subduction processes.Journal of Petrology,49(9):1589-1618
Wang Y,Wang K,Xing CM,Wei B,Dong H and Cao YH.2017.Metallogenic diversity related to the late Middle Permian Emeishan large igneous province.Bulletin of Mineralogy,Petrology and Geochemistry,36(3):404-417(in Chinese with English abstract)
Wijbrans CH,Klemme S,Berndt J and Vollmer C.2015.Experimental determination of trace element partition coefficients between spinel and silicate melt:The influence of chemical composition and oxygen fugacity.Contributions to Mineralogy and Petrology,169(4):45
Wood BJ,Bryndzia LT and Johnson KE.1990.Mantle oxidation state and its relationship to tectonic environment and fluid speciation.Science,248(4953):337-345
Wood BJ.1991.Oxygen barometry of spinel peridotites.Reviews in Mineralogy and Geochemistry,25(1):417-432
Woodland AB,Kornprobst J,Mc Pherson E,Bodinier JL and Menzies MA.1996.Metasomatic interactions in the lithospheric mantle:Petrologic evidence from the Lherz massif,French Pyrenees.Chemical Geology,134(1-3):83-112
Woodland AB and Koch M.2003.Variation in oxygen fugacity with depth in the upper mantle beneath the Kaapvaal craton,Southern Africa.Earth and Planetary Science Letters,214(1-2):295-310
Xu YG,Wang Y,Wei X and He B.2013.Mantle plume-related mineralization and their principal controlling factors.Acta Petrologica Sinica,29(10):3307-3322(in Chinese with English abstract)
Yu XH.1990.An introduction to research on mantle redox state and its oxygen fugacity.Geological Science and Technology Information,9(4):25-29(in Chinese with English abstract)
Zhang HL,Hirschmann MM,Cottrell E,Newville M and Lanzirotti A.2016.Structural environment of iron and accurate determination of Fe3+/∑Fe ratios in andesitic glasses by XANES and M9ssbauer spectroscopy.Chemical Geology,428:48-58
Zhang HL,Hirschmann MM,Cottrell E and Withers AC.2017.Effect of pressure on Fe3+/∑Fe ratio in a mafic magma and consequences for magma ocean redox gradients.Geochimica et Cosmochimica Acta,204:83-103
Zhong H,Zhou XH,Zhou MF,Sun M and Liu BG.2002.Platinumgroup element geochemistry of the Hongge Fe-V-Ti deposit in the Pan-Xi area,southwestern China.Mineralium Deposita,37(2):226-239
Zhong H,Hu RZ,Wilson AH and Zhu WG.2005.Review of the link
between the Hongge layered intrusion and Emeishan flood basalts,
Southwest China.International Geology Review,47(9):971-985
赖绍聪,周天祯.1993.岩浆氧逸度及其研究进展.青海地质,2(2):64-69
刘丛强,李和平,黄智龙,苏根利.2001.地幔氧逸度的研究进展.地学前缘,8(3):73-82
王焰,王坤,邢长明,魏博,董欢,曹永华.2017.二叠纪峨眉山地幔柱岩浆成矿作用的多样性.矿物岩石地球化学通报,36(3):404-417
徐义刚,王焰,位荀,何斌.2013.与地幔柱有关的成矿作用及其主控因素.岩石学报,29(10):3307-3322
喻学惠.1990.地幔氧化状态和氧逸度简介.地质科技情报,9(4):25-29
Arndt NT,Czamanske GK,Walker RJ,Chauvel C and Fedorenko VA.2003.Geochemistry and origin of the intrusive hosts of the Noril’skTalnakh Cu-Ni-PGE sulfide deposits.Economic Geology,98(3):495-515
Arndt NT,Lesher CM and Czamanske GK.2005.Mantle-derived magmas and magmatic Ni-Cu-(PGE)deposits.In:Hedenquist JW,Thompson JFH,Goldfarb RJ and Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,5-23
Balan E,De Villiers JPR,Eeckhout SG,Glatzel P,Toplis MJ,Fritsch E,Allard T,Galoisy L and Calas G.2006.The oxidation state of vanadium in titanomagnetite from layered basic intrusions.American Mineralogist,91(5-6):953-956
Ballhaus C,Berry RF and Green DH.1990.Oxygen fugacity controls in the Earth’s upper mantle.Nature,348(6300):437-440
Ballhaus C,Berry RF and Green DH.1991.High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer:Implications for the oxidation state of the upper mantle.Contributions to Mineralogy and Petrology,107(1):27-40
Ballhaus C.1993.Redox states of lithospheric and asthenospheric upper mantle.Contributions to Mineralogy and Petrology,114(3):331-348
Barnes SJ and Lightfoot PC.2005.Formation of magmatic nickel-sulfide ore deposits and processes affecting their copper and platinum-group element contents.In:Hedenquist JW,Thompson JFH,Goldfarb RJand Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,179-214
Berry AJ,Stewart GA,O’Neill HSC,Mallmann G and Mosselmans JFW.2018.A re-assessment of the oxidation state of iron in MORBglasses.Earth and Planetary Science Letters,483:114-123
Bézos A and Humler E.2005.The Fe3+/∑Fe ratios of MORB glasses and their implications for mantle melting.Geochimica et Cosmochimica Acta,69(3):711-725
Bowen NL.1928.The Evolution of the Igneous Rocks.Princeton:Princeton University Press
Brandon AD and Draper DS.1996.Constraints on the origin of the oxidation state of mantle overlying subduction zones:An example from Simcoe,Washington,USA.Geochimica et Cosmochimica Acta,60(10):1739-1749
Brounce M,Stolper E and Eiler J.2017.Redox variations in Mauna Kea lavas,the oxygen fugacity of the Hawaiian plume,and the role of volcanic gases in Earth’s oxygenation.Proceedings of the National Academy of Sciences of the United States of America,114(34):8997-9002
Brounce MN,Kelley KA and Cottrell E.2014.Variations in Fe3+/∑Fe of mariana arc basalts and mantle wedge fO2.Journal of Petrology,55(12):2513-2536
Buddington AF and Lindsley DH.1964.Iron-titanium oxide minerals and synthetic equivalents.Journal of Petrology,5(2):310-357
Canil D.1997.Vanadium partitioning and the oxidation state of Archaean komatiite magmas.Nature,389(6653):842-845
Canil D.1999.Vanadium partitioning between orthopyroxene,spinel and silicate melt and the redox states of mantle source regions for primary magmas.Geochimica et Cosmochimica Acta,63(3-4):557-572
Carmichael ISE and Ghiorso MS.1986.Oxidation-reduction relations in basic magma:A case for homogeneous equilibria.Earth and Planetary Science Letters,78(2-3):200-210
Carmichael ISE.1991.The redox states of basic and silicic magmas:Areflection of their source regions?Contributions to Mineralogy and Petrology,106(2):129-141
Cawthorn RG,Barnes SJ,Ballhaus C and Malitch K.2005.Platinum group element,chromium,and vanadium deposits in mafic and ultramafic rocks.In:Hedenquist JW,Thompson JFH,Goldfarb RJand Richards JP(eds.).Economic Geology 100thAnniversary Volume.Littleton:Society of Economic Geologists,215-249
Cottrell E,Kelley KA,Lanzirotti A and Fischer RA.2009.Highprecision determination of iron oxidation state in silicate glasses using XANES.Chemical Geology,268(3-4):167-179
Cottrell E and Kelley KA.2011.The oxidation state of Fe in MORBglasses and the oxygen fugacity of the upper mantle.Earth and Planetary Science Letters,305(3-4):270-282
Crabtree SM and Lange RA.2012.An evaluation of the effect of degassing on the oxidation state of hydrous andesite and dacite magmas:A comparison of pre-and post-eruptive Fe2+concentrations.Contributions to Mineralogy and Petrology,163(2):209-224
Creighton S,Stachel T,Matveev S,H9fer H,Mc Cammon C and Luth RW.2008.Oxidation of the Kaapvaal lithospheric mantle driven by metasomatism.Contributions to Mineralogy and Petrology,157(4):491-504
de Hoog JCM,Mason PRD and van Bergen MJ.2001.Sulfur and chalcophile elements in subduction zones:Constraints from a laser ablation ICP-MS study of melt inclusions from Galunggung Volcano,Indonesia.Geochimica et Cosmochimica Acta,65(18):3147-3164
Dixon JE,Clague DA,Wallace P and Poreda R.1997.Volatiles in alkalic basalts form the North arch volcanic field,Hawaii:Extensive degassing of deep submarine-erupted alkalic series lavas.Journal of Petrology,38(7):911-939
Evans KA,Elburg MA and Kamenetsky VS.2012.Oxidation state of subarc mantle.Geology,40(9):783-786
Fenner CN.1929.The crystallization of basalts.American Journal of Science,18(105):225-253
Foley SF.2011.A reappraisal of redox melting in the earth’s mantle as a function of tectonic setting and time.Journal of Petrology,52(7-8):1363-1391
Frost BR,Lindsley DH and Andersen DJ.1988.Fe-Ti oxide-silicate equilibrium:Assemblages with fayalitic olivine.American Mineralogist,73(7-8):727-740
Frost BR and Lindsley DH.1992.Equilibria among Fe-Ti oxides,pyroxenes,olivine,and quartz:PartⅡ.Application.American Mineralogist,77(9-10):1004-1020
Gaetani GA and Grove TL.1997.Partitioning of moderately siderophile elements among olivine,silicate melt,and sulfide melt:Constraints on core formation in the Earth and Mars.Geochimica et Cosmochimica Acta,61(9):1829-1846
Gaetani GA.2016.The behavior of Fe3+/∑Fe during partial melting of spinel lherzolite.Geochimica et Cosmochimica Acta,185:64-77
Gaillard F,Scaillet B,Pichavant M and Iacono-Marziano G.2015.The redox geodynamics linking basalts and their mantle sources through space and time.Chemical Geology,418:217-233
Ganino C,Arndt NT,Zhou MF,Gaillard F and Chauvel C.2008.Interaction of magma with sedimentary wall rock and magnetite ore genesis in the Panzhihua mafic intrusion,SW China.Mineralium Deposita,43(6):677-694
Ganino C,Harris C,Arndt NT,Prevec SA and Howarth GH.2013.Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit(SW China):Evidence from stable isotopes.Geoscience Frontiers,4(5):547-554
Ghiorso MS and Sack O.1991.Fe-Ti oxide geothermometry:Thermodynamic formulation and the estimation of intensive variables in silicic magmas.Contributions to Mineralogy and Petrology,108(4):485-510
Goncharov AG,Ionov DA,Doucet LS and Pokhilenko LN.2012.Thermal state,oxygen fugacity and C-O-H fluid speciation in cratonic lithospheric mantle:New data on peridotite xenoliths from the Udachnaya kimberlite,Siberia.Earth and Planetary Science Letters,357-358:99-110
Grocke SB,Cottrell E,de Silva S and Kelley KA.2016.The role of crustal and eruptive processes versus source variations in controlling the oxidation state of iron in Central Andean magmas.Earth and Planetary Science Letters,440:92-104
Hao HD,Campbell IH,Park JW and Cooke DR.2017.Platinum-group element geochemistry used to determine Cu and Au fertility in the Northparkes igneous suites,New South Wales,Australia.Geochimica et Cosmochimica Acta,216:372-392
Head E,Lanzirotti A,Newville M and Sutton S.2018.Vanadium,sulfur,and iron valences in melt inclusions as a window into magmatic processes:A case study at Nyamuragira volcano,Africa.Geochimica et Cosmochimica Acta,226:149-173
Iacono-Marziano G,Gaillard F,Scaillet B,Polozov AG,Marecal V,Pirre M and Arndt NT.2012.Extremely reducing conditions reached during basaltic intrusion in organic matter-bearing sediments.Earth and Planetary Science Letters,357-358:319-326
Jayasuriya KD,O’Neill HSC,Berry AJ and Campbell SJ.2004.AM9ssbauer study of the oxidation state of Fe in silicate melts.American Mineralogist,89(11-12):1597-1609
Jugo PJ.2009.Sulfur content at sulfide saturation in oxidized magmas.Geology,37(5):415-418
Jugo PJ,Wilke M and Botcharnikov RE.2010.Sulfur K-edge XANESanalysis of natural and synthetic basaltic glasses:Implications for Sspeciation and S content as function of oxygen fugacity.Geochimica et Cosmochimica Acta,74(20):5926-5938
Karner JM,Papike JJ,Shearer CK,Mckay G,Le L and Burger P.2007.Valence state partitioning of Cr and V between pyroxene-melt:Estimates of oxygen fugacity for martian basalt QUE 94201.American Mineralogist,92(7):1238-1241
Karner JM,Papike JJ,Sutton SR,Shearer CK,Burger P,Mc Kay G and Le L.2008.Valence state partitioning of V between pyroxene-melt:Effects of pyroxene and melt composition,and direct determination of V valence states by XANES.Application to Martian basalt QUE94201 composition.Meteoritics&Planetary Science,43(8):1275-1285
Keays RR.1995.The role of komatiitic and picritic magmatism and S-saturation in the formation of ore deposits.Lithos,34(1-3):1-18
Kelley KA and Cottrell E.2012.The influence of magmatic differentiation on the oxidation state of Fe in a basaltic arc magma.Earth and Planetary Science Letters,329-330:109-121
Kress VC and Carmichael ISE.1991.The compressibility of silicate liquids containing Fe2O3and the effect of composition,temperature,oxygen fugacity and pressure on their redox states.Contributions to Mineralogy and Petrology,108(1-2):82-92
Lai SC and Zhou TZ.1993.Study on the oxygen fugacity of magmas and its advance.Qinghai Geology,2(2):64-69(in Chinese with English abstract)
Lanzirotti A,Dyar MD,Sutton S,Newville M,Head E,Carey CJ,Mc Canta M,Lee L,King PL and Jones J.2018.Accurate predictions of microscale oxygen barometry in basaltic glasses using VK-edge X-ray absorption spectroscopy:A multivariate approach.American Mineralogist 103(8):1282-1297.
Laubier M,Grove TL and Langmuir CH.2014.Trace element mineral/melt partitioning for basaltic and basaltic andesitic melts:An experimental and laser ICP-MS study with application to the oxidation state of mantle source regions.Earth and Planetary Science Letters,392:265-278
Lazarov M,Woodland AB and Brey GP.2009.Thermal state and redox conditions of the Kaapvaal mantle:A study of xenoliths from the Finsch mine,South Africa.Lithos,112(Suppl.2):913-923
Lee CA.1996.A review of mineralization in the bushveld complex and some other layered intrusions.In:Cawthorn RG(ed.).Layered Intrusions.Amsterdam:Elsevier,103-145
Lee CTA,Leeman WP,Canil D and Li ZXA.2005.Similar V/Sc systematics in MORB and arc basalts:Implications for the oxygen fugacities of their mantle source regions.Journal of Petrology,46(11):2313-2336
Lee CTA,Luffi P,Le Roux V,Dasgupta R,Albaréde F and Leeman WP.2010.The redox state of arc mantle using Zn/Fe systematics.Nature,468(7324):681-685
Lee CTA,Luffi P,Chin EJ,Bouchet R,Dasgupta R,Morton DM,Le Roux V,Yin QZ and Jin D.2012.Copper systematics in arc magmas and implications for crust-mantle differentiation.Science,336(6077):64-68
Li C and Ripley EM.2011.The giant Jinchuan Ni-Cu-(PGE)deposit:Tectonic setting,magma evolution,ore genesis,and exploration implications.In:Li C and Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry,and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,163-180
Li ZXA and Lee CTA.2004.The constancy of upper mantle fO2through time inferred from V/Sc ratios in basalts.Earth and Planetary Science Letters,228(3-4):483-493
Lindsley DH and Frost BR.1992.“Equilibria among Fe-Ti oxides,pyroxenes,olivine,and quartz;PartⅠ,Theory.”American Mineralogist 77(9-10):987-1003
Liu CQ,Li HP,Huang ZL and Su GL.2001.A review of studies on oxygen fugacity of the earth mantle.Earth Science Frontiers,8(3):73-82(in Chinese with English abstract)
Mallmann G and O’Neill HSC.2009.The crystal/melt partitioning of Vduring mantle melting as a function of oxygen fugacity compared with some other elements(Al,P,Ca,Sc,Ti,Cr,Fe,Ga,Y,Zr and Nb).Journal of Petrology,50(9):1765-1794
Mallmann G and O’Neill HSC.2013.Calibration of an empirical thermometer and oxybarometer based on the partitioning of Sc,Y and V between olivine and silicate melt.Journal of Petrology,54(5):933-949
Marks MAW,Scharrer M,Ladenburger S and Markl G.2016.“Comment on“Apatite:A new redox proxy for silicic magmas?”[Geochimica et Cosmochimica Acta 132(2014)101-119].”Geochimica et Cosmochimica Acta 183:267-270
Matjuschkin V,Blundy JD and Brooker RA.2016.The effect of pressure on sulphur speciation in mid-to deep-crustal arc magmas and implications for the formation of porphyry copper deposits.Contributions to Mineralogy and Petrology,171(7):66
Mc Cammon C and Kopylova MG.2004.A redox profile of the Slave mantle and oxygen fugacity control in the cratonic mantle.Contributions to Mineralogy and Petrology,148(1):55-68
Mc Cammon CA,Griffin WL,Shee SR and O’Neill HSC.2001.Oxidation during metasomatism in ultramafic xenoliths from the Wesselton kimberlite,South Africa:Implications for the survival of diamond.Contributions to Mineralogy and Petrology,141(3):287-296
Miles AJ,Graham CM,Hawkesworth CJ,Gillespie MR,Hinton RW and Bromiley GD.2014.Apatite:A new redox proxy for silicic magmas?Geochimica et Cosmochimica Acta,132:101-119
Molyneux TG.1974.A geological investigation of the Bushveld Complex in Sekhukhuneland and part of the Steelpoort Valley.South African Journal of Geology,77(3):329-338
Morse SA.1981.Kiglapait geochemistryⅣ:The major elements.Geochimica et Cosmochimica Acta,45(3):461-479
Morse SA.2015.Kiglapait intrusion,labrador.In:Charlier B,Namur O,Latypov R and Tegner C(eds.).Layered Intrusions.Dordrecht:Springer,589-648
Moussallam Y,Oppenheimer C,Scaillet B,Gaillard F,Kyle P,Peters N,Hartley M,Berlo K and Donovan A.2014.Tracking the changing oxidation state of Erebus magmas,from mantle to surface,driven by magma ascent and degassing.Earth and Planetary Science Letters,393:200-209
Moussallam Y,Edmonds M,Scaillet B,Peters N,Gennaro E,Sides Iand Oppenheimer C.2016.The impact of degassing on the oxidation state of basaltic magmas:A case study of Kīlauea volcano.Earth and Planetary Science Letters,450:317-325
Mungall JE,Hanley JJ,Arndt NT and Debecdelievre A.2006.Evidence from meimechites and other low-degree mantle melts for redox controls on mantle-crust fractionation of platinum-group elements.Proceedings of the National Academy of Sciences of the United States of America,103(34):12695-12700
Naldrett AJ.2011.Fundamentals of magmatic sulfide deposits.In:Li Cand Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,1-50
Naslund HR.1983.The effect of oxygen fugacity on liquid immiscibility in iron-bearing silicate melts.American Journal of Science,283(10):1034-1059
O’Neill HSC,Berry AJ,Mc Cammon CC,Jayasuriya KD,Campbell SJand Foran G.2006.An experimental determination of the effect of pressure on the Fe3+/∑Fe ratio of an anhydrous silicate melt to 3.0GPa.American Mineralogist,91(2-3):404-412
O’Neill HSC and Wall VJ.1987.The olivine-orthopyroxene-spinel oxygen geobarometer,the nickel precipitation curve,and the oxygen fugacity of the Earth’s upper mantle.Journal of Petrology,28(6):1169-1191
Palme H and O’Neill HSC.2014.Cosmochemical estimates of mantle composition.In:Holland HD and Turekian KK(ed.).Treatise on Geochemistry.2ndEdition.Amsterdam:Elsevier,1-39
Pang KN,Zhou MF,Lindsley D,Zhao DG and Malpas J.2008.Origin of Fe-Ti oxide ores in mafic intrusions:Evidence from the panzhihua intrusion,SW China.Journal of Petrology,49(2):295-313
Papike JJ,Burger PV,Bell AS,Le L,Shearer CK,Sutton SR,Jones Jand Newville M.2013.Developing vanadium valence state oxybarometers(spinel-melt,olivine-melt,spinel-olivine)and V/(Cr+Al)partitioning(spinel-melt)for martian olivine-phyric basalts.American Mineralogist,98(11-12):2193-2196
Papike JJ,Simon SB,Burger PV,Bell AS,Shearer CK and Karner JM.2016.Chromium,vanadium,and titanium valence systematics in Solar System pyroxene as a recorder of oxygen fugacity,planetary provenance,and processes.American Mineralogist,101(4):907-918
Park JW,Campbell IH,Kim J and Moon JW.2015.The role of late sulfide saturation in the formation of a Cu-and Au-rich Magma:Insights from the platinum group element geochemistry of NiuatahiMotutahi Lavas,Tonga Rear Arc.Journal of Petrology,56(1):59-81
Philpotts AR and Doyle CD.1983.Effect of magma oxidation state on the extent of silicate liquid immiscibility in a tholeiitic basalt.American Journal of Science,283(9):967-986
Putirka KD.2008.Thermometers and barometers for volcanic systems.Reviews in Mineralogy and Geochemistry,69(1):61-120
Putirka K.2016.Rates and styles of planetary cooling on Earth,Moon,Mars,and Vesta,using new models for oxygen fugacity,ferricferrous ratios,olivine-liquid Fe-Mg exchange,and mantle potential temperature.American Mineralogist,101(4):819-840
Righter K,Sutton SR,Newville M,Le L,Schwandt CS,Uchida H,Lavina B and Downs RT.2006.An experimental study of the oxidation state of vanadium in spinel and basaltic melt with implications for the origin of planetary basalt.American Mineralogist,91(10):1643-1656
Ripley EM and Li C.2011.A review of conduit-related Ni-Cu-(PGE)sulfide mineralization at the Voiseys Bay Deposit,Labrador,and the Eagle Deposit,northern Michigan.In:Li C and Ripley EM(eds.).Magmatic Ni-Cu and PGE Deposits:Geology,Geochemistry,and Genesis.Reviews in Economic Geology.Littleton:Society of Economic Geologists,181-197
Rowe MC,Kent AJR and Nielsen RL.2009.Subduction influence on oxygen fugacity and trace and volatile elements in basalts across the cascade volcanic arc.Journal of Petrology,50(1):61-91
Shishkina T,Portnyagin M,Botcharnikov R,Almeev R,Simonyan A,Garbe-Sch9nberg D,Schuth S,Oeser M and Holtz F.2018.Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas.American Mineralogist,103(3):369-383
Sisson TW.2003.Native gold in a Hawaiian alkalic magma.Economic Geology,98(3):643-648
Smythe DJ and Brenan JM.2016.Magmatic oxygen fugacity estimated using zircon-melt partitioning of cerium.Earth and Planetary Science Letters,453:260-266
Song XY,Qi HW,Hu RZ,Chen LM,Yu SY and Zhang JF.2013.Formation of thick stratiform Fe-Ti oxide layers in layered intrusion and frequent replenishment of fractionated mafic magma:Evidence from the Panzhihua intrusion,SW China.Geochemistry,Geophysics,Geosystems,14(3):712-732
Song XY,Yi JN,Chen LM,She YW,Liu CZ,Dang XY,Yang QA and Wu SK.2016.The giant Xiarihamu Ni-Co sulfide deposit in the East Kunlun orogenic belt,Northern Tibet Plateau,China.Economic Geology,111(1):29-55
Sun WD,Arculus RJ,Kamenetsky VS and Binns RA.2004.Release of gold-bearing fluids in convergent margin magmas prompted by magnetite crystallization.Nature,431(7011):975-978
Sutton SR,Karner J,Papike J,Delaney JS,Shearer C,Newville M,Eng P,Rivers M and Dyar MD.2005.Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry.Geochimica et Cosmochimica Acta,69(9):2333-2348
Tegner C and Cawthorn RG.2010.Iron in plagioclase in the Bushveld and Skaergaard intrusions:Implications for iron contents in evolving basic magmas.Contributions to Mineralogy and Petrology,159(5):719-730
Thakurta J,Ripley EM and Li C.2008.Geochemical constraints on the origin of sulfide mineralization in the Duke Island Complex,southeastern Alaska.Geochemistry,Geophysics,Geosystems,9(7):Q07003
Tomkins AG,Rebryna KC,Weinberg RF and Schaefer BF.2012.Magmatic sulfide formation by reduction of oxidized arc basalt.Journal of Petrology,53(8):1537-1567
Toplis MJ and Carroll MR.1995.An experimental study of the influence of oxygen fugacity on Fe-Ti oxide stability,phase relations,and mineral-melt equilibria in ferro-basaltic systems.Journal of Petrology,36(5):1137-1170
Toplis MJ and Corgne A.2002.An experimental study of element partitioning between magnetite,clinopyroxene and iron-bearing silicate liquids with particular emphasis on vanadium.Contributions to Mineralogy and Petrology,144(1):22-37
Trail D,Bruce Watson E and Tailby ND.2012.Ce and Eu anomalies in zircon as proxies for the oxidation state of magmas.Geochimica et Cosmochimica Acta,97:70-87
Vigouroux N,Wallace PJ and Kent AJR.2008.Volatiles in high-Kmagmas from the western trans-Mexican volcanic belt:Evidence for fluid fluxing and extreme enrichment of the mantle wedge by subduction processes.Journal of Petrology,49(9):1589-1618
Wang Y,Wang K,Xing CM,Wei B,Dong H and Cao YH.2017.Metallogenic diversity related to the late Middle Permian Emeishan large igneous province.Bulletin of Mineralogy,Petrology and Geochemistry,36(3):404-417(in Chinese with English abstract)
Wijbrans CH,Klemme S,Berndt J and Vollmer C.2015.Experimental determination of trace element partition coefficients between spinel and silicate melt:The influence of chemical composition and oxygen fugacity.Contributions to Mineralogy and Petrology,169(4):45
Wood BJ,Bryndzia LT and Johnson KE.1990.Mantle oxidation state and its relationship to tectonic environment and fluid speciation.Science,248(4953):337-345
Wood BJ.1991.Oxygen barometry of spinel peridotites.Reviews in Mineralogy and Geochemistry,25(1):417-432
Woodland AB,Kornprobst J,Mc Pherson E,Bodinier JL and Menzies MA.1996.Metasomatic interactions in the lithospheric mantle:Petrologic evidence from the Lherz massif,French Pyrenees.Chemical Geology,134(1-3):83-112
Woodland AB and Koch M.2003.Variation in oxygen fugacity with depth in the upper mantle beneath the Kaapvaal craton,Southern Africa.Earth and Planetary Science Letters,214(1-2):295-310
Xu YG,Wang Y,Wei X and He B.2013.Mantle plume-related mineralization and their principal controlling factors.Acta Petrologica Sinica,29(10):3307-3322(in Chinese with English abstract)
Yu XH.1990.An introduction to research on mantle redox state and its oxygen fugacity.Geological Science and Technology Information,9(4):25-29(in Chinese with English abstract)
Zhang HL,Hirschmann MM,Cottrell E,Newville M and Lanzirotti A.2016.Structural environment of iron and accurate determination of Fe3+/∑Fe ratios in andesitic glasses by XANES and M9ssbauer spectroscopy.Chemical Geology,428:48-58
Zhang HL,Hirschmann MM,Cottrell E and Withers AC.2017.Effect of pressure on Fe3+/∑Fe ratio in a mafic magma and consequences for magma ocean redox gradients.Geochimica et Cosmochimica Acta,204:83-103
Zhong H,Zhou XH,Zhou MF,Sun M and Liu BG.2002.Platinumgroup element geochemistry of the Hongge Fe-V-Ti deposit in the Pan-Xi area,southwestern China.Mineralium Deposita,37(2):226-239
Zhong H,Hu RZ,Wilson AH and Zhu WG.2005.Review of the link
between the Hongge layered intrusion and Emeishan flood basalts,
Southwest China.International Geology Review,47(9):971-985
赖绍聪,周天祯.1993.岩浆氧逸度及其研究进展.青海地质,2(2):64-69
刘丛强,李和平,黄智龙,苏根利.2001.地幔氧逸度的研究进展.地学前缘,8(3):73-82
王焰,王坤,邢长明,魏博,董欢,曹永华.2017.二叠纪峨眉山地幔柱岩浆成矿作用的多样性.矿物岩石地球化学通报,36(3):404-417
徐义刚,王焰,位荀,何斌.2013.与地幔柱有关的成矿作用及其主控因素.岩石学报,29(10):3307-3322
喻学惠.1990.地幔氧化状态和氧逸度简介.地质科技情报,9(4):25-29