壳聚糖基吸附剂去除水中重金属离子的研究进展
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摘要
介绍了壳聚糖的结构、理化性质和内在性质;简要阐述了壳聚糖复合材料的种类和壳聚糖改性常用的交联、接枝和分子印迹等方法;主要论述了壳聚糖基吸附剂去除重金属离子的研究进展。
The structure,physicochemical properties and intrinsic properties of chitosan are introduced.The types of chitosan composites and the methods of crosslinking,grafting and molecular imprinting commonly used in chitosan modification are briefly described. The research progress of chitosan-based adsorbents for removing heavy metal ions is mainly discussed.
The structure,physicochemical properties and intrinsic properties of chitosan are introduced.The types of chitosan composites and the methods of crosslinking,grafting and molecular imprinting commonly used in chitosan modification are briefly described. The research progress of chitosan-based adsorbents for removing heavy metal ions is mainly discussed.
引文
[1]王爱勤.甲壳素化学[M].北京:科学出版社,2008:554-563.
[2] Kumar M. A review of chitin and chitosan applications[J]. React Funct Polym,2000,46:1-27.
[3] Crini G,Badot P M. Application of chitosan,a natural aminopolysaccharide,for dye removal from aqueous solutions by adsorption processes using batch studies:a review of recent literature[J]. Progress in Polymer Science,2008,33:399-447.
[4]刘维俊.壳聚糖对微量金属离子吸附作用研究[J].上海工程技术大学学报,2002,16(3):227-230.
[5] Jayakumar R,Prabaharan M,Reis R L,et al. Graft copolymerized chitosan-present status and applications[J]. Carbohydrate Polymers,2005,62:142-148.
[6] Varma A J,Deshpande S V,Kennedy J F. Metal complexation by chitosan and its derivatives:a review[J]. Carbohydrate Polymers,2004,55:77-93.
[7] Yong S K,Bolan N S,Lombi E,et al. Sulfur-containing chitin and chitosan derivatives as trace metal adsorbents:a review[J]. Critical Reviews in Environmental Science and Technology,2013,43:1741-1794.
[8] Boddu V M,Abburi K,Talbott J L,et al. Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent[J]. Environmental Science&Technology,2003,37(19):4449-4456.
[9]杨媛,罗丙红,周长忍.新型生物降解交联剂的制备和交联壳聚糖的性能[J].材料研究学报,2007,21(1):25-31.
[10] Ngah W S W,Endud C S,Mayanar R. Removal of copper(II)ions from aqueous solution onto chitosan and crosslinked chitosan beads[J]. Reactive&Functional Polymers,2002,50(2):181-190.
[11] Shimizu Y,Saito Y,Nakamura T. Crosslinking of chitosan with a trifunctional crosslinker and the adsorption of acid dyes and metal ions onto the resulting polymer[J]. Adsorption Science and Technology,2006,24(1):29-39.
[12] Zhuang S T,Yin Y N,Wang J L. Simultaneous detection and removal of cobalt ions from aqueous solution by modified chitosan beads[J]. International Journal of Environmental Science and Technology,2017,47(23):2331-2386.
[13] Varma A,Deshpande S V,Kennedy J F. Metal complexation by chitosan and its derivatives:A review[J]. Carbohydrate Polymers,2004,55(1):77-93.
[14] Monier M,Abdel-Latif D A. Fabrication of Au(III)ionimprinted polymer based on thiol-modified chitosan[J].International Journal of Biological Macromolecules,2017,105(1):777-787.
[15] Nishad P A,Bhaskarapillai A,Velmurugan S,et al. Cobalt(II)imprinted chitosan for selective removal of cobalt during nuclear reactor decontamination[J]. Carbohydrate Polymers,2012,87(4):2690-2696.
[16] Zhu Y,Bai Z S,Luo W Q,et al. A facile ion imprinted synthesis of selective biosorbent for Cu2+via microfluidic technology[J]. Journal of Chemical Technology and Biotechnology,2017,92(8):2009-2022.
[17]汪玉庭,刘玉红,张淑琴.甲壳素、壳聚糖的化学改性及其衍生物应用研究进展[J].功能高分子学报,2002,15(1):107-114.
[18]彭湘红,潘雪龙.壳聚糖接枝共聚物的应用研究[J].湖北化工,2000(4):32-33.
[19] Benamer S,Mahlous M,Tahtat D,et al. Radiation synthesis of chitosan beads grafted with acrylic acid for metal ions sorption[J]. Radiation Physics and Chemistry,2011,80(12):1391-1397.
[20] Yu J,Zheng J D,Lu Q F,et al. Reusability and selective adsorption of Pb2+on chitosan/P(2-acrylamido-2-methyl-1-propane-sulfonic acid-co-acrylic acid)hydrogel[J].Iranian Polymer Journal,2016,25(12):1009-1019.
[21] Yang S B,Okada N,Nagatsu M. The highly effective removal of Cs C by low turbidity chitosan-grafted magnetic bentonite[J]. Journal of Hazardous Materials,2016,301:8-16.
[22] Guo T Y,Xia Y Q,Hao G J,et al. Chemically modified chitosan beads as matrices for adsorptive separation of proteins by molecularly imprinted polymer[J]. Carbohydrate Polymers,2005,62(3):214-221.
[23] Rocha L S,Almeida A,Nunes C,et al. Simple and effective chitosan based films for the removal of Hg from waters:Equilibrium,kinetic and ionic competition[J].Chemical Engineering Journal,2016,300:217-229.
[24] Ge H C,Hua T T. Synthesis and characterization of poly(maleic acid)-grafted crosslinked chitosan nanomaterial with high uptake and selectivity for Hg(II)sorption[J].Carbohydrate Polymers,2016,153:246-252.
[25] Ayati A,Tanhaei B,Sillanpaa M. Lead(II)-ion removal by ethylenediaminetetra-acetic acid ligand functionalized magnetic chitosan-aluminum oxide-iron oxide nanoadsorbents and microad-sorbents:Equilibrium,kinetics,and thermodynamics[J]. Journal of Applied Polymer Science,2017,134(4):44360.
[26] Li K,Li P,Cai J,et al. Efficient adsorption of both methyl orange and chromium from their aqueous mixtures using a quaternary ammonium salt modified chitosan magnetic composite adsorbent[J]. Chemosphere,2016,154:310-318.
[27] Wang J S,Peng R T,Yang J H,et al. Preparation of ethylenediamine-modified magnetic chitosan complex for adsorption of uranyl ions[J]. Carbohydrate Polymers,2011,84(3):1169-1175.
[28] Merrifield J D,Davids W G,MacRae J D,et al. Uptake of mercury by thiol-grafted chitosan gel beads[J]. Water Research,2004,38(13):3132-3138.
[29] Zhu Y H,Hu J,Wang J L. Competitive adsorption of Pb(II),Cu(II)and Zn(II)onto xanthate-modified magnetic chitosan[J]. Journal of Hazardous Materials,2012,221/222:155-161.
[30] Ngah W S W,Endud C S,Mayanar R. Removal of copper(II)ions from aqueous solution onto chitosan and crosslinked chitosan beads[J]. React Funct Polym,2002,50:181-190.
[31] Monier M,Ayad D M,Wei Y,et al. Adsorption of Cu(II),Co(II),and Ni(II)ions by modifid magnetic chitosan chelating resin[J]. Journal of Hazardous Materials,2010,177:962-970.
[32] Kannamba B,Reddy K L,AppaRao B V. Removal of Cu(II)from aqueous solutions using chemically modified chitosan[J]. Journal of Hazardous Materials,2010,175:939-948.
[33] Wang X,Zheng Y,Wang A. Fast removal of copper ions from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite composites[J]. Journal of Hazardous Materials,2009,168:970-977.
[34] Donia A M,Atia A A,Elwakeel K Z. Selective separation of mercury(II)using magnetic chitosan resin modifid with Schiff’s base derived from thiourea and glutaraldehyde[J]. Journal of Hazardous Materials,2008,151:372-379.
[2] Kumar M. A review of chitin and chitosan applications[J]. React Funct Polym,2000,46:1-27.
[3] Crini G,Badot P M. Application of chitosan,a natural aminopolysaccharide,for dye removal from aqueous solutions by adsorption processes using batch studies:a review of recent literature[J]. Progress in Polymer Science,2008,33:399-447.
[4]刘维俊.壳聚糖对微量金属离子吸附作用研究[J].上海工程技术大学学报,2002,16(3):227-230.
[5] Jayakumar R,Prabaharan M,Reis R L,et al. Graft copolymerized chitosan-present status and applications[J]. Carbohydrate Polymers,2005,62:142-148.
[6] Varma A J,Deshpande S V,Kennedy J F. Metal complexation by chitosan and its derivatives:a review[J]. Carbohydrate Polymers,2004,55:77-93.
[7] Yong S K,Bolan N S,Lombi E,et al. Sulfur-containing chitin and chitosan derivatives as trace metal adsorbents:a review[J]. Critical Reviews in Environmental Science and Technology,2013,43:1741-1794.
[8] Boddu V M,Abburi K,Talbott J L,et al. Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent[J]. Environmental Science&Technology,2003,37(19):4449-4456.
[9]杨媛,罗丙红,周长忍.新型生物降解交联剂的制备和交联壳聚糖的性能[J].材料研究学报,2007,21(1):25-31.
[10] Ngah W S W,Endud C S,Mayanar R. Removal of copper(II)ions from aqueous solution onto chitosan and crosslinked chitosan beads[J]. Reactive&Functional Polymers,2002,50(2):181-190.
[11] Shimizu Y,Saito Y,Nakamura T. Crosslinking of chitosan with a trifunctional crosslinker and the adsorption of acid dyes and metal ions onto the resulting polymer[J]. Adsorption Science and Technology,2006,24(1):29-39.
[12] Zhuang S T,Yin Y N,Wang J L. Simultaneous detection and removal of cobalt ions from aqueous solution by modified chitosan beads[J]. International Journal of Environmental Science and Technology,2017,47(23):2331-2386.
[13] Varma A,Deshpande S V,Kennedy J F. Metal complexation by chitosan and its derivatives:A review[J]. Carbohydrate Polymers,2004,55(1):77-93.
[14] Monier M,Abdel-Latif D A. Fabrication of Au(III)ionimprinted polymer based on thiol-modified chitosan[J].International Journal of Biological Macromolecules,2017,105(1):777-787.
[15] Nishad P A,Bhaskarapillai A,Velmurugan S,et al. Cobalt(II)imprinted chitosan for selective removal of cobalt during nuclear reactor decontamination[J]. Carbohydrate Polymers,2012,87(4):2690-2696.
[16] Zhu Y,Bai Z S,Luo W Q,et al. A facile ion imprinted synthesis of selective biosorbent for Cu2+via microfluidic technology[J]. Journal of Chemical Technology and Biotechnology,2017,92(8):2009-2022.
[17]汪玉庭,刘玉红,张淑琴.甲壳素、壳聚糖的化学改性及其衍生物应用研究进展[J].功能高分子学报,2002,15(1):107-114.
[18]彭湘红,潘雪龙.壳聚糖接枝共聚物的应用研究[J].湖北化工,2000(4):32-33.
[19] Benamer S,Mahlous M,Tahtat D,et al. Radiation synthesis of chitosan beads grafted with acrylic acid for metal ions sorption[J]. Radiation Physics and Chemistry,2011,80(12):1391-1397.
[20] Yu J,Zheng J D,Lu Q F,et al. Reusability and selective adsorption of Pb2+on chitosan/P(2-acrylamido-2-methyl-1-propane-sulfonic acid-co-acrylic acid)hydrogel[J].Iranian Polymer Journal,2016,25(12):1009-1019.
[21] Yang S B,Okada N,Nagatsu M. The highly effective removal of Cs C by low turbidity chitosan-grafted magnetic bentonite[J]. Journal of Hazardous Materials,2016,301:8-16.
[22] Guo T Y,Xia Y Q,Hao G J,et al. Chemically modified chitosan beads as matrices for adsorptive separation of proteins by molecularly imprinted polymer[J]. Carbohydrate Polymers,2005,62(3):214-221.
[23] Rocha L S,Almeida A,Nunes C,et al. Simple and effective chitosan based films for the removal of Hg from waters:Equilibrium,kinetic and ionic competition[J].Chemical Engineering Journal,2016,300:217-229.
[24] Ge H C,Hua T T. Synthesis and characterization of poly(maleic acid)-grafted crosslinked chitosan nanomaterial with high uptake and selectivity for Hg(II)sorption[J].Carbohydrate Polymers,2016,153:246-252.
[25] Ayati A,Tanhaei B,Sillanpaa M. Lead(II)-ion removal by ethylenediaminetetra-acetic acid ligand functionalized magnetic chitosan-aluminum oxide-iron oxide nanoadsorbents and microad-sorbents:Equilibrium,kinetics,and thermodynamics[J]. Journal of Applied Polymer Science,2017,134(4):44360.
[26] Li K,Li P,Cai J,et al. Efficient adsorption of both methyl orange and chromium from their aqueous mixtures using a quaternary ammonium salt modified chitosan magnetic composite adsorbent[J]. Chemosphere,2016,154:310-318.
[27] Wang J S,Peng R T,Yang J H,et al. Preparation of ethylenediamine-modified magnetic chitosan complex for adsorption of uranyl ions[J]. Carbohydrate Polymers,2011,84(3):1169-1175.
[28] Merrifield J D,Davids W G,MacRae J D,et al. Uptake of mercury by thiol-grafted chitosan gel beads[J]. Water Research,2004,38(13):3132-3138.
[29] Zhu Y H,Hu J,Wang J L. Competitive adsorption of Pb(II),Cu(II)and Zn(II)onto xanthate-modified magnetic chitosan[J]. Journal of Hazardous Materials,2012,221/222:155-161.
[30] Ngah W S W,Endud C S,Mayanar R. Removal of copper(II)ions from aqueous solution onto chitosan and crosslinked chitosan beads[J]. React Funct Polym,2002,50:181-190.
[31] Monier M,Ayad D M,Wei Y,et al. Adsorption of Cu(II),Co(II),and Ni(II)ions by modifid magnetic chitosan chelating resin[J]. Journal of Hazardous Materials,2010,177:962-970.
[32] Kannamba B,Reddy K L,AppaRao B V. Removal of Cu(II)from aqueous solutions using chemically modified chitosan[J]. Journal of Hazardous Materials,2010,175:939-948.
[33] Wang X,Zheng Y,Wang A. Fast removal of copper ions from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite composites[J]. Journal of Hazardous Materials,2009,168:970-977.
[34] Donia A M,Atia A A,Elwakeel K Z. Selective separation of mercury(II)using magnetic chitosan resin modifid with Schiff’s base derived from thiourea and glutaraldehyde[J]. Journal of Hazardous Materials,2008,151:372-379.