特种聚酯丙烯酸酯的研发及产业化
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- 英文论文题名：Research and Industrialization of special Polyester Acrylate
- 论文作者：罗侃 ; 蒋乙峰
- 英文论文作者：Kan-Luo ; Yifeng-Jiang ; Jiangsu Sanmu Group Co. ; Ltd
- 年：2016
- 作者机构：江苏三木集团有限公司;
- 论文关键词：特种聚酯丙烯酸酯 ; 产业化
- 英文论文关键词：special polyester acrylate ; industrialization
- 会议召开时间：2016-09-07
- 会议录名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛论文报告集
- 语种：中文
- 分类号：TQ630.43
- 学会代码：GGXH
- 会议名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛
- 会议地点：中国安徽安庆
- 主办单位：中国感光学会辐射固化专业委员会、安庆市政府
- 学会名称：中国感光学会辐射固化专业委员会
- 页数：11
- 文件大小：931k
- 原文格式：O
- 会议级别：全国
摘要
紫外光固化涂料自上世纪90年代研发成功以来以其节能、高效和低污染的特点被广泛应用于涂料、油墨和粘合剂等多种领域。本文将特种聚酯的概念引申至光固化树脂领域,解决了现有光固化涂料体积收缩大、深层固化等问题。分别简述了超支化聚酯丙烯酸酯、双重固化聚酯丙烯酸酯和水性聚酯丙烯酸酯的具体合成方法及其性能优势,最后以其中超支化聚酯丙烯酸酯为例简单介绍产品产业化过程及程度。
Since the 1990s,UV-curing technology was widely used in a variety of domains such as coatings,printing ink,and adhesive for its energy saving,high efficiency,and environmental protection.In this paper,special polyester was applied to UV-curable resin field to deal with the problems such as large volume shrinkage and deep curing.The synthetic methods of hyperbranched polyester acrylate,dual-curing polyester acrylate,and water-based polyester acrylate were introduced here and performance advantages were also mentioned.Finally,the industrialization process of hyperbranched polyester acrylate and its level were briefly described.
Since the 1990s,UV-curing technology was widely used in a variety of domains such as coatings,printing ink,and adhesive for its energy saving,high efficiency,and environmental protection.In this paper,special polyester was applied to UV-curable resin field to deal with the problems such as large volume shrinkage and deep curing.The synthetic methods of hyperbranched polyester acrylate,dual-curing polyester acrylate,and water-based polyester acrylate were introduced here and performance advantages were also mentioned.Finally,the industrialization process of hyperbranched polyester acrylate and its level were briefly described.
引文
[1]廖峰.UV固化超支化聚合物的合成及其二氧化硅杂化涂层的制备与性能研究[D].广州:华南理工大学,2012.
[2]Masson F.,Decker G,Andre S.,et al.UV-curable formulations for UV-transparent optical fiber coatings:I.Acrylic resins[J].Progress in Organic Coatings,2004,49:1-12.
[3]韩文松.紫外光固化超支化聚酯丙烯酸酯/二氧化硅杂化材料的制备[J].高分子材料科学与工程,2014,30:160-164,171.
[4]李三梅,赵磊.含三嗪环的超支化聚酯丙烯酸酯的合成和应用[J].广东化工,2012,39:31-33.
[5]王兴元,罗运军,夏敏等.端丙烯酸酯基超支化聚酯/聚氨酯丙烯酸酯体系的紫外光固化行为及性能[J].高分子材料科学与工程,2010,26:77-79,83.
[6]施文芳.可光固化星形超支化聚酯的合成与表征[J].高分子学报,1997,5:549-554.
[7]杨晓明,苏秋晨,韩文松.含羧基超支化聚酯丙烯酸酯的合成及其性能研究[J].涂料工业,2012,45:35-39.
[8]肖俊芳.低温光-热双重固化的紫外光固化涂料[D].广州:华南理工大学,2012.
[9]郭婧,梁亮,刘楠等.纳米二氧化硅/聚丙烯酸酯符合双重固化乳液的结构与性能[J].高分子材料科学与工程,2013,29:81-84.
[10]刘身凯.双组分水性聚氨酯涂料用水性聚酯分散体的制备及其性能研究[D].广州:华南理工大学,2010.
[11]俞剑锋.新型水性卷材涂料的制备及应用技术[D].上海:华东理工大学,2013.
[12]王孝科,田敉.光固化水性超支化聚酯的合成及性能研究[J].涂料工业,2008,38:12-15.
[2]Masson F.,Decker G,Andre S.,et al.UV-curable formulations for UV-transparent optical fiber coatings:I.Acrylic resins[J].Progress in Organic Coatings,2004,49:1-12.
[3]韩文松.紫外光固化超支化聚酯丙烯酸酯/二氧化硅杂化材料的制备[J].高分子材料科学与工程,2014,30:160-164,171.
[4]李三梅,赵磊.含三嗪环的超支化聚酯丙烯酸酯的合成和应用[J].广东化工,2012,39:31-33.
[5]王兴元,罗运军,夏敏等.端丙烯酸酯基超支化聚酯/聚氨酯丙烯酸酯体系的紫外光固化行为及性能[J].高分子材料科学与工程,2010,26:77-79,83.
[6]施文芳.可光固化星形超支化聚酯的合成与表征[J].高分子学报,1997,5:549-554.
[7]杨晓明,苏秋晨,韩文松.含羧基超支化聚酯丙烯酸酯的合成及其性能研究[J].涂料工业,2012,45:35-39.
[8]肖俊芳.低温光-热双重固化的紫外光固化涂料[D].广州:华南理工大学,2012.
[9]郭婧,梁亮,刘楠等.纳米二氧化硅/聚丙烯酸酯符合双重固化乳液的结构与性能[J].高分子材料科学与工程,2013,29:81-84.
[10]刘身凯.双组分水性聚氨酯涂料用水性聚酯分散体的制备及其性能研究[D].广州:华南理工大学,2010.
[11]俞剑锋.新型水性卷材涂料的制备及应用技术[D].上海:华东理工大学,2013.
[12]王孝科,田敉.光固化水性超支化聚酯的合成及性能研究[J].涂料工业,2008,38:12-15.