希夫碱与β-二酮构筑的稀土配合物的合成结构与荧光和单分子磁性
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- 英文论文题名：A Series of dinuclear lanthanide(Ⅲ) complexes constructed by Schiff Base and β-diketonate Ligands:synthesis,structure,luminescence and SMM behavior
- 论文作者：高婷 ; 孙鸥 ; 闫鹏飞
- 英文论文作者：Ting Gao ; Ou Sun ; Pengfei Yan ; Key Laboratory of Functional Inorganic Material Chemistry(MOE) ; School of Chemistry and Materials Science ; Heilongjiang University
- 年：2016
- 作者机构：黑龙江大学功能无机材料化学教育部重点实验室;
- 论文关键词：希夫碱 ; β-二酮 ; 稀土配合物 ; 荧光 ; 单分子磁性
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十六分会：晶体工程
- 语种：中文
- 分类号：O641.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十六分会 ; 晶体工程
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：324k
- 原文格式：D
- 会议级别：全国
摘要
由希夫碱与β-二酮构筑了一系列稀土配合物,它们是双核配合物[Ln_2(DBM)_6(L)](Ln=Sm(1);Eu(2);Gd(3);Dy(4);Yb(5);(L=乙二胺缩吡啶甲醛,DBM=二苯甲酰甲烷)),并对其结构与荧光和单分子磁性进行研究。
A series of new isostructural lanthanide(Ⅲ) complexes are reported which are constructed from Schiff base andβ-diketonate ligands,namely,[Ln_2(DBM)_6(L)](Ln = Sm(1);Eu(2);Gd(3);Dy(4);Yb(5));L = N,N'-bis(pyridin-2-ylmethylene)ethane-1,2-diamine,DBM = dibenzoylmethanide).Detailed crystal structures of these complexes were determined by single crystal X-ray crystallographic studies and their luminescent properties and single molecular magnetic properties were investigated.
A series of new isostructural lanthanide(Ⅲ) complexes are reported which are constructed from Schiff base andβ-diketonate ligands,namely,[Ln_2(DBM)_6(L)](Ln = Sm(1);Eu(2);Gd(3);Dy(4);Yb(5));L = N,N'-bis(pyridin-2-ylmethylene)ethane-1,2-diamine,DBM = dibenzoylmethanide).Detailed crystal structures of these complexes were determined by single crystal X-ray crystallographic studies and their luminescent properties and single molecular magnetic properties were investigated.
引文
[1]Gao,T.;Yan,P.F.;Li,G.M.;Hou,G.F.;Gao,J.S.Polyhedron 2007,26,5382.
[2]Yan,P.F.;Chen,S.;Chen,P.;Zhang,J.W.;Li,G.M.CrystE ng Comm 2011,13,36.
[3]Gao,T.;Yang,Y.;Sun,W.B.;Li,G.M.;Hou,G.F.;Yan,P.F.;Li,J.T.;Ding,D.D.CrystE ngC omm 2013,15,6213.
[2]Yan,P.F.;Chen,S.;Chen,P.;Zhang,J.W.;Li,G.M.CrystE ng Comm 2011,13,36.
[3]Gao,T.;Yang,Y.;Sun,W.B.;Li,G.M.;Hou,G.F.;Yan,P.F.;Li,J.T.;Ding,D.D.CrystE ngC omm 2013,15,6213.