双核席夫碱配合物Cu-Ni的晶体结构及性质研究
详细信息 查看官网全文
- 英文论文题名：Crystal structure and properties of a dinuclear Shiff base Cu-Ni Complex
- 论文作者：张雁红 ; 王作鹏
- 英文论文作者：Yanhong Zhang ; Zuopeng Wang ; College of Chemistry and Environment Science ; Inner Mongolia Normal University
- 年：2016
- 作者机构：内蒙古师范大学化学与环境科学学院;
- 论文关键词：席夫碱配体 ; 双核配合物 ; 晶体结构
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十六分会：晶体工程
- 语种：中文
- 分类号：O641.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十六分会 ; 晶体工程
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：139k
- 原文格式：D
- 会议级别：全国
摘要
席夫碱配合物由于其结构的可调控性以及在催化、化学生物学及功能材料等领域的广泛应用而受到广泛关注。本文设计合成了一个新的席夫碱配体组装的双核配合物,并解析了其晶体结构:配合物属于单斜晶系,P2(1)/n空间群,组成为[CuL(CH_3OH)Ni(phen)_2](ClO_4)_2·CH_3OH,其Ni(Ⅱ)离子处于畸变的八面体配位环境中,配位原子由草酰胺氧原子与邻菲哕啉氮原子共同构成。Cu(Ⅱ)处于扭曲的四方锥配位环境中,配位原子来自于有机配体的四个氮原子和一个溶剂甲醇分子的氧原子。
Schiff base complexes have been drawn increasing attention due to their adjustable structures and wide applications such as catalysis,chemical biology and functional materials.A new dinuclear complex[CuL(CH_3OH)Ni(phen)_2](C1O_4)_2·CH_3OH has been prepared and characterized by X-ray diffraction analysis.The complex belongs to monoclinic,space group P2(1)/n.The Ni(Ⅱ) is set in a distorted octahedral coordination sphere,connected to the four oxygen atoms of the oxamido ligands and two nitrogen atoms from phenanthrolines.The Cu(Ⅱ) possesses square pyramidal geometry and surrounded by four donor nitrogen atoms and one coordinated CH_3OH molecule.
Schiff base complexes have been drawn increasing attention due to their adjustable structures and wide applications such as catalysis,chemical biology and functional materials.A new dinuclear complex[CuL(CH_3OH)Ni(phen)_2](C1O_4)_2·CH_3OH has been prepared and characterized by X-ray diffraction analysis.The complex belongs to monoclinic,space group P2(1)/n.The Ni(Ⅱ) is set in a distorted octahedral coordination sphere,connected to the four oxygen atoms of the oxamido ligands and two nitrogen atoms from phenanthrolines.The Cu(Ⅱ) possesses square pyramidal geometry and surrounded by four donor nitrogen atoms and one coordinated CH_3OH molecule.
引文
[1]Dong,Y B.;Smith,M D.;Zur Loye,HC.Inorg.Chem.2000,39:4927.
[2]Andruh,M.Chem Commun.2011,47(11):3025.
[3]Gavey,E L.;Pilkington,M.Coord.Chem.Rev.2015,296:125.
[2]Andruh,M.Chem Commun.2011,47(11):3025.
[3]Gavey,E L.;Pilkington,M.Coord.Chem.Rev.2015,296:125.